Coatings

8 pages, 3225 KiB

Open AccessArticle

Preparation and Characterization of Sprayed-Yttrium Oxyfluoride Corrosion Protective Coating for Plasma Process Chambers

by Tzu-Ken Lin, Dong-Sing Wuu, Shih-Yung Huang and Wei-Kai Wang

Coatings 2018, 8(10), 373; https://doi.org/10.3390/coatings8100373 - 22 Oct 2018

Cited by 27 | Viewed by 5879

Abstract

This study investigates the microstructure, mechanical and electrical properties of dense yttrium oxyfluoride (YOF) coatings fabricated by the atmospheric plasma spraying technique. Transmission electron microscopy and X-ray diffraction analysis revealed a well crystallized YOF coating with preferred orientations. The YOF coatings were more [...] Read more.

This study investigates the microstructure, mechanical and electrical properties of dense yttrium oxyfluoride (YOF) coatings fabricated by the atmospheric plasma spraying technique. Transmission electron microscopy and X-ray diffraction analysis revealed a well crystallized YOF coating with preferred orientations. The YOF coatings were more porous (approximate porosity 0.5%), with higher hardness (290 ± 30 HV), lower electrical resistivity (10¹⁶ Ω⋅cm), and breakdown voltage (5.57 kV), than conventional yttrium-fluoride plasma-protective coating. These results indicate the potential of the YOF coating as a novel antiplasma and corrosion-resistant ceramic. Full article

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13 pages, 1451 KiB

Open AccessArticle

Effects of Chitosan-Based Coatings Enriched with Cinnamaldehyde on Mandarin Fruit cv. Ponkan during Room-Temperature Storage

by Yang Gao, Chaonan Kan, Ming Chen, Chuying Chen, Yuhuan Chen, Yongqi Fu, Chunpeng Wan and Jinyin Chen

Coatings 2018, 8(10), 372; https://doi.org/10.3390/coatings8100372 - 22 Oct 2018

Cited by 25 | Viewed by 3973

Abstract

The current work aimed to evaluate the efficacy of four coating formulations—chitosan coating (CH), 0.5% cinnamaldehyde + chitosan (0.5% CI–CH), 1.0% cinnamaldehyde + chitosan (1.0% CI–CH), and 1.5% cinnamaldehyde + chitosan (1.5% CI–CH)—on fresh mandarin fruit cv. Ponkan quality maintenance (weight loss, decay [...] Read more.

The current work aimed to evaluate the efficacy of four coating formulations—chitosan coating (CH), 0.5% cinnamaldehyde + chitosan (0.5% CI–CH), 1.0% cinnamaldehyde + chitosan (1.0% CI–CH), and 1.5% cinnamaldehyde + chitosan (1.5% CI–CH)—on fresh mandarin fruit cv. Ponkan quality maintenance (weight loss, decay rate, total soluble solids, titratable acidity, vitamin C, color index, malondialdehyde, and antioxidant activity) over 100 days of storage at 20 °C. Compared to the control, chitosan treatment effectively reduced the decay and weight loss rates of mandarin fruit cv. Ponkan during storage at room temperature, delayed the decline of nutritional quality in fruits, increased the antioxidant capacity, and inhibited the accumulation of malondialdehyde (MDA). In comparison to chitosan coating, 1.5% CI–CH did not improve the fruit storage effect, but inhibited the normal color change of fruits and increased the accumulation of MDA. Both 0.5% CI–CH and 1.0% CI–CH effectively reduced the rate of fruit decay, improved the quality of fruits after harvest, and delayed fruit aging. Our study suggests that 0.5% CI–CH and 1.0% CI–CH might be good formulations for maintaining the quality of mandarin fruit cv. Ponkan during room-temperature storage. Full article

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17 pages, 8458 KiB

Open AccessArticle

In Situ Study of Road Marking Durability Using Glass Microbeads and Antiskid Aggregates as Drop-On Materials

by Andrés Coves-Campos, Luis Bañón, José Andrés Coves-García and Salvador Ivorra

Coatings 2018, 8(10), 371; https://doi.org/10.3390/coatings8100371 - 21 Oct 2018

Cited by 11 | Viewed by 5242

Abstract

Road markings play an important role in road safety because they provide significant information to drivers about the road. For that reason, they must be replaced when they are not correctly perceived by road users. To analyse which are the main factors that [...] Read more.

Road markings play an important role in road safety because they provide significant information to drivers about the road. For that reason, they must be replaced when they are not correctly perceived by road users. To analyse which are the main factors that affect road marking perception over time, a test section was designed in a two-lane rural highway, running actual traffic over 18 different types of markings fabricated with different combinations of drop-on materials. Chromatic coordinates, luminance, and retroreflectivity of each sample were measured during 18 months in order to study their evolution over time. The results obtained show different behaviours depending on the aggregates and application method used. An increment of the durability has been observed with the use of different layers and mixtures of glass microbeads with different sizes. Full article

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15 pages, 5332 KiB

Open AccessArticle

Structure, Mechanical and Tribological Properties of Me-Doped Diamond-Like Carbon (DLC) (Me = Al, Ti, or Nb) Hydrogenated Amorphous Carbon Coatings

by Imane Bouabibsa, Salim Lamri and Frederic Sanchette

Coatings 2018, 8(10), 370; https://doi.org/10.3390/coatings8100370 - 19 Oct 2018

Cited by 46 | Viewed by 7544

Abstract

Metal containing hydrogenated diamond-like carbon coatings (Me-DLC, Me = Al, Ti, or Nb) of 3 ± 0.2 μm thickness were deposited by a magnetron sputtering-RFPECVD hybrid process in an Ar/H₂/C₂H₂ mixture. The composition and structure were investigated by [...] Read more.

Metal containing hydrogenated diamond-like carbon coatings (Me-DLC, Me = Al, Ti, or Nb) of 3 ± 0.2 μm thickness were deposited by a magnetron sputtering-RFPECVD hybrid process in an Ar/H₂/C₂H₂ mixture. The composition and structure were investigated by Energy Dispersive X-ray Spectroscopy (EDS), X-ray Diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. The residual stress was measured using the curvature method and nanoindentation was used to determine the hardness and the Young’s modulus. A Ball-on-disk tribometer was employed to investigate the frictional properties and sliding wear resistance of films. The results show that the properties depend on the nature and the Me content in the coatings. The doping of the DLC coatings leads to a decrease in hardness, Young’s modulus, and residual stresses. Wear rate of the films first decreases with intermediate Me contents and then increases for higher Me contents. Significant improvements in the friction coefficient on steel as well as in the wear rate are observed for all Al-DLC coatings, and, concerning the friction coefficient, the lowest value is measured at 0.04 as compared to 0.07 for the undoped DLC. Full article

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16 pages, 4315 KiB

Open AccessFeature PaperArticle

Structural and Optical Properties of Luminescent Copper(I) Chloride Thin Films Deposited by Sequentially Pulsed Chemical Vapour Deposition

by Richard Krumpolec, Tomáš Homola, David C. Cameron, Josef Humlíček, Ondřej Caha, Karla Kuldová, Raul Zazpe, Jan Přikryl and Jan M. Macak

Coatings 2018, 8(10), 369; https://doi.org/10.3390/coatings8100369 - 18 Oct 2018

Cited by 11 | Viewed by 5074

Abstract

Sequentially pulsed chemical vapour deposition was used to successfully deposit thin nanocrystalline films of copper(I) chloride using an atomic layer deposition system in order to investigate their application to UV optoelectronics. The films were deposited at 125 °C using [Bis(trimethylsilyl)acetylene](hexafluoroacetylacetonato)copper(I) as a Cu [...] Read more.

Sequentially pulsed chemical vapour deposition was used to successfully deposit thin nanocrystalline films of copper(I) chloride using an atomic layer deposition system in order to investigate their application to UV optoelectronics. The films were deposited at 125 °C using [Bis(trimethylsilyl)acetylene](hexafluoroacetylacetonato)copper(I) as a Cu precursor and pyridine hydrochloride as a new Cl precursor. The films were analysed by XRD, X-ray photoelectron spectroscopy (XPS), SEM, photoluminescence, and spectroscopic reflectance. Capping layers of aluminium oxide were deposited in situ by ALD (atomic layer deposition) to avoid environmental degradation. The film adopted a polycrystalline zinc blende-structure. The main contaminants were found to be organic materials from the precursor. Photoluminescence showed the characteristic free and bound exciton emissions from CuCl and the characteristic exciton absorption peaks could also be detected by reflectance measurements. Full article

(This article belongs to the Special Issue Atomic Layer Deposition)

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14 pages, 5038 KiB

Open AccessArticle

Development of Silane-Based Coatings with Zirconia Nanoparticles Combining Wetting, Tribological, and Aesthetical Properties

by Sara Lopez de Armentia, Mariola Pantoja, Juana Abenojar and Miguel Angel Martinez

Coatings 2018, 8(10), 368; https://doi.org/10.3390/coatings8100368 - 18 Oct 2018

Cited by 27 | Viewed by 6462

Abstract

Silane-based coatings with nanoparticles have been widely used in applications related to surface protection. Between them, the improvement of corrosion resistance by increasing the hydrophobicity is one of the main research goals. However, most coatings present problems of low wear resistance and poor [...] Read more.

Silane-based coatings with nanoparticles have been widely used in applications related to surface protection. Between them, the improvement of corrosion resistance by increasing the hydrophobicity is one of the main research goals. However, most coatings present problems of low wear resistance and poor aesthetic appearance. Therefore, the overall goal of this research is to manufacture hydrophobic sol-gel coatings based on silanes which comply with good tribological and aesthetical properties. In the present study, stainless steel plates were coated with a silane-based solution containing zirconia nanoparticles by dip coating. Water–ethanol solutions with silanes (methyltrimethoxysilane (MTS) and tetrathoxysilane (TEOS)) and different percentages of ZrO₂ nanoparticles were prepared. Gloss, color, contact angle, surface energy, wear resistance, and thickness of coating were analyzed to elucidate the effect of zirconium oxide on the performance of the coatings. Results demonstrate that the ZrO₂–silane coatings on stainless steel offer a balanced combination of properties: low wettability, high wear resistance, and similar color and brightness compared to pristine stainless steel. Full article

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9 pages, 6223 KiB

Open AccessArticle

Numerical and Experimental Investigation on Bonding Behavior of Cold Sprayed Porous WC-17Co Particles onto Different Substrates

by Xinkun Suo, Shuo Yin, Hua Li and Rocco Lupoi

Coatings 2018, 8(10), 367; https://doi.org/10.3390/coatings8100367 - 17 Oct 2018

Cited by 7 | Viewed by 3194

Abstract

Cold sprayed WC-Co metal matrix composite coatings have shown great potential in wear-resistance applications. This work aims to use experimental and numerical methods to clarify the deposition and particle–substrate bonding behavior of a single porous WC-17Co particle onto various substrates. To achieve this [...] Read more.

Cold sprayed WC-Co metal matrix composite coatings have shown great potential in wear-resistance applications. This work aims to use experimental and numerical methods to clarify the deposition and particle–substrate bonding behavior of a single porous WC-17Co particle onto various substrates. To achieve this objective, porous WC-17Co particles were used as the feedstock; soft Al 2024 (Al alloy) and hard stainless steel 316 (SS) were used as the substrates. The experimental results revealed that brittle WC-Co particles tended to remain intact after depositing on a soft Al alloy substrate, but underwent serious fracture when impacting on a hard SS substrate. Further results indicated that the high energy dissipation and the consequent high stress concentration in the WC-Co particle was the main reason for inducing the particle fracture. In addition, two different mechanical interlocking mechanisms were identified during the WC-Co particle deposition process (namely WC reinforcement interlock and WC-Co particle interlock), dominating the particle-substrate bonding. A soft Al alloy substrate resulted in better interlocking than a hard SS substrate, thereby the corresponding particle bonding ratio was also much higher. Full article

(This article belongs to the Special Issue From Metallic Coatings to Additive Manufacturing)

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19 pages, 1970 KiB

Open AccessReview

Edible Films and Coatings for Fresh Fish Packaging: Focus on Quality Changes and Shelf-life Extension

by Maria-Ioana Socaciu, Cristina Anamaria Semeniuc and Dan Cristian Vodnar

Coatings 2018, 8(10), 366; https://doi.org/10.3390/coatings8100366 - 16 Oct 2018

Cited by 55 | Viewed by 9215

Abstract

Fresh fish is extensively consumed and is one of the most-traded food commodities in the world. Conventional preservation technologies include vacuum and modified atmosphere packaging, but they are costly since requires capital investment. In the last decade, research has been directed towards the [...] Read more.

Fresh fish is extensively consumed and is one of the most-traded food commodities in the world. Conventional preservation technologies include vacuum and modified atmosphere packaging, but they are costly since requires capital investment. In the last decade, research has been directed towards the development of antimicrobial packaging systems, as an economical alternative to these. This paper outlines antimicrobial films and coatings applied so far on fresh fish, their efficacy against targeted microorganism/group and effects on chemical quality of the product. Findings show that edible films/coatings incorporated with different active agents applied to fresh fish are able to inhibit the microbial growth and decrease the rate of fish nutrients degradation, thus preventing the formation of chemical metabolites; a shelf-life extension of 6 to 13 days was obtained for fish fillets, depending on the species on which the active packaging materials were applied. The manufacturing use of these formulations could lead to a significant reduction in fish waste, consequently, a diminution of economic losses for fish traders and retailers. Therefore, their industrial production and commercialization could be an exploitable sector by the packaging industry. Full article

(This article belongs to the Special Issue Advances in Antimicrobial Coatings)

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15 pages, 4557 KiB

Open AccessArticle

Improvement of Corrosion Protection of Coating System via Inhibitor Response Order

by Mei Yu, Xiangni Zhao, Liangliang Xiong, Bing Xue, Xiangxin Kong, Jianhua Liu and Songmei Li

Coatings 2018, 8(10), 365; https://doi.org/10.3390/coatings8100365 - 16 Oct 2018

Cited by 12 | Viewed by 4363

Abstract

This study aims at investigating the effect of inhibitor response order on anticorrosion properties of AA2024 with coating system. The inhibitor response order was constructed by adding different inhibitor in sol-gel primer or epoxy top coating of the coating system. Nanocontainers of graphene [...] Read more.

This study aims at investigating the effect of inhibitor response order on anticorrosion properties of AA2024 with coating system. The inhibitor response order was constructed by adding different inhibitor in sol-gel primer or epoxy top coating of the coating system. Nanocontainers of graphene oxide/layered double hydroxides (GO/LDHs) were loaded with 2-mercaptobenzothiazole (MBT) and vanadate separately to get the inhibitors of GO/LDHs-MBT and GO/LDHs-VO_x, which were used in this work. The protection performances of the coating systems with different inhibitor combination and different inhibitor response order were investigated. The best protective coating system is composed of sol-gel coating with GO/LDHs-MBT and epoxy coating with GO/LDHs-VO_x. It is contributed to inhibitor combination and a proper response order of the inhibitors. When filiform corrosion occurs, MBT anions from the sol-gel coating are close to the alloy and they inhibit the corrosion in anodic areas immediately, and then vanadate anions from the out and thick epoxy coating reduce the kinetics of the cathodic oxygen reduction reaction. Response order enhances the corrosion protection properties provided by inhibitor combination, which gives a promising way to design good anticorrosive coating system. Full article

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13 pages, 6382 KiB

Open AccessArticle

Superhydrophobic Bio-Coating Made by Co-Continuous Electrospinning and Electrospraying on Polyethylene Terephthalate Films Proposed as Easy Emptying Transparent Food Packaging

by Maria Pardo-Figuerez, Alex López-Córdoba, Sergio Torres-Giner and José M. Lagaron

Coatings 2018, 8(10), 364; https://doi.org/10.3390/coatings8100364 - 16 Oct 2018

Cited by 29 | Viewed by 5782

Abstract

Interest in coated films with micro/nanofeatures has grown rapidly in recent years due to their enhanced functional performance and better durability under demanding contact conditions or aggressive environments. In the current work, it is reported a one-step co-continuous bilayer coating process to generate [...] Read more.

Interest in coated films with micro/nanofeatures has grown rapidly in recent years due to their enhanced functional performance and better durability under demanding contact conditions or aggressive environments. In the current work, it is reported a one-step co-continuous bilayer coating process to generate a multilayer film that rendered superhydrophobicity to a polyethylene terephthalate (PET) substrate. A continuous coating based on ultrathin polylactide (PLA) fibers was deposited onto PET films by means of electrospinning, which increased the water contact angle of the substrate. Sequentially, nanostructured silica (SiO₂) microparticles were electrosprayed onto the coated PET/PLA films to achieve superhydrophobic behavior. This multilayer was then treated at different annealing temperatures, that is, 150 °C, 160 °C, and 170 °C, in order to create interlayers’ adhesion to each other and to the substrate. It was found that co-continuous deposition of PLA fibers and nanostructured SiO₂ microparticles onto PET films constituted a useful strategy to increase the surface hydrophobicity of the PET substrate, achieving an optimal apparent water contact angle of 170° and a sliding angle of 6°. Unfortunately, a reduction in background transparency was observed compared to the uncoated PET film, especially after electrospraying of the SiO₂ microparticles but the films were seen to have a good contact transparency. The materials developed show significant potential in easy emptying transparent food packaging applications. Full article

(This article belongs to the Special Issue Functional Coatings for Food Packaging Applications)

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24 pages, 8564 KiB

Open AccessArticle

Novel Coatings on Zirconia for Improved Bonding with Veneer Ceramics

by Fenik K. Muhammed, Sarah Pollington, Xudong Sun, Adil O. Abdullah and Yi Liu

Coatings 2018, 8(10), 363; https://doi.org/10.3390/coatings8100363 - 12 Oct 2018

Cited by 10 | Viewed by 5208

Abstract

This study aimed to compare the effects of two surface-coating methods on the shear bond strength (SBS) of veneering ceramics (VC) to zirconia. Eighty pre-sintered zirconia cubes were randomly assigned into four study groups: E60S, E60P, N60S, and N60P. The zirconia surface was [...] Read more.

This study aimed to compare the effects of two surface-coating methods on the shear bond strength (SBS) of veneering ceramics (VC) to zirconia. Eighty pre-sintered zirconia cubes were randomly assigned into four study groups: E60S, E60P, N60S, and N60P. The zirconia surface was coated with a mixture of two types of glaze and alumina (<60 μm) by airbrush spraying and fine- brush painting. Surface roughness (R_a), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and SBS measurements (both initial and artificial aged conditions, including one month of water storage) were performed. The R_a results revealed significant differences among all groups (p < 0.001). The N60P group exhibited higher values of R_a (5.717 ± 0.20 µm) and SBS before and after water storage with values of 37.22 ± 4.954 MPa and 34.42 ± 3.977 MPa, respectively. The fine-brush coatings showed significantly higher SBS than that of airbrush coatings, in both initial and artificial conditions. Both coating methods and various coating materials (p < 0.001) produced a significant influence on VC-zirconia SBS. A significant correlation between R_a and SBS (Spearman’s rho = 0.808; p < 0.001) was found. The novel coating by fine-brush painting is a promising surface treatment and an easy technique for obtaining a rougher surface, which subsequently improves the bond strength to VC. Full article

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13 pages, 4872 KiB

Open AccessArticle

Temperature–Power Simultaneous Effect on Physical Properties of Ba_xSr_1−x TiO₃ Thin Films Deposited by RF–Magnetron Cosputtering for 0 ≤ x ≤1

by Juan Reséndiz-Muñoz, Jorge Estrada-Martínez, Miguel Ángel Meléndez-Lira, Orlando Zelaya-Ángel, José De Jesús Medel-Juárez, Felipe Caballero-Briones and José Luis Fernández-Muñoz

Coatings 2018, 8(10), 362; https://doi.org/10.3390/coatings8100362 - 12 Oct 2018

Cited by 4 | Viewed by 3095

Abstract

The combined effect on the variation of the in-situ deposition temperature and the variation of the applied power on the deposition rate (DR), gap energy (E_g), and resistivity (ρ) in barium strontium titanate thin films, deposited into RF (radio frequency)–magnetron [...] Read more.

The combined effect on the variation of the in-situ deposition temperature and the variation of the applied power on the deposition rate (DR), gap energy (E_g), and resistivity (ρ) in barium strontium titanate thin films, deposited into RF (radio frequency)–magnetron cosputtering equipment, are presented in this research. The simultaneous action of two magnetrons (BaTiO₃ and SrTiO₃) is explained using the first and second derivative of Boltzmann’s sigmoidal equation. This found that a deposition gradient is a very novel analysis. Using the color-code lines built through MATLAB^® and analyzing the trend information, taking into account the influence of the calculated “x” parameter, by means of the Boltzmann’s sigmoidal equation fit, we propose a method to set up an RF–magnetron cosputtering system to predict the DR(x,T), E_g(x,T), and ρ(x,T) values of Ba_xSr_1−xTiO₃ solid solutions with 0 ≤ x ≤ 1 for amorphous and crystalline phases. This method can be a versatile tool to optimize the deposition process with, or without, in situ deposition temperature. Full article

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13 pages, 6479 KiB

Open AccessArticle

Isothermal Oxidation Behavior of Zr-Y Coating on γ-TiAl by Double Glow Plasma Surface Metal Alloying Technique

by Feng Ding, Pingze Zhang, Dongbo Wei, Xiaohu Chen, Shiyuan Wang, Zhangzhong Wang and Yimin Zhu

Coatings 2018, 8(10), 361; https://doi.org/10.3390/coatings8100361 - 12 Oct 2018

Cited by 4 | Viewed by 3232

Abstract

Oxidation resistance of Zr-Y coating on γ-TiAl alloy prepared by a double-glow plasma surface alloying technique was investigated in static air at 750 °C, 800 °C and 850 °C for 100 h. A pure Zr coating was also prepared for comparison. Addition of [...] Read more.

Oxidation resistance of Zr-Y coating on γ-TiAl alloy prepared by a double-glow plasma surface alloying technique was investigated in static air at 750 °C, 800 °C and 850 °C for 100 h. A pure Zr coating was also prepared for comparison. Addition of Y improved high-temperature oxidation resistance of the alloying coating because of its refining effect and inhibition of cationic diffusion. Oxidation kinetic curves indicated that the high-temperature oxidation resistance of the Zr-Y coating was about eight times higher than that of the bare substrate and about 3 times higher than that of pure Zr coating. Full article

(This article belongs to the Special Issue Advanced Coatings for Corrosion Protection in Extreme Environments)

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11 pages, 3406 KiB

Open AccessArticle

Design and Fabrication of Moth-Eye Subwavelength Structure with a Waist on Silicon for Broadband and Wide-Angle Anti-Reflection Property

by He Lin, Mingzhao Ouyang, Bingxu Chen, Qifan Zhu, Jinshuang Wu, Nan Lou, Litong Dong, Zuobin Wang and Yuegang Fu

Coatings 2018, 8(10), 360; https://doi.org/10.3390/coatings8100360 - 9 Oct 2018

Cited by 24 | Viewed by 7274

Abstract

Reflection loss on the optical component surface is detrimental to performance. Several researchers have discovered that the eyes of moths are covered with micro- and nanostructured films that reduce broadband and wide-angle light reflection. This research proposes a new type of moth-eye subwavelength [...] Read more.

Reflection loss on the optical component surface is detrimental to performance. Several researchers have discovered that the eyes of moths are covered with micro- and nanostructured films that reduce broadband and wide-angle light reflection. This research proposes a new type of moth-eye subwavelength structure with a waist, which is equivalent to a gradient refractive index film layer with high–low–high hyperbolic-type fill factor distribution. The diffraction order characteristics of a moth-eye subwavelength structure are first analyzed using a rigorous coupled wave analysis. The moth-eye structural parameters are optimized within the spectral range of 2–5 μm using the finite-difference time-domain method. The experimental fabrication of the moth-eye structure with a waist array upon a silicon substrate is demonstrated by using three-beam laser interferometric lithography and an inductively coupled plasma process. The experimental and simulation results show good agreement. The experimental results show that the reflectivity of the moth-eye structure with a waist is less than 1.3% when the incidence angle is less than 30°, and less than 4% when the incidence angle is less than 60°. This research can guide the development of AR broadband optical components and wide-angle applications. Full article

(This article belongs to the Special Issue Applications of Optical Thin Film Coatings)

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8 pages, 984 KiB

Open AccessArticle

Effects of Air Exposure on Hard and Soft X-ray Photoemission Spectra of Ultrananocrystalline Diamond/Amorphous Carbon Composite Films

by Mohamed Egiza, Hiroshi Naragino, Aki Tominaga, Kenji Hanada, Kazutaka Kamitani, Takeharu Sugiyama, Eiji Ikenaga, Koki Murasawa, Hidenobu Gonda, Masatoshi Sakurai and Tsuyoshi Yoshitake

Coatings 2018, 8(10), 359; https://doi.org/10.3390/coatings8100359 - 9 Oct 2018

Cited by 12 | Viewed by 3402

Abstract

Hard X-ray photoemission spectroscopy (HAXPES) was employed for the structural evaluation of ultrananocrystalline diamond/amorphous carbon (UNCD/a-C) composite films deposited on cemented carbide substrates, at substrate temperatures up to 550 °C by coaxial arc plasma deposition. The results were compared with those of soft [...] Read more.

Hard X-ray photoemission spectroscopy (HAXPES) was employed for the structural evaluation of ultrananocrystalline diamond/amorphous carbon (UNCD/a-C) composite films deposited on cemented carbide substrates, at substrate temperatures up to 550 °C by coaxial arc plasma deposition. The results were compared with those of soft X-ray photoemission spectroscopy (SXPES). Since nanocrystalline diamond grains are easily destroyed by argon ion bombardment, the structural evaluation of UNCD/a-C films, without the argon ion bombardment, is preferable for precise evaluation. For samples that were preserved in a vacuum box after film preparation, the sp³ fraction estimated from HAXPES is in good agreement with that of SXPES. The substrate temperature dependencies also exhibited good correspondence with that of hardness and Young’s modulus of the films. On the other hand, the sp³ fraction estimated from SXPES for samples that were not preserved in the vacuum box had an apparent deviation from those of HAXPES. Since it is possible for HAXPES to precisely estimate the sp³ fraction without the ion bombardment treatment, HAXPES is a feasible method for UNCD/a-C films, comprising nanocrystalline diamond grains. Full article

(This article belongs to the Special Issue Thin Film Deposition and Characterization Techniques)

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9 pages, 4984 KiB

Open AccessArticle

Magnetic Properties and Microstructure of FePt(BN, Ag, C) Films

by Jai-Lin Tsai, Yu-Ren Chen, Jyun-You Chen, Ting-Wei Hsu, Cheng Dai and Chia-Jen Hsu

Coatings 2018, 8(10), 358; https://doi.org/10.3390/coatings8100358 - 9 Oct 2018

Cited by 2 | Viewed by 2989

Abstract

The microstructure and magnetic properties of FePt(BN, Ag, C) granular films grown on the MgTiON intermediate layer with and without the MoC inserting layer were studied. Without the MoC inserting layer, the 6 nm thick FePt film is continuous, which favors the domain [...] Read more.

The microstructure and magnetic properties of FePt(BN, Ag, C) granular films grown on the MgTiON intermediate layer with and without the MoC inserting layer were studied. Without the MoC inserting layer, the 6 nm thick FePt film is continuous, which favors the domain wall motion magnetization reversal process and shows a lower out-of-plane coercivity (H_c) value of 6.7 kOe. The FePt(BN, Ag, C) granular film was grown in ball- and square-like grains with an almost vertical contact angle, and the out-of-plane coercivity (H_c) was increased to 15.5 kOe. When the MoC with a thickness of 3 nm was capped on the MgTiON intermediate layer, the FePt grains with and without (BN, Ag, C) segregants were both formed in large trapezoidal islands with a low contact angle morphology. The out-of-plane H_c value changed from 14.9 to 13.2 kOe and the reduced coercivity was due to larger grain sizes and a lower ordering degree of the FePt(BN, Ag, C) film. Full article

(This article belongs to the Special Issue Advanced Thin Films Deposited by Magnetron Sputtering)

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12 pages, 3303 KiB

Open AccessArticle

Preparation of Nano-Hydroxyapatite Coated Carbon Nanotube Reinforced Hydroxyapatite Composites

by Xueni Zhao, Xueyan Chen, Li Zhang, Qingyao Liu, Yao Wang, Weigang Zhang and Jiamei Zheng

Coatings 2018, 8(10), 357; https://doi.org/10.3390/coatings8100357 - 8 Oct 2018

Cited by 24 | Viewed by 4487

Abstract

Uniform and dense nano-hydroxyapatite (nHA) coating with nanorod-shaped structure was fabricated on carbon nanotubes (CNTs) by combining electrodeposition with biomineralization. The CNTs with nHA coating (nHA–CNTs) were used as reinforcement to improve the mechanical properties of HA. Firstly, a mixed acid solution of [...] Read more.

Uniform and dense nano-hydroxyapatite (nHA) coating with nanorod-shaped structure was fabricated on carbon nanotubes (CNTs) by combining electrodeposition with biomineralization. The CNTs with nHA coating (nHA–CNTs) were used as reinforcement to improve the mechanical properties of HA. Firstly, a mixed acid solution of nitric acid and sulfuric acid was used to treat CNTs (NS–CNTs). The dispersion of NS–CNTs was obviously improved, and O-containing functional groups were grafted on the surfaces of NS–CNTs by treatment. Then, calcium phosphate (CaP) was deposited on NS–CNTs by electrodeposition, and NS–CNTs were provided with numerous active nucleation sites for the next coating preparation process. Then nanorod-shaped HA crystals were obtained on the surfaces of NS–CNTs by biomineralization. Using the CNTs with nHA coating (nHA–CNTs) as reinforcement, HA-based composites reinforced with CNTs and nHA–CNTs (nHA–CNTs/HA) were fabricated by pressure-less process. Bending strength and fracture toughness of 1.0 wt % nHA–CNTs reinforced HA composites (HAnC1) reaches a maximum (30.77 MPa and 2.59 MPa), which increased by 26.94% and 7.02% compared with 1.0 wt % CNTs reinforced HA composites, respectively. Importantly, the fracture toughness of HAnC1 is within the range of that to compact bone. This work provides theoretical and practical guidance for preparing nHA coating on nanomaterials. It also contributes to the potential application of nHA–CNTs/HA composites for artificial bone implants. Full article

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23 pages, 5407 KiB

Open AccessArticle

TiO₂ Nanocrystal Based Coatings for the Protection of Architectural Stone: The Effect of Solvents in the Spray-Coating Application for a Self-Cleaning Surfaces

by Francesca Petronella, Antonella Pagliarulo, Alessandra Truppi, Mariateresa Lettieri, Maurizio Masieri, Angela Calia, M. Lucia Curri and Roberto Comparelli

Coatings 2018, 8(10), 356; https://doi.org/10.3390/coatings8100356 - 5 Oct 2018

Cited by 24 | Viewed by 4910

Abstract

A colloidal route was exploited to synthesize TiO₂ anisotropic nanocrystal rods in shape (TiO₂ NRs) with a surface chemistry suited for their dispersibility and processability in apolar organic solvents. TiO₂ NRs were dispersed in chloroform and n-heptane, respectively, and the [...] Read more.

A colloidal route was exploited to synthesize TiO₂ anisotropic nanocrystal rods in shape (TiO₂ NRs) with a surface chemistry suited for their dispersibility and processability in apolar organic solvents. TiO₂ NRs were dispersed in chloroform and n-heptane, respectively, and the two resulting formulations were investigated to identify the optimal conditions to achieve high-quality TiO₂ NR-based coatings by the spray-coating application. In particular, the two types of TiO₂ NR dispersions were first sprayed on silicon chips as a model substrate in order to preliminarily investigate the effect of the solvent and of the spraying time on the morphology and uniformity of the resulting coatings. The results of the SEM and AFM characterizations of the obtained coatings indicated n-heptane as the most suited solvent for TiO₂ NR dispersion. Therefore, an n-heptane dispersion of TiO₂ NRs was sprayed on a highly porous limestone—Lecce stone—very commonly used as building material in historic constructions and monuments present in Apulia Region (Italy). A comprehensive physical-chemical investigation of the TiO₂ NR based treatment on the surface of the stone specimens, including measurements of colour variation, static contact angle, water transfer properties, and morphological characterization were performed. Finally, the photocatalytic properties of the coatings were assessed under solar irradiation by using Lecce stone specimens and Methyl Red as a model target compound. The obtained results demonstrated that TiO₂ NRs based coatings can be successfully applied by spray-coating resulting in an effective photocatalytic and hydrophobic treatment, which holds great promise as a material for the environmental protection of architectural stone in the field of cultural heritage conservation. Full article

(This article belongs to the Special Issue Nanostructured Thin Films)

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20 pages, 11066 KiB

Open AccessArticle

Texturing Effect of Crater-Like Cavities Induced by High-Current Pulsed Electron Beam (HCPEB) Irradiation

by Bo Wu, Guangze Tang, Xiaoli Zhao, Liqin Wang and Le Gu

Coatings 2018, 8(10), 355; https://doi.org/10.3390/coatings8100355 - 5 Oct 2018

Viewed by 2969

Abstract

High-current pulsed electron beam (HCPEB) irradiation commonly induces crater-like cavities on irradiated surfaces, making them tribologically resemble textured ones. However, the effect of crater-like cavities on the lubricated tribological properties of HCPEB-treated surfaces has not been reported in the literature. This work was [...] Read more.

High-current pulsed electron beam (HCPEB) irradiation commonly induces crater-like cavities on irradiated surfaces, making them tribologically resemble textured ones. However, the effect of crater-like cavities on the lubricated tribological properties of HCPEB-treated surfaces has not been reported in the literature. This work was aimed at exploring the potential texturing effect of the crater-like cavities. Surfaces with continuous and uniform crater-like cavities were prepared through HCPEB irradiating a 400-nm thick Ta coating that was pre-deposited on polished M50 steel. Their boundary tribological behaviors were studied while sliding in chemically inert, low-viscosity hydrocarbon fuel JP-10 against a Si₃N₄ ball under 2.0–4.0 GPa. At 2.0 GPa, the coefficient of friction (COF) and wear rate of the polished M50 steel were above 0.16 on average, with large fluctuation, and 1.49 × 10⁻⁵ mm³/N·m (a rectangle-like profile of 167.9 μm × 8.1 μm), respectively. In comparison, the HCPEB-treated Ta coating had a stable, marginally fluctuant COF of 0.11 and a near-zero wear rate. Under other higher loads, the HCPEB-treated Ta coating still exhibited a stable COF of 0.11 on average with small fluctuation, and its wear track width was only half that of the M50 steel. The analysis of the wear topographies indicates that the substantial reduction in both the COF and wear rate was mainly due to the texturing effect originating from the crater-like cavities. Full article

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19 pages, 17774 KiB

Open AccessArticle

Mechanical Properties and Oxidation Behavior of Multilayered Hf–Si–N Coatings

by Li-Chun Chang, Bo-Wei Liu and Yung-I Chen

Coatings 2018, 8(10), 354; https://doi.org/10.3390/coatings8100354 - 3 Oct 2018

Cited by 12 | Viewed by 3819

Abstract

Monolithic Hf–Si–N coatings and multilayered Hf–Si–N coatings with cyclical gradient concentration were fabricated using reactive direct current magnetron cosputtering. The structure of the Hf–Si–N coatings varied from a crystalline HfN phase, to a mixture of HfN and amorphous phases and to an amorphous [...] Read more.

Monolithic Hf–Si–N coatings and multilayered Hf–Si–N coatings with cyclical gradient concentration were fabricated using reactive direct current magnetron cosputtering. The structure of the Hf–Si–N coatings varied from a crystalline HfN phase, to a mixture of HfN and amorphous phases and to an amorphous phase with continuously increasing the Si content. The multilayered Hf₄₈Si₃N₄₉ coatings exhibited a mixture of face-centered cubic and near-amorphous phases with a maximal hardness of 22.5 GPa, a Young’s modulus of 244 GPa and a residual stress of −1.5 GPa. The crystalline phase-dominant coatings exhibited a linear relationship between the hardness and compressive residual stress, whereas the amorphous phase-dominant coatings exhibited a low hardness level of 15–16 GPa; this hardness is close to that of Si₃N₄. Various oxides were formed after annealing of the Hf–Si–N coatings at 600 °C in a 1% O₂–99% Ar atmosphere. Monoclinic HfO₂ formed after Hf₅₄N₄₆ annealing and amorphous oxide formed for the oxidation-resistant Hf₃₂Si₁₉N₄₉ coatings. The oxidation behavior with respect to the Si content was investigated by using transmission electron microscopy and X-ray photoelectron spectroscopy. Full article

(This article belongs to the Special Issue Advanced Thin Films Deposited by Magnetron Sputtering)

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13 pages, 4835 KiB

Open AccessArticle

Anti-Fouling Ceramic Coating for Improving the Energy Efficiency of Steel Boiler Systems

by Minh Dat Nguyen, Jung Won Bang, Young Hee Kim, An Su Bin, Kyu Hong Hwang, Vuong-Hung Pham and Woo-Teck Kwon

Coatings 2018, 8(10), 353; https://doi.org/10.3390/coatings8100353 - 2 Oct 2018

Cited by 10 | Viewed by 6408

Abstract

Boilers are systems used mainly to generate steam in industries and waste-to-energy facilities. During operation, heat transfer loss occurs because a fouling layer with low thermal conductivity is deposited on the external surfaces of the boiler tube system, which contributes to the overall [...] Read more.

Boilers are systems used mainly to generate steam in industries and waste-to-energy facilities. During operation, heat transfer loss occurs because a fouling layer with low thermal conductivity is deposited on the external surfaces of the boiler tube system, which contributes to the overall poor energy efficiency of waste-to-energy power plants. To overcome the fouling problem, a ceramic coating was developed and applied to carbon steel with a simple and inexpensive coating method. Anti-fouling testing, thermal conductivity measurement, and microstructure observation were performed to evaluate the performance of the coating. All evaluated properties of the coating were found to be excellent. The developed ceramic coating can be applied to boiler tubes in a real facility to protect them from the fouling problem and improve their energy efficiency. Full article

(This article belongs to the Special Issue Advanced Coatings for Buildings)

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10 pages, 11394 KiB

Open AccessArticle

Highly-Conductive and Well-Adhered Cu Thin Film Fabricated on Quartz Glass by Heat Treatment of a Precursor Film Obtained Via Spray-Coating of an Aqueous Solution Involving Cu(II) Complexes

by Philipus N. Hishimone, Hiroki Nagai, Masato Morita, Tetsuo Sakamoto and Mitsunobu Sato

Coatings 2018, 8(10), 352; https://doi.org/10.3390/coatings8100352 - 2 Oct 2018

Cited by 10 | Viewed by 3213

Abstract

A Cu thin film on a quartz glass substrate was fabricated by a wet process involving heat-treatment of a precursor film spray-coated with an aqueous ammonia solution containing Cu(HCOO)₂∙4H₂O and Cu(II) complex of ethylenediamine-N,N,N′N′-tetraacetic acid. The precursor film that [...] Read more.

A Cu thin film on a quartz glass substrate was fabricated by a wet process involving heat-treatment of a precursor film spray-coated with an aqueous ammonia solution containing Cu(HCOO)₂∙4H₂O and Cu(II) complex of ethylenediamine-N,N,N′N′-tetraacetic acid. The precursor film that formed on the substrate at 180 °C in air was heat-treated at 350 °C and post annealed at 400 °C by placing an identical-sized glass on top, under Ar gas flow in a tubular furnace. X-ray diffraction pattern of the resultant film showed only peaks of Cu. The resultant film of 100 nm thickness has an adhesion strength and electrical resistivity of 37(7) MPa and 3.8(6) × 10⁻⁵ Ω cm, respectively. The images of atomic force and field-emission scanning-electron microscopies revealed a film of well-connected Cu grains with an average surface roughness of 11 nm. The reflectance of the thin film is more than 90% in the far-infrared region. The film’s chemical composition was also examined by using Auger electron spectroscopy. Full article

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10 pages, 2456 KiB

Open AccessFeature PaperArticle

Superhydrophobic Fabrics with Mechanical Durability Prepared by a Two-Step Plasma Processing Method

by Kosmas Ellinas, Angeliki Tserepi and Evangelos Gogolides

Coatings 2018, 8(10), 351; https://doi.org/10.3390/coatings8100351 - 2 Oct 2018

Cited by 19 | Viewed by 5268

Abstract

Most studies on superhydrophobic fabrics focus on their realization using additive manufacturing (bottom-up) techniques. Here we present the direct modification of three different fabrics using a plasma-based method to obtain anti-adhesive and self-cleaning properties. A two-step plasma processing method is used: (a) for [...] Read more.

Most studies on superhydrophobic fabrics focus on their realization using additive manufacturing (bottom-up) techniques. Here we present the direct modification of three different fabrics using a plasma-based method to obtain anti-adhesive and self-cleaning properties. A two-step plasma processing method is used: (a) for the creation of micro-nanoscale features on the fabric surface (plasma texturing step) and (b) the minimization of the fabric surface energy (by a short plasma deposition step of a very thin, low surface energy layer). The entire process takes only 14 min and all fabrics after processing exhibit high water static contact angles (WSCA > 150°), low contact angle hysteresis (CAH < 7°) and advantageous mechanical durability against hand-rumpling. The method is simple and generic, and it can be therefore expanded to other polymeric fabrics (i.e., acrylic) in addition to polyester, without any limitation rising from the weaving characteristics of the fabric or the starting nature of the material (i.e., hydrophobic or hydrophilic). Full article

(This article belongs to the Special Issue Superhydrophobic Coatings)

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17 pages, 723 KiB

Open AccessArticle

Adhesion of Soft Materials to Rough Surfaces: Experimental Studies, Statistical Analysis and Modelling

by Andrey Pepelyshev, Feodor M. Borodich, Boris A. Galanov, Elena V. Gorb and Stanislav N. Gorb

Coatings 2018, 8(10), 350; https://doi.org/10.3390/coatings8100350 - 30 Sep 2018

Cited by 22 | Viewed by 4088

Abstract

Adhesion between rough surfaces is an active field of research where both experimental studies and theoretical modelling are used. However, it is rather difficult to conduct precise experimental evaluations of adhesive properties of the so-called anti-adhesive materials. Hence, it was suggested earlier by [...] Read more.

Adhesion between rough surfaces is an active field of research where both experimental studies and theoretical modelling are used. However, it is rather difficult to conduct precise experimental evaluations of adhesive properties of the so-called anti-adhesive materials. Hence, it was suggested earlier by Purtov et al. (2013) to prepare epoxy resin replicas of surfaces having different topography and conduct depth-sensing indentation of the samples using a micro-force tester with a spherical smooth probe made of the compliant polydimethylsiloxane polymer in order to compare values of the force of adhesion to the surfaces. Surprising experimental observations were obtained in which a surface having very small roughness showed the greater value of the force of adhesion than the value for a replica of smooth surface. A plausible explanation of the data was given suggesting that these rough surfaces had full adhesive contact and their true contact area is greater than the area for a smooth surface, while the surfaces with higher values of roughness do not have full contact. Here, the experimental results of surface topography measurements and the statistical analysis of the data are presented. Several modern tests of normality used showed that the height distribution of the surfaces under investigation is normal (Gaussian) and hence the classic statistical models of adhesive contact between rough surfaces may formally be used. Employing one of the Galanov (2011) models of adhesive contact between rough surfaces, the plausible explanation of the experimental observations has been confirmed and theoretically justified. Full article

(This article belongs to the Special Issue Advanced Bioadhesive and Bioabhesive Coatings)

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7 pages, 2247 KiB

Open AccessArticle

Continuous Tip Widening Technique for Roll-to-Roll Fabrication of Dry Adhesives

by Sung Ho Lee, Hoon Yi, Cheol Woo Park, Hoon Eui Jeong and Moonkyu Kwak

Coatings 2018, 8(10), 349; https://doi.org/10.3390/coatings8100349 - 30 Sep 2018

Cited by 14 | Viewed by 3734

Abstract

In this study, we reported continuous partial curing and tip-shaped modification methods for continuous production of dry adhesive with microscale mushroom-shaped structures. Typical fabrication methods of dry adhesive with mushroom-shaped structures are less productive due to the failure of large tips on pillar [...] Read more.

In this study, we reported continuous partial curing and tip-shaped modification methods for continuous production of dry adhesive with microscale mushroom-shaped structures. Typical fabrication methods of dry adhesive with mushroom-shaped structures are less productive due to the failure of large tips on pillar during demolding. To solve this problem, a typical pillar structure was fabricated through partial curing, and tip widening was realized through applying the proper pressure. Polyurethane acrylate was used in making the mushroom structure using two-step UV-assisted capillary force lithography (CFL). To make the mushroom structure, partial curing was performed on the micropillar, followed by tip widening. Dry adhesives with properties similar to those of typical mushroom-shaped dry adhesives were fabricated with reasonable adhesion force using the two-step UV-assisted CFL. This production technology was applied to the roll-to-roll process to improve productivity, thereby realizing continuous production without any defects. Such a technology is expected to be applied to various fields by achieving the productivity improvement of dry adhesives, which is essential for various applications. Full article

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8 pages, 3783 KiB

Open AccessFeature PaperArticle

Hardening of HVOF-Sprayed Austenitic Stainless-Steel Coatings by Gas Nitriding

by Thomas Lindner, Pia Kutschmann, Martin Löbel and Thomas Lampke

Coatings 2018, 8(10), 348; https://doi.org/10.3390/coatings8100348 - 29 Sep 2018

Cited by 19 | Viewed by 5032

Abstract

Austenitic stainless steel exhibits an excellent corrosion behavior. The relatively poor wear resistance can be improved by surface hardening, whereby thermochemical processes offer an economic option. The successful diffusion enrichment of bulk material requires a decomposition of the passive layer. A gas nitriding [...] Read more.

Austenitic stainless steel exhibits an excellent corrosion behavior. The relatively poor wear resistance can be improved by surface hardening, whereby thermochemical processes offer an economic option. The successful diffusion enrichment of bulk material requires a decomposition of the passive layer. A gas nitriding of high velocity oxygen fuel spraying (HVOF)-sprayed AISI 316L coatings without an additional activation step was studied with a variation of the process temperature depending on the heat-treatment state of the coating. A successful nitrogen enrichment was found in as-sprayed condition, whereas passivation prevents diffusion after solution heat treatment. The phase composition and microstructure formation were examined. The crystal structure and lattice parameters were determined using X-ray diffraction analysis. The identified phases were assigned to the different microstructural elements using the color etchant Beraha II. In as-sprayed condition, the phase formation in the coating is related to the process temperature. The formation of the S-phase with interstitial solvation of nitrogen is achieved by a process temperature of 420 °C. Precipitation occurs during the heat treatment at 520 °C. In both cases, a significant increase in wear resistance was found. The correlation of the thermochemical process parameters and the microstructural properties contributes to a better understanding of the requirements for the process combination of thermal spraying and diffusion. Full article

(This article belongs to the Special Issue Tribology and Surface Engineering)

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18 pages, 3758 KiB

Open AccessFeature PaperArticle

Quantification of Thermal Barrier Efficiency of Intumescent Coatings on Glass Fibre-Reinforced Epoxy Composites

by Piyanuch Luangtriratana, Baljinder K. Kandola, Sophie Duquesne and Serge Bourbigot

Coatings 2018, 8(10), 347; https://doi.org/10.3390/coatings8100347 - 29 Sep 2018

Cited by 13 | Viewed by 4196

Abstract

In this work, the thermal barrier efficiency of three commercial intumescent coatings of varying thicknesses on glass fibre-reinforced epoxy (GRE) composites has been studied using cone calorimetric parameters and temperature profiles through the thicknesses, obtained by inserting thermocouples in the sample during the [...] Read more.

In this work, the thermal barrier efficiency of three commercial intumescent coatings of varying thicknesses on glass fibre-reinforced epoxy (GRE) composites has been studied using cone calorimetric parameters and temperature profiles through the thicknesses, obtained by inserting thermocouples in the sample during the experiment. The methodologies developed to measure char expansion of the three coatings during the cone experiment as well under slow heating conditions using an advanced rheometric expansion system have been discussed. While the expansion ratios in the two experiments were different, the trends were similar. Thermal conductivities of the chars as a function of time were measured, which could be related to the intumescence steps of respective coatings. The accurate measurements of these parameters are important in predicting the surface requirements of an ideal coating that can enable a given composite structure to survive a defined thermal threat for a specified period of time. Full article

(This article belongs to the Special Issue Thermal Barrier Coatings)

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17 pages, 6986 KiB

Open AccessArticle

Cavitation Erosion and Jet Impingement Erosion Behavior of the NiTi Coating Produced by Air Plasma Spraying

by Zhenping Shi, Jiqiang Wang, Zhengbin Wang, Yanxin Qiao, Tianying Xiong and Yugui Zheng

Coatings 2018, 8(10), 346; https://doi.org/10.3390/coatings8100346 - 28 Sep 2018

Cited by 28 | Viewed by 4616

Abstract

Cavitation erosion and jet impingement erosion can result in a great loss of materials. NiTi alloy is a very promising candidate to acquire cavitation erosion resistance and jet impingement erosion resistance because of its superelasticity. Due to the high cost and poor workability [...] Read more.

Cavitation erosion and jet impingement erosion can result in a great loss of materials. NiTi alloy is a very promising candidate to acquire cavitation erosion resistance and jet impingement erosion resistance because of its superelasticity. Due to the high cost and poor workability of NiTi alloy, many people tried to overcome such drawbacks by preparing NiTi coatings on the basis of deteriorating the good properties as little as possible. From the aspect of the application of NiTi coating, the erosion resistance should be evaluated comprehensively. One of these evaluations involves the comparison of cavitation erosion resistance and jet impingement erosion resistance of NiTi. This evaluation has not been made thus far. Thus, in this study, the NiTi coating was prepared by air plasma spraying (APS) using pre-alloyed NiTi powder. Its microstructure, chemical composition and phase transformation were identified. Cavitation erosion behavior and jet impingement erosion behavior of the as-sprayed NiTi coating were compared. The results showed that the coating exhibited better jet impingement erosion resistance than cavitation erosion resistance. This was attributed to the oxides, impurities, cracks and pores that existed in the coating, whose effects on deteriorating the cavitation erosion were far greater than those worsening the jet impingement erosion. Full article

(This article belongs to the Special Issue Development and Characterization of Nanostructured Functional Coatings/Films)

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13 pages, 1836 KiB

Open AccessFeature PaperReview

Cellulose Aerogels for Thermal Insulation in Buildings: Trends and Challenges

by Danny Illera, Jaime Mesa, Humberto Gomez and Heriberto Maury

Coatings 2018, 8(10), 345; https://doi.org/10.3390/coatings8100345 - 28 Sep 2018

Cited by 77 | Viewed by 12218

Abstract

Cellulose-based aerogels hold the potential to become a cost-effective bio-based solution for thermal insulation in buildings. Low thermal conductivities (<0.025 W·m⁻¹·K⁻¹) are achieved through a decrease in gaseous phase contribution, exploiting the Knudsen effect. However, several challenges need to [...] Read more.

Cellulose-based aerogels hold the potential to become a cost-effective bio-based solution for thermal insulation in buildings. Low thermal conductivities (<0.025 W·m⁻¹·K⁻¹) are achieved through a decrease in gaseous phase contribution, exploiting the Knudsen effect. However, several challenges need to be overcome: production energy demand and cost, moisture sensitivity, flammability, and thermal stability. Herein, a description and discussion of current trends and challenges in cellulose aerogel research for thermal insulation are presented, gathered from studies reported within the last five years. The text is divided into three main sections: (i) an overview of thermal performance of cellulose aerogels, (ii) an identification of challenges and possible solutions for cellulose aerogel thermal insulation, and (iii) a brief description of cellulose/silica aerogels. Full article

(This article belongs to the Special Issue Advanced Coatings for Buildings)

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8 pages, 2863 KiB

Open AccessArticle

A Novel Electrolytic Plasma Spraying Preparation SiO₂/SiC Coating on Carbon Fiber Fabric

by Aiming Bu, Yongfu Zhang, Yuping Zhang, Weiwei Chen, Huanwu Cheng, Lu Wang and Yuxin Wang

Coatings 2018, 8(10), 344; https://doi.org/10.3390/coatings8100344 - 27 Sep 2018

Cited by 13 | Viewed by 4311

Abstract

A good quality of SiO₂/SiC coating was successfully fabricated on carbon fiber fabric by a novel electrolytic plasma spraying method, where Na₂SiO₃·9H₂O aqueous solution was used as an electrolyte. In this study, we discussed the [...] Read more.

A good quality of SiO₂/SiC coating was successfully fabricated on carbon fiber fabric by a novel electrolytic plasma spraying method, where Na₂SiO₃·9H₂O aqueous solution was used as an electrolyte. In this study, we discussed the effect of spraying distance on the coating. The microstructure and composition coating were characterized by scanning electron microscopy with energy-dispersive spectroscopy and XPS, respectively. An effective coating can be easily prepared within several tens of seconds through this approach by adjusting the spraying distance. Results show that the sample oxidation resistance temperature was up to 1000 °C while the spraying distance was 15 mm, and tensile strength increased by 73 MPa after heat treatment at 900 °C for 20 min. The study provides additional insights into the feasibility of modification of carbon fiber fabric. Meanwhile, this method can be expected to extend to the fabrication of other oxide coatings or the modification of the surfaces of other complicated and/or large-scale easily oxidized materials. Full article

(This article belongs to the Special Issue Development and Characterization of Nanostructured Functional Coatings/Films)

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Coatings, Volume 8, Issue 10 (October 2018) – 45 articles

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