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Article

Geological Controls on Mineralogy and Geochemistry of the Permian and Jurassic Coals in the Shanbei Coalfield, Shaanxi Province, North China

by
Yunfei Shangguan
1,
Xinguo Zhuang
1,*,
Jing Li
1,
Baoqing Li
1,
Xavier Querol
1,2,
Bo Liu
1,
Natalia Moreno
2,
Wei Yuan
3,
Guanghua Yang
4 and
Lei Pan
4
1
Key Laboratory of Tectonics and Petroleum Resources, China University of Geosciences (Wuhan), Ministry of Education, Wuhan 430074, China
2
Institute of Environmental Assessment and Water Research, IDÆA-CSIC C/Jordi Girona, 18–26, 08034 Barcelona, Spain
3
Inner Mongolia Geology Engineering Co., Ltd., Xinhuadong Street 87, Hohhot 010010, China
4
Xi’an Institute of Geology and Mineral Exploration, Western Duling Road 56, Xi’an 710100, China
*
Author to whom correspondence should be addressed.
Minerals 2020, 10(2), 138; https://doi.org/10.3390/min10020138
Submission received: 3 December 2019 / Revised: 3 February 2020 / Accepted: 4 February 2020 / Published: 6 February 2020
(This article belongs to the Collection Critical Metals and Minerals in Coal and Coal Combustion Products)
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Abstract

:
Coal as the source of critical elements has attracted much attention and the enrichment mechanisms are of significant importance. This paper has an opportunity to investigate the mineralogical and geochemical characteristics of the Permian and Jurassic bituminous coals and associated non-coals from two underground coal mines in the Shanbei Coalfield (Northeast Ordos basin), Shaanxi Province, North China, based on the analysis of X-ray diffraction (XRD), inductively coupled plasma atomic-emission spectrometry (ICP-AES/MS), and scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM-EDS). The Jurassic and Permian coals have similar chemical features excluding ash yield, which is significantly higher in the Permian coals. Major mineral matters in the Jurassic coals are quartz, kaolinite, and calcite. By contrast, mineral assemblages of the Permian coals are dominated by kaolinite; and apatite occurring in the middle section’s partings. The Jurassic coals are only enriched in B, whereas the Permian coals are enriched in some trace elements (e.g., Nb, Ta, Th, and REY). Boron has a mixed inorganic and organic association which may be absorbed by organic matter from fluid (or groundwater) or inherited from coal-forming plants. Additionally, climatic variation also plays an important role. As for the Permian coals, kaolinite and apatite as the major carriers of elevated elements; the former were derived from the sedimentary source region (the Yinshan Oldland and the Benxi formation) and later precipitated from Ca-, and P-rich solutions. We deduced that those elevated elements may be controlled by the source rock and diagenetic fluid input. The findings of this work offered new data to figure out the mechanism of trace element enrichment of coal in the Ordos basin.

1. Introduction

Coal and fly ash with high concentrations of critical elements (e.g., Ge, U, Li, Ga, rare earth elements and yttrium (REYs), Nb (Ta)-Zr (Hf)-REY) have attracted much attention in recent studies because of their potential as raw materials to extract these metals [1,2,3,4,5,6,7,8]. Germanium-rich coal has been discovered and used industrially in Wulantuga, Yimin, Lincang and the Russian Far East [1,9,10,11,12,13,14]. The occurrence of uranium in coal, another metal industrially extracted from coal, was also studied by many researchers in the Yili basin, Guiding, Mopingpo [15,16,17]. In addition, coal from the Ordos Basin, which is the second largest sedimentary basin in China, is enriched in a number of critical elements in different coalfields, for instance, the Permo-Carboniferous coals in the Junger Coalfield, especially No. 6 coal seam, have been reported to be enriched in some critical elements in different coal mines [18,19,20,21,22].
The geological factors affecting enrichment of valuable metals in coals have been discussed by many researchers [5,23,24,25,26,27]. Dai et al. (2012) proposed five genetic types of trace elements enrichment in Chinese coals [5]. However, in some cases, the enrichment of trace elements is probably a consequence of multiple geological factors [17,19,27,28]. For example, the enrichment of some critical elements in the Junger coalfield was ascribed to a combination of the input of terrigenous detrital materials (mostly bauxite and moyite) and the leaching of groundwater [18,19,20]. Abundant information has been obtained in recent years on the geological factors causing elevated elements concentration in the Ordos Basin [18,19,20,22,29,30,31,32,33,34]. Compared with the Permo-Carboniferous coals, a few studies have been carried out on the Jurassic coals due to low ash yield and absence of geochemical anomalies [22,30,31,33,34,35].
The Shanbei Coalfield is located in the northeast of the Ordos Basin and is adjacent to the south part of the Junger Coalfield, where some coals rich in critical elements were found in the Heidaigou, Haerwusu, and Guanbanwusu coal mines. Thus, the Shanbei coals, especially the Permo-Carboniferous coals, would be expected to be enriched in some critical elements. Based on mineralogical and geochemical analyses of coals and associated non-coals from two different coal mines, this paper discusses the heterogeneity of geochemical and mineralogical compositions of coals formed in different periods, and investigates the geological factors controlling the enrichment of some trace elements.

2. Geological Setting

The Shanbei Coalfield, located in the northeast of the Ordos Basin, consists of the Shanbei Permo-Carboniferous, Shanbei Triassic and Shanbei Jurassic Coalfields, the first of which belongs to the Jinxi Fold Belt and the latter two to the Yishan Slope (Figure 1). The main coal-bearing strata in this region consist of the Late Carboniferous Taiyuan (C2t), the Early Permian Shanxi (P1sh), the Late Triassic Wayaobao (T3w), and the Middle Jurassic Yan’an Formations (J2y). The Cuijiagou underground coal mine is located in the northeastern part of the Shanbei Jurassic Coalfield, and the Puran coal mine is located in the north of the Shanbei Permo- Carboniferous Coalfield (Figure 1).
Based on the occurrence of different types of fossils, the Taiyuan Formation is subdivided into three members (Figure 2A), all of which were deposited in lagoon and tidal flat-barrier environments [35]. Member 1 overlies conformably the Benxi Formation limestone and is composed of bauxite, sandstone and coal seams (No. 10 and 11 Coal); member 2 is the main limestone-bearing section, which consists of limestone, sandstone, mudstone and, 3 coal seams (No. 9, 8, and 7 Coals); and member 3 contains limestone and one coal seam (No. 6 Coal) which has been extensively studied [18,19].
The Shanxi Formation, subdivided into 2 members, consists mainly of sandstone and several coal seams (Nos. 1 to 5, Figure 2A). The No. 3, No. 4, and No. 5 coal seams within member 1 are the main workable coals, while other coal seams are mostly unminable. The Shanxi Formation was mainly formed in a fluvial-delta environment.
The Jurassic Yan’an Formation is subdivided into 5 members according to coal-bearing characteristics and lithological compositions (Figure 2B), all of which are composed of sandstone, mudstone, and five coal seams (Nos. 5 to 1 coals from bottom to top). The No. 1 and No. 3 coals were formed in the delta plain while No. 2 in the shallow lake environment [36].

3. Samples and Methods

A total of 32 channel samples were collected from the Cuijiagou (Shanbei Jurassic Coalfield) and the Puran (Shanbei Permo-Carboniferous Coalfield) underground coal mines, including 23 coal samples from the Cuijiagou, 5 coal samples, 3 parting samples (with a suffix P), and one roof sample (with a suffix T) from the Puran mine. According to the natural stratification of the Cuijiagou coals, 8 (identified as CJG-1-1 to CJG-1-8), 9 (identified as CJG-2-1 to CJG-2-9), and 6 (identified as CJG-3-1 to CJG-3-6) coal samples were respectively collected from Nos. 1, 2, and 3 coal seams from the top to bottom. In the Puran coal mine, one roof sample (PR-4-T) and 8 coal (PR-4-1, PR-4-5 to PR-4-8) and parting samples (PR-4-2 to PR-4-4) were collected from the No. 4 coal from top to bottom. The thickness of individual samples is shown in Figure 2C,D).
The samples were crushed and ground to pass through an 80-mesh sieve for proximate analysis. Thereafter the remaining splitting samples were further milled to pass through a 200-mesh sieve for geochemical and mineralogical analyses. Proximate analysis was carried out according to ASTM (American Society for Testing and Materials) Standards D3173/D3173M-17a (2017), D3174-12 (2018), and D3175-18 (2018) [37,38,39]. Powder X-ray diffraction (XRD), using a Bruker D8 Advance A25 powder diffractometer (Bruker AXS GmbH, Karlsruhe, Germany) with monochromatic CuKα radiation operated at 40 kV and 40 mA, scanning from 4° to 60° 2 theta with a step size of 0.05° and a counting time of 3 s/step, was used to determine minerals compositions of the collected samples. Meanwhile, semi-quantitative XRD estimation of the mineral contents was obtained by using the reference internal standard method [40]. In order to identify the morphology and composition of individual minerals, some perpendicular to coal layer polished fragments obtain from relatively higher mineral content samples were studied by a field emission-scanning electron microscope (FE-SEM, FEI Quanta™ 450 FEG, Thermo Fisher, Hillsboro, OR, USA) with an energy-dispersive X-ray spectrometer (EDAX; Genesis Apex 4, Mahwah, NJ, USA).
With respect to the major and trace elements concentrations, a two-step digestion method proposed by Querol et al. (1997) was used to retain volatile elements in the solution [41]. Subsequently, the contents of major and selected trace elements were detected by inductively coupled plasma atomic-emission spectrometry (ICP-AES, Iris Advantage Radial ER/S device from Thermo Jarrell-Ash, Waltham, MA, USA), and the contents of most trace elements by inductively coupled plasma mass spectrometry (ICP-MS, X-SERIES II Thermo Fisher Scientific, Bremen, Germany). In order to guarantee the accuracy of the digestion and the analytical methods, digestion of blank samples and international reference materials (SARM-19) was also carried out following the same procedure.

4. Results

4.1. Coal Quality and Rank

The Jurassic coals (Nos. 1, 2, and 3) are characterized by low moisture contents (7.2%, 5.8%, and 6.0%, respectively), low high-temperature ash (HTA, under 750 °C) yields (3.8%, 7.4%, and 3.1%, respectively), and high volatile matter yields (33.8%, 40.7%, and 36.9%, respectively) (Table 1), indicating that the Jurassic coals are high volatile bituminous coals (ASTM, 2011). All coal seams have similar total S contents ranging from 0.3% to 0.8%, indicating low-sulfur coals according to Chou (2012) [42].
By contrast, the Permian No. 4 coal in the Puran coal mine has lower moisture content (2.3% ad, on average) and higher ash yield (24.4%), which is also higher than the coals of late Carboniferous Taiyuan Formation in the Jungar Coalfield [18,19,20,22]. In addition, the ash yields show an increasing trend from PR-4-8 (15.3%) to PR-4-1 (45.0%). The Permian coals have high volatile matter yields ranging from 38.7% to 41.9% (daf.), indicating that the coal rank belongs to high volatile bituminous coal (ASTM, 2011). The total S contents of the Permian coals range 0.3% to 0.4% (Table 1), also indicating low-sulfur coal [42].

4.2. Mineralogy

4.2.1. Mineralogical Compositions and Vertical Distribution

In this study, we using major (>10%, dry basis-db), minor (1–10%, db), and trace (<1%, db) amount of mineral to group all minerals. In the Permian coals, minerals consist mainly of kaolinite (average of 23.6%, db) and traces of calcite, and apatite only detected in the PR-4-5 and PR-4-6 (Table 2). Trace amounts of zircon and boehmite are observed in some samples using scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM-EDS). The major minerals in the roof sample (PR-4-T) are kaolinite (68.3%, db.), followed by tobelite, and minor amount of dolomite. The parting samples mainly consist of kaolinite (75.9%, 68.7%, 59.8%, db.), and PR-4-4 (P) contains trace amount of apatite. Zircon, galena, dolomite, and anatase in the partings were also occasionally identified by SEM-EDS analysis. In addition, the vertical variation of kaolinite content is consistent with ash yield, increasing from bottom to the top. Calcite was detected in the top and bottom of the coal seam but is absent in the middle parting samples.
The Jurassic coals contain variable mineral assemblages among different coal seams. The No. 1 coal consists of minor calcite (2.3% db.) and trace amount of quartz (0.9% db), and to a lesser extent, kaolinite, pyrite and gypsum only present in a few samples. The mineral in the No. 2 coal mainly consists of calcite, quartz, and kaolinite, with the exceptions of samples CJG-2-2 and CJG-2-4, the former of which is primarily dominated by calcite (17.6%, db) and to a less extent, ankerite (3.1% db), and the latter of which is dominated by siderite (4.4%, db). Traces of dolomite, pyrite, and gypsum were also detected in some samples. The No. 3 coal mainly consists of quartz (2.4%, db), with trace amounts of kaolinite and calcite, pyrite, and gypsum only present in a few samples (Table 2). Vertically, calcite is concentrated in No. 1 and top of No. 2 (top) coals. The amount of quartz is markedly higher near the floor and roof rocks of the No. 1 and 3 coals, possibly indicating some input of terrigenous detrital materials as the peat was being established or being progressively overwhelmed by other depositional environments as reported by Ward and Christie [43]. The content of kaolinite decreases from the bottom to the top in the No. 1 and 2 coal seams, but shows no obvious variation in the No. 3 coal seam.

4.2.2. The Modes of Occurrence of Minerals

Silicate Minerals

Kaolinite is the major constituent in the Jurassic and Permian coals and occurs in the following three types: (Ⅰ) as lumps and thin-layered forms in collodetrinite (Figure 3A and Figure 4A,B), with the size ranging from 1 μm to 200 μm, indicating a terrigenous detrital origin; (Ⅱ) as fracture/cleat infillings (Figure 5A–C), indicating an epigenetic precipitation from the migrating diagenetic/epigenetic fluids. (Ⅲ) as cell infillings, in a few cases, along with apatite (Figure 3AB–D, Figure 4C,D and Figure 6A,B), indicating an authigenic origin during syngenetic to early diagenetic stages; and unlike in the coal samples, kaolinite occurs primarily as discrete particles and thin layers (Figure 7A), sometimes as vermicular form in the non-coal rock samples (Figure 7B).
Quartz associated with organic matter as euhedral crystals (Figure 3E), analogous to that of volcanic origin with relatively short transport from source region. It is also found as rounded fine grains (<5 μm, Figure 3A and Figure 5D) typical of a detrital origin with relatively long transport from source region.
Chamosite has been identified by SEM-EDS analysis and is present as cell fillings, sometimes co-exciting with kaolinite (Figure 5A). A similar mode of occurrence has also been identified in some coals [44,45]. The coexistence of kaolinite and chamosite possibly indicates that chamosite was derived from the interaction of pre-existing kaolinite and Fe-Mg-rich fluids during early diagenesis [46].
Zircon primarily occurs as euhedral crystals within the kaolinite matrix (Figure 8A) and organic matter (Figure 9A). The SEM-EDS data show that zircon grains contain Y, Nb, Hf, P and Sc (Figure 8A and Figure 9A).
Tobelite, although only detected in the roof sample PR-4-T by XRD, is a typical mineral in tonsteins of Permo-Carboniferous coal accumulation area of Northern China [47]. Based on the previously published literature, tobelite is almost exclusively observed in high-rank coals and formed by interaction of already present K-illite and/or kaolinite with nitrogen which released by decomposition of organic matter during rank advance or hydrothermal alteration [48,49,50,51,52,53]. In present study, illite has not been detected by XRD or SEM-EDS, we deduced that tobelite may be formed from the interaction of kaolinite and nitrogen which is similar to the Permian coals in Tongzi Coalfield [51].

Carbonate Minerals

The carbonate minerals detected by XRD include calcite, siderite, ankerite, and dolomite. Siderite occurs as cavities infillings of kaolinite (Figure 3F). Calcite occurs as fracture infillings (Figure 5B) Dolomite has euhedral crystals morphology and precipitated along fractures in the organic matter matrix (Figure 4E), indicating epigenetic precipitation from Ca-Fe-rich solutions.

Sulfide Minerals

Pyrite is only detected in the Jurassic coals and occurs as framboidal euhedral crystals within organic matter (Figure 3D,F). Here, the framboidal pyrite with a relatively uniform distribution closely to one another is different with the bacteriogenic framboidal pyrite which occurs as separated globules described by Kostava et al. [54], indicating authigenic origin during syn-depositional or early diagenetic stage. Galena, containing Cu and Hg, occurs as crystals included within the kaolinite matrix (Figure 7B–D), indicating an authigenic origin.

Oxide and Hydroxide Minerals

Anatase grains occur in the kaolinite matrix in the parting samples (Figure 7E) and contain traces of La, Ce, and V (Figure 8B).
Boehmite is detected by SEM-EDS in the Permian coals and mainly occurs as finely disseminated grains within the kaolinite matrix (Figure 9B), possibly indicating a detrital origin. It has also been found in other Permian coals in the Jungar Coalfield and Weibei Coalfield [3,18,19,20,21,52].

Sulfate Minerals

Gypsum occurs as lamellar aggregate infilling the fracture alone or together with kaolinite (Figure 5C,E,F). Sometimes, gypsum has beein considered as the produce of the storage of coal [55] or derived from marine water before compaction [56], however, the two genesis types were excluded based on the following evidence: on the one hand, the morphology of marine derived gypsum, which occurs in platy crystals as fillings in plant cells and vugs, is different from this study, and on the other hand, the absence of calcite and pyrite in this sample. Thus, gypsum in this study has an authigenic origin involving precipitated from the Ca-rich solutions.

Phosphate Mineral

Phosphates are represented by apatite in the Permian coals and occur as cell-fillings (Figure 6C,D and Figure 7F) which represents syngenetic precipitation in the peat bed, and individual grains with angular shape (Figure 6E). Some apatite occurs in the matrix of kaolinite (Figure 4C and Figure 6F) or organic matter matrix (Figure 4F and Figure 9C). In addition, apatite in the partings contains Zr, Y, and Nb (Figure 8C) whereas in coal sample contain Zr (Figure 9C).

4.3. Geochemistry

4.3.1. Major and Trace Element Concentration

The major elements in No. 4 coal seam of the Puran coal mine are dominated by Al2O3 (13%) and SiO2 (11%), followed by CaO and Fe2O3, with trace amounts of K2O, MgO and Na2O (Table 3), as would be expected from the mineral composition that is dominated by kaolinite (Table 2). By contrast, the Cuijiagou coals (No. 1, No. 2, and No. 3 coals) have lower contents of most major elements due to lower ash yields. More specifically, the major elements of No. 1 coal seam are SiO2 (1.3%) and Al2O3 (1.2%), followed by CaO and Fe2O3, with trace amounts of K2O, MgO and Na2O. The No.2 coal seam has higher contents of CaO (3.1%) and Fe2O3 (2.1%), which may have been caused by higher amounts of carbonate minerals (such as siderite, calcite, dolomite and ankerite) and pyrite. The No. 3 coal seam is mainly dominated by SiO2 (2.5%).
The SiO2/Al2O3 ratios of No. 4 coal seam (Table 3, 1.5) in the Permian coals are approximately equivalent to that for the Chinese coals (1.4) [5] but slightly higher than the theoretical ratio for kaolinite (1.2). The SiO2/Al2O3 ratio is elevated by sample PR-4-7 with SiO2/Al2O3 ratio of 3.7. The middle and upper portions have lower ratios of SiO2/Al2O3 (Table 3, 0.6–0.9) due to the presence of Al-oxyhydroxide such as boehmite (Figure 9B). The SiO2/Al2O3 ratio in the No. 1 (1.1), No. 2 (1.5), and No. 3 (2.9) coal seam of the Jurassic coals are close to or even higher than the theoretical ratio for kaolinite, indicating the existence of free SiO2.
Concentration coefficient (CC) was proposed by Dai et al. [16] in the present study. Comparing with the average of Chinese coals [5], most trace elements are depleted in the Jurassic coals with CC <0.5 (Figure 10). Beryllium, B, Cr, Ta, and W in the No. 1 coal seam, Be and Sr in the No. 2 coal seam, and B, Sr Ta and W in the No. 3 coal seam are similar to the averages for Chinese coals [5]. Boron in the No. 2 coal seam is slightly enriched. The Permian coals are enriched in Ta, slightly enriched in P, Ga, Zr, Nb, and W. The remaining trace elements are similar or less than the average for Chinese coals (Figure 11) [5]. Vertically, the elevated elements, such as Nb, Ta, Ga, Zr and REY, are mainly concentrated in coal benches close to the partings of the No. 4 coal seam.

4.3.2. Rare Earth Elements and Yttrium (REY)

The classification of the REY proposed by Seredin and Dai [57], divided REY into three groups: LREY(La, Ce, Pr, Nd, and Sm), MREY (Eu, Gd, Tb, Dy, and Y), and HREY (Ho, Er, Tm, Yb, and Lu), and three enrichment types (L-type, M-type, and H-type), was used in this study. The REYs concentrations of the Jurassic coals ranged from 1 to 70 μg/g with an average of 29, 6.4, and 8.4 μg/g respectively in No. 1, 2, and 3 coal seams, which is significantly lower than that of Chinese coal (136 μg/g) [3].
The REY contents of the Permian coals range from 93 to 381 μg/g (189 μg/g, average), slightly higher than that of Chinese coals (136 μg/g, Dai et al. [3]). Furthermore, the parting samples have higher concentrations (367 μg/g on average) than coal samples. The contents of REY increase from the bottom to the top and reach the maximum adjacent to the partings. It is worth noting that the contents of REY in the roof sample are distinctly lower than in adjacent coal immediately below the roof (105 and 219 μg/g, respectively). The Upper Continental Crust (UCC [58])-normalized REY distribution pattern is characterized by an L-type in the partings (PR-4-3, PR-4-4), M-type in the coal sample (PR-4-5), and H-type both in coal and non-coal samples (roof PR-4-T, coal PR-4-1, and parting PR-4-2). In addition, all the samples have moderate negative Eu anomalies (average Eu/Eu* value of 0.61) (Figure 12), indicating a derivation from felsic composition [6].

4.3.3. Modes of Occurrence of Selected Elements in Coal

There are three modes of occurrence of elements in coals proposed by Dai et al., (2020), i.e., organic, mineral, and intimate organic associations [59]. The organic and intimate organic association were preliminarily identified by evaluating the coefficients of element contents with ash yield for the different coals [60,61]. In order to obtain full interpretation of the relationship, we showed the X-Y plots of selected elements and ash yield (Figure 13 and Figure 14).
In Jurassic No. 1 coal from the Cuijiagou coal mine, MgO shows positive correlation with ash yield (r = 0.88), indicating mineral association (Figure 13A). There is no obvious correlation among MgO, CaO and Fe2O3, whereas SiO2 and Al2O3 (r = 0.86, Figure 13B), MgO and SiO2 (r = 0.79), MgO and Al2O3 (r = 0.77) have significant positive correlations, which is in agreement with the presence of clay minerals such as kaolinite in the coals. In addition, the correlation coefficient of Mn and CaO is 0.97 (Figure 13C), indicating a carbonate association. B and ash yield have negative correlation ship with correlation coefficient −0.73, indicating that B may has intimate organic association (Figure 13D).
With respect to the elements in No. 2 coal, CaO and ash yield (r = 0.91) as well as CaO and MgO (r = 0.99) have significantly positive correlation that may be due to the high content of calcite, dolomite, and ankerite in the coals (Figure 13E,F). In addition, Mn has higher correlation coefficient with MgO (r = 0.71) indicating a dominant dolomite association (Figure 13G). B has some degree of positive correlation ship with ash yield when we removed some single outlier points (r = 0.87, Figure 13H) indicating that B may has both inorganic and organic associations.
In No. 3 coal, SiO2 and Al2O3 has a significant positive correlation with ash yield (r = 0.98, Figure 13I–K) and the correlation coefficients of most of the trace elements with SiO2 and Al2O3 are >0.7, indicating an aluminosilicate association. B presents slightly negative correlation with ash yield (r = −0.62, Figure 13L) indicating an intimate organic association.
As for the Permian No. 4 coal, most of the elements have mineral associations (rash = 0.52–0.99, Figure 14A,B,D–I). As the major clay mineral in the coal samples, kaolinite plays an important role in hosting most of the trace elements, which is confirmed by the correlation coefficients between most elements and SiO2–Al2O3. Besides, Ca, P, and Sr have strong positive correlation with each other (rCa-P = 0.74, rCa-Sr = 0.79, rP-Sr = 0.95, Figure 14J–L) which may be caused by abundance of apatite in the coal seam. Some other elements, such as Y, Ba, U, REYs, also have positive correlations with Ca, P, or Sr (r > 0.5) indicating an apatite association. Besides, the correlation coefficient of S and ash yield is −0.81 indicating that S occurs in organic matter (Figure 14B).

5. Discussion

5.1. Sedimentary Source Rocks

The sediment source region of coal deposits is generally identified by using geochemical indicators [61,62,63,64,65]. The Al2O3/TiO2 ratio has been proved to be an effective index to reflect the geochemical composition of source rocks due to its stability during sedimentary processes, with ratios of 3–8, 8–21, >21, being respectively indicative of mafic, intermediate, and felsic rocks [65]. All coal samples of this study have higher Al2O3/TiO2 ratios (more than 21), indicating detrital materials with a felsic-dominated composition (Figure 15). In the plot of Th/Sc vs. Zr/Sc (Figure 16) [66], the Permo-Carboniferous coals, including Jungar Coalfield [18,19,20,67], Daqingshan Coalfield [27,66], Shanbei Coalfield (this study), assembled in the felsic rock zone reflecting the same source rock type. The Jurassic coals, including Dongsheng Coalfield [34] and Shanbei Coalfield (this study), are scattered between the zone of intermediate and felsic rock but more closely to felsic rock (Figure 16).
The REY distribution patterns and Eu anomalies are also used as important identifications of sedimentary source rocks [6,65]. However, the content of Eu may be interfered with by Ba during ICP-MS analysis [68]. Yang et al., (2018) proposed if Ba/Eu > 1000, Ba would significantly interfere with Eu [68]. In the present study, the ratio of Ba/Eu range from 148 to 402 (Table 4) indicating that Eu was not interfered by Ba. The felsic volcanic rocks have higher ratios of LREY/HREY and strong negative Eu anomalies, whereas mafic volcanic rocks have low LREE/HREE ratios and no negative Eu anomalies [64,69].The samples have moderate negative Eu anomalies (Eu/Eu*, average 0.61) indicating felsic rocks origin (Table 4), which is in accordance with previous studies that the major sediment-source region of the N China Coal Basin is the Yinshan Oldland, which is made up of felsic rocks [5].
Prior studies reported that there are two different sediment source regions: the Yinshan Oldland (N and W); and the Benxi Formation (N and E) [18,20,29,35]. Boehmite is generally thought to be derived from the weathering crust, and it has two modes of occurrence in the adjacent coalfield: (Ⅰ) boehmite occurs as massive lumps in collodetrinite and cell infillings of fusinite [18,19,29]; (Ⅱ) boehmite is also enclosed by kaolinite and occurs as a massive lens which may be derived from the breakdown of kaolinite rather than detrital input or by precipitation from an Al-rich colloidal solution [52]. The mode of occurrence of boehmite in this study is different from that stated above, occurring as finely disseminated impregnations within the kaolinite matrix (Figure 9B), which may be precipitated from Al-rich solution derived from the bauxite of the Benxi Formation.

5.2. Diagenetic Fluid Supplies

Hydrothermal fluid (syngenetic and epigenetic) is another important geological controlling factor on the mineralogy and geochemistry of the coal and non-coal samples in this study.
Comparing with the Permian coals, the Jurassic coals, especially No. 1 and 2 coals, have high proportion of carbonate minerals. These minerals mainly occur as a fracture or cleat in-fillings (Figure 5) indicating precipitation from fluids that permeated through the coal along fracture or/and cleat after burial and rank advance [45]. Furthermore, some epigenetic fracture or cleat infilling of kaolinite, was also observed under the SEM-EDS (Figure 5), also providing some evidence for the input of hydrothermal fluids.
With respect to the Permian coals, partings and roof sample, although epigenetic fluids influenced some samples, such as fracture in-filling dolomite in PR-4-6 (Figure 4E), but did not have a noticeable impact on the trace element distribution in the coal seam. Hydrothermal fluid of syngenetic stage played more important role in the enrichment of trace elements. Unlike in the Jurassic coals, kaolinite mainly occurs as cell or pore space infillings which precipitated from fluids derived from weathered source region. Apatite also occurs cell infillings alone or together with kaolinite, indicating the input of syngenetic hydrothermal fluid. Furthermore, sample PR-4-5 is characterized by M-type REY distribution and positive Gd anomaly (GdN/GdN* = 1.2), indicating the input of hydrothermal fluids as reported by Seredin and Dai [57].
As mentioned above (Section 4.2.2), P was detected in zircon grain (Figure 8A and Figure 9A), and Zr was also detected in apatite grain (Figure 8C and Figure 9C) which may be caused by acid hydrothermal fluid. Generally, Zr are essentially immobile during chemical weathering [70,71], however, under the effect of intense acid hydrothermal fluids, it may become mobilized [28,72]. In this study, during syngenetic to early diagenetic stage, zircon was corroded by acid hydrothermal fluid which eventually precipitated and formed apatite. The coupled substitution of REY3+ + P5+ for Zr4+ + Si4+ or REY3+ + (Nb, Ta)5+ for 2Zr4+ in the zircon crystal lattice may cause zircon to contain some P [73].

5.3. Enrichment of Trace Elements

5.3.1. Boron

The ash yield is approximately 10 times lower in the Jurassic than in the Permian coals but the B contents are approximately 2 times higher in the Jurassic ones. Boron has organic association in the Permian coals (rash = −0.93), and both organic (No. 1 and 3 coals with rash = −0.73, −0.62) and inorganic association (No. 2 coals with rash = 0.87) in the Jurassic coals. Calcite, as a primary mineral in the No. 2 coal, has significant positive correlation with B (rcal-B = 0.97). This differs markedly to previous studies where B is inorganic association was closely related with clay minerals (especially illite) or tourmaline [74,75,76,77].
In general, B concentrations are closely related to the paleo-salinity of the depositional water. The coals deposited in the marine-influenced environments, such as tidal flat environments of restricted carbonate platforms [5,19,78,79], and some non-marine-influenced environments such as brackish peat formed in the distributary channel–delta front, beach bar and interdistributary bay [24], are enriched in B. In addition, hydrothermal fluids, volcanic activity, acidic water, and climatic variation also elevated the concentration of B [80,81,82,83,84,85,86,87].
Previous studies showed that the Permian Shanxi Formation coals were deposited in the fluvial and deltaic environments [35,88] and the No. 1 and 3 coals of the Jurassic Yan’an Formation were deposited in the lake delta plain [37,89]. However, the indicator of Sr/Ba, which is a useful indicator for climatic conditions with >1 for arid and <1 for humid [90,91], is different between the Jurassic and Permian coals. The average ratios of Sr/Ba in the Jurassic coals are 4.7 (No. 1), 8.6 (No. 2), and 5.3 (No. 3) whereas in the Permian coal it is 1.2 indicating a more arid climate. The climatic variation may be one of the reasons caused enrichment of B in the Jurassic coals.
On the other hand, as mentioned above, B has organic associations, suggesting that the elevated concentration of B may be absorbed by organic matter from fluid (or groundwater) or inherited from coal-forming plants as evidenced by the boron content being higher in the lower ash-yield coals [89]. According to Wang (1996) the dominant coal-forming plants of the Late Paleozoic are herbaceous vegetation (90.1%) which is mainly fern, whereas the Jurassic Yan’an Formation are both woody plants (66.9%) and herbaceous vegetation [35]. The different types of coal-forming plants might result in the different B contents between the Jurassic and Permian coals.

5.3.2. Phosphorus, Sr, and Ba

Comparing with adjacent coalfields, the Permian coals in the Puran coal mine have higher contents of P in both coals (1818 μg/g, average) and non-coal rocks (1603 μg/g, average), especially in the coal sample of PR-4-5 (6256 μg/g), approximately 15 times higher than the average of common Chinese coals (402 μg/g) [5]. Phosphorous was concentrated in the samples where apatite was detected. The strong positively correlation between P and CaO (r = 0.74) also indicates that P is mainly incorporated into apatite. In addition, P and Sr (r = 0.96), P and Ba (r = 0.94) have significant positive correlations, which is in accordance with the Heidaigou [18], Haerwusu [19], and Buertanhai–Tianjiashipan [21] coals. In these coalfields, the major carrier of P is goyazite (Haerwusu and Heidaigou coals) and svanbergite (Buertanhai–Tianjiashipan coals) [18,19,20,21]. However, these minerals are neither detected by XRD nor by SEM-EDS in this study. Accordingly, Sr and Ba probably occur in apatite. Besides, P and REYs also have a good positive correlation (r = 0.87) indicating apatite as the host of REYs. Furthermore, Nb and Y were detected in apatite by means of SEM-EDS (Figure 8C). This mode of occurrence of REYs is different from P-bearing minerals (goyazite and svanbergite) in the Junger Coalfield coals [19,21].
In the present study, almost all apatite shows syngenetic origin, which may derive from volcanic input [45,90] or to the supply of Ca- and Al-rich solutions combined with P which was released from the decay of organic matter in a suitable geochemical setting [92], and non-fracture filling apatite (epigenetic origin), was identified by SEM-EDS. Dai et al., (2017) distinguished authigenic apatite from volcanic apatite based on the mode of occurrence [93]. Generally, volcanic apatite “occurs as euhedral and elongate hexagonal grains, and can contain distinctive fluid inclusions, in some cases, the delicate and elongate apatite grains may have fractured as a result of compaction, or have been altered [93]”, which obviously is different from present study.
The Al-rich solution arising from the weathering of bauxite (Benxi Formation) yielded to mineral precipitation under a higher pH environment to initially form aluminum hydroxide mineral (gibbsite and boehmite). In general, gibbsite is unstable in the presence of SiO2, and if SiO2 is available, authigenic kaolinite precipitation might be favored [45]. With respect to apatite, it has also been detected in the Adaohai mine and was also affected by input of diagenetic solution from bauxite contained in the Benxi Formation [53]. In this study, authigenic apatite occurs always intimately enclosed or surrounded by kaolinite or organic matter (Figure 6E,F), indicating that apatite precipitated from Al-, Si-, Ca-, and P-rich solutions during syngenetic to early diagenetic stages. This occurrence of apatite is similar to that described elsewhere for coals from the Muli Coalfield on the Tibetan Plateau [93].

5.3.3. Niobium, Ta, Ga, and Th

The concentrations of Nb and Ta in the Permian coal samples, respectively range from 7 to 133 μg/g (43 μg/g, average), and from <0.1 to 12 μg/g (7 μg/g, average). Gallium and Th are enriched in different coal mine of the Junger and Daqingshan Coalfields in varying degrees [19,20,21,53] and are similar to the Daqingshan Coalfield in No. 4 coal, but lower than that of Junger Coalfield, especially Ga. However, the associated non-coal samples are enriched in a number of elements including Li (163 μg/g), Pb (37 μg/g), Ti (6272 μg/g), Sr (352 μg/g), and U (6 μg/g).
The correlation coefficients of Nb and Ta with ash yield (rNb-Ash = 0.94, rTa-Ash = 0.94) and kaolinite (rNb-Kal = 0.93, rTa-Kal = 0.96) demonstrate a major kaolinite association. Moreover, some Nb and Ta also occur in heavy mineral (zircon, anatase), as evidenced by SEM-EDS (Figure 8A,B and Figure 9A). With respect to the parting samples, Nb and Ta are negatively correlated with ash yield, but positively with Ca and P, suggesting that apatite is the predominant carrier of Nb and Ta in parting samples. This is also further confirmed by the SEM-EDS mappings where Nb has a similar distribution with P within apatite and with Zr in the zircon (Figure 8A,C).
According to previous studies, the elevated contents of Ga in the Junger and Daqingshan Coalfield mainly occurs in aluminosilicate mineral (kaolinite), aluminum hydroxide mineral (boehmite, diaspore, goyazite), and svanbergite [18,19,20,21,53], and Th in boehmite, clay minerals, accessory minerals such as zircon, and organic matter [20]. In No. 4 coals, both Ga and Th have aluminosilicate association, as evidenced by the significant correlation with Al2O3 and SiO2 (Al2O3: rGa = 0.91, rTh = 0.92; SiO2: rGa = 0.94, rTh = 0.97), specifically with kaolinite (r = 0.94, 0.98). In addition, Th intimately correlated with Ti (r = 0.99) and Zr (r = 0.99), which also shows that some accessory minerals (e.g., zircon, rutile) may contribute to some proportions of Th in the coal samples. The heavy minerals in the bauxite of Benxi Formation in the north China, one of the main sediment source rocks, are mainly zircon, rutile, and galena [18]. Meanwhile, the other source rocks, the Middle Proterozoic moyite of the Yinshan Oldland also provides a relatively high background value of Th [53]. In the non-coal samples, the correlation analysis shows Ga occurs in kaolinite and Th may occur in apatite (rTh-CaO = 0.89, rTh-P = 0.88).

5.3.4. Rare Earth Elements and Y

In the adjacent coalfield, LREY, MREY, and HREY have different degrees of organic matter association in different coal mines. In the Haerwusu coal mine, LREEs have a stronger organic matter association than the HREEs, whereas the opposite was found for the Adaohai coal mine [19,53]. Furthermore, in the Guanbanwusu coal mine, all REYs have similar organic matter association [20]. As for the Puran coal mine, REYs in coals, including LREY, MREY, and HREY, were found with a similar high correlation with ash yield (r = 0.91–0.96), suggesting a similar inorganic association. Finkelman et al., (2019) proposed that in bituminous coals, the bulk (>50%) of all elements except Br were associated with minerals, such as clays, phosphate, and carbonate minerals [94]. Different from the Guanbanwusu coal mine in which LREY are retained in the goyazite, and MREY and HREY occur both in boehmite and accessory minerals, the REYs of the Permian coals have multiple mineral affinities, as evidenced by the positive correlation of REY with kaolinite (r = 0.54), and the SEM-EDS mappings showing that zircon, apatite, and boehmite contains Nb and Y (Figure 9).
There are four genetic types of REY enrichment in the coal basin including (Ⅰ) terrigenous; (Ⅱ) tuffaceous; (Ⅲ) infiltrational or meteoric groundwater driven; and (Ⅳ) hydrothermal types [57]. Different REY distribution patterns (L-type, M-type, and H-type) indicate different genetic types in coals [20,29,57]. In the Permian coals, REY are mainly enriched in some benches with sample PR-4-1 with H-type distribution, PR-4-5 with M-type, as well as PR-4-6, PR4-3, and PR4-4 with L-type distributions (Figure 12). The L-type REY distribution, in accordance with the Guanbanwusu, Heidaigou, and Haerwusu coals, may be caused by REY-rich colloidal input from the weathered bauxite of the Benxi Formation [18,19,20].
The uppermost coal sample PR-4-1 is characterized by H-type enrichment which may be affected by stronger groundwater leaching than the other coal samples [20]. Comparing with the middle and bottom parting samples (PR-4-3 and PR-4-4), the upper parting sample PR-4-2 has lower contents of REY, lower ratio of LREY/HREY and LaN/YbN, which was probably caused by the leaching of groundwater. The LREY are more readily leached by ground water than the HREYs, leads to HREYs enrichment in the PR-4-2 but LREYs enrichment in the PR-4-3 and PR-4-4. However, coal samples in the lower portion (especially PR-4-5) have lower contents of REYs (381 vs. 494 μg/g), lower ratio of LREY/HREY (25 vs. 36), and lower ratio of LaN / YbN (1.05 vs. 1.75) than the overlying parting, which may not be effected by groundwater leaching. The coal sample PR-4-5 is the only one that is characterized by an M-type REY enrichment, which was also identified in the Hailiushu mine by [29], probably indicating the input of a REY-bearing acid hydrothermal solution [29,57].

6. Conclusion

The Jurassic and Permian coals have similar chemical characteristics excluding ash yield, which is significantly higher in the Permian coals. The Jurassic coals have relatively lower amounts of mineral matter, which mainly consist of quartz, kaolinite, and calcite while the Permian coals are dominated by kaolinite. Apatite is detected in the partings and coals close to partings, and calcite occurs in the bottom portion of the coal seam. Compared to Chinese coals, the Jurassic coals enriched in B, the Permian coals enriched P, Nb, Ta, Zr, Ga, W, Th and REY.
Previous studies have indicated the Jurassic and Permian coals are formed in similar sedimentary environment and similar B content would be expected, however, the Jurassic coals contain much higher B than the Permian ones. The discrepancy is possibly due to (1) the climatic variation. From the Permian to Jurassic, the climate has become more arid evidenced by increasing ratio of Sr/Ba; (2) B has significant organic matter association indicating the elevated concentration of B may be absorbed by organic matter from fluid (or groundwater) or inherited from coal-forming plants.
In the Permian coals, the sedimentary source rocks dominantly controlled the enrichment of trace elements. Most of the elevated elements, such as Nb, Ta, Ga, Th, have kaolinite association which was derived from weathering of sedimentary source region. Some other elements, P, Sr and Ba, have apatite associations which may be derived from the bauxite on the weathered basement (Benxi Formation) in the sediment source region. Furthermore, REY enrichment is found to be both controlled by ground water and acid hydrothermal fluid based on the genetic types of REY.
Although the present study provides new data of coal mineralogy and geochemistry in the northeastern of Ordos and discussed geological controls about enrichment of some trace elements, there is still an absence of systematic research in temporal and spatial distributions and modes of occurrence of critical elements which need further study.

Author Contributions

Conceptualization, Y.S., X.Z., J.L. and B.L. (Baoqing Li); methodology, Y.S., B.L. (Bo Liu) and N.M.; formal analysis, Y.S.; investigation, Y.S., W.Y., B.L. (Baoqing Li); resources, X.Z., G.Y., L.P.; data curation, Y.S., N.M.; writing—original draft preparation, Y.S.; writing—review and editing, Y.S., X.Z., J.L., B.L. (Baoqing Li) and X.Q.; supervision, X.Z., J.L. B.L. (Baoqing Li) and X.Q.; project administration, X.Z., J.L., B.L. (Baoqing Li) and X.Q.; funding acquisition, X.Z., J.L., B.L. (Baoqing Li) and X.Q. All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by the National Science Foundation of China (Nos. 41972179, 41972180), the National Key R&D Program of China (No. 2018YFF0215400), the Fundamental Research Funds for the Central Universities, China University of Geosciences (Wuhan) (No. CUGCJ1823), the “Overseas Top Scholars Program”, part of the “Recruitment Program of Global Experts” (No. G20190017067), and the Open Research Fund Project for Key Laboratory of Tectonics and Petroleum Resources (China University of Geosciences), Ministry of Education (No. TPR-2019-14).

Conflicts of Interest

The authors declare no conflict of interest.

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Figure 1. Geological map of Ordos Basin showing the location of the Shanbei Coalfield (Modified from Wang et al., [35]). 1. province boundary; 2. Ordos basin boundary; 3. tectonic unit boundary; 4. Shanbei Coalfield; 5. study coal mine; 6. main city in Ordos basin.
Figure 1. Geological map of Ordos Basin showing the location of the Shanbei Coalfield (Modified from Wang et al., [35]). 1. province boundary; 2. Ordos basin boundary; 3. tectonic unit boundary; 4. Shanbei Coalfield; 5. study coal mine; 6. main city in Ordos basin.
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Figure 2. Sedimentary sequence of the Taiyuan and Shanxi Formations (A) and Yanan Formation (B) in the Ordos Basin [35] and sampling location from the Puran (C) and Cuijiagou (D) underground coal mines [35].
Figure 2. Sedimentary sequence of the Taiyuan and Shanxi Formations (A) and Yanan Formation (B) in the Ordos Basin [35] and sampling location from the Puran (C) and Cuijiagou (D) underground coal mines [35].
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Figure 3. SEM back-scattered images of kaolinite, quartz, pyrite and siderite in the sample of CJG-1-1. (A) dispersed kaolinite and quartz particles; (B,C) syngenetic cell-filling kaolinite; (D) syngenetic cell-filling kaolinite and detrital pyrite grain; (E) authigenic quartz; (F) mineral assemblage including siderite, kaolinite, and framboidal pyrite.
Figure 3. SEM back-scattered images of kaolinite, quartz, pyrite and siderite in the sample of CJG-1-1. (A) dispersed kaolinite and quartz particles; (B,C) syngenetic cell-filling kaolinite; (D) syngenetic cell-filling kaolinite and detrital pyrite grain; (E) authigenic quartz; (F) mineral assemblage including siderite, kaolinite, and framboidal pyrite.
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Figure 4. SEM back-scattered images of kaolinite, apatite and dolomite in PR-4-6. (A,B) dispersed kaolinite particles or kaolinite lenses; (C) apatite filling cavities of kaolinite; (D) cell-filling kaolinite; (E) fracture-filling dolomite; (F) apatite fillings pore/cavity of organic matter.
Figure 4. SEM back-scattered images of kaolinite, apatite and dolomite in PR-4-6. (A,B) dispersed kaolinite particles or kaolinite lenses; (C) apatite filling cavities of kaolinite; (D) cell-filling kaolinite; (E) fracture-filling dolomite; (F) apatite fillings pore/cavity of organic matter.
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Figure 5. SEM back-scattered images of kaolinite, chamosite, calcite, gypsum and quartz (sample CJG 3-4). (A) syngenetic cell-filling chamosite and cleat/fracture-filling kaolinite; (B,C,E,F) cleat/fracture-filling kaolinite, gypsum and calcite; (D) Sub-round quartz grain associated with organic matter.
Figure 5. SEM back-scattered images of kaolinite, chamosite, calcite, gypsum and quartz (sample CJG 3-4). (A) syngenetic cell-filling chamosite and cleat/fracture-filling kaolinite; (B,C,E,F) cleat/fracture-filling kaolinite, gypsum and calcite; (D) Sub-round quartz grain associated with organic matter.
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Figure 6. SEM back-scattered images of kaolinite and apatite (sample PR 4-5-P). (A,B) cell-filling kaolinite; (C,D) syngenetic cell or pore space infillings apatite; (E) dispersed apatite particles within organic matter; (F) the growth of kaolinite and apatite.
Figure 6. SEM back-scattered images of kaolinite and apatite (sample PR 4-5-P). (A,B) cell-filling kaolinite; (C,D) syngenetic cell or pore space infillings apatite; (E) dispersed apatite particles within organic matter; (F) the growth of kaolinite and apatite.
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Figure 7. SEM back-scattered images of kaolinite, apatite, galena and anatase in the parting sample of PR-4-4 (P). (A) dispersed kaolinite particles; (B) vermicular kaolinite; (C,D) apatite, galena fillings cavity of kaolinite; (E) kaolinite matrix, anatase filling the cavities of kaolinite matrix; (F) cell-filling apatite.
Figure 7. SEM back-scattered images of kaolinite, apatite, galena and anatase in the parting sample of PR-4-4 (P). (A) dispersed kaolinite particles; (B) vermicular kaolinite; (C,D) apatite, galena fillings cavity of kaolinite; (E) kaolinite matrix, anatase filling the cavities of kaolinite matrix; (F) cell-filling apatite.
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Figure 8. SEM-EDS mappings of zircon (A), anatase (B), and apatite(C) in the parting sample PR-4-4.
Figure 8. SEM-EDS mappings of zircon (A), anatase (B), and apatite(C) in the parting sample PR-4-4.
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Figure 9. SEM-EDS mappings of zircon (A), boehmite (B)and apatite (C) in the coal sample of PR-4-6.
Figure 9. SEM-EDS mappings of zircon (A), boehmite (B)and apatite (C) in the coal sample of PR-4-6.
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Figure 10. Concentration coefficients (CC) of trace elements of the Jurassic coals in the Cuijiagou underground coal mine compared to the averages trace elements for Chinese coals [5].
Figure 10. Concentration coefficients (CC) of trace elements of the Jurassic coals in the Cuijiagou underground coal mine compared to the averages trace elements for Chinese coals [5].
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Figure 11. Concentration coefficients (CC) of trace elements of the No. 4 coals in the Permian of the Puran coal mine. Normalized by averages of trace elements in the Chinese coals [3].
Figure 11. Concentration coefficients (CC) of trace elements of the No. 4 coals in the Permian of the Puran coal mine. Normalized by averages of trace elements in the Chinese coals [3].
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Figure 12. The Upper Continental Crust (UCC)-normalized rare earth elements and yttrium (REY) distribution patterns in the Permian coals. (UCC data are from Taylor and McLennan [56]).
Figure 12. The Upper Continental Crust (UCC)-normalized rare earth elements and yttrium (REY) distribution patterns in the Permian coals. (UCC data are from Taylor and McLennan [56]).
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Figure 13. Relationship between selected elements/oxide and ash yield in Jurassic coals (CJG-1, 2, 3). CJG-1: (A) MgO-Ash yield; (B) Al2O3-SiO2; (C) Mn-CaO; (D)B-Ash yield. CJG-2: (E) CaO-Ash yield; (F) CaO- MgO; (G) Mn-MgO; (H)B-Ash yield. CJG-3: (I) SiO2-Ash yield; (J) Al2O3-Ash yield; (K) Al2O3-SiO2; (L)B-Ash yield.
Figure 13. Relationship between selected elements/oxide and ash yield in Jurassic coals (CJG-1, 2, 3). CJG-1: (A) MgO-Ash yield; (B) Al2O3-SiO2; (C) Mn-CaO; (D)B-Ash yield. CJG-2: (E) CaO-Ash yield; (F) CaO- MgO; (G) Mn-MgO; (H)B-Ash yield. CJG-3: (I) SiO2-Ash yield; (J) Al2O3-Ash yield; (K) Al2O3-SiO2; (L)B-Ash yield.
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Figure 14. Relationship between selected elements/oxide and ash yield in Permian coals/non-coals (PR-4). PR-4: (A) SiO2-Ash yield; (B) Al2O3-SiO2; (C) S-Ash yield; (D) Li-Ash yield. PR-4-coal: (E) Ga-Ash yield; (F) Nb-Ash yield; (G) Ta-Ash yield; (H) Th-Ash yield; (I) REY-Ash yield; (J) Sr-CaO; (K) Sr-P; (L) P-CaO.
Figure 14. Relationship between selected elements/oxide and ash yield in Permian coals/non-coals (PR-4). PR-4: (A) SiO2-Ash yield; (B) Al2O3-SiO2; (C) S-Ash yield; (D) Li-Ash yield. PR-4-coal: (E) Ga-Ash yield; (F) Nb-Ash yield; (G) Ta-Ash yield; (H) Th-Ash yield; (I) REY-Ash yield; (J) Sr-CaO; (K) Sr-P; (L) P-CaO.
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Figure 15. Al2O3-TiO2 cross-correlation plot for the Cuijiagou and Puran coals as well as partings and roof.
Figure 15. Al2O3-TiO2 cross-correlation plot for the Cuijiagou and Puran coals as well as partings and roof.
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Figure 16. Th/Sc-Zr/Sc cross-correlation plot for the Cuijiagou and Puran coals as well as partings and roof, comparing with the Junger and Daqingshan coals.
Figure 16. Th/Sc-Zr/Sc cross-correlation plot for the Cuijiagou and Puran coals as well as partings and roof, comparing with the Junger and Daqingshan coals.
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Table
Table 1. Proximate analysis (%) and S content (%) of the coal samples in the studied mines. M, moisture; A, ash yield; V, volatile yield; St, total sulfur; ad, air dry basis; d, dry basis; daf., dry and ash-free basis.
Table 1. Proximate analysis (%) and S content (%) of the coal samples in the studied mines. M, moisture; A, ash yield; V, volatile yield; St, total sulfur; ad, air dry basis; d, dry basis; daf., dry and ash-free basis.
SampleMad%Ad%Vdaf%St, d%
CJG-1-17.40 5.10 35.00 0.81
CJG-1-27.20 4.00 32.30 0.28
CJG-1-36.80 3.30 30.50 0.29
CJG-1-46.80 4.80 32.20 0.27
CJG-1-57.10 3.70 34.60 0.34
CJG-1-66.70 3.30 28.40 0.23
CJG-1-78.50 2.00 38.60 0.43
CJG-1-87.20 4.00 39.10 0.40
Average7.213.7833.840.38
CJG-2-15.40 6.00 38.30 0.38
CJG-2-25.30 21.90 47.00 0.27
CJG-2-35.50 7.10 38.70 0.29
CJG-2-46.20 17.00 43.50 0.28
CJG-2-55.10 5.00 40.60 0.51
CJG-2-67.00 2.30 38.90 0.28
CJG-2-76.10 2.70 41.30 0.27
CJG-2-86.00 2.30 40.10 0.35
CJG-2-95.60 2.40 37.90 0.34
Average5.807.4140.700.33
CJG-3-15.60 4.80 37.20 0.28
CJG-3-25.50 4.10 32.70 0.23
CJG-3-36.00 3.00 36.70 0.25
CJG-3-46.30 2.00 36.00 0.22
CJG-3-56.30 1.80 37.30 0.29
CJG-3-66.20 2.70 41.60 0.31
Average5.983.0736.920.26
PR-4-T1.10 79.50 76.70 0.05
PR-4-11.80 45.00 40.30 0.30
PR-4-2(P)1.40 76.90 69.90 0.05
PR-4-3(p)1.70 69.80 55.90 0.07
PR-4-41.80 61.60 48.90 0.20
PR-4-52.10 30.70 38.70 0.33
PR-4-62.40 22.10 41.70 0.35
PR-4-72.70 18.80 41.30 0.34
PR-4-82.90 15.30 41.90 0.44
Average (coals)2.3826.3840.780.35
Table
Table 2. Mineral contents in coals and non-coals as determined by X-ray diffraction (XRD) from the two coal mines (on whole-coal basis; unit in %, db.). The Numbers in this Table represent results of XRD; * represent mineral detected by scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM-EDS).
Table 2. Mineral contents in coals and non-coals as determined by X-ray diffraction (XRD) from the two coal mines (on whole-coal basis; unit in %, db.). The Numbers in this Table represent results of XRD; * represent mineral detected by scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM-EDS).
SampleKaoliniteCalciteDolomiteTobeliteApatite GalenaAnataseZirconBoehmite
PR-4-T68.3 1.78.6
PR-4-1431.3
PR-4-2 (P)75.9
PR-4-3 (P)68.7
PR-4-4 (P)59.8 0.7***
PR-4-527.3 2.8
PR-4-620.60.3* 0.7 **
PR-4-717.90.5
PR-4-89.45.5
SampleQuartzKaoliniteCalcitePyriteGypsumSideriteChamosite
CJG-1-11.60.42.30.30.1*
CJG-1-21.30.61.8
CJG-1-30.50.42.2
CJG-1-41.30.62.6
CJG-1-50.40.22.9
CJG-1-60.50.52
CJG-1-70.90.8
CJG-1-82.21.6
CJG-3-14.10.4 0.1
CJG-3-23.20.6 0.10.1
CJG-3-320.60.2
CJG-3-41.50.3 *
CJG-3-51.20.5
CJG-3-62.50.1
SampleQuartzKaoliniteCalciteDolomitePyriteSideriteAnkeriteGypsum
CJG-2-10.30.24.6 0.6
CJG-2-2 17.6 3.1
CJG-2-30.10.45.6 0.10.3
CJG-2-43.40.57.20.2 4.4 0.2
CJG-2-53.50.70.2 0.1 0.2
CJG-2-61.10.40.6 0.1
CJG-2-72.30.1 0.1
CJG-2-8 2.1
CJG-2-91.40.9
Table
Table 3. Major elements (%, db) content and geochemical ratios in coal and non-coal samples from the two studied coal mines.
Table 3. Major elements (%, db) content and geochemical ratios in coal and non-coal samples from the two studied coal mines.
SampleSiO2Al2O3CaOFe2O3K2OMgONa2OSiO2/Al2O3Al2O3/TiO2
CJG-1-11.751.121.091.390.040.060.071.629.5
CJG-1-21.561.490.790.270.040.060.071.164.1
CJG-1-30.671.110.820.310.040.050.060.697.3
CJG-1-41.451.481.250.300.040.060.07160.2
CJG-1-50.460.731.500.380.040.050.070.761.4
CJG-1-60.750.960.990.180.050.050.070.883.8
CJG-1-71.280.830.230.250.040.040.061.631.2
CJG-1-82.782.100.280.280.040.060.081.463.2
Average1.341.230.870.420.040.050.071.154.4
CJG-2-10.380.612.821.370.040.170.260.738.2
CJG-2-20.000.4815.443.210.040.830.130117.9
CJG-2-30.321.423.350.970.040.140.230.2133
CJG-2-43.482.244.4710.440.040.220.171.649.8
CJG-2-53.701.300.401.290.050.040.222.926.1
CJG-2-61.220.610.410.410.040.020.202.144.2
CJG-2-72.290.760.260.420.040.030.223.125.1
CJG-2-80.961.150.220.560.040.030.200.973.5
CJG-2-91.761.080.220.420.050.020.221.770.6
Average1.571.073.062.120.040.170.201.548.1
CJG-3-14.121.410.160.460.040.040.22340.6
CJG-3-23.311.200.210.620.040.070.222.944.4
CJG-3-32.180.790.250.680.040.060.202.943.8
CJG-3-41.600.590.150.480.040.040.192.847.8
CJG-3-51.350.600.130.540.040.030.182.353.9
CJG-3-62.440.690.140.330.040.020.163.749.6
Average2.500.880.170.520.040.040.192.944.4
PR-4-T34.8551.600.140.810.130.070.130.746.2
PR-4-119.2727.250.380.760.200.090.110.724.3
PR-4-2 (P)34.0239.450.130.670.140.070.120.933.3
PR-4-3 (P)30.7937.390.340.890.950.150.160.940.1
PR-4-4 (P)26.8439.150.760.880.190.070.110.738.6
PR-4-512.2521.161.900.420.110.040.070.663.8
PR-4-69.2210.410.620.370.040.040.060.935.1
PR-4-78.012.270.350.170.050.020.063.736.5
PR-4-84.222.401.480.350.040.050.051.845.5
Average (coal)10.5912.700.940.410.090.050.071.541.0
Table
Table 4. Trace elements concentrations (μg/g, db) in coals and non-coals from the two coal mines (on whole-coal basis). Average concentrations of Chinese coal date from Dai et al., [5].
Table 4. Trace elements concentrations (μg/g, db) in coals and non-coals from the two coal mines (on whole-coal basis). Average concentrations of Chinese coal date from Dai et al., [5].
SampleLiBeBPScVCrNiCuZnGaRbSrYZrNbBaLa
CJG-1-11.28.6104175.927358.13.25.76.9<dl3525.7115.55.35.7
CJG-1-21.5<dl7918<dl3.64.22.3<dl100.80<dl294.473.15.94.3
CJG-1-31.1<dl7118<dl3.53.32.2<dl7.7<dl<dl242.44.51.72.52.8
CJG-1-41.5<dl7417<dl3.84.13.01.56.4<dl<dl351.9113.0.3.63.0
CJG-1-5<dl<dl10419<dl5.82.97.31.618<dl<dl331.43.40.864.52.3
CJG-1-60.90<dl7020<dl4.23.12.61.28.0<dl<dl251.12.40.982.52.3
CJG-1-7<dl<dl15419<dl8.65.16.79.49.51.0<dl254.87.51.7143.5
CJG-1-81.64.6114171.1149.79.17.19.85.82.636216.52.7127.2
Average0.981.796180.888.88.45.23.09.41.80.33307.86.72.46.33.9
CJG-2-11.0<dl12318<dl2.52.72.51.712<dl<dl160<dl3.21.115<dl
CJG-2-20.84<dl13418<dl1.01.81.9<dl4.6<dl<dl323<dl1.0.<dl391.0
CJG-2-31.5<dl11418<dl1.42.32.11.44.3<dl<dl145<dl1.9<dl161.3
CJG-2-42.0<dl11317<dl6.34.82.74.37.71.41.92242.0112.5253.4
CJG-2-51.4<dl10419<dl2.12.92.32.84.4<dl<dl1462.093.1222.2
CJG-2-60.78<dl10618<dl1.82.33.01.55.0<dl<dl142<dl2.60.8519<dl
CJG-2-71.1<dl9619<dl2.02.82.51.93.5<dl<dl1590.855.42.0261.2
CJG-2-81.6<dl10016<dl6.12.43.61.66.0<dl<dl179<dl6.11.3192.0
CJG-2-91.1<dl7419<dl2.12.23.41.44.5<dl<dl1902.03.61.0182.2
Average1.3010718<dl2.82.72.71.85.80.160.211850.764.91.3221.5
CJG-3-11.41.38716<dl4.54.23.64.16.20.870.81935.07.12.5202.9
CJG-3-21.5<dl5818<dl3.23.32.22.24.9<dl<dl971.14.71.8172.2
CJG-3-31.1<dl8317<dl4.52.62.22.111<dl<dl84<dl3.51.3161.2
CJG-3-4<dl<dl8819<dl3.82.21.51.45.9<dl<dl63<dl2.1<dl11<dl
CJG-3-5<dl<dl11117<dl8.02.53.21.75.0<dl<dl62<dl2.3<dl111.2
CJG-3-60.832.211918<dl5.12.24.11.56.9<dl<dl565.03.11.1112.7
Average0.810.589118<dl4.92.82.82.26.70.150.14761.93.81.1141.7
Chinese coal322.1534024.435151418416.69.314018909.415923
SampleCePrNdSmGdDyHoErYbTaWPbThUΣREYLREYMREYHREYCe/Ce*
CJG-1-115.12.2112.93.44.91.13.64.02.51.53.61.7<dl7937348.70.99
CJG-1-27.60.843.4<dl<dl<dl<dl<dl<dl<dl1.1<dl1.2<dl21164.4<dl0.93
CJG-1-35.0<dl2.2<dl<dl<dl<dl<dl<dl1.0<dl<dl<dl<dl129.92.4<dl-
CJG-1-44.8<dl2.0<dl<dl<dl<dl<dl<dl<dl<dl<dl1.3<dl129.71.9<dl-
CJG-1-53.5<dl1.6<dl<dl<dl<dl<dl<dl<dl<dl0.87<dl<dl8.87.41.4<dl-
CJG-1-63.4<dl1.4<dl<dl<dl<dl<dl<dl0.99<dl1.0<dl<dl8.27.11.1<dl-
CJG-1-77.60.963.7<dl<dl<dl<dl<dl<dl1.03.32.01.1<dl21164.8<dl0.99
CJG-1-817.22.3102.42.73.2<dl2.01.7<dl3.33.51.70.87040273.70.98
Average80.794.40.660.761.00.140.70.710.691.11.40.880.1029189.61.50.97
CJG-2-11.3<dl<dl<dl<dl<dl<dl<dl<dl<dl<dl1.6<dl<dl1.31.3<dl<dl-
CJG-2-21.5<dl<dl<dl<dl<dl<dl<dl<dl0.82<dl1.1<dl<dl2.42.4<dl<dl-
CJG-2-32.1<dl0.82<dl<dl<dl<dl<dl<dl<dl<dl1.6<dl<dl4.24.2<dl<dl-
CJG-2-46.8<dl2.6<dl<dl<dl<dl<dl<dl<dl<dl2.61.0<dl1512.82.1<dl-
CJG-2-55.1<dl2.4<dl<dl<dl<dl<dl<dl<dl<dl1.6<dl<dl129.72.0<dl-
CJG-2-61.3<dl<dl<dl<dl<dl<dl<dl<dl1.0<dl1.8<dl<dl1.31.3<dl<dl-
CJG-2-71.9<dl0.88<dl<dl<dl<dl<dl<dl<dl<dl1.4<dl<dl4.73.90.88<dl-
CJG-2-82.9<dl1.1<dl<dl<dl<dl<dl<dl<dl<dl2.11.0<dl6.06.0<dl<dl-
CJG-2-94.8<dl2.2<dl<dl<dl<dl<dl<dl<dl1.01.9<dl<dl119.32.0<dl-
Average3.1<dl1.1<dl<dl<dl<dl<dl<dl0.200.111.70.22<dl6.45.61.7<dl-
CJG-3-16.3<dl3.3<dl<dl<dl<dl<dl<dl<dl3.63.00.78<dl17132.9<dl-
CJG-3-23.5<dl1.4<dl<dl<dl<dl<dl<dl<dl<dl1.8<dl<dl8.27.12.2<dl-
CJG-3-32.1<dl0.83<dl<dl<dl<dl<dl<dl<dl<dl1.6<dl<dl4.24.21.2<dl-
CJG-3-41.0<dl<dl<dl<dl<dl<dl<dl<dl<dl<dl1.4<dl<dl1.01.0<dl<dl-
CJG-3-51.9<dl0.78<dl<dl<dl<dl<dl<dl<dl<dl2.0<dl<dl3.93.91.2<dl-
CJG-3-65.2<dl2.7<dl<dl<dl<dl<dl<dl<dl2.62.4<dl<dl16112.7<dl-
Average3.3<dl1.5<dl<dl<dl<dl<dl<dl<dl1.02.00.13<dl8.46.61.7<dl-
Chinese coal476.4224.14.73.71.01.82.10.61.115.15.82.4-----
SampleLiBeBPScVCrNiCuZnGaRbSrYZrNbBaLaCePrNd
PR-4-T1713.3346367.8368.55.11132352.55620372947714334.317
PR-4-1759.6332279.844135.81241324564145513722934718.632
PR-4-2(P)1673.6355459.240105.71234363582543396841537.94.920
PR-4-3(P)1776.43318501555239.7212837256264143199232119188.81969
PR-4-4(P)1596.54233811238177.71132333.976241444211354114195.52077
PR-4-5564.24262565.7279.96.81315171.8420591533566856127.41669
PR-4-64124416323.8307.77.1111716<dl20721127311753766.97.327
PR-4-7201.5534261.3174.14.414138.2<dl1306.5466.4361731.23.312
PR-4-8161.464551<dl132.54.17.41210<dl1739.75912411936.94.014
Average (coal)423.74718184.1267.45.61120171.2197271684423033677.831
Chinese coal322.1534024.435151418416.69.314018909.415923476.422
SampleSmEuGdTbDyHoErYbHfTaWPbThUΣREYLREYMREYHREYBa/EuEu/Eu*Ce/Ce*
PR-4-T3.8<dl3.9<dl4.40.842.22.08.38.110.436197.110571285.0--0.99
PR-4-15.90.825.81.17.61.65.15.19.3139.749263.421915156122690.680.95
PR-4-2(P)4.6<dl4.90.865.61.02.82.4106.99.841257.312482366.1--1.02
PR-4-3(P)121.6111.79.51.74.84.19.59.31039265.048240764111480.660.91
PR-4-4(P)121.3111.69.41.85.24.8112210.838355.849441964122650.540.93
PR-4-5141.7142.0112.05.33.93.54.03.328125.838128387114020.570.96
PR-4-64.9<dl4.7<dl4.2<dl2.21.92.93.02.9208.23.3177142304.1--0.94
PR-4-72.0<dl1.7<dl1.4<dl<dl<dl1.1<dl1.0245.31.275669.7<dl--0.94
PR-4-82.5<dl2.3<dl2.0<dl1.10.901.3<dl2.1134.51.09377142.0--0.97
Average (coal)5.90.505.70.625.20.722.72.43.64.03.827112.9189144395.8-0.630.95
Chinese coal4.10.84.70.63.711.82.13.70.61.115.15.82.4-------
db-dry basis; <dl, below detection limit.

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Shangguan, Y.; Zhuang, X.; Li, J.; Li, B.; Querol, X.; Liu, B.; Moreno, N.; Yuan, W.; Yang, G.; Pan, L. Geological Controls on Mineralogy and Geochemistry of the Permian and Jurassic Coals in the Shanbei Coalfield, Shaanxi Province, North China. Minerals 2020, 10, 138. https://doi.org/10.3390/min10020138

AMA Style

Shangguan Y, Zhuang X, Li J, Li B, Querol X, Liu B, Moreno N, Yuan W, Yang G, Pan L. Geological Controls on Mineralogy and Geochemistry of the Permian and Jurassic Coals in the Shanbei Coalfield, Shaanxi Province, North China. Minerals. 2020; 10(2):138. https://doi.org/10.3390/min10020138

Chicago/Turabian Style

Shangguan, Yunfei, Xinguo Zhuang, Jing Li, Baoqing Li, Xavier Querol, Bo Liu, Natalia Moreno, Wei Yuan, Guanghua Yang, and Lei Pan. 2020. "Geological Controls on Mineralogy and Geochemistry of the Permian and Jurassic Coals in the Shanbei Coalfield, Shaanxi Province, North China" Minerals 10, no. 2: 138. https://doi.org/10.3390/min10020138

APA Style

Shangguan, Y., Zhuang, X., Li, J., Li, B., Querol, X., Liu, B., Moreno, N., Yuan, W., Yang, G., & Pan, L. (2020). Geological Controls on Mineralogy and Geochemistry of the Permian and Jurassic Coals in the Shanbei Coalfield, Shaanxi Province, North China. Minerals, 10(2), 138. https://doi.org/10.3390/min10020138

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