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Volume 2006
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10.3390/M465
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Short Note

New bis-tridentate Nitrogen Ligand : N,N,N',N'-tetra-(3-carbomethoxy-5-methylpyrazol-1-ylmethyl)p-phenylenediamine

by
Maria Daoudi
1,
Brahim Bennani
1,
Assou Zahidi
2,
Mohamed Mchic
2 and
Taibi Ben Hadda
2,*
1
Laboratoire de Chimie Organique, Faculté des Sciences Dhar El Mehraz, 50000 Fès, Morocco
2
Laboratoire d’Activation Moléculaire, Faculté des Sciences, 60000 Oujda, Morocco
*
Author to whom correspondence should be addressed.
Molbank 2006, 2006(2), M465; https://doi.org/10.3390/M465
Submission received: 15 July 2005 / Accepted: 6 September 2005 / Published: 28 February 2006
Versions Notes

Molbank 2006 m465 i001
The product 2 was prepared by the addition of p-phenylendiamine (NH2C6H4NH2) to 1 [1] according to the reported procedure [2]. To a solution of 1 (3.4 g, 20 mmol) in acetonitrile (45 ml) was added p-phenylendiamine (0.54 g, 5 mmol) and the mixture was stirred. The stirring was continued at room temperature for a week. The residue was precipitated by addition of cold water, purified and dried by hexane and under vacuum, to afford 2.63 g (74% yield) 2 as a white solid.
Melting Point: 197 °C.
IR (KBr, cm–1): 3140 (=CH), 2990 (CH), 1730 (C=O), 1540 (C=C), 1480 (-C=N), 1450, 1410.
1H-NMR (400 MHz, CDCl3): δ= 7.25 (s, 4H, Ph); 6.5 (s, 4H, Pyrazol); 5.6 (s, 8H, N-CH2-N); 4 (s, 12H, O-CH3); 2.2 (s, 12H, CH3).
MS (m/z): 739 [M + Na+]; 716 [M]+; 613; 585; 460.

Supplementary Materials

Supplementary File 1Supplementary File 2Supplementary File 3

Acknowledgment

We are indebted to the "Programme Thématique d'Appui à la Recherche Scientifique PROTARS N° P1T2/27", and the "Wylaya d'Oujda" for financial support.

References

  1. Dvoretzky, I.; Richter, G.H. J.Org.Chem. 1950, 15, 1285.
  2. Sheu, S-C.; Tien, M-J.; Cheng, M-C.; Ho, T-I.; Peng, S-M.; Lin, Y-C. J. Chem. Soc. Dalton Trans 1995, 3503–3510.
  • Sample Availability: Available from the authors and MDPI.

Share and Cite

MDPI and ACS Style

Daoudi, M.; Bennani, B.; Zahidi, A.; Mchic, M.; Ben Hadda, T. New bis-tridentate Nitrogen Ligand : N,N,N',N'-tetra-(3-carbomethoxy-5-methylpyrazol-1-ylmethyl)p-phenylenediamine. Molbank 2006, 2006, M465. https://doi.org/10.3390/M465

AMA Style

Daoudi M, Bennani B, Zahidi A, Mchic M, Ben Hadda T. New bis-tridentate Nitrogen Ligand : N,N,N',N'-tetra-(3-carbomethoxy-5-methylpyrazol-1-ylmethyl)p-phenylenediamine. Molbank. 2006; 2006(2):M465. https://doi.org/10.3390/M465

Chicago/Turabian Style

Daoudi, Maria, Brahim Bennani, Assou Zahidi, Mohamed Mchic, and Taibi Ben Hadda. 2006. "New bis-tridentate Nitrogen Ligand : N,N,N',N'-tetra-(3-carbomethoxy-5-methylpyrazol-1-ylmethyl)p-phenylenediamine" Molbank 2006, no. 2: M465. https://doi.org/10.3390/M465

APA Style

Daoudi, M., Bennani, B., Zahidi, A., Mchic, M., & Ben Hadda, T. (2006). New bis-tridentate Nitrogen Ligand : N,N,N',N'-tetra-(3-carbomethoxy-5-methylpyrazol-1-ylmethyl)p-phenylenediamine. Molbank, 2006(2), M465. https://doi.org/10.3390/M465

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