Mineral-Based Composite Catalytic Materials

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: 31 January 2025 | Viewed by 4783

Special Issue Editors


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Guest Editor
Institute of Green Chemistry and Chemical Technology, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
Interests: photocatalysis; CO2 reduction; energy conversion; nano-materials design

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Guest Editor
Institute of Green Chemistry and Chemical Technology, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
Interests: VOCs degradation; flue gas denitrification; catalytic oxidation; nano-materials design

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Guest Editor
Institute of Green Chemistry and Chemical Technology, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
Interests: wastewater treatment; photothermal catalysis; energy conversion; micro-and nano-materials

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Guest Editor
Institute of Green Chemistry and Chemical Technology, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
Interests: heterogeneous catalysis; biomass conversion; catalytic oxidation

Special Issue Information

Dear Colleagues,

Minerals are widely distributed across nature, and are often used as a support for catalysts due to their special physical–chemical properties. Generally, most minerals used as catalyst supports have a layered structure, which can be roughly divided into kaolinite, smectite, vermiculite, hydromica, fiber rod stone, etc. In this structure, octahedrons and tetrahedrons can form different layered structures with adjustable ratios, resulting in the controlled pore sizes, surface areas and surface groups. Moreover, after acidification, purification, pillar and calcification, minerals will easily allow reactants to diffuse, transfer and absorb, which is favorable for compounding with catalysts and promotes the efficiency of catalytic treatment for heavy metals, organic pollutants and gas molecules. Thus, developing mineral-based catalysts is an important part of green catalytic technology that should be noticed in environment protection, energy conversion and other green chemical fields. This Special Issue is dedicated to collecting original research on environment protection and energy conversion, and original research, reviews and perspective articles are welcome. All the papers should relate to the following topics:

  • Synthesis and modification of mineral-based catalysts;
  • Catalytic pollutant degradation (including air and water pollution treatment);
  • Catalytic water splitting and H2 production;
  • Catalytic CO2 reduction;
  • Catalytic conversion of biomass.

If you would like to submit papers to this Special Issue or have any questions, please contact the editor, Mr. Ives Liu ([email protected]).

Prof. Dr. Pengwei Huo
Dr. Xin Liu
Dr. Zhi Zhu
Dr. Yunlei Zhang
Guest Editors

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Keywords

  • mineral-based catalysts
  • pollutant degradation
  • water splitting
  • CO2 reduction
  • biomass conversion

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Published Papers (4 papers)

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Research

13 pages, 7474 KiB  
Article
Construction of ZnCdS Quantum-Dot-Modified CeO2 (0D–2D) Heterojunction for Enhancing Photocatalytic CO2 Reduction and Mechanism Insight
by Junzhi Yan, Yuming Sun, Junxi Cai, Ming Cai, Bo Hu, Yan Yan, Yue Zhang and Xu Tang
Catalysts 2024, 14(9), 599; https://doi.org/10.3390/catal14090599 - 6 Sep 2024
Cited by 1 | Viewed by 833
Abstract
It is important to improve the separation ability of photogenerated electrons and the adsorption capacity of carbon dioxide (CO2) for efficient photoreduction of CO2. Here, we synthesized ZnCdS quantum dots (ZCS-QDs) and cerium dioxide nanosheets (CeO2) using [...] Read more.
It is important to improve the separation ability of photogenerated electrons and the adsorption capacity of carbon dioxide (CO2) for efficient photoreduction of CO2. Here, we synthesized ZnCdS quantum dots (ZCS-QDs) and cerium dioxide nanosheets (CeO2) using the solvothermal method and calcination method. We combined CeO2 and ZCS-QDs to effectively enhance the charge separation efficiency, and the lifetime of photogenerated electrons was increased 4.5 times. The CO evolution rate of the optimized composite (ZCS-QDs/CeO2) was up to 495.8 μmol g−1 h−1, and it had 100% product selectivity. In addition, the stability remained high after five cycles. The CO2 adsorption capacity of the catalyst surface was observed by in situ FTIR. The test results showed that improving CO2 capture ability and promoting photogenic electron separation had positive effects on enhancing photoreduction of CO2. This study provides a reference for constructing a zero-dimensional–two-dimensional (0D–2D) heterojunction and explores potential CO2 reduction reaction mechanisms. Full article
(This article belongs to the Special Issue Mineral-Based Composite Catalytic Materials)
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14 pages, 4821 KiB  
Article
Research on Cu-Site Modification of g-C3N4/CeO2-like Z-Scheme Heterojunction for Enhancing CO2 Reduction and Mechanism Insight
by Yiying Zhou, Junxi Cai, Yuming Sun, Shuhan Jia, Zhonghuan Liu, Xu Tang, Bo Hu, Yue Zhang, Yan Yan and Zhi Zhu
Catalysts 2024, 14(8), 546; https://doi.org/10.3390/catal14080546 - 20 Aug 2024
Viewed by 661
Abstract
In this work, the successful synthesis of a Cu@g-C3N4/CeO2-like Z-scheme heterojunction through hydrothermal and photo-deposition methods represents high CO2 reduction activity with remarkable CO selectivity, as evidenced by the impressive CO yield of 33.8 [...] Read more.
In this work, the successful synthesis of a Cu@g-C3N4/CeO2-like Z-scheme heterojunction through hydrothermal and photo-deposition methods represents high CO2 reduction activity with remarkable CO selectivity, as evidenced by the impressive CO yield of 33.8 μmol/g for Cu@g-C3N4/CeO2, which is over 10 times higher than that of g-C3N4 and CeO2 individually. The characterization and control experimental results indicate that the formation of heterojunctions and the introduction of Cu sites promote charge separation and the transfer of hot electrons, as well as the photothermal effect, which are the essential reasons for the improved CO2 reduction activity. Remarkably, Cu@g-C3N4/CeO2 still exhibits about 92% performance even after multiple cycles. In situ FTIR was utilized to confirm the production of COOH* at 1472 cm−1 and to elucidate the mechanism behind the high selectivity for CO production. The study’s investigation into the wide-ranging applicability of the Cu@g-C3N4/CeO2-like Z-scheme heterojunction catalysts is noteworthy, and the exploration of potential reaction mechanisms for CO2 reduction adds valuable insights to the field of catalysis. Full article
(This article belongs to the Special Issue Mineral-Based Composite Catalytic Materials)
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15 pages, 5759 KiB  
Article
Facile Preparation of Attapulgite-Supported Ag-AgCl Composite Photocatalysts for Enhanced Degradation of Tetracycline
by Xiaojie Zhang, Huiqin Wang and Chenlong Yan
Catalysts 2024, 14(7), 464; https://doi.org/10.3390/catal14070464 - 19 Jul 2024
Viewed by 688
Abstract
In this study, Ag-AgCl/attapulgite (Ag-AgCl/ATP) composites were synthesized via a direct precipitation method using ATP nanorods as a catalyst supporter. ATP nanorods helped to increase the dispersion of Ag-AgCl particles and broaden the light absorption spectrum, which would also help to increase the [...] Read more.
In this study, Ag-AgCl/attapulgite (Ag-AgCl/ATP) composites were synthesized via a direct precipitation method using ATP nanorods as a catalyst supporter. ATP nanorods helped to increase the dispersion of Ag-AgCl particles and broaden the light absorption spectrum, which would also help to increase the active site of the catalyst to promote the degradation of tetracycline (TC). The photocatalytic activity of the Ag-AgCl/ATP composites was evaluated through the degradation of TC, identifying the loading amount of Ag-AgCl, the concentration of TC, and the reaction temperature as critical factors influencing activity. Specifically, the optimal conditions were observed when the loading of Ag-AgCl was 75%, resulting in a photocatalytic degradation efficiency of 77.65%. Furthermore, the highest degradation efficiency (85.01%) was achieved with a TC concentration of 20 mg/L at 20 °C. Radical trapping experiments suggested that the superoxide anion radical (·O2) was the primary active species in the degradation process, although hydroxyl radicals (·OH) and holes (h+) also contributed. Reusability tests confirmed that the Ag-AgCl/ATP composites exhibited excellent stability and could be effectively reused. Full article
(This article belongs to the Special Issue Mineral-Based Composite Catalytic Materials)
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14 pages, 4664 KiB  
Article
PAN/TiO2 Ultrafiltration Membrane for Enhanced BSA Removal and Antifouling Performance
by Yinshan Xie, Xinning Wang, Hulin Li, Tao Wang, Wei Feng and Jian Li
Catalysts 2023, 13(10), 1320; https://doi.org/10.3390/catal13101320 - 23 Sep 2023
Viewed by 1838
Abstract
Membrane separation has been widely utilized to eliminate pollutants from wastewater. Among them, a polyacrylonitrile (PAN) ultrafiltration (UF) membrane has presented outstanding stability, and distinguished chemical and thermal properties. However, UF membranes inevitably incur fouling issues during their operation procedure caused by contaminant [...] Read more.
Membrane separation has been widely utilized to eliminate pollutants from wastewater. Among them, a polyacrylonitrile (PAN) ultrafiltration (UF) membrane has presented outstanding stability, and distinguished chemical and thermal properties. However, UF membranes inevitably incur fouling issues during their operation procedure caused by contaminant adhesion on the membrane surface, which would restrict the operational efficiency and increase the maintenance cost. The conventional physical and chemical cleaning is not an effective technique to reduce the fouling due to the additional chemical addition and inevitable structure damage. Recently, UF membranes combined with photocatalytic materials are suggested to be a useful approach to conquer the membrane fouling issues. Herein, TiO2 nanoparticles were utilized to blend with a PAN casting solution for fabricating a composite UF membrane via a phase inversion method. With a certain TiO2 addition, the obtained membranes presented an enhancement of hydrophilicity, which could promote the water permeability and antifouling performance. The optimized M3 membrane prepared with 15.0 wt% PAN and 0.6 wt% TiO2 exhibited an excellent water permeability up to 207.0 L m−2 h−1 bar−1 with an outstanding 99.0% BSA rejection and superior antifouling property. In addition, the photocatalytic TiO2 nanoparticles endowed the M3 membrane with a remarkable self-cleaning ability under the UV irradiation. This facile construction method offered new insight to enhance the UF membrane separation performance with an enhanced antifouling ability. Full article
(This article belongs to the Special Issue Mineral-Based Composite Catalytic Materials)
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