Recycling, Volume 7, Issue 4 (August 2022) – 20 articles

This review paper shows several sections of bitumen, asphalt mixtures, polymers, and waste plastic in pavement engineering. The paper reviews and evaluates the influence of using waste polymer in improving the rheological and engineering properties of the modified binder and mixtures. Evaluation of properties and design of stone mastic asphalt mixtures are reviewed. Reports and studies had investigated the advantages and importance of using polymer in bitumen modification; however, they yet show a gap in research in terms of the role of waste polymer in improving the durability, aging, and fatigue life in the long term of service. Full article

Few prior studies have examined the social and environmental consequences of waste generation and recycling, resulting in a policy gap in the sustainability agenda. The research filled a knowledge vacuum in the literature by investigating the environmental repercussions of different waste generation and recycling processes in the Chinese economy. The study analyzed waste production and recycling statistics over the last 46 years, from 1975 to 2020, and their impact on the nation’s emissions per capita. This study used four primary approaches to determine the links between the examined variables, beginning with the unit root test, which identifies the stationary process of the variables’ underlying processes. Second, the autoregressive distributed lag (ARDL) model was used to produce the variables’ short- and long-run estimates. Third, estimations of Granger causality examined the causal relationships between the variables. Finally, innovation accounting matrices (IAM)were utilized to predict the relationships between variables during the following decade. The unit root estimates imply the mix order of variable integration; hence, it is appropriate to employ ARDL modeling for parameter estimations. The ARDL estimations demonstrate that combustible renewables and waste decrease a nation’s carbon emissions by boosting industrial waste recycling. Despite recycling systems, carbon emissions have escalated to uncontrolled levels owing to the massive production of municipal solid garbage. Sustainable waste management and recycling are vital to reducing carbon emissions. Granger’s estimations of causation imply that combustible renewables and waste and carbon emissions cause industrial and municipal solid waste recycling. Additionally, population growth is responsible for greenhouse gas emissions, biowaste recycling, and industrial waste recycling. Furthermore, this shows the two-way connections between combustible renewables and waste and carbon emissions, implying the need to develop green waste recycling strategies in a nation. The IAM method identified future relationships between variables, which aids policymakers in implementing sustainable waste management practices for a nation. This study concludes that the environmental consequences of waste generation and recycling impede the nation’s circular economy agenda, which can be sustained by knowledge spillovers, chemical reduction in manufacturing, and allocating a certain amount of US dollars to ecological resource conservation. Full article

This study pertains to incorporation of coffee silverskin (CSS) in partial replacement for ordinary Portland cement (OPC) in mortar, by investigating its fresh properties (setting and workability), compressive strength (3, 7, 14 and 28-day), absorption and microstructural characteristics. The objectives were to reduce environmental solid wastes and achieve cost efficiency in the use of construction materials. The CSS was expressed as a ratio of total binder (CSS/(OPC + CSS)) and varied from 0 to 5%. The findings revealed that CSS could reduce workability, setting time and early strength. It could also enhance the absorption of the CSS-blended mortar (CBM). The cause of reduction in workability was due to its contribution to the viscosity of the mixture due to the emulsification of the fat component (acetate) and aromatic compounds, as observed in the Fourier Transform Infrared (FTIR) spectroscopy and X-ray diffraction techniques. The presence of these compounds also caused microstructural disintegration that resulted in the lower strength. In addition, the presence of other organic compound in CSS but absent in OPC enhanced microstructural disintegration and porosity in CBM. The 28-day strength of 25 MPa could be achieved in CSS-blended mortar if the CSS/(CSS + OPC) ratios were kept below 3%. The maximum compressive strength of 38.5 MPa was obtained with the optimum CSS content of 1 wt%. The relative density (water) of CSS was 0.345; therefore, it could also be used to produce lightweight concrete. This study promotes the valorization of raw CSS waste as construction material which could be used for subgrade in the construction of road pavement. Full article

PET bottle waste is easy to recycle because it is easy to separate, abundant, and competitively priced. Technologies for the treatment of PET bottle waste have been evaluated to date by using life cycle assessment (LCA), but this does not take into account all of the aspects that policymakers consider necessary when selecting an acceptable technology. Aspects such as society, economics, policies, and technical applicability need to be considered along with the environment and resource consumption to complement the LCA results for PET bottle waste. These aspects were selected as criteria for the analytical hierarchy process (AHP), and stakeholders were invited to make a comparison evaluation of the criteria and sub-criteria. Academics were involved to compare the technology options. The results show that society is the highest priority because it is the main actor that ensures the application of the technology, and that job creation is the most important indicator for the selection of the technology in society criteria. After comparing open landfills, sanitary landfills, incineration with energy recovery, pelletizing, glycolysis, and hydrolysis for the utilization of PET bottle waste, this study suggests pelletizing as the acceptable technology for Indonesia because pelletizing is dominant in all the criteria and sub-criteria which support sustainability in waste management. This is the first time that a single plastic fraction that is easy to collect and recycle has been studied with the AHP. The results show that this type of plastic could also be reused in developing countries through mechanical recycling. Full article

The fashion industry is becoming one of the largest emitters worldwide due to its high consumption of raw materials, its effluents, and the fact that every garment will eventually contribute to the vast amount of waste being incinerated or accumulating in landfills. Although fiber-to-fiber recycling processes are being developed, the mechanical properties of the textile fibers are typically degraded with each such recycle. Thus, tertiary recycling alternatives where textiles are depolymerized to convert them into valuable products are needed to provide end-of-life alternatives and to achieve circularity in the fashion industry. We have developed a method whereby cotton waste textiles are depolymerized to form a glucose solution, using sulfuric acid as the sole catalyst, with a high yield (>70%). The glucose solution produced in this process has a high concentration (>100 g/L), which reduces the purification cost and makes the process industrially relevant. This method can be applied regardless of the quality of the fibers and could therefore process other cellulosic fibers such as viscose. The glucose produced could subsequently be fermented into butanediol or caprolactam, precursors for the production of synthetic textile fibers, thus retaining the value of the waste textiles within the textile value chain. Full article

The environmental concerns regarding the production of the most widely consumed cement construction material have led to the need for developing sustainable alternatives. Using recycled industry waste products such as fly ash and slag via geopolymerisation has led to the development of geopolymer cement—an efficient replacement for ordinary Portland cement (OPC). Adopting geopolymer cement and concrete as a construction material reduces greenhouse gas and promotes the recycling of waste products. This study explores the suitability of a unique geopolymer concrete mix made of recycled cementitious materials including industry waste products such as fly ash, micro fly ash and slag for use in aggressive environments. Sorptivity tests are conducted to assess the durability of concrete and indicate the cementitious material’s ability to transmit water through the capillary forces. This study thus reports on the sorptivity characteristics of a newly developed self-compacting geopolymer concrete and two other fibre geopolymer concrete mixes containing 1% (by weight) of 12 mm- or 30 mm-long basalt fibres. The addition of basalt fibres indicated less water absorption and moisture ingress than the mix without fibres. The study used 18 specimens from three geopolymer concrete mixes, and the results showed that adding fibres improved the durability performance in terms of resistance to moisture ingress. Finally, an artificial neural network model is developed to predict the absorption rates of geopolymer concrete specimens using MATLAB. The prediction models reported excellent agreement between experimental and simulated datasets. Full article

The removal of dissolved organic carbon (DOC) and total polyphenols (TPh) from agro-industrial wastewater was evaluated via the application of coagulation–flocculation–decantation (CFD) and Fenton-based processes. For the CFD process, an organic coagulant based on Acacia dealbata Link. leaf powder (LP) was applied. The results showed that the application of the LP at pH 3.0, with an LP:DOC ratio of 0.5:1 (w/w), achieved a high removal of turbidity, total suspended solids (TSS), and volatile suspended solids (VSS) of 84.7, 79.1, and 76.6%, respectively. The CFD sludge was recycled as fertilizer in plant culture (germination index ≥ 80%). Afterwards, the direct application of Fenton-based processes to raw WW was assessed. The Fenton-based processes (UV/Fenton, UV/Fenton-like, and heterogeneous UV/Fenton) showed high energy efficiency and a cost of 1.29, 1.31 and 1.82 €/g/L DOC removal, respectively. The combination of both processes showed the near complete removal of TPh and DOC after 240 min of reaction time, with high energy efficiency. In accordance with the results obtained, the combination of CFD with Fenton-based processes achieves the legal limits for the disposal of water into the environment, thus allowing the water to be recycled for irrigation. Full article

Increased fashion consumption spurred by fast fashion has led to excessive textile waste, giving rise to a global crisis as textile waste pollutes land and waterways, while landfill and incineration contribute to global greenhouse gas emissions. Extending a product’s life for as long as possible is a core principle of the circular economy (CE) to ensure that the maximum value of the original product is realized over its lifetime. As such, repair is an essential component of a CE because it supports the preferred waste hierarchy elements of reduce and reuse, with recycling being the last resort in a CE necessary to close resource loops. Consumers are an essential enabler of a CE; therefore, it is critical to understand consumers’ characteristics in the context of behaviors such as repair. The purpose of this study was to examine the role of gender on engagement in clothing repair practices; women have often only been the focus of clothing repair studies. An online survey was conducted to collect responses from Canadian and U.S. consumers (n = 512). Findings showed that self-repair was the most common form of clothing repair, with women being more highly engaged in self-repair practices, increasing with age. Paid repair is the type of repair that has the lowest level of engagement, and there are only negligible differences between the genders. Men utilize unpaid forms of repair more than women. However, among the youngest age group (18–24), both genders are equally likely to have clothing repaired for free. Gender gaps exist, but opportunities for increased utilization in repair can be created to encourage full participation within a CE. In particular, the findings point to the importance of increasing repair activities amongst men and younger consumers. Full article

This paper investigates the factors influencing the behavior of individuals in source-separation of municipal solid waste in an immature system for collection of recyclable waste (Saint Petersburg, Russia) and a more mature waste system (selected urban areas, Finland). Online questionnaires were applied to collect data from citizens of Saint Petersburg and the Finnish urban population. The data were examined within an extended theory of planned behavior using structural equation modeling for the identification of factors affecting waste source-separation behavior. The findings indicate that the factors differed significantly in the two waste systems. In Russia, the inconvenience of waste collection limited waste source-separation behavior, while intentions of individuals and information availability had an almost equal positive effect. In Finland, waste source-separation behavior was mostly affected by people’s intentions. Based on the findings, recommendations for the development of recycling practices were made for practitioners in Russia and possibly other early-stage systems for the collection of recyclable waste. Limitations of the study pinpointed the possibilities for future research. Full article

Geopolymer concrete (GC) has the potential to incorporate recycled concrete aggregates (RCA) obtained from construction and demolition waste. This research aims to review the current state-of-the-art knowledge of the RCA in GC and identify the existing knowledge gaps for future research direction. This paper highlights the essential factors that impact the GC’s mechanical and durability properties. Moreover, the influence of various percentages of coarse and fine RCA and the pattern of their replacement will be assessed. The effect of aluminosilicate material, alkaline activators, and curing regime also will be evaluated. Besides, the durability-related characteristics of this concrete will be analysed. The impact of exposure to a higher temperature, freeze–thaw cycles, marine environment, and acid and alkali attack will be comprehensively reviewed. A literature review revealed that increasing alumina silicate content, such as slag and metakaolin, and increasing the Na₂SiO₃/NaOH ratio and alkali-activator-to-binder ratio improve the hardened GC. However, increasing slag and metakaolin content and the Na₂SiO₃/NaOH ratio has an adverse impact on its workability. Therefore, finding the optimum mix design for using RCA in GC is vital. Moreover, there is a scope for developing a self-compacting GC cured at ambient temperature using RCA. Full article

The extraction of precious minerals leaves behind an important amount of tailings. When stored in nature, these tailings contribute to environmental degradation. To reduce this degradation, tailings are incorporated in construction as substitute to natural materials. The objective of this study was to use a design of experiments (DOE) to reveal how the substitution of natural river sand (NRS) by gold mine tailings (GMT) in concrete manufacturing can be optimally achieved. This DOE considered three constituents: the amounts of NRS/GMT, that of gravel and of cement. The experimental domain was defined within the concrete standards dosage of 350 kg/m³ and 400 kg/m³ as the lower and upper levels, respectively. The smallest compressive strength on standard cubic specimens on the 28th day varied between 11 N/mm² and 37 N/mm² following to the experimental domain. The values of the compressive strength of the experiments carried out allowed to acquire the model of the strength with the coefficients of each factor: $Strength=23.25-5.86*A+4.56*B-1.96*C-0.56*A*B+1.41*A*C+1.08*B*C+0.71*A*B*C$ (with A: GMT+NRS; B: cement; C: gravel). The values of the cumulative weight of the coefficients of each factor were 36.7% (A), 64.5% (B) and 76.6% (C). The study also found that a larger dosage of gravel (40 kg) improves the concrete compressive strength when GMT substitutes NRS between 70% and 100% and when 15 kg of cement is used. For a sustainable and better reuse of GMT as construction materials, an economic and environmental study (the leaching of metals) of the concrete based on GMT would be ideal to consider a large scale production. Full article

Agricultural land degradation, urban migration, increasing food demand and waste, and inadequate sanitation systems all affect farmers, local society, and the environment in South India. Joint recycling of biodegradable secondary household resources to close nutrient cycles between urban and rural regions can address all these challenges and thus several SDGs at the same time. Efforts are being made to this end, but many attempts fail. The central research question is, therefore: how can co-recycling concepts be evaluated in this context? For this purpose, composting plants, biogas fermenters, and a high-tech concept to produce plant charcoal, design fertilizer, and biopolymers are considered. The aim of this study is to evaluate the recycling concepts from the stakeholders’ perspective to avoid gaps between theory and practice. Six expert and one focus group interviews on two successful on-site case studies and 15 online expert interviews with thematic actors were qualitatively evaluated and presented in a social network analysis to identify preferences and indicators for the further evaluation of co-recycling concepts. The results show that the focus is on mature technologies such as compost and biogas. High-tech solutions are currently still in rudimentary demand but will play a more important role in the future. To evaluate such concepts, seven key indicators and their measured values were identified and clustered into the categories ecological, social, technical, economic, and connective. The results show that this methodology of close interaction with stakeholders and the evaluation of successful regional case studies minimize the gap between practice and theory, contribute to several goals of the SDGs, and thus enable such concepts to be implemented sustainably. Full article

A large number of battery pack returns from electric vehicles (EV) is expected for the next years, which requires economically efficient disassembly capacities. This cannot be met through purely manual processing and, therefore, needs to be automated. The variance of different battery pack designs in terms of (non-) solvable fitting technology and superstructures complicate this. In order to realize an automated disassembly, a computer vision pipeline is proposed. The approach of instance segmentation and point cloud registration is applied and validated within a demonstrator grasping busbars from the battery pack. To improve the sorting of the battery pack components to achieve high-quality recycling after the disassembly, a labeling system containing the relevant data (e.g., cathode chemistry) about the battery pack is proposed. In addition, the use of sensor-based sorting technologies for peripheral components of the battery pack is evaluated. For this purpose, components such as battery pack and module housings of multiple manufacturers were investigated for their variation in material composition. At the current stage, these components are usually produced as composites, so that, for a high-quality recycling, a pre-treatment may be necessary. Full article

One of the challenges of using recycled materials in road structures is to maintain safe and durable pavements. A multitude of research has been conducted over the years on various recycled materials, with a focus on the structural performance of pavements. Another crucial, but almost overlooked, aspect is the pavement’s ability to provide adequate skid resistance for road users under different climatic conditions. With this in mind, the present study aimed to investigate the skid resistance of asphalt mixtures containing two different types of recycled materials under laboratory-simulated weather conditions. Conventional hot-mix asphalt (HMA) and mixtures containing either reclaimed asphalt pavement (RAP) for aggregate replacement or crumb rubber (CR) as a bitumen additive were prepared and tested at different temperatures and different surface conditions (i.e., dry/wet) following a wetting protocol. Skid resistance was measured using a British Pendulum Tester (BPT). The results showed that the recycled mixtures performed similarly to conventional ones in terms of the skid resistance when the temperature was varied and under variable simulated surface conditions too. In some cases, they performed even better than conventional mixtures. Overall, a promising potential is demonstrated towards the use of the investigated recycled materials in asphalt surface courses. Full article

Wales is one of the world leaders in household waste recycling with a steady recent recycling rate of ~65%. The Welsh Assembly Government (WAG) set a statutory target of achieving a 70% recycling rate by 2024/25. We reviewed historical trends in waste management in Wales from 2006 to 2020, with a focus on recycling. Authoritative, official data were obtained from WasteDataFlow, an Internet system for municipal waste data reporting by UK local authorities to government. Data are collected quarterly allowing the generation of time series plots, trendlines and like-for-like comparisons between groupings of various characteristics, such as number of separate kerbside collections, income, political preference, and impact of policy changes. Results showed that the approach taken by the WAG to politically prioritise and encourage participation in household recycling has achieved impressive results that contrast starkly with the recycling performance of other UK countries. In Wales, household waste disposed annually per person via landfill decreased from ~410 kg to <50 kg and household waste recycled increased from to ~150 kg to ~310 kg, with a recent increase in incineration with energy recovery to ~135 kg as infrastructure has come online. Recycling rates show a seasonal variation due to increases in garden waste sent for composting in the summer. There are variations in local authority performance across Wales, mainly caused by variations in the number of separate collections. Co-mingled collections tend to lead to higher contamination of recyclates that are then not able to be sold for recycling. Deprivation, as indicated by differences in income, also influences total waste arisings and recycling rates. A plateau of ~65% recycling rate was reached in 2020, with incineration reaching a rate of >25%. The recycling rate plateaus at exactly the same time as incineration comes on stream. Evidence demonstrates that improvements to recycling rates can become more difficult when incineration becomes available. Whilst further reductions and improvements to recycling in Wales will be more challenging, the WAG’s track record of focused proactive political and policy support shows what can be achieved when there is suitable political will. The WAG has demonstrated that it tends to deliver on its waste-related plans, and it clearly has the best chance of any of the UK’s four countries of achieving its aims. Full article

Lead–acid batteries are important to modern society because of their wide usage and low cost. The primary source for production of new lead–acid batteries is from recycling spent lead–acid batteries. In spent lead–acid batteries, lead is primarily present as lead pastes. In lead pastes, the dominant component is lead sulfate (PbSO₄, mineral name anglesite) and lead oxide sulfate (PbO•PbSO₄, mineral name lanarkite), which accounts for more than 60% of lead pastes. In the recycling process for lead–acid batteries, the desulphurization of lead sulfate is the key part to the overall process. In this work, the thermodynamic constraints for desulphurization via the hydrometallurgical route for recycling lead pastes are presented. The thermodynamic constraints are established according to the thermodynamic model that is applicable and important to recycling of lead pastes via hydrometallurgical routes in high ionic strength solutions that are expected to be in industrial processes. The thermodynamic database is based on the Pitzer equations for calculations of activity coefficients of aqueous species. The desulphurization of lead sulfates represented by PbSO₄ can be achieved through the following routes. (1) conversion to lead oxalate in oxalate-bearing solutions; (2) conversion to lead monoxide in alkaline solutions; and (3) conversion to lead carbonate in carbonate solutions. Among the above three routes, the conversion to lead oxalate is environmentally friendly and has a strong thermodynamic driving force. Oxalate-bearing solutions such as oxalic acid and potassium oxalate solutions will provide high activities of oxalate that are many orders of magnitude higher than those required for conversion of anglesite or lanarkite to lead oxalate, in accordance with the thermodynamic model established for the oxalate system. An additional advantage of the oxalate conversion route is that no additional reductant is needed to reduce lead dioxide to lead oxide or lead sulfate, as there is a strong thermodynamic force to convert lead dioxide directly to lead oxalate. As lanarkite is an important sulfate-bearing phase in lead pastes, this study evaluates the solubility constant for lanarkite regarding the following reaction, based on the solubility data, PbO•PbSO₄ + 2H⁺ ⇌ 2Pb²⁺ + SO₄²⁻ + H₂O(l). Full article

A dramatic increase in plastic waste has resulted in a strong need to increase plastic recycling accordingly. A selective flotation has been highlighted due to its outstanding efficiency for the separation of mixed plastics with analogous physicochemical characteristics. In this study, the effects of design and operational factors on the bubble’s hydrodynamic and mixing parameters in induced air flotation (IAF) with a mixing device were investigated through a design of experiment method (DOE) analysis for improving the plastic separation efficiency (i.e., PS and ABS). As a result of DOE analysis, the increase in the induced air tube diameter together with the rotational speed could generate a smaller bubble size. This led to the enhancement of the ratio of interfacial area to velocity gradient (a/G), which was interestingly found to be a significant factor affecting plastic recovery apart from the chemical agents. It demonstrates that operating IAF with a mixing device at a greater a/G ratio improved the plastic separation performance. These findings suggest that operating an IAF process with a mixing device at suitable a/G conditions could be a promising technique for separating plastic wastes, which have similar physicochemical characteristics as PS and ABS. Full article

Recycled aggregates (RAs) have been playing an important role in replacing natural aggregates (NAs) in concrete production, thereby contributing to a reduction in the extraction of natural resources and the promotion of a circular economy. However, it is important to assess the global impacts of this replacement, in both environmental and economic terms. In this study, an overview of the impacts of the production of natural and recycled aggregates is presented, using the life cycle assessment (LCA) methodology. Through this methodology, products with the same function are compared and information about the best solutions is given, considering their environmental and economic impacts. Studies with data collected from specific producers were compared, as well as environmental product declarations (EPDs) and generic databases, regarding the production of natural and recycled, coarse and fine, and rolled and crushed aggregates. This study intends therefore to provide the environmental and economic impact comparison at the global level through LCA from different data sources. According to this literature review, the best and worst environmental results are assigned to lower and higher transport distances, respectively. Regarding EPDs, the lowest environmental impacts are related to recycled coarse aggregates and the highest to natural coarse crushed aggregates. In terms of generic databases, the results are similar, with the lowest impacts associated with natural fine rolled aggregates and the highest to natural coarse crushed aggregates. In what concerns the economic impacts, in general, recycled aggregates are associated with the lowest costs. However, these results are highly dependent on transport distances and costs. Full article

Circularity and recycling are gaining increased attention, yet the amount of recycled plastic applied in new products remains low. To accelerate its uptake by businesses, it will be useful to empirically investigate the barriers, enablers, needs and, ultimately, requirements to increase uptake of recycled plastic feedstock for the production of new plastic products. During the six focus group sessions we conducted, a value chain approach was used to map the factors that actors face regarding the implementation of recycled materials. The identified factors were structured based on three levels: determining whether a certain factor acted as a barrier or enabler, identifying the steps in the value chain that the factor directly affected and the category it could be subdivided into. The results were then further processed by translating the (rather abstract) needs of businesses into (specific) requirements from industry. This study presented eight business requirements that require actions from other actors in the value chain: design for recycling, optimised waste processing, standardisation, material knowledge, showing possibilities, information and education, cooperation, and regulation and government intervention. The main scientific contributions were the value chain perspective and the applied relevance of the findings. Future studies may delve deeper into the individual factors identified. Full article