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14 pages, 1071 KiB

Open AccessArticle

Soil Characteristics in Private Gardens of Different City Neighborhoods: A Case Study of Taibe, Israel

by Pariente Sarah, Helena Zhevelev, Shatha Haj-Yehia, Eyal Sachs and Anatoly G. Fragin

Geosciences 2022, 12(5), 217; https://doi.org/10.3390/geosciences12050217 - 23 May 2022

Viewed by 1875

Abstract

City green areas including private gardens, provide ecological, sociological, cultural, health, and engineering advantages that motivate the urban system. Manmade impacts on the development of urban soils are of greater importance than natural ones. Soil properties were studied in an Arab city—Taibe—in Israel. [...] Read more.

City green areas including private gardens, provide ecological, sociological, cultural, health, and engineering advantages that motivate the urban system. Manmade impacts on the development of urban soils are of greater importance than natural ones. Soil properties were studied in an Arab city—Taibe—in Israel. Two neighborhoods in the city, which differed in time of establishment, were selected: An older residential neighborhood constructed more than 70 years ago, and a newer one built 10 years ago. In each neighborhood, 15 private gardens were randomly chosen. In total, the study was conducted in 30 gardens. In each garden, soil samples were collected from three depths: 0–2, 2–10, and 10–30 cm, respectively. In each sample, organic matter, hygroscopic moisture, calcium carbonate, bulk density, field water content, lead, copper and zinc contents, and texture were determined. The soil of the older neighborhood expressed greater values of soil properties and higher profile differentiation than the newer one. The heavy metals in the soil of the private gardens of both neighborhoods are not present in excess nor are they toxic. Under the prevailing environmental conditions, the soil of the newer neighborhood will become like that of the older one in the future unless a new soil interruption occurs. The calcium carbonate and heavy metals contents in the soil can be used as indicators of soil maturity in different areas of the city having similar environmental conditions. In addition, the gradients of these properties along profiles can be helpful in restoring the history of human activity, which prevailed in the area. Full article

(This article belongs to the Special Issue Medical Geology in the Urban Environment)

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15 pages, 865 KiB

Open AccessArticle

Determination of Total Mercury and Carbon in a National Baseline Study of Urban House Dust

by Christine Levesque and Pat E. Rasmussen

Geosciences 2022, 12(2), 52; https://doi.org/10.3390/geosciences12020052 - 22 Jan 2022

Cited by 5 | Viewed by 2701

Abstract

Mercury (Hg) is one of the top ten chemicals of concern for public health, according to the World Health Organization. This study investigates Hg concentrations in house dust collected from urban single family homes, to better understand typical indoor residential exposures. Using direct [...] Read more.

Mercury (Hg) is one of the top ten chemicals of concern for public health, according to the World Health Organization. This study investigates Hg concentrations in house dust collected from urban single family homes, to better understand typical indoor residential exposures. Using direct solid sample analysis, total Hg and carbon (TC) were determined in the <80 µm fraction of settled dust samples collected under the Canadian House Dust Study. Hg concentrations displayed a log-normal distribution with median/geomean of 0.68/0.70 mg/kg (n = 995). A small subset (<1%) of homes exhibited anomalously high dust Hg concentrations (>9.0 mg/kg). A comparison of Hg concentrations in fresh dust and household vacuum dust collected from the same homes indicated no significant difference in the two sampling methods. Total carbon concentrations displayed a median/geomean of 29.3/28.5% (n = 1011). A significant correlation between total Hg and TC in house dust (p < 0.00001) reflects the association between Hg and organic carbon previously observed in soil and sediments. The results of this study indicate a 10-fold enrichment in house dust compared with the average background concentrations reported for soil and sediments (0.07 mg/kg). The observed enrichment is attributable to Hg emissions from indoor sources and/or Hg carried home from occupational sources. Full article

(This article belongs to the Special Issue Medical Geology in the Urban Environment)

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14 pages, 2121 KiB

Open AccessArticle

Effects of Artificial Sweat Formulation and Extraction Temperature on Estimation of the Dermal Bioaccessibility of Potentially Toxic Elements in a Contaminated Soil from an E-Waste Recycling Site

by Oluwaseun H. Anselm, Christine M. Davidson, Aderonke O. Oyeyiola and Temilola O. Oluseyi

Geosciences 2022, 12(1), 31; https://doi.org/10.3390/geosciences12010031 - 7 Jan 2022

Cited by 5 | Viewed by 2792

Abstract

Informal recycling of electronic waste leads to soil contamination that can impact human health. To accurately assess exposure to potentially toxic elements (PTE) in soil it is necessary to consider their bioavailability through ingestion, inhalation and dermal contact. However, bioaccessibility tests that estimate [...] Read more.

Informal recycling of electronic waste leads to soil contamination that can impact human health. To accurately assess exposure to potentially toxic elements (PTE) in soil it is necessary to consider their bioavailability through ingestion, inhalation and dermal contact. However, bioaccessibility tests that estimate dermal absorption following adhesion of contaminated soil particles to skin are not well established. In this study the concentrations of As, Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn were estimated in the <45 µm particle size fraction of a bulk composite soil from an e-waste recycling site using five different artificial sweat formulations. Extractions were performed at temperatures ranging from 17 to 47 °C to investigate the effect of ambient temperature on bioaccessibility. Results obtained using the different artificial sweats were not consistent with one another. In particular, the NIHS 96-10 formulation solubilized larger amounts of analytes (ranging from 6.3 times the next most effective extractant for Cu to 1700 times the next most effective for Pb). There was a general increase in release of PTE with increasing temperature, except for As. Although trends varied between analytes and formulations, this highlights the need to consider ambient temperature when estimating dermal bioaccessibility of PTE in soil. Full article

(This article belongs to the Special Issue Medical Geology in the Urban Environment)

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22 pages, 5375 KiB

Open AccessArticle

Modelling and Mapping Total and Bioaccessible Arsenic and Lead in Stoke-on-Trent and Their Relationships with Industry

by Joanna Wragg and Mark Cave

Geosciences 2021, 11(12), 515; https://doi.org/10.3390/geosciences11120515 - 15 Dec 2021

Cited by 2 | Viewed by 3076

Abstract

This study was based on a geochemical soil survey of Stoke-on-Trent in the UK of 747 surface soil samples analysed for 53 elements. A subset of 50 of these soil samples were analysed for their bioaccessible As and Pb content using the Unified [...] Read more.

This study was based on a geochemical soil survey of Stoke-on-Trent in the UK of 747 surface soil samples analysed for 53 elements. A subset of 50 of these soil samples were analysed for their bioaccessible As and Pb content using the Unified Barge Method. Random Forest modelling, using the total element data as predictor variables, was used to predict bioaccessible As and Pb for all 747 samples. Random Forest modelling, using inverse distance weighed predictors and bedrock and superficial geology, was also used to map both total and bioaccessible As and Pb on a 400 × 400 spatial prediction grid with a 50 m resolution. The predicted bioaccessible As ranged from ca. 1 to 8 mg/kg and the total As ca. 8 to 45 mg/kg. The bioaccessible Pb and the total Pb both covered the range ca. 16–1200 mg/kg, with the highest values for both forms of Pb showing similar spatial distributions. Predictor variable importance and information on past industry suggest that the source of both of these elements is driven by anthropogenic causes. Full article

(This article belongs to the Special Issue Medical Geology in the Urban Environment)

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15 pages, 1861 KiB

Open AccessArticle

Modifying Effect of Soil Properties on Bio-Accessibility of As and Pb from Human Ingestion of Contaminated Soil

by Loryssa M. Lake, Nicholas T. Basta and David J. Barker

Geosciences 2021, 11(3), 126; https://doi.org/10.3390/geosciences11030126 - 10 Mar 2021

Cited by 11 | Viewed by 2515

Abstract

Exposure to soils contaminated with heavy metals can pose human health risk to children through ingestion of contaminated soil. Soil properties such as soil pH, reactive Fe and Al oxide content, clay content, soil organic matter (SOM), and cation exchange capacity (CEC) can [...] Read more.

Exposure to soils contaminated with heavy metals can pose human health risk to children through ingestion of contaminated soil. Soil properties such as soil pH, reactive Fe and Al oxide content, clay content, soil organic matter (SOM), and cation exchange capacity (CEC) can reduce contaminant bio-accessibility and exposure. In vitro bio-accessibility (%IVBA) of As and Pb in 19 soils was determined using U.S. EPA Method 1340. Soil properties reduced the bio-accessibility of As by 17–96.5% and 1.3–38.9% for Pb. For both As and Pb, bio-accessibility decreased with increasing Al and Fe oxide content. Al oxides were found to be the primary driver of As and Pb bio-accessibility. Multiple regressions with AlOx, soil pH, %clay and/or FeOx predicted %IVBA As (p < 0.001). The multiple regression including log (FeOx + AlOx) and %clay explained 63% of the variability in %IVBA Pb (p < 0.01). Fe and Al oxides were found to be important drivers of As and Pb bio-accessibility, regardless of in vitro method. These findings suggested soil pH should be used in addition to reactive oxides to predict bio-accessible As. Risk-based adjustments using soil properties for exposure via incidental ingestion should be considered for soils contaminated with As and/or Pb. Full article

(This article belongs to the Special Issue Medical Geology in the Urban Environment)

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18 pages, 2298 KiB

Open AccessArticle

Thoracic Fraction (PM₁₀) of Resuspended Urban Dust: Geochemistry, Particle Size Distribution and Lung Bioaccessibility

by Christine Levesque, Clare L. S. Wiseman, Suzanne Beauchemin and Pat E. Rasmussen

Geosciences 2021, 11(2), 87; https://doi.org/10.3390/geosciences11020087 - 13 Feb 2021

Cited by 12 | Viewed by 3365

Abstract

A fluidized bed aerosol generator was connected to a 13-stage cascade impactor (nanoMOUDI) for the size fractionation of urban dust (<10 µm), followed by the gravimetric analysis of loaded PTFE filter samples. This method was used to characterize the PM₁₀ (thoracic) fraction [...] Read more.

A fluidized bed aerosol generator was connected to a 13-stage cascade impactor (nanoMOUDI) for the size fractionation of urban dust (<10 µm), followed by the gravimetric analysis of loaded PTFE filter samples. This method was used to characterize the PM₁₀ (thoracic) fraction of road dust sampled from expressways, arterial roads and local roads in Toronto, Canada. The fine particle fractions (<1.8 µm) of all the studied samples accounted for 51–72% of the resuspended PM₁₀ (by weight). Elemental analysis using ICP-MS and ICP-OES revealed an overall trend of element enrichment in the <1.8 µm fraction compared to the coarse fraction (1.8–10 µm) of the road dust. By contrast, archived house dust samples displayed the reverse trend for most elements. The lung bioaccessibility of target elements (Al, B, Ba, Co, Cr, Fe, La, Mn, Mo, Sb, Sr, Ti, V and Zn) was assessed for each road dust fraction using 0.1 M ammonium citrate (pH 4.4) to simulate intracellular fluid and Gamble solution (pH 7.2) to simulate interstitial lung fluid. The <1.8 µm fraction of local road dust displayed significantly higher bioaccessibility (p < 0.05) for Zn when using Gamble solution, and for seven out of the 14 target elements when using ammonium citrate. These results show the importance of characterizing the fine fraction of road dust. Full article

(This article belongs to the Special Issue Medical Geology in the Urban Environment)

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16 pages, 3392 KiB

Open AccessArticle

New Insights into Health Risk Assessments for Inhalational Exposure to Metal(loid)s: The Application of Aqueous Chemistry Modelling in Understanding Bioaccessibility from Airborne Particulate Matter

by Michael E. Deary, Patrick M. Amaibi, John R. Dean and Jane A. Entwistle

Geosciences 2021, 11(2), 47; https://doi.org/10.3390/geosciences11020047 - 23 Jan 2021

Cited by 4 | Viewed by 2068

Abstract

Aqueous modelling of chemical speciation in simulated lung fluid (SLF) enables a better understanding of the underlying chemical factors that influence metal(loid) inhalation bioaccessibility from airborne particulate matter. Such an approach can be used to supplement experimental techniques that are integral to the [...] Read more.

Aqueous modelling of chemical speciation in simulated lung fluid (SLF) enables a better understanding of the underlying chemical factors that influence metal(loid) inhalation bioaccessibility from airborne particulate matter. Such an approach can be used to supplement experimental techniques that are integral to the health risk assessment of metal(loid) exposure by inhalational routes. In this paper, we modelled the aqueous chemistry of airborne particulate-bound metal(loid)s (As, Cu, Mn, Pb and Zn) in a SLF based on Gamble’s solution (neutral pH). The modelling was performed using two software packages (Geochemist’s Workbench 14 and OLI Studio 9.5) and a total of five thermochemical databases (GWB Thermo, MINTEQ, PHREEQC, WATEQ4F and the default database for OLI Studio). Modelled results were compared with experimentally determined bioaccessibilities for the NIST 2710a standard reference material (SRM) and with literature-reported bioaccessibilities for NIST 1648a and BCR 038 SRMs. Whilst the models correctly describe the observed increase in bioaccessibility for more dilute solid/liquid extraction ratios, the performance of the models against the fractional bias of the mean (FB_mean) and the normalised mean square error (NMSE) statistical metrics was generally outside the acceptance criteria. Findings from an analysis of the main aqueous chemical species predicted to be present in SLF indicate that carbonate and chloride complexes of Cu, Mn, Pb and Zn predominate, whilst free cations (for Cu, Mn and Zn) and hydroxides (for Cu) also play a role in solubilisation. Arsenic is not predicted to form significant complexes with the SLF components and is present in solution mainly as the HAsO₄²⁻ ion and its conjugate acid, H₂AsO₄⁻. For modelled runs where glycine and citrate were present, significant increases in the bioavailability of Cu and Zn were predicted as a result of complexation with these ligands. An additional finding from our experimental bioaccessibility results for NIST 2710a was that the inclusion of the lung fluid surfactant dipalmitoylphosphatidylcholine (DPPC) in the SLF did not significantly affect the bioaccessibility. Our study provides useful insights into the likely aqueous- and solid-phase speciation of metal(loid)s in SLF and highlights that future developments in this area should consider the role of mineralogy and surface interactions. Full article

(This article belongs to the Special Issue Medical Geology in the Urban Environment)

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14 pages, 2158 KiB

Open AccessPerspective

Unnatural Cycles: Anthropogenic Disruption to Health and Planetary Functions

by Gillian Gibson and Alex G. Stewart

Geosciences 2022, 12(3), 137; https://doi.org/10.3390/geosciences12030137 - 15 Mar 2022

Viewed by 4000

Abstract

Natural cycles underpin the very stuff of life. In this commentary we consider unnatural cycles: that is, anthropogenic activities which have a circularity, but whose nature is to have a detrimental effect on human health, exacerbating existing problems. Natural cycles have feedback loops, [...] Read more.

Natural cycles underpin the very stuff of life. In this commentary we consider unnatural cycles: that is, anthropogenic activities which have a circularity, but whose nature is to have a detrimental effect on human health, exacerbating existing problems. Natural cycles have feedback loops, some of which have recently come to light, with an understanding that everything is connected in some way. In health, feedback loops are imperative in homeostatic mechanisms. However, in the unnatural cycle the feedback loops serve to reinforce (and in some cases amplify) negative problems. We offer a commentary on an unnatural cycle moving from air quality to lung function and back to air quality; we call this the lung disease unnatural cycle. We suggest where links occur, and where wider consideration of interactions between various disciplines can lead to breaking this unnatural (or vicious) cycle, changing it to a healthy cycle where individual health can be improved, along with better global scale outcomes. We suggest that many activities within this unnatural cycle occur within silos. However, the improved cycle incorporates joint activities at geological, health, and financial levels, to the mutual benefit of all, breaking the unnatural cycle and improving health, life, and financial costs. Full article

(This article belongs to the Special Issue Medical Geology in the Urban Environment)

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