Recent Development in Carbon-LiFePO₄ Cathodes for Lithium-Ion Batteries: A Mini Review ^†

Abstract

Li-ion batteries are in demand due to technological advancements in the electronics industry; thus, expanding the battery supply chain and improving its electrochemical performance is crucial. Carbon materials are used to increase the cyclic stability and specific capacity of cathode materials, which are essential to batteries. LiFePO₄ (LFP) cathodes are generally safe and have a long cycle life. However, the common LFP cathode has a low inherent conductivity, and adding a carbon nanomaterial significantly influences how well it performs electrochemically. Therefore, the major focus of this review is on the importance, current developments, and future possibilities of carbon-LFP (C-LFP) cathodes in LIBs. Recent research on the impacts of different carbon sizes, LFP’s shape, diffusion, bonding, additives, dopants, and surface functionalization was reviewed. Overall, with suitable modifications, C-LFP cathodes are expected to bring many benefits to the energy storage sector in the forthcoming years.

1. Introduction

The growth of renewable energy technologies and the electric vehicles market requires developing low-cost batteries with high energy density. With high operating voltage (~3.2 V to 3.4 V), and relatively high capacity, Li-ion batteries (LIBs) have been used popularly in electric vehicles. However, the energy density of LIBs is often limited by the low electrochemical capacity of cathode materials (<200 mAh g⁻¹) and the poor rate performance of the electrodes. LiCoO₂ was the first commercially used cathode material (i.e., used by SONY electronics) in LIBs; however, it causes environmental pollution during manufacturing, overcharging while being used, posing a possible safety concern, and is costly given the low storage capacity [1]. LiNiO₂ has an affordable price and analogous crystal structure to LiCoO₂; regrettably, it is challenging to manufacture and has limited temperature and rate capability. Although the spinel structure LiMn₂O₄ is reliable and easy to make, the Jahn–Teller distortion in the lattice often during the cyclic process causes it to deform, leading to fast degradation of capacity, particularly at high temperature and stress levels. Lithium iron phosphate (LiFePO₄) cathodes are relatively safer to use and have longer cycle life than LiNi_1−x−yMn_xCo_yO₂ (NMC) and LiNi_1−x−yCo_xAl_yO₂ (NCA) cathodes [1,2,3]. Though NMC cathodes account for a higher market share than LFP, Companies like Tesla are switching to LFP cathodes due to their long cycle life and thermal stability, up to 270 °C [4].

Destenay discovered LiFePO₄ (LFP) in triphylite mineral solid solutions, forming olivine and isomorphous structure with Li phosphates of divalent Mn and Fe. Remarkably, Prof Goodenough and his colleagues’ ground-breaking work demonstrated the possibility of extracting Li from LFP using an insertion method for the first time [5]. He foretold the stability of sulfides, and phosphates at high oxidation states and mentioned the higher potentials (>3.2 V Vs. Li/Li⁺) for transition metal oxides [6]. Besides these efforts, LFP exhibited a low intrinsic conductivity reducing its operating efficiency. Prof Michel Armand and his coworkers postulated that adding carbon materials to LFP cathodes would be able to significantly improve their performance, allowing them to achieve a practical, reversible capacity comparable to the theoretical value (~170 mAh g⁻¹). LFP rechargeable batteries have high specific energy (90–170 Wh Kg⁻¹) and high volumetric energy density (1200 kJ L⁻¹), indicating that they can deliver the required energy for powering EVs and grid; it is also important to note that specific LFP-based batteries offer good cyclic performance (~1500 cycles) with nominal cell voltage (~3.2 Vs. Li/Li⁺) and in commercial scale (18,650 cells) offers the cyclic performance of 10,000 cycles at 0.5 C, reported by Preger et al. [7]. LFP is a benign substance that does not emit either harmful or toxic gases, safer for humans and the ecosystem. LFPs are resistant to chemicals (oxygen) and less combustible; therefore, they are less vulnerable to thermal runaway and withstand temperatures up to 270 °C. LFP cathodes are less expensive at ~353,000 won per kWh than NCM622 cathodes at ~385,000 won per kWh, [8] and Fe metal is abundant in the Earth’s crust (50,500 ppm, according to Israel Science and Technology) [9].

Though, LFP has undeniable benefits of its olivine structure, high theoretical capacity (~170 mAh g⁻¹), safety, low cost, and environmental benignity [10], there exist a few disadvantages in LFP, namely, (i) low electron conduction (10⁻⁶ to 10⁻¹⁰ s cm⁻¹), (ii) inadequate Li-ion diffusion, which limits their performance [11]. The broken octahedral sites of FeO₆ in LiFePO₄ diminish the speed of Li-ion diffusion across Fe–O–Fe (~10⁻¹⁴ cm² s⁻¹) [12]. Researchers improve the electrical conductance and ion migration in LFP by adding metal oxide, reducing LFP’s particle size, encapsulating a porous carbon layer, and multi-element doping [13]. Doping widens the Li⁺ migration pathway, enhances the output voltage, and working potential of LFP [12]. To develop LIBs with an operating voltage of 3.4 V and above vs. Li/Li⁺, the redox potential of the cathode materials must be boosted, which is considerably achieved by ion doping, being a trendy research hotspot [12]. Boosting the operating potential, on the other hand, is generally linked with a few constraints [2]. To avoid loss of the battery’s electrochemical efficiency, the potential must remain within the electrochemical stability window of the electrolyte (i.e., the battery can be recharged and discharged repeatedly without provoking thermal decomposition and redox failure of the electrolytes) [14]. Due to variations in free energy (∆G°) during the chemical reactions, the electrochemical stability window of the electrolyte becomes shorter than the energy barrier separating the lowest unoccupied molecular orbital (LUMO) and highest occupied molecular orbital (HOMO) of the electrolyte [12]. Furthermore, high output voltage could induce permanent structural changes in the cathode materials, compromising the electromechanical stability and decreasing the LIBs operational lifetime [12]. As a result, doping numerous ions necessitates a great deal of thought in terms of performance and post-doping outcomes. The Li⁺ migration route can be shortened by shrinking the size of LFP particles; however, this has the drawback of introducing the interface effect, where ions get crowded, resulting in uneven polarization and extensive electron generation; these disadvantages may cause thermal instabilities, necessitating optimization and management [14].

Coating of battery electrode materials has become essential for enhancing the performance, and protecting the surfaces from temperature, pressure, and stress [2]. Surface modification has proven to be a cost-effective and viable method for improving LFP’s performance by altering either the physiochemical properties or adding a protective barrier to reduce excessive interaction between the electrode layer and the electrolyte. Several multifunctional materials have already been employed to stabilize LFP, notably carbon, polymers, alloys, inorganic salts, nitrides, transition metal oxides, etc. Among them carbon nanomaterials improve the electrical characteristics of LFP crystals, are ubiquitous, and are simple to implement [14].

Carbon materials have received significant attention [15] because of the following benefits:

(i)

The large surface area, strong heat resistance, electrical conductivity, and high structural integrity of carbon promotes the performance of LIBs [16].

(ii)

Carbon compounds are available in various structures and dimensions, including graphene, graphite, reduced graphene oxide (rGO), carbon nanofibers, and nanotubes each with its own set of physical and chemical characteristics, allowing for a wide range of options for stabilizing electrodes [17].

(iii)

Sources for Carbon materials are plentiful and inexpensive [17].

(iv)

The light weight and compatibility of carbon compounds ameliorate the electrode space utilization in LIBs [18].

Carbon is one of the highly suitable materials to stabilise LFP due to the above-mentioned points, which contribute to their practical adaptability [16]. Adding carbon is one of the most effective ways to alter the properties of LFP, boosting the material’s electron transport and performance rate. Carbon addition influences the electrode’s electrochemical performance, determined mainly by fabrication quality, including graphitization level, sorption capacity, and spread on the electrode surface [17]. Although carbon treatment may significantly increase the conductivity of LFP, too much carbon may impede Li⁺ ion transport. A carbon matrix of 1 to 10 nm thick is generally adequate to ensure a stable passage of lithium-ions across the electrodes [19]. Further, different chemical origins and structures of carbon exhibit different characteristics and thereby impacting the electrochemical and interfacial interactions.

This review paper highlights the present, future research tracks and hurdles of adding carbon structures into LFP (Figure 1). Some of the recent findings from 2015 to 2022 on carbon-LFP cathodes have been discussed. Recent literature has documented mostly on hydrothermal, electrospinning, electrophoretic deposition, template synthesis, and in-situ preparation of C-LFP. Further, the size, thickness, morphology, moisture level, porosity, and surface features of carbon impact the electrochemical performance of C-LFP. The effects of carbon addition to LFP, and its future research directions were also discussed.

2. Effects of Adding Carbon to LFP Cathodes

Carbon compounds, especially graphite, were introduced as electrodes from the 1960s in LIBs [20]. Because of the low equivalent weight and excellent intercalation chemistry of fluorinated graphite, Armand et al. identified them as ideal anode materials in 1977 [21]. Graphite is also a suitable material for battery cathodes because of its strong oxidizing power (electron affinity), mixed electron-ion conductivity, and structural stability. The type of carbon, production method, morphologies, particle size, coating thickness, additives, and surface functionalization all affect the capacity and performance of LFP-carbon batteries; this section discusses the recent developments and effects of carbon-LFP cathodes.

2.1. Carbon Sources

Carbon materials offer high electrical conductivity, thermal stability, and chemical stability in various electrolytes, from severely acidic to basic. The electrochemical performance of the C/LFP electrodes is determined by the carbon precursor, such as organic, inorganic, polymer, and biomass. The following section discusses the impact of various carbon sources on the electrochemical performance of LFP-C cathodes.

2.1.1. MOFs-Derived Carbon

Metal organic frameworks (MOFs) are porous periodic structures created by organic ligands and metal ions. MOFs have recently been employed as precursors for in-situ synthesis of MOF-derived carbon cathode materials, which has sparked researchers’ interest and gained popularity. MOF-derived carbon exhibits high porosity, tunable pore size, high surface area, excellent cycle life, and charge storage capacity [22]; they are frequently produced by the hydrothermal or solvothermal method and used as templates to make carbon materials. As a conductive buffer layer, a porous carbon framework produced from MOFs by calcination and post-annealing treatments benefits the homogeneous electroactive species distribution. Dopants such as F, B, Cl, S, and O may also be added to MOF-derived carbon to improve electronic conductivity, active sites, and defect reduction [22]. Simultaneous doping of heteroatoms into carbon nanomaterials increases their electrochemical activity, resulting in a stable reversible capacity. Lin et al. used Metal Organic Framework (MOF) to derive C-LFP cathodes with F and O co-doping via a solid sintering process [23]. At first, the Fe-MOF was prepared using a solvothermal self-assembly process and mixed, sintered with ammonium fluoride and ammonium dihydrogen phosphate. Finally, the prepared MOF-derived LFP was encapsulated in an O doped carbon matrix. Because of its greater sorption capacities and reduced Li transport obstacles, the dense carbon matrix becomes thermodynamically advantageous, supporting more reaction species and enhancing the diffusion rate and electron conductivity; this MOF-derived C-LFP had a remarkable specific capacity of 169.9 mAh g⁻¹ at 0.1 C. Song et al. reported the use of Co²⁺–Co conversion reactions in cobalt MOF nanowire anodes and LFP cathodes. The Co MOF exhibited a high Li-ion storage capacity of 1100 mAh g⁻¹ at 20 mA g⁻¹ and stable cycling over 1000 cycles [24]. Despite some promising results, utilization and research of MOF-derived carbon cathode materials are currently in their early phases, owing to the repeatability of the same structures during synthesis.

Xu et al. presented two distinct methods for preparing carbon coated LFP cathodes, in which carbon was obtained from ZIF-8 MOF by carbonization and in-situ annealing; they reported that the LFP-carbon composites still retained the olivine structure with additional characteristics of mesoporous graphitic carbon [25]. Electron microscopy analysis show no relative structure between LFP and ZIF-derived carbon. However, the LFP@CZIF-8 sample has a core-shell structure. The in-situ prepared carbon-derived ZIF-derived carbon/LFP had pores of size ranging from 1.9 to 244 nm. The interconnected porous structure was advantageous for electrolyte wetting, lithium-ion diffusion (shortening the route of mass and charge transfer), charge transfer, and increased degree of freedom for volume change during charge-discharge cycles. Here, the Li-ion diffusion rate of ZIF-derived carbon/LFP 1.17 × 10⁻¹³ cm² s⁻¹ was 20 times higher than conventional LFP cathodes (6.7553 × 10⁻¹⁵ cm² s⁻¹). The fabricated cathode material delivered a discharge-specific capacity of 159.3 mAh g⁻¹ at 0.1 C and discharge-specific energy of 141.7 mWh g⁻¹ after 200 cycles at 5.0 C with 99% capacity retention [25]. MOF structures aid in the creation of carbon with high porosity and electrical conductivity, which can then be employed with LFP to improve Li⁺ ion diffusion and cycle life.

2.1.2. Biomass and Organic-Derived Carbon

Biomass-derived carbon has eco-friendliness and renewability. After multiple refining, acid, and heat treatments, the biomass waste is transformed into porous carbon materials. Previously, pyrolysis, chemical activation, solid state synthesis and thermal decomposition processes were performed to synthesis carbon from biomass waste. Porous structures such as hierarchical pores, 3D pores, and cross-linked pores are reported for biomass-derived carbon [26]. The presence of surface functional groups is relatively higher in biomass-derived carbon than chemically-derived carbon; these additional functional groups promote the adsorption of ions, electrolyte penetration, and their reactivity and, at times, lead to the formation of different compounds during the electrochemical reactions. In addition, different sources of biomass have different chemical components. For example, carbon-rich biomass contains significant amounts of nitrogen, oxygen, and hydrogen. The natural existence of nitrogen, boron, and hydrogen in biomass, which persists as heteroatoms after converting into carbon, boosts porosity, electrical conductivity, and ion absorption; as a result, the overall electrochemical performance can be improved [26]. Other elements that may be found in trace levels include phosphorus, silica, calcium, magnesium, sodium, and potassium. Some commonly used biomass sources are rice husk, coconut shell, wheat bran, vegetable wastes, spinach, groundnut shell, and nut’s shell. Among them, coconut shells have popularly been investigated as promising carbon sources. One recent example is the use of coconut shell-derived rGO composited with LFP using mechanical ultracentrifugation technique, where the rGO and LFP were prepared separately using pyrolysis and sol-gel technique and mixed via ultrasonication. Initially, the rGO solution was added to LFP nanoparticles mixed with n-butanol and ultrasonicated till the formation of a slurry. Post heat treatments at 80 °C for several hours, the rGO/LFP cathodes were obtained [27]. The LFP particles adhere firmly on both sides of rGO layers with increased surface area and reduced Li-ion diffusion path; this post-synthesis mixing protocol opens up opportunities in the future to explore other biomasses and mixing procedures. The study also suggests that sp² hybridised surface carbon on LFP performed electrochemically better than sp³ hybridised carbon [27]. Another study showed that a significant number of defects created by nitrogen-doping in the sp² carbon structure are advantageous for lithium transport at the interface [28]. Orange peel is another commonly used biomass to derive carbon. Recently, Carbon was extracted from orange peel using a mechanical activation process and coated on LFP. The orange peel-derived carbon-coated LFP was found to have homogeneous particle size and good electrical conductivity [29]. In general, chemical and physical activation processes are used for the surface functionalization of prepared carbons; each has its own benefits and drawbacks. Physical activation, particularly when utilizing steam, generates a lot of pyrolytic oil, although the yields are minimal. In comparison, the yield is greater in the chemical activation process, and little or no pyrolytic oil is produced. Similarly, in physical activation the particle size varies with temperature, but less aggregate formation is noted, whereas in chemical activation, the converse happens upon increases in temperature. Several considerations must be addressed while selecting a surfactant or activation reagent in an activation process. H₃PO₄, H₂SO₄, HNO₃, ZnCl₂, NaOH, KOH, H₂O₂, K₂CO₃, and CaCl₂ are some of the activation agents used for carbon synthesis; it is also worth noting that the effects of different activation reagents on biomass vary. For example, it is widely assumed that oxygenated compounds favor activating impacts on biomass [30]. One method for determining whether or not new functional groups have arisen on the carbon surfaces is to do an FT-IR study. Cellulose, lignin, glucose, and citric acids were used as biomass sources for preparing carbon-coated LFP, as reported in previous reviews [30].

Most recently, sericin, a protein layer that silkworms use in the creation of silk, was used as a bio precursor for preparing carbon-coated LFP. Sericin powder was obtained from silk worms by degumming process, mixed with LFP, and heat treated at 500 °C for 3 h in Argon atmosphere to obtain nitrogen-doped carbon coated LFP (N-C@LFP). The sericin layer is rich in nitrogen and carbon, thus creating nitrogen-based functional groups on the surface of C-LFP. The excellent discharge capacity of 113.5 mAh g⁻¹ with 1 wt% of N-C@LFP was observed, which was 20% higher than bare LFP. Further, the carbon derived from sericin was observed to be susceptible to the transport of Li-ions between the electrode and electrolyte. The Rct value of N-C@LFP was lower than bare LFP, accounting for increased electrical conductivity in N-C@LFP samples [26]. In a similar work, Gangaraju et al. employed an in-situ preparation of silk cocoon-derived carbon-LFP composites. At first, salts of Li, Fe and P were dissolved in ethanol and heat treated, followed by the addition of silk cocoon and microwave heating at 220 °C for 70 min and calcination at 700 °C in argon gas for 4 h. The prepared C-LFP composite had a discharge capacity of 140 mAh g⁻¹ at 1 C and 98% capacity retention after 200 cycles [31].

Organic precursors have the benefits of inducing surface functional groups such as nitrogen, fluorine to the carbon structure. Organic groups with ring structure and aromatic groups have been reported to exhibit high graphitization levels, promoting electrical conductivity. Several organic precursors such as phytic acid, N-methylimidazole, Oleylamine, and butyl-3-methylimidazolium dicyanamide were used as organic precursors [32]. The method of preparing the carbon from these organic precursors and the parameters such as temperature, atmosphere and additives added during the preparation stage, influence the electrical conductivity, surface functional groups, porosity and additional properties of carbon. At high temperature (>700 °C) and in N₂, Ar atmosphere, maximum carbon yield has been obtained. Porosity was induced by chemical activation and post synthesis thermal treatments. At times, porosity can be induced in-situ by the addition of chemical additives and surfactants, which has been previously discussed in other reviews.

Table 1. List of recent works on biomass-derived carbon-coated LFP.

Carbon Sources	Synthesis Method	Morphology	Particle Size (LFP and C-LFP)	Mass Loading of C-LFP	Discharge Capacity	Reference
Sericin	Solid state synthesis and calcination	Spherical	--	0.5 wt%	113.51 mAh g−1 at 1 C	[26]
Orange peel	Mechincal activation process	Spherical	LFP—140 nm C-LFP—90 nm	2.7 mg cm−2	139.8 mAh g−1 at 1 C-rate	[29]
Glucose	in situ solvothermal and calcination process	Microcavity pores	LFP—100 to 300 nm	85 wt%	192 mA h g−1 at 0.1 C	[32]
Vegetable cooking oil	Catalytic process and chemical vapour deposition	Spherical	Carbon >200 nm	80 wt%	102 mA h g−1 at 50 mA g−1	[33]

provides a comparison between the different biomass sources of carbon, method of preparation and coating, functional groups on carbon, discharge capacity and other relative features of papers published from 2016 to 2022.

2.1.3. Polymer-Derived Carbon

Polymers-derived carbon (PDC) has different surface functional groups depending on the base monomer. The conversion of polymers to carbon is not always perfect. Short-chain polymers break down rapidly in organic electrolytes, limiting battery cycle life. Long-chain polymers are stable and have negligible solubility in electrolytes. Polymers such as polypyrrole, polythiophene, PEDOT, polyvinyl pyrrolidone, and polyaniline are used to build porous carbon. Conducting polymers are more suited for obtaining carbon for its use in battery applications. In particular, highly graphitized carbons are produced when functionalized heterocyclic or ring-forming compounds are used in pyrolysis. Nien et al. compared the carbonization behavior of four different polymers, namely poly(ethylene oxide) (PEO), polybutadiene (PB), polystyrene (PS), and styrene-butadiene-styrene (SBS). The pyrolysis process was employed, and vinyl compounds (PS) were observed to form scissions. Main chain scissions develop without the formation of volatile chemicals during the pyrolysis of PS, and the carbonization process of unsaturated bonds and aromatic rings promotes the formation of graphite. The authors revealed that PS is the best suitable polymer for developing a fine particle size LiFePO₄/C composite and an evenly coated carbon conductive layer with improved electrochemical performance. The main advantages of using PS as a polymer additive include coordinated LiFePO₄ crystallization and PS pyrolysis [34].

Depending on the process conditions, PDC has diverse morphologies and is commonly synthesised by template or direct synthesis. Phase separation and heat treatment are used to create porous structures in polymers. Various inorganic, organic, and hybrid templates are employed in template synthesis. Fischer et al. used block copolymer (300 mg of Pi-b-PEO) and homopolymer (500 mg of PS) as templating and extra carbon sourcing agents, respectively, for preparing LFP-C composites using template synthesis. The block copolymer (BCP) acted as a structure-directing agent and aided in forming stable molecular complexes. Furthermore, the homopolymer does not interact with BCP, thus increasing the electrical conductivity without forming larger aggregates. LFP/C composites based on BCP exhibit high cyclability, with over 92% capacity retention after 1000 cycles at 1 C and an average Coulombic efficiency of 99.5% [19]; it is essential to choose polymers rich in carbon for higher carbon extraction. Polyacetylene and its derivatives are rich in carbon and available in nature (plants and fungi) [35]. Poly(carborane-siloxane-arylacetylene), poly(1-(4-trimethylsilylphenyl)-2-phenylacetylene), and polyacetylene derivatives may also be investigated in the future for carbon extraction and use in batteries [36]. Anna et al. used polydopamine-derived carbon, which exhibited higher ionic diffusion coefficients due to the thinner coatings (~6.5 nm) and thereby facilitating the stable phases without either much nucleation or formation of new phases. The overlap of current peaks was observed during galvanostatic cycling for thicker carbon coatings on LFP, which was neither a kinetic nor diffusion type of intercalation and was thus attributed to the development of new phases during the charge-discharge process [37]. Different morphologies of carbon can be obtained with different polymer sources and process conditions. Porous structures are highly beneficial in improving the cyclic performance due to the creation of excessive surface area of ion insertion and disinsertion, especially in the case of graphene. To summarise, there is no standard morphology for PDC, and new morphologies emerge on a monthly basis. Specifically, an LFP cathode with a conductive framework and porosity, a high degree of graphitization, thinner coating (2 to 20 nm), and surface functional groups (N, P, B) can all contribute to improved electrochemical performance. The charge transfer resistance reduces as the degree of graphitization increases, and thereby promoting the electrical conductivity; it is critical to fine-tune the coating thickness and graphitization level to properly protect the electrodes from electrolytes while allowing ions to pass between the electrodes.

2.2. Dimensions at Nanoscale

The tendency of a material’s characteristics to vary rapidly at the nanoscale (below around 100 nanometers) is vital to recognize; these unforeseen changes are known as “quantum effects”, which can be seen in low-dimensional structures. Due to these quantum effects, the nanomaterials exhibit higher electrical conductivity, elasticity, mechanical strength, and stronger reactivity.

2.2.1. One Dimensional (1D) C-LFP

Carbon nanotubes (CNTs), a one dimensional carbon nanomaterial, with diameters ranging from 0.6 to 50 nm, commonly formed from a thin sheet of pure graphite, have excellent features of strength, thermal, and electrical conductivity that have been employed in the field of energy storage for the past two decades. The electrons navigate easily in 1D carbon materials. The increased surface area of multiple carbon coating, sandwich, mesoporous, and hollow structures leads to improved ion mobility. Carbon materials, coating techniques, and associated electrochemical performances have all been explored in previous papers. As a reason, this section concentrates on the influence of key factors in determining LFP’s electro-chemical performance.

Effects of Synthesis, Particle Size, Diffusion Path and Bonding on 1D C-LFP

The effect of particle size, shape, diffusion path, and velocity has been explored here, as well as the most modern and widely used methodologies. Firstly, the limited conductivity of LFP causes strong polarisation under significant charging rate conditions, causing a drop in overall capacity. In order to overcome this main issue and for making high-quality LFP cathodes, researchers used a variety of synthesis procedures [38]. Hydrothermal synthesis of LFP with carbon coating through heat treatment has been rejuvenated for fabricating the cathode in Li-based batteries because of its low cost, simplicity, and familiarity. One of the recent examples is the work done by Kanagaraj et al., which discusses the preparation of multiwall carbon nanotubes (MWCNT) coated LFP using the hydrothermal method combined with tape coating methodology, as shown in the Figure 2a. The densely packed carbon-coated LFP exhibited excellent Li-ion storage capacity of up to 4.3 V. On the other hand, the half-cell study (Figure 2b) failed to yield adequate capacity values, which might be attributed to the increased crystallite size (51.07 nm) and shape (Capsule-like) of the synthesized LFP, thereby restricting the ionic mobility and conduction of electrons [39].

The size distribution, shape, temperature, and thickness of the carbon layer influence the production of the secondary surface phase (Fe₂P) in LFP [38]. In general, temperature-assisted carbon coatings entails two processes (i) Reduction of carbon to gas (ii) Formation of secondary phases Fe₂P and LiPO₄. The carbon reduction by smaller particles (less than 20 nm) of LFP may result in improved reactivity because of the increased surface area. In a recent study, it was found that 60 nm thick carbon coating on LFP necessitates high temperature for formation of secondary phases, whereas 2 nm thick carbon coating can form Fe₂P phase at low temperature [42]; this study suggests that these additional Fe₂P phases facilitate improvements in the electrochemical performance because of its active species. MV Reddy et al. and group designed uniform carbon (30 to 40 nm) coated LFP nanoplates (Figure 2c–e) cathodes for LIBs and identified the shorter Li⁺ diffusion pathway because of the reduced size and plate morphology [40]. The same group also identified the increase in volume and linear expansion coefficient of LFP in accordance with increased temperature (777 °C). Figure 2f,g shows the volume expansion of LFP with an increase in temperature, simulated using molecular dynamics. Precisely, the Fe-Fe distance in LFP increases upon increasing the temperature.

Secondly, the effect of carbon-coated LFP on Li-ion intercalation, diffusion pathway is a recent topic of discussion. Le et al. identified that CNTs prepared via a hydrothermal route would not affect the Li-LFP intercalation-deintercalation routes but ameliorate the electronic conductivity and ion diffusion velocity [43]. In terms of endeavoring a good perception of LFP intercalation mechanisms, Lu et al. and co-workers reported an X-ray microscopic investigation on Li_0.5FePO₄ nano- and bulk structures. Using multiple spectroscopic, microscopic tools, and DFT calculations, they found a drastic decline in Li concentration from surface to bulk of Li-rich particles. In contrast, there was no change in the concentration of Li for the Li deficient particles, which reveals the surface sluggish lithiation behavior of Li-rich particles transferred from Li deficient to Li rich bulk particles as shown in Figure 3a,b. Li-rich particles are mapped in red, whereas Li-poor particles are marked in green. Further, the X-ray absorption near edge structure (XANES), photoemission electron microscopy (PEEM), and Scanning transmission X-ray microscopy (STXM) of Li rich and deficient particles obtained in the bulk, surface, their lithiated, delithiated spectral profiles are shown in Figure 3c. The lithiation and movement of ions in the [010] transport plane change slightly since the [010] plane is the fastest Li diffusion pathway in LFP [44]. From Figure 3d, both Li rich and deficient particles spread evenly avoiding clumps, which might be ascribed to interparticle diffusion of ions.

Finally, the bonding involving a heat-injected coating is significantly stronger than mechanical linkages. Ventrapragada et al. developed a CNT-coated LFP cathode via sustainable spray coating without any surfactants. Carboxymethylcellulose, rubber, graphite and carbon super P were taken as source materials to derive C-LFP cathode, which boosted the cell performance by enhancing the energy density (~460 Wh Kg⁻¹) [45].

Achieving the optimal diffusion of CNTs in LFP is a happening concern. Compared to standard CNT sludge, LFP coupled with a conductive framework made of agglomerated CNT and PVDF mixtures had better device performance. Zhang et al. used PVDF for enhancing the dispersibility of CNT in the N-methyl pyrrolidone/LFP mixture, which was stable even after 48 h as shown in Figure 4c,d. The corresponding TEM images of the agglomerated CNT were shown in Figure 4a with the size distribution spectra (Figure 4b). The inclusion of PVDF reduced the diameter of CNT agglomerates and enhanced the miscibility of CNTs, which was inferred from Figure 4b. Further adding PVDF, the mixture’s viscosity (CNT-PVDF) increased to 37 mPa S⁻¹ from 35 mPa S⁻¹, enhancing the shear force within the solvent and CNT; this leads to the development of the CNT dispersion stability even at extreme disturbances [46].

Effects of Fabrication Method, Additives, and Surfactant on 1D C/LFP

1D Carbon nanofibers (CNF) with a high specific surface area have an extensively carbonized framework with a short d spacing ((d002) > 0.335 nm) and considerable crystal thickness, allowing for superior mechanical characteristics. Further, multifunctional additives change the design, morphology, and physical traits of CNFs, encompassing a wide range of properties required for electrochemical application. Fongy et al. and group produced CNF and used a non-ionic surfactant to blend them into a slurry of LFP cathode; they estimated the influence of CNF on the ionic and electronic conductivities of LFP and identified that the addition of CNF has enhanced the capacity; they analyzed the impact of CNF on LFP’s electron transfer conductivities and reported that adding CNF boosted the capacity; they further asserted that the porosity of LFP-CNF structure has contributed to improved electronic wiring properties and diffusion of Li⁺ ions by generating multiple 1D channels [47]. Adepoju et al. found a similar result, demonstrating a higher C-rate (>5 C) when CNF was added to the LFP cathode. The slurry was made up of LFP, vapor-grown CNF, carbon black, and PVDF, which were combined in an 80:10:10 ratio with the assistance of the N-methyl 2-pyrrolidone solvent. In comparison to the virgin LFP electrode (140 mAh g⁻¹), the altered LFP-CNF cathode has a more extended voltage as well as operational threshold (30 C) and produces a greater discharge capacity of 150 mAh g⁻¹ (Figure 5a). The enhanced electrochemical performance achieved by incorporating CNFs notably reduces the solution viscosity of the pores. Hence, it improves the diffusion of ions across the CNF combined cathode, which can be elucidated to the immense current capacity. Having a larger peak current, the CV of the LFP/CNF electrode has the finest harmonious and sharper curve pattern of the oxidation (0.24 V) and reduction potentials (0.39 V). As shown in the CV (Figure 5b) the highly oriented peaks and larger potential differences were attributed to the addition of CNF, which boosted the ion diffusion with reduced resistance between the particles [48].

The electrochemical activity of the cathode is influenced by C and LFP production methods, based on scientific observations. Three practices were mostly reported in the past for preparing LFP-carbon composites, namely,

(i)

Mixing of carbon and LFP, post synthesis;

(ii)

Depositing or coating carbon structures over LFP via solution/vapor phase;

(iii)

In-situ co-formation of LFP carbon composite.

Though hydrothermal synthesis was simple and familiar, electrospinning, electrophoretic deposition, and template synthesis processes proved to be promising for manufacturing C-LFP cathodes since many operational parameters may be adjusted in line with the material’s architecture and conductivity. Hagberg et al. developed CNF structures as a strengthening material and current collector for LFP cathode using electrophoretic deposition (Figure 5c) with a bath mixture of carbon black, I₂, Triton-X and PVDF in acetone. The I₂ triggers the release of H⁺ ions during the supply of electric current, promoting the build-up of positive charges, which are then driven towards the CNF, producing a thin layer coating. In addition, Triton-X was employed as an additive to prevent the formation of clumps. However, high resolution SEM images revealed a few uneven and dense coating, lowering mechanical characteristics, electrochemical contact, and capacity. As illustrated in the SEM image of Figure 5d, altering the inter-electrode spacing between the Pt counter electrode and the CNF culminated in a homogeneous and consistent deposition. The fabricated cathode was crucial in achieving a capacity of 110 mAhg⁻¹, with a decent capacity retention of 0.75 and a coulombic efficiency of ~99%. After multiple charge-discharge cycles, the electrophoretic coating continued to persist without significant wear [49]. Similarly, Cao et al. used PVP-derived single pot electrospinning method for synthesizing in-situ CNF (010) faced LFP hybrid cathode. Interestingly, 98.2% of the initial capacity (152 mAh g⁻¹) was retained after 500 cycles, which was attributed to the porous cathode framework and fast ion transport [50].

Recently, in situ soft template synthesis of LFP on 1D carbon nanosheets (CNSs) and CNTs have been reported to perform synergistic outcome due to the structural framework facilitating both electron transfer outside the circuit and ion transfer inside the electrolyte with high mobility, thus improving the overall electrochemical performance. Further, the dual nanosheet and nanotube network improves the electron conduction and eliminates the formation of aggregates during continuous cycles [51].

Effects of Surface Functionalization on 1D C-LFP

Surface properties and ion conduction of the CNF can be adjusted via the functionalization of –OH, C=O, –COOH groups into the active sites of the CNF. Exterior functional groups primarily function as binding spots and thereby crosslinking or interlinking the molecules during the fabrication and electrochemical testing processes. Activating structures such as CNT, graphene, Mxene, and Prussian blue analogues have been decorated over the CNF-LFP cathodes to widen the pores and increase the surface roughness; this will lead to enhanced ion kinetics favoring sufficient capacity and extended shelf life of the cell. Increasing the reactive spots and changing the hydration tendency of the carbon frameworks on the exterior portion of CNF might increase sorption capacity. Carbon sources like CH₄ and C₂H₂ have typically been utilized to mount CNTs onto CNFs while using vapor deposition methods. The morphological traits of the coated carbon can be altered through catalysts. One such example is the synthesis of CNFs employing Pd and Fe-based catalysts. Similarly, Au nanoparticles are used to boost the interfacial ion transport and thermal properties of precoated CNF-LFP composites. The significant reason for the distribution of Au into the carbon atoms is to activate the resonance of LFP, resulting in increased convection throughout the electrode interface. Secondly, due to the removal of unequal electron symmetries, the Au-loaded CNF-LFP exhibits increased electrical mobility with low heat production and, consequently, high thermal resistance [52].

2.2.2. Two-Dimensional (2D) C-LFP

As discussed in the previous section, owing to their excellent electrical conductivity, 1D carbon nanostructures have been routinely integrated into LFP to increase their electrochemical usefulness. In recent decades, the Monolayer 2D material, graphene (G), invented in 2004 with Sp² hybridized structure, has been prominent as a mixture or addition to LFP due to its high electronic conductance (~2 × 10⁵ cm² V⁻¹ S⁻¹), thermal conductance (~5 × 10³ W m⁻¹ K⁻¹), high surface to volume ratio, and excellent mechanical properties; it is widely assumed that graphene can make quite effective structures for cathodes than ordinary carbon additives such as carbon black.

Effects of Fabrication Methods and Additives

The easiest and the most direct way to produce LFP-G composites is to manually combine the two materials that are synthesized separately. However, significant improvement in the electrochemical performances were not observed, resulting in decrease in electron conduction. The decrease in electronic conductivity in such circumstances might be due to inadequate interaction among graphene and LFP. Considering this limitation, Yang et al. developed LFP-G composites using a self-assembly approach based on an electrostatic interplay between LFP and graphene oxide (GO) sheets, resulting in the reduction of GO to G wrapped LFP structures. According to the authors, selective graphene wrapping over LFP can keep ion and electron transport stable within the LFP-G composite, whereas complete wrapping separates LFP from the electrolyte species and thus impedes ion permeation to a certain extent, resulting in higher charge transfer resistance [53,54].

In situ growth of LFP on pre-produced G has promoted the contact between LFP-G, dispersion strength and reduced aggregate formations, resulting in improved ion diffusion. Wang et al. prepared LFP-G composite via in-situ approach using Li₂CO₃ and NH₄H₂PO₄ as precursors. He reported that the concentration of G greater than 5 wt% was additives, which generated notable improvements in the discharge capacity [55]. Yang et al. synthesized homogeneously distributed 2D graphene on 3D LFP porous structure via sol gel technique, with an evolution of xerogel framework comprising GO, LiH₂PO₄ and additives, which gets reduced into G decorated 3D LFP [56]. Another interesting work by Kim et al. and co-workers showcased the separate preparation of GO/FePO₄ and subsequent integration of Li⁺ via the lithiation process holding benefits such as (i) minimal oxidation of Fe²⁺ and (ii) high contact between LFP and G. The developed platelet-like G structure had minimal surface defects allowing straightforward anchoring of Li⁺, which leads to faster ion transfer as Li⁺ ions are available on the surface [57].

Another interesting method is powder extrusion for manufacturing granular LFP-C particles on a polymer matrix as shown in Figure 6a. The extrusion method has several advantages compared to conventional tape casting or compaction techniques. Extrusion offers binder-free and self-standing electrodes with adjustable thickness and areal capacity. Additionally, the morphology preservation after extrusion is outstanding due to the feedstock’s constant pseudoplastic characteristic. Carmen et al. employed an inert extrusion set-up for binding and sintering to achieve a durable carbon coating on LFP and to reduce Fe oxidation [58]. The employed parameters such as loading volume and sintering temperature to prepare ~500 μm thick electrodes were 55 vol% and 650 °C respectively. The areal capacity of the extruded electrode was 13.7 mAh cm⁻²; this finding opens the door for the generation of eco-friendly Li batteries. However, the extrusion process is not suitable for producing electrodes below 20 µm. Cao et al. demonstrated the use of LFP cathodes with glucose-derived carbon and graphene microspheres prepared via solvothermal method having a diameter of 5 to 12 µm [59]. The group used Phytic acid as a source of phosphorus, which also aided in the formation of spherical structures. Figure 6b,c shows the assembled carbon-LFP-graphene composites via solvothermal synthesis. The micro spherical carbon structures contributed to the high-rate capability of 137.3 mAh g⁻¹ at 1 C and the discharge capacity of 163.7 mAh g⁻¹ at 0.1 C. Similarly, morphology-tuned cathodes have the modified electrode interfacial characteristics. For instance, Bao et al. prepared morphology controllable LFP structures by varying the KOH concentration and pH in the hydrothermal method [60]. At first, the self-assembled LFP microspheres were formed, and upon increasing the KOH concentration, the spheres transformed into spindle, needle, and flower shapes, respectively as depicted in Figure 6d. The combined impact of pH and adsorbed K⁺ ions on the surface might underlie the crystal formation process. The OH⁻ anions reflect the increased pH value controlling the multilevel shapes; however, under moderate KOH concentrations, the K⁺ ions contribute to the monodispersed LFP. The LFP flowers exhibited the highest reversible capacity ~145 mAh g⁻¹ with 98% capacity retention and stable cycles.

Effects of Particle Size, Thickness, and Surface Functionalities

Dual coating or compositing of carbon-LFP-G (G-Graphene) structures can improve the electrochemical performance as the overall conductive framework and structural rigidity increases. However, unevenly distributed carbon over LFP or multiple disordered deposition of G/carbon layers may reduce the effectiveness of complete electrode functionality. Further the amount of G composited with LFP has a significant effect on the electrochemical performance. Substantial incorporation of G into LFP has the possibilities of reducing the volumetric energy density due to poor dispersion of G, attributed to large G to smaller LFP ratio and reduces the tap density. The optimal concentration of G in LFP, according to several study groups, is between 2 to 25 wt% [61]. However, it appears that there is no one standard value for comparing these optimal carbon content levels. Considering this, most research suggests that a small proportion and adequate distribution of G are critical, enabling its use as a conduction enhancer in a cell.

The thickness of rGO layer has an impact on the electrochemical performance. Multiple stacking of folded G/rGO layers might result in reduced dispersion of G into LFP and creates aggregates. On the other hand, unfolded stacking of G layers can facilitate the migration of Li⁺ ions evenly from both the electrode direction, decreasing the polarization, and charge transfer resistance [62]. Though, G/rGO/carbon additives improve electron conduction, their excessive usage may hinder the passage of Li⁺ ions. Alternatively, highly porous carbon structures have adequate spacing for the migration of Li⁺ ions between LFP and the active anode material [63]. Considering this, Ha et al. introduced chemically activated G into LFP with the generation of pores during the activation process aided by KOH. Here, KOH gets reduced to metallic K during the activation process, whereas carbon atoms in G undergo oxidation producing carbonates, resulting in the formation of numerous pores on the top of G [64].

Extrusion method can be utilized to change the electrode thickness (from over 20 µm to a few µm), but recent researchers suggest that the carbon thickness must be kept below 20 µm for high electrochemical performance. Yi Cui and group demonstrated a new technique for producing Li-rGO anode below 20 µm thickness by employing a calendaring process for rGO preparation followed by contact loading of molten Li, as shown in Figure 7a [65]. The same can be possibly used for preparing LFP-carbon cathodes. Similarly, Yang et al. and colleagues used a different technique for fabricating LFP nanosheets of ~15 nm thickness. The group used ultrasonic waves to exfoliate LFP (Figure 7b) and subsequently self-assembled with rGO via amido bonds. Here, the large percentage of (010) facets accessible to LFP reduces the distance of the diffusion path, improving the transport rate of Li-ions. Furthermore, sintering the self-assembled rGO for adhering it into LFP enables an efficient conductive matrix, facilitating electron transmission. The ultrathin diffusion path with conductive rGO matrix enabled a high-rate discharge of 102 mAh g⁻¹ at 30 C with 93.4% capacity retention after 500 cycles [66].

Owing to huge surface area and enhanced electrical conduction, 2D materials have become an effective battery electrode. In this regard, next to graphene, Ti₃C₂T_x and Mxene structures have received the most particular attention for functionalizing with carbon-coated LFP. Furthermore, Mxene’s surface reactive groups promote its solubility and dissolution rate and thereby making it simpler to integrate with additional compounds.

2.2.3. 3D Carbon LFP Composite

As previously stated, graphene has a large surface area as well as a high electrical conductivity. However stacking of multiple layers and porosity are crucial factors to be considered while designing LFP-G electrodes. Many benefits, such as systematic porosity pathways, excellent electronic conductance, and outstanding mechanical strength, may be found in the 3D carbon nanostructure due to structural interconnections. More research in the realm of 3D C-LFP is required for optimizing the performance characteristics. At present, in situ template synthesis and polymerization reactions aid in fabricating 3D C/LFP. Weng et al. and colleagues used a one-step condensation polymerisation reaction to prepare the precursor, hydroquinone-formaldehyde resin (HFR). Then, NH₄H₂PO₄, Fe(NO₃)_3, and Li(OH)₂ were then mixed with the HFR and subsequently carbonized at 600 °C for obtaining LFP/3D carbon structures. Next, they synthesized 3D carbon/LFP in-situ using glucose as a carbon source for comparison. Due to carbonization and polymerization, a solid 3D structure with higher number of internal pores were reported; these internal pores boost the Li⁺ ion migration and the electrochemical conversion efficiency. The 3D solid sourced from glucose and HFR polymerization has resulted in the discharge capacity of 151.1 mAh g⁻¹ and 169.3 mAh g⁻¹ at 0.1 C, due to the interconnected porous structure [67]. Porous 3D LFP-G composites were found to increase the conductivity and reversible capacity even at varied current densities [68].

Xing et al. fabricated a 3D LFP/C conductive, porous, core-shell structure with 2D carbon thin coating (~2 nm) using template synthesis, exhibiting high ionic and electrical conductivities. The discharge capacity of LFP/C was 166 mAh g⁻¹ at 0.1 C with 98% active material utilization, while the mass loading of active material was 80%. The 3D LFP/C structure increased the interfacial contact between the electrolyte and electrode, allowing for better ionic diffusion and increased electrical conductivity. According to the recorded CV curves and Randles–Sevcik Equation (equation to find peak current in the diffusion-limited process), the 3D LFP/C has a linear relationship (i.e., Ip, the peak current, is proportional to the square root of scan rate) with a diffusion coefficient of 1 × 10⁻¹⁰ cm² s⁻¹. [69]. In another study, LFP/C nanowires with a 3D nano framework were synthesized using a controllable self-assembly process, where amylose was used as one of the precursors. Amylose has a unique spiral structure with short branches serving as a carbon source and a self-assembly stimulator of other precursors along its core axis. The amorphous carbon from the short chains connects the co-axis 1D LiFePO₄/C nanowires to the intricate 3D nano-framework structure [70]. In a different way, pechini-assisted polyol synthesis and electrospinning were used to prepare 3D LFP/C with cauliflower-like morphology. The surface examination of the produced composites indicated a homogenous coverage of carbon nonwoven nanofibers and uniform distribution of crystals. The 3D LFP/C showed an excellent discharge capacity of 156 mAh g⁻¹ at C/25 discharging rate [71].

Recently, composite of CNT has been used with a 3D LFP cathode in the shape of nanoribbons via crosslinking of bisphosphonate (risedronic acid) by insitu hydrothermal method. The prepared 3D structure was found to have size less than 300 nm with perfect olivine structure, promoting the cell performance to 162.2 mAh g⁻¹ beyond 800 cycles; this was ascribed to the size effect and coverage of 3D LFP with porous CNT [72]. Chen et al. developed a fusion of 3D networks consisting of LFP-CNT doped with nitrogen that combines the benefits of nanotubes and nitrogen doping sourced from PVP. Additionally, a simple ball milling synthesis method followed by sintering was used to produce nitrogen doped LFP-CNT composite. The calcination temperatures (550 °C, 650 °C, 750 °C) and duration were varied for obtaining the different LFP-CNT samples. The polarization losses and impedance have been reduced significantly owing to maximum capacity ~100 mAh g⁻¹ with 95.7% capacity preservation for LFP calcined at 750 °C for 5 h [73]. In another work, high temperature synthesis was used to prepare 3D CNT-LFP using polyethylene glycol, as shown in Figure 8a. PEG acted as a conductive additive, binder and dispersant enabling high reversible capacity and ion mobility [74]. Lin et al. used Metal Organic Framework (MOF) to derive C-LFP cathodes with F and O co-doping via a solid sintering process [23]. The experimental process is shown in Figure 8b. At first, the Fe-MOF was prepared using a solvothermal self-assembly process and mixed, sintered with ammonium fluoride and ammonium dihydrogen phosphate. Finally, the prepared MOF-derived LFP was encapsulated in an O doped carbon matrix. Because of its greater sorption capacities and reduced Li transport obstacles, the dense carbon matrix becomes thermodynamically advantageous, supporting more reaction species and enhancing the diffusion rate and electron conductivity. The MOF-derived C-LFP had a remarkable specific capacity of 169.9 mAh g⁻¹ at 0.1 C.

Qian et al. reported the formation of macro-mesoporous 3D bicontinuous LFP/C nanocomposites via the microwave-assisted solvothermal method with sucrose as a carbon source. The LFP/C composite showed excellent cycling stability with 87% capacity retention after 1000 cycles at 2 C charge-discharge rate and a discharge capacity of 129 mAh g⁻¹ at 2 C. The rapid synthesis method favored forming several 3D macropores, which promote Li⁺ ions diffusion, and the mesopores being an active reaction site enhances the cycle life [75]. Carbon coating improves electrical conductivity with Fe³⁺ to Fe²⁺ redox transition and increases the polarization. Researchers from National Taipei University, Taiwan, recently reported the high-performance 3D mesoporous carbon encapsulated LFP, delivering a specific capacity of 184.8 mA h g⁻¹, higher than the theoretical capacity of LFP (170 mAh g⁻¹). After 1000 cycles, at a higher current rate of 10 C, the 3D LFP/C reveals an excellent discharge capacity of 120 mA h g⁻¹ with 96.7% capacity retention [76].

Table 2. Preparation methods and performance of C-LFP cathodes in LIBs.

Source of Carbon	Type of Carbon/LFP	Preparation Methods	Performance	Reference
Graphite	C-rGO/LFP	Modified Hummer’s method, In-situ polymerization	168 mAh g−1 at 0.05 C	[77]
Graphite	rGO/LFP	Ball milling, modified Hummer’s method	158 mAh g−1 at 0.1 C	[78]
Graphite	Graphene/LFP	Graphite oxidation, thermal treatment, and chemical reduction	142 mAh g−1 at 0.1 C	[79]
Graphite	Nitrogen doped C/LFP	Electrostatic grafting	171.9 mAh g−1 at 0.1 C	[80]
Graphite	Boron doped C/LFP	Solgel, Thermal treatment, Modified Hummers method	162.2 mAh g−1 at 0.1 C	[81]
Commercial	LFP/MWCNT	Hydrothermal	121 mA h g-1 at 1 C	[82]
Commercial	LFP/MWCNT	Hydrothermal, heat treatment	160.3 mAh g−1 at 0.3 C	[83]
Commercial	LFP/MWCNT	Plasma treatment	114 mAh g−1 at 1 C	[84]
Commercial	LFP/MWCNT	Spray drying	157.4 mAh g−1 at 0.2 C	[85]
Commercial	LFP/MWCNT	Vacuum freeze drying/solvothermal	152.7 mAh g−1 at 1 C	[86]
Commercial	LFP/MWCNT	tape-cast fabrication	144.9 mA h g−1 at 0.1 C	[87]
Commercial	LFP/MWCNT	Chemical synthesis	~192 mAh g at 0.1 C	[88]
Commercial	LFP/CNT	Co-precipitation	195 mAh g−1	[43]
Commercial	3D LFP/CNT-PVP	CVD, Vacuum drying	123 mAh g−1	[89]
Commercial	C-LFP	Wet processing	143.8 mAh g−1 at 1 C	[90]
Commercial	C/LFP	Solgel	150 mAh g−1	[91]
Graphene	G/LFP/C	Ball mill, solid state reaction	163.8 mAh g−1 at 0.1 C	[92]
Graphene oxide	LFP/C/rGO	Solvothermal, carbon coating	129 mAh g−1	[93]
CNT	LFP/MWCNT	3D printing	1.44 mA h cm−2 at 0.5 C	[94]
CNT	LFP/C/CNT	Sol-gel	158 mA h g−1 at a rate of 1 C	[95]
CNT	LFP/Core shell	Solvothermal, liquid deposition	132.8 mAh g−1 at 0.2 C	[96]
Glucose	LFP/C	CVD, Thermal processing	89.69 mAh g–1 at 200 C	[97]
Glucose	C/LFP	Hydrothermal synthesis	162 mAh g−1 at 1 C	[98]
Glucose	Graphite sheet/N doped C/LFP	Insitu plasma treatment	100.7 mAh g−1 at 150 C	[99]
Glucose	C/LFP	Hydrothermal, calcination	170 mAh g−1	[100]
Glucose	C-LFPsupra balls	Solvothermal, Thermal treatment	162 mAh g−1 at 1 C	[101]
Fructose	C/LFP	Hydrothermal	98 mAh g−1 at 0.1 C	[102]
Sucrose	C/LFP	Vacuum deposition	123.9 mAh g−1 at 5 C	[103]
Chitosan	C/LFP	Freeze drying, thermal processing	155.5 mAh g−1 at 0.1 C	[104]
Citric acid	C/LFP	Ball mill, heat treatment	148.3 mAh g−1 at 0.1 C	[105]
Citric acid	Graphitized LFP/C	Insitu synthesis	164 mAh g−1 at 2 C	[106]
Citrate	Co doped C-LFP	Combustion method	49 mAh.g−1 at 2.4 mg.cm−2	[107]
Citric acid	LFP/C	Solgel	93.54 mAh g−1	[108]
Polymer	C/LFP Core-shell	Chemical synthesis	120.2 mAh·g−1	[109]
Polystyrene	C/LFP	Carbothermal reduction	147 mAh·g−1 at 0.1 C	[110]
xylitol-PVA	C/LFP	Ball mill, Chemical treatment	Volumetric energy density17.8 Wh L−1 at 10 C	[111]
PVDF	Fluorine doped C-LFP	Ball mill, rheological solid state phase method	100.2 mA h g–1 at 20 C	[112]
Thermoplastic polyurethane/Super P	LFP/C	phase separation	153 mAh g−1 at 0.2 C	[113]
N-methylimidazole	C-LFP	Colloidal synthesis	164 mAh g−1	[114]
butyl-3-methylimidazolium dicyanamide	Nitrogen doped C/LFP	microwave pyrolysis	133.6 mAh g−1	[115]
Oleylamine	LFP/C	Supercritical alcohol, calcination	84 mAh g−1 at 20 C	[116]
[BMIm]N(CN)2—Ionic liquid	C-LFP	microwave-assisted pyrolysis	149.4 mAh g−1	[117]
[VEIm]NTf2—Ionic liquid	C/LFP	Hydrothermal	136.4 mAhg− 1 at 0.1 C	[118]
Polybenzoxazine	LFP/Nitrogen doped C	Thermal treatment	156.9 mA h g−1	[119]
Dopamine, polyethylene glycol	Nitrogen doped C-LFP	Spray drying	156 mAh g−1 at 0.1 C	[120]
[BMIM]BF4—Ionic liquid	Fluorine doped N-C-LFP	Hydrothermal	162.2 mAh g−1 at 0.1 C	[121]
Mxene	Mxene/LFP/C	Electrostatic self-assembly	156.6 mAh·g−1 at 1 C	[122]

shows the preparation methods and performance for various carbon sources for C-LFP. From Table 2, it can be observed that the specific capacity ranged from 120 mA h g⁻¹ to 165 mA hg⁻¹. One of the works using MWCNT/LFP reported 195.2 mA h g⁻¹ and hydrothermal, solvothermal, carbothermal and in-situ synthesis are mostly used. Microwave-assisted synthesis resulted in a decent capacity of 133.6 mAh g⁻¹.

3. Effects of Electrolyte in Performance of C-LFP

Electrolyte type has a significant influence on LIBs performance. Solid-state electrolytes, especially polymer electrolytes popularized by Armand et al. are safer, sustainable, and hold high energy densities [122,123,124,125,126,127]. Perhaps, liquid electrolytes that are electrochemically, mechanically, and thermally stable, paired with a polymer/ceramic separator, could help until solid electrolytes become commercially viable. Armand et al. developed salts such as LiTFSI, TFSI, LiFPFSI and DFTFSI and polymers such as polyethylene oxide (PEO), pentaerythritol tetraacrylate (PETEA) for solid polymer electrolytes (SPE) [14]. Nanosized carbon, Si, and alumina fillers have been shown to increase the ionic conduction of SPE with the conductance augmentation being more beneficial for smaller nanofillers. The clumping of fillers in SE, on the other hand, inhibits ionic charge transport enhancement. Other challenges such as formation of Li dendrites, unstable electrochemical window, and conductivity concerned with SPE, are recapturing to be optimized by the researchers. Integration of ionic liquids into the polymer electrolytes has enhanced the conductivity. All solid-state LIBs could be the future version of rechargeable batteries, according to studies published in the previous few years.

4. Conclusions and Prospects

The evolution of LIBs was influenced by research on LFP since this compound has considerably increased the reliability, safety, and sustainability. However, because of the reduced work potential (3.1 V), low tap density, and limited ionic conductivity, research on substantial materials and cell fabrication optimizations are essential. Carbon layer thickness, surface area, porosity, and surface functionalities have all been proven in the previous literature, indicating the viability of rapid charging in the foreseeable. Particularly, in the recent years, doping of graphene, Mxene, and MOFs with porous carbon have resulted in the improved working potential and ion transport. The incorporation of conductive additives with high specific surface area has increased the conductivity of C/LFP.

Utilizing in situ, in operando characterization tools for real time detection and analysis of cell performance is recommended. Modern advancements in simulation tools, machine learning, and data science could possibly help for optimizing the electrode materials in LIBs. Moreover, future batteries are expected to be fully solid state considering the safety, energy density, and sustainability. In the near future, data science and artificial neural networks will make the process of selecting acceptable and potential solid-state electrolytes, electrodes, and cell components quicker by lowering experimental expense and time; it is impossible to predict which of the foregoing multiple alternatives will be the victor for subsequent generations of LFP based LIBs. Overall, with suitable modification, the truly excellent C-LFP is expected to bring a wide range of benefits to the energy storage sector in the forthcoming years.