Materials

14 pages, 3622 KiB

Open AccessEditor’s ChoiceArticle

Flexible Dry Electrode Based on a Wrinkled Surface That Uses Carbon Nanotube/Polymer Composites for Recording Electroencephalograms

by Jihyeon Oh, Kun-Woo Nam, Won-Jin Kim, Byung-Ho Kang and Sung-Hoon Park

Materials 2024, 17(3), 668; https://doi.org/10.3390/ma17030668 - 30 Jan 2024

Cited by 1 | Viewed by 1710

Abstract

Electroencephalography (EEG) captures minute electrical signals emanating from the brain. These signals are vulnerable to interference from external noise and dynamic artifacts; hence, accurately recording such signals is challenging. Although dry electrodes are convenient, their signals are of limited quality; consequently, wet electrodes [...] Read more.

Electroencephalography (EEG) captures minute electrical signals emanating from the brain. These signals are vulnerable to interference from external noise and dynamic artifacts; hence, accurately recording such signals is challenging. Although dry electrodes are convenient, their signals are of limited quality; consequently, wet electrodes are predominantly used in EEG. Therefore, developing dry electrodes for accurately and stably recording EEG signals is crucial. In this study, we developed flexible dry electrodes using polydimethylsiloxane (PDMS)/carbon-nanotube (CNT) composites with isotropically wrinkled surfaces that effectively combine the advantages of wet and dry electrodes. Adjusting the PDMS crosslinker ratio led to good adhesion, resulting in a highly adhesive CNT/PDMS composite with a low Young’s modulus that exhibited excellent electrical and mechanical properties owing to its ability to conformally contact skin. The isotropically wrinkled surface also effectively controls dynamic artifacts during EEG signal detection and ensures accurate signal analysis. The results of this study demonstrate that dry electrodes based on flexible CNT/PDMS composites and corrugated structures can outperform wet electrodes. The introduction of such electrodes is expected to enable the accurate analysis and monitoring of EEG signals in various scenarios, including clinical trials. Full article

(This article belongs to the Special Issue Preparation, Processing, and Application of Advanced Functional Carbon Materials)

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15 pages, 5964 KiB

Open AccessEditor’s ChoiceArticle

Mesoporous Silica MCM-41 from Fly Ash as a Support of Bimetallic Cu/Mn Catalysts for Toluene Combustion

by Jakub Mokrzycki, Monika Fedyna, Dorota Duraczyńska, Mateusz Marzec, Rafał Panek, Wojciech Franus, Tomasz Bajda and Robert Karcz

Materials 2024, 17(3), 653; https://doi.org/10.3390/ma17030653 - 29 Jan 2024

Viewed by 1228

Abstract

The main outcome of this research was to demonstrate the opportunity to obtain a stable and well-ordered structure of MCM-41 synthesized from fly ash. A series of bimetallic (Cu/Mn) catalysts supported at MCM-41 were prepared via grinding method and investigated in catalytic toluene [...] Read more.

The main outcome of this research was to demonstrate the opportunity to obtain a stable and well-ordered structure of MCM-41 synthesized from fly ash. A series of bimetallic (Cu/Mn) catalysts supported at MCM-41 were prepared via grinding method and investigated in catalytic toluene combustion reaction to show the material’s potential application. It was proved, that the Cu/Mn ratio had a crucial effect on the catalytic activity of prepared materials. The best catalytic performance was achieved with sample Cu/Mn(2.5/2.5), for which the temperature of 50% toluene conversion was found to be 300 °C. This value remains in line with the literature reports, for which comparable catalytic activity was attained for 3-fold higher metal loadings. Time-on-stream experiment proved the thermal stability of the investigated catalyst Cu/Mn(2.5/2.5). The obtained results bring a valuable background in the field of fly ash utilization, where fly ash-derived MCM-41 can be considered as efficient and stable support for dispersion of active phase for catalyst preparation. Full article

(This article belongs to the Special Issue Applications of Silica and Silica-Based Composites)

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15 pages, 9796 KiB

Open AccessEditor’s ChoiceArticle

Microstructure, Mechanical Properties and Wear Behaviors of Ultrafine-Grain WC-Based Cermets with Different Binder Phases Fabricated by Spark Plasma Sintering

by Kangwei Xu, Zhe Wang, Peipei Cao, Xiangyang Peng, Chao Chen, Qingsong Liu, Shufeng Xie, Xiaoyu Wu and Yongxin Jian

Materials 2024, 17(3), 659; https://doi.org/10.3390/ma17030659 - 29 Jan 2024

Cited by 2 | Viewed by 1146

Abstract

In this work, to explore potential substitutions for the Co binder phase, ultrafine-grain WC-based cermets with various binder phases of Co, Ni and AlCoCrNiFeCu HEA were prepared using the SPS method. Based on SPS, WC-based cermets were fabricated at higher speed, showing fine [...] Read more.

In this work, to explore potential substitutions for the Co binder phase, ultrafine-grain WC-based cermets with various binder phases of Co, Ni and AlCoCrNiFeCu HEA were prepared using the SPS method. Based on SPS, WC-based cermets were fabricated at higher speed, showing fine carbide particles less than 410 μm. The microstructure, mechanical properties and wear properties were systematically evaluated. By comparison, the grain size of WC was the lowest for WC-10Co, while WC-10 HEA cermet held the coarsest WC particles. The hardness and fracture toughness of WC-10 HEA were the best among all three samples, with values of 93.2 HRA and 11.3 MP·m^1/2. However, the bending strength of WC-10HEA was about 56.1% lower than that of WC-10Co, with a value of 1349.6 MPa. The reduction in bending strength is attributed to the lower density, formation of a newly Cr-Al rich phase and coarser WC grains. In dry sliding wear conditions, WC-10 HEA showed the lowest wear rate (0.98 × 10⁻⁶ mm³/(N·m)) and coefficient of friction (0.19), indicating the best wear resistance performance. This reveals that WC-based cermet with a HEA binder phase has superior wear performance due to the higher hardness and good self-lubricating effect of the wear products. Full article

(This article belongs to the Special Issue Advanced Ceramic-Based Materials/Coatings for Anti-Wear and Corrosion Applications)

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19 pages, 37911 KiB

Open AccessEditor’s ChoiceArticle

Near Net Shape Manufacturing of Sheets from Al-Cu-Li-Mg-Sc-Zr Alloy

by Barbora Kihoulou, Rostislav Králík, Lucia Bajtošová, Olexandr Grydin, Mykhailo Stolbchenko, Mirko Schaper and Miroslav Cieslar

Materials 2024, 17(3), 644; https://doi.org/10.3390/ma17030644 - 28 Jan 2024

Cited by 1 | Viewed by 1151

Abstract

Thin twin-roll cast strips from a model Al-Cu-Mg-Li-Zr alloy with a small addition of Sc were prepared. A combination of a fast solidification rate and a favorable effect of Sc microalloying refines the grain size and the size of primary phase particles and [...] Read more.

Thin twin-roll cast strips from a model Al-Cu-Mg-Li-Zr alloy with a small addition of Sc were prepared. A combination of a fast solidification rate and a favorable effect of Sc microalloying refines the grain size and the size of primary phase particles and reduces eutectic cell dimensions to 10–15

μ

m. Long-term homogenization annealings used in conventionally cast materials lasting several tens of hours followed by a necessary dimension reduction through rolling/extruding could be substituted by energy and material-saving procedure. It consists of two-step short annealings at 300 °C/30 min and 450 °C/30 min, followed by the refinement and hardening of the structure using constrained groove pressing. A dense dispersion of 10–20 nm spherical

{Al}_{3} (Sc, Zr)

precipitates intensively forms during this treatment and effectively stabilizes the structure and inhibits the grain growth during subsequent solution treatment at 530 °C/30 min. Small (3%) pre-straining after quenching assures more uniform precipitation of strengthening

{Al}_{2} Cu

(

θ^{'}

),

{Al}_{2} CuMg

(

S'

), and Al₂CuLi (

T_{1}

) particles during subsequent age-hardening annealing at 180 °C/14 h. The material does not contain a directional and anisotropic structure unavoidable in rolled or extruded sheets. The proposed procedure thus represents a model near net shape processing strategy for manufacturing lightweight high-strength sheets for cryogenic applications in aeronautics. Full article

(This article belongs to the Special Issue The 15th Anniversary of Materials—Recent Advances in Materials Physics)

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16 pages, 4173 KiB

Open AccessEditor’s ChoiceArticle

The Added Value of a Collagenated Thermosensitive Bone Substitute as a Scaffold for Bone Regeneration

by Charlotte Jeanneau, Jean-Hugues Catherine, Thomas Giraud, Romain Lan and Imad About

Materials 2024, 17(3), 625; https://doi.org/10.3390/ma17030625 - 27 Jan 2024

Cited by 2 | Viewed by 1592

Abstract

A pre-hydrated thermosensitive collagenated biomaterial which sets at body temperature and maintains the space of the missing alveolar bone volume, OsteoBiol GTO^® (GTO), has been released as a bone substitute. This study was designed to check its angiogenic and osteogenic potentials compared [...] Read more.

A pre-hydrated thermosensitive collagenated biomaterial which sets at body temperature and maintains the space of the missing alveolar bone volume, OsteoBiol GTO^® (GTO), has been released as a bone substitute. This study was designed to check its angiogenic and osteogenic potentials compared to OsteoBiol Gen-Os^® (Gen-Os) and Geistlich Bio-Oss^® (Bio-Oss). Samples of materials were incubated in culture media to obtain the extracts. Collagen release was measured in the extracts, which were used to investigate human periodontal ligament (hPDL) cell proliferation (MTT), colonization (Scratch assays) and growth factor release (ELISA). The effects on endothelial cell proliferation (MTT) and organization (Matrigel^® assays) were also studied. Finally, endothelial and mesenchymal Stem Cell (hMSC) recruitment (Boyden Chambers) were investigated, and hMSC Alkaline Phosphatase (ALP) activity was measured. A higher collagen concentration was found in GTO extract, which led to significantly higher hPDL cell proliferation/colonization. All materials increased VEGF/FGF-2 growth factor secretion, endothelial cell recruitment, proliferation, and organization, but the increase was highest with GTO. All materials increased hMSC recruitment and ALP activity. However, the increase was highest with collagenated GTO and Gen-Os, which enhanced C5a and BMP-2 secretion. Overall, GTO has higher angiogenic/osteogenic potentials than the collagenated Gen-Os and the anorganic Bio-Oss. It provides a suitable scaffold for endothelial and mesenchymal stem cell recruitment, which represent essential bone regeneration requirements. Full article

(This article belongs to the Special Issue Advances in Biomaterials: Synthesis, Characteristics and Applications)

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17 pages, 8300 KiB

Open AccessEditor’s ChoiceArticle

The Influence of the Molecular Structure of Compounds on Their Properties and the Occurrence of Chiral Smectic Phases

by Magdalena Urbańska, Monika Zając, Paweł Perkowski and Aleksandra Deptuch

Materials 2024, 17(3), 618; https://doi.org/10.3390/ma17030618 - 27 Jan 2024

Viewed by 1152

Abstract

We have designed new chiral smectic mesogens with the -CH₂O group near the chiral center. We synthesized two unique rod-like compounds. We determined the mesomorphic properties of these mesogens and confirmed the phase identification using dielectric spectroscopy. Depending on the length [...] Read more.

We have designed new chiral smectic mesogens with the -CH₂O group near the chiral center. We synthesized two unique rod-like compounds. We determined the mesomorphic properties of these mesogens and confirmed the phase identification using dielectric spectroscopy. Depending on the length of the oligomethylene spacer (i.e., the number of methylene groups) in the achiral part of the molecules, the studied materials show different phase sequences. Moreover, the temperature ranges of the observed smectic phases are different. It can be seen that as the length of the alkyl chain increases, the liquid crystalline material shows more mesophases. Additionally, its clearing (isotropization) temperature increases. The studied compounds are compared with the structurally similar smectogens previously synthesized. The helical pitch measurements were performed using the selective reflection method. These materials can be useful and effective as chiral components and dopants in smectic mixtures targeted for optoelectronics and photonics. Full article

(This article belongs to the Special Issue Advanced Materials for Luminescent Applications)

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19 pages, 2228 KiB

Open AccessEditor’s ChoiceArticle

The Design of a Piecewise-Integrated Composite Bumper Beam with Machine-Learning Algorithms

by Seokwoo Ham, Seungmin Ji and Seong Sik Cheon

Materials 2024, 17(3), 602; https://doi.org/10.3390/ma17030602 - 26 Jan 2024

Cited by 1 | Viewed by 1144

Abstract

In the present study, a piecewise-integrated composite bumper beam for passenger cars is proposed, and the design innovation process for a composite bumper beam regarding a bumper test protocol suggested by the Insurance Institute for Highway Safety is carried out with the help [...] Read more.

In the present study, a piecewise-integrated composite bumper beam for passenger cars is proposed, and the design innovation process for a composite bumper beam regarding a bumper test protocol suggested by the Insurance Institute for Highway Safety is carried out with the help of machine learning models. Several elements in the bumper FE model have been assigned to be references in order to collect training data, which allow the machine learning model to study the method of predicting loading types for each finite element. Two-dimensional and three-dimensional implementations are provided by machine learning models, which determine the stacking sequences of each finite element in the piecewise-integrated composite bumper beam. It was found that the piecewise-integrated composite bumper beam, which is designed by a machine learning model, is more effective for reducing the possibility of structural failure as well as increasing bending strength compared to the conventional composite bumper beam. Moreover, the three-dimensional implementation produces better results compared with results from the two-dimensional implementation since it is preferable to choose loading-type information, which is achieved from surroundings when the target elements are located either at corners or junctions of planes, instead of using information that comes from the identical plane of target elements. Full article

(This article belongs to the Special Issue Advanced Fiber-Reinforced Composites: Design, Properties and Applications)

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11 pages, 1786 KiB

Open AccessEditor’s ChoiceArticle

Rapid Plasma Electrolytic Oxidation Synthesis of Intermetallic PtBi/MgO/Mg Monolithic Catalyst for Efficient Removal of Organic Pollutants

by Jiayi Rong, Mengyang Li, Feng Cao, Qianwei Wang, Mingran Wang, Yang Cao, Jun Zhou and Gaowu Qin

Materials 2024, 17(3), 605; https://doi.org/10.3390/ma17030605 - 26 Jan 2024

Cited by 1 | Viewed by 1044

Abstract

The intermetallic PtBi/MgO/Mg monolithic catalyst was first prepared using non-equilibrium plasma electrolytic oxidation (PEO) technology. Spherical aberration-corrected transmission electron microscope (ACTEM) observation confirms the successful synthesis of the PtBi intermetallic structure. The efficiency of PtBi/Mg/MgO catalysts in catalyzing the reduction of 4-nitrophenol (4-NP) [...] Read more.

The intermetallic PtBi/MgO/Mg monolithic catalyst was first prepared using non-equilibrium plasma electrolytic oxidation (PEO) technology. Spherical aberration-corrected transmission electron microscope (ACTEM) observation confirms the successful synthesis of the PtBi intermetallic structure. The efficiency of PtBi/Mg/MgO catalysts in catalyzing the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) in the presence of NaBH₄ was demonstrated. The activity factor for the catalyst is 31.8 s⁻¹ g⁻¹, which is much higher than reported values. In addition, the resultant catalyst also exhibits excellent catalytic activity in the organic pollutant reaction of p-nitrobenzoic acid (p-NBA) and methyl orange (MO). Moreover, benefiting from ordered atomic structures and the half-embedded PtBi nanoparticles (NPs), the catalyst demonstrates excellent stability and reproducibility in the degradation of 4-NP. This study provides an example of a simple method for the preparation of intermetallic structures as catalysts for organic pollutant degradation. Full article

(This article belongs to the Special Issue Advances in Multicomponent Catalytic Materials)

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55 pages, 26035 KiB

Open AccessEditor’s ChoiceArticle

On the Importance of the Recovery Procedure in the Semi-Analytical Solution for the Static Analysis of Curved Laminated Panels: Comparison with 3D Finite Elements

by Francesco Tornabene, Matteo Viscoti and Rossana Dimitri

Materials 2024, 17(3), 588; https://doi.org/10.3390/ma17030588 - 25 Jan 2024

Cited by 5 | Viewed by 1317

Abstract

The manuscript presents an efficient semi-analytical solution with three-dimensional capabilities for the evaluation of the static response of laminated curved structures subjected to general external loads. A two-dimensional model is presented based on the Equivalent Single Layer (ESL) approach, where the displacement field [...] Read more.

The manuscript presents an efficient semi-analytical solution with three-dimensional capabilities for the evaluation of the static response of laminated curved structures subjected to general external loads. A two-dimensional model is presented based on the Equivalent Single Layer (ESL) approach, where the displacement field components are described with a generalized formulation based on a higher-order expansion along the thickness direction. The fundamental equations are derived from the Hamiltonian principle, and the solution is found by means of Navier’s approach. Then, an efficient recovery procedure, derived from the three-dimensional elasticity equations and based on the Generalized Differential Quadrature (GDQ) method, is adopted for the derivation of the three-dimensional solution. Some examples of investigation are presented, where the numerical predictions of refined three-dimensional Finite-Element-based models are matched with a high level of accuracy. The model is validated for both straight and curved panels, taking into account different lamination schemes and load shapes. Furthermore, it is shown that the numerical solution to the elasticity problem in the recovery procedure is determining and accurately predicting the three-dimensional static response of the doubly-curved shell solid. Full article

(This article belongs to the Special Issue Multi-Scale Modeling of Advanced Materials: Numerical Methods and Experimental Research)

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78 pages, 27700 KiB

Open AccessEditor’s ChoiceReview

Cryogenic Treatment of Martensitic Steels: Microstructural Fundamentals and Implications for Mechanical Properties and Wear and Corrosion Performance

by Peter Jurči and Ivo Dlouhý

Materials 2024, 17(3), 548; https://doi.org/10.3390/ma17030548 - 23 Jan 2024

Cited by 8 | Viewed by 1973

Abstract

Conventional heat treatment is not capable of converting a sufficient amount of retained austenite into martensite in high-carbon or high-carbon and high-alloyed iron alloys. Cryogenic treatment induces the following alterations in the microstructures: (i) a considerable reduction in the retained austenite amount, (ii) [...] Read more.

Conventional heat treatment is not capable of converting a sufficient amount of retained austenite into martensite in high-carbon or high-carbon and high-alloyed iron alloys. Cryogenic treatment induces the following alterations in the microstructures: (i) a considerable reduction in the retained austenite amount, (ii) formation of refined martensite coupled with an increased number of lattice defects, such as dislocations and twins, (iii) changes in the precipitation kinetics of nano-sized transient carbides during tempering, and (iv) an increase in the number of small globular carbides. These microstructural alterations are reflected in mechanical property improvements and better dimensional stability. A common consequence of cryogenic treatment is a significant increase in the wear resistance of steels. The current review deals with all of the mentioned microstructural changes as well as the variations in strength, toughness, wear performance, and corrosion resistance for a variety of iron alloys, such as carburising steels, hot work tool steels, bearing and eutectoid steels, and high-carbon and high-alloyed ledeburitic cold work tool steels. Full article

(This article belongs to the Special Issue Physical Metallurgy of Metals and Alloys II)

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13 pages, 2282 KiB

Open AccessEditor’s ChoiceArticle

Structural and Photoelectronic Properties of κ-Ga₂O₃ Thin Films Grown on Polycrystalline Diamond Substrates

by Marco Girolami, Matteo Bosi, Sara Pettinato, Claudio Ferrari, Riccardo Lolli, Luca Seravalli, Valerio Serpente, Matteo Mastellone, Daniele M. Trucchi and Roberto Fornari

Materials 2024, 17(2), 519; https://doi.org/10.3390/ma17020519 - 22 Jan 2024

Cited by 3 | Viewed by 1532

Abstract

Orthorhombic κ-Ga₂O₃ thin films were grown for the first time on polycrystalline diamond free-standing substrates by metal-organic vapor phase epitaxy at a temperature of 650 °C. Structural, morphological, electrical, and photoelectronic properties of the obtained heterostructures were evaluated by optical [...] Read more.

Orthorhombic κ-Ga₂O₃ thin films were grown for the first time on polycrystalline diamond free-standing substrates by metal-organic vapor phase epitaxy at a temperature of 650 °C. Structural, morphological, electrical, and photoelectronic properties of the obtained heterostructures were evaluated by optical microscopy, X-ray diffraction, current-voltage measurements, and spectral photoconductivity, respectively. Results show that a very slow cooling, performed at low pressure (100 mbar) under a controlled He flow soon after the growth process, is mandatory to improve the quality of the κ-Ga₂O₃ epitaxial thin film, ensuring a good adhesion to the diamond substrate, an optimal morphology, and a lower density of electrically active defects. This paves the way for the future development of novel hybrid architectures for UV and ionizing radiation detection, exploiting the unique features of gallium oxide and diamond as wide-bandgap semiconductors. Full article

(This article belongs to the Special Issue Thin Films and Semiconductor Heterostructures: From Fundamental to Applications)

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18 pages, 24962 KiB

Open AccessEditor’s ChoiceArticle

Feasibility Study on the Generation of Nanoporous Metal Structures by Means of Selective Alloy Depletion in Halogen-Rich Atmospheres

by Jörg Weise, Birgit Uhrlaub, Dirk Lehmhus, Joachim Baumeister, Kerstin Hantzsche and Karsten Thiel

Materials 2024, 17(2), 498; https://doi.org/10.3390/ma17020498 - 20 Jan 2024

Viewed by 908

Abstract

A new approach to produce nanoporous metals has been investigated, which is based on the dealloying of bi- or multi-component alloys. Depletion and pore formation of the alloy substrate are obtained by the transport of certain alloy components at high temperatures via volatile [...] Read more.

A new approach to produce nanoporous metals has been investigated, which is based on the dealloying of bi- or multi-component alloys. Depletion and pore formation of the alloy substrate are obtained by the transport of certain alloy components at high temperatures via volatile halogen compounds. These halogen compounds are transferred to materials acting as sinks based on their higher affinity to the respective components, and chemically bound there. Transfer via volatile halogen compounds is known from the pack cementation coating process and from high-temperature corrosion in certain industrial atmospheres. The approach was tested on different precursor alloys: Ti-43.5Al-4Nb-1Mo-0.1B (TNM-B1), TiNb42, and AlCu. Both dealloying effects and micro-scale pore formation were observed. The detailed size of the porous structures is in the range of 50 nm for both TNM-B1 and TiNB42 and 500 nm for AlCu. Full article

(This article belongs to the Section Porous Materials)

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12 pages, 4522 KiB

Open AccessEditor’s ChoiceArticle

Impact of Glass Free Volume on Femtosecond Laser-Written Nanograting Formation in Silica Glass

by Nadezhda Shchedrina, Maxime Cavillon, Julien Ari, Nadège Ollier and Matthieu Lancry

Materials 2024, 17(2), 502; https://doi.org/10.3390/ma17020502 - 20 Jan 2024

Cited by 2 | Viewed by 1233

Abstract

In this study, we investigate the effects of densification through high pressure and temperature (up to 5 GPa, 1000 °C) in the making of nanogratings in pure silica glass, inscribed with femtosecond laser. The latter were monitored through retardance measurements using polarized optical [...] Read more.

In this study, we investigate the effects of densification through high pressure and temperature (up to 5 GPa, 1000 °C) in the making of nanogratings in pure silica glass, inscribed with femtosecond laser. The latter were monitored through retardance measurements using polarized optical microscopy, and their internal structure was observed under scanning electron microscopy. We reveal the difficulty in making nanogratings in densified silica glasses. Based on this observation, we propose that free volume may be a key precursor to initiate nanograting formation. Full article

(This article belongs to the Special Issue The 15th Anniversary of Materials—Recent Advances in Materials Physics)

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15 pages, 2605 KiB

Open AccessEditor’s ChoiceReview

Divalent Metal Ion Depletion from Wastewater by RVC Cathodes: A Critical Review

by Alessandro Dell’Era, Carla Lupi, Erwin Ciro, Francesca A. Scaramuzzo and Mauro Pasquali

Materials 2024, 17(2), 464; https://doi.org/10.3390/ma17020464 - 18 Jan 2024

Viewed by 964

Abstract

In this paper, a critical review of results obtained using a reticulated vitreous carbon (RVC) three-dimensional cathode for the electrochemical depletion of various divalent ions, such as Cu⁺², Cd⁺², Pb⁺², Zn⁺², Ni⁺², and [...] Read more.

In this paper, a critical review of results obtained using a reticulated vitreous carbon (RVC) three-dimensional cathode for the electrochemical depletion of various divalent ions, such as Cu⁺², Cd⁺², Pb⁺², Zn⁺², Ni⁺², and Co⁺², often present in wastewater, has been carried out. By analyzing the kinetics and fluid dynamics of the process found in literature, a general dimensionless equation, Sh = f(Re), has been determined, describing a general trend for all the analyzed systems regardless of the geometry, dimensions, and starting conditions. Thus, a map in the log(Sh) vs. log(Re) plane has been reported by characterizing the whole ion electrochemical depletion process and highlighting the existence of a good correlation among all the results. Moreover, because in recent years, the interest in using this three-dimensional cathode material seems to have slowed, the intent is to revive it as a useful tool for metal recovery, recycling processes, and water treatments. Full article

(This article belongs to the Special Issue Electrochemical Material Science and Electrode Processes)

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19 pages, 765 KiB

Open AccessEditor’s ChoiceArticle

Dynamics of a Magnetic Polaron in an Antiferromagnet

by Kaijun Shen, Maxim F. Gelin, Kewei Sun and Yang Zhao

Materials 2024, 17(2), 469; https://doi.org/10.3390/ma17020469 - 18 Jan 2024

Cited by 2 | Viewed by 1255

Abstract

The t-J model remains an indispensable construct in high-temperature superconductivity research, bridging the gap between charge dynamics and spin interactions within antiferromagnetic matrices. This study employs the multiple Davydov Ansatz method with thermo-field dynamics to dissect the zero-temperature and finite-temperature behaviors. We uncover [...] Read more.

The t-J model remains an indispensable construct in high-temperature superconductivity research, bridging the gap between charge dynamics and spin interactions within antiferromagnetic matrices. This study employs the multiple Davydov Ansatz method with thermo-field dynamics to dissect the zero-temperature and finite-temperature behaviors. We uncover the nuanced dependence of hole and spin deviation dynamics on the spin–spin coupling parameter J, revealing a thermally-activated landscape where hole mobilities and spin deviations exhibit a distinct temperature-dependent relationship. This numerically accurate thermal perspective augments our understanding of charge and spin dynamics in an antiferromagnet. Full article

(This article belongs to the Special Issue The 15th Anniversary of Materials—Recent Advances in Materials Physics)

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23 pages, 425 KiB

Open AccessEditor’s ChoiceReview

A Review of Modeling of Composite Structures

by Wenbin Yu

Materials 2024, 17(2), 446; https://doi.org/10.3390/ma17020446 - 17 Jan 2024

Cited by 1 | Viewed by 3225

Abstract

This paper provides a brief review on modeling of composite structures. Composite structures in this paper refer to any structure featuring anisotropy and heterogeneity, including but not limited to their traditional meaning of composite laminates made of unidirectional fiber-reinforced composites. Common methods used [...] Read more.

This paper provides a brief review on modeling of composite structures. Composite structures in this paper refer to any structure featuring anisotropy and heterogeneity, including but not limited to their traditional meaning of composite laminates made of unidirectional fiber-reinforced composites. Common methods used in modeling of composite structures, including the axiomatic method, the formal asymptotic method, and the variational asymptotic method, are illustrated in deriving the classical lamination theory for the composite laminated plates. Future research directions for modeling composite structures are also pointed out. Full article

(This article belongs to the Special Issue Methodology of the Design and Testing of Composite Structures)

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15 pages, 11105 KiB

Open AccessEditor’s ChoiceArticle

Influence of Porosity on Fatigue Behaviour of 18Ni300 Steel SLM CT Specimens at Various Angles

by Pablo M. Cerezo, Jose A. Aguilera, Antonio Garcia-Gonzalez and Pablo Lopez-Crespo

Materials 2024, 17(2), 432; https://doi.org/10.3390/ma17020432 - 16 Jan 2024

Cited by 5 | Viewed by 1234

Abstract

In order to improve understanding of the fatigue behaviour in additive manufactured samples, this research delves into the challenging interplay between building parameters, particularly fabrication angles, and the presence of pores. The primary objective is to explore the characterisation of these pores and [...] Read more.

In order to improve understanding of the fatigue behaviour in additive manufactured samples, this research delves into the challenging interplay between building parameters, particularly fabrication angles, and the presence of pores. The primary objective is to explore the characterisation of these pores and unravel their relationship with the fatigue properties of the material under investigation. Through a systematic analysis of porosity distribution in various fabrication orientations, supplemented by a detailed examination of the elemental dispersion around specific porous structures using energy-dispersive X-ray spectroscopy, a consistent behavioural pattern emerges across the samples. In assessing fatigue behaviour, an examination of the variables reveals that only area and aspect ratio significantly influence the behaviour of the samples. Such studies can contribute substantially to academic research in the field of material science and engineering. Full article

(This article belongs to the Special Issue Fatigue Crack Growth in Metallic Materials (Volume II))

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10 pages, 2051 KiB

Open AccessEditor’s ChoiceArticle

Fabrication and Luminescence Properties of Highly Transparent Green-Emitting Ho:Y₂O₃ Ceramics for Laser Diode Lighting

by Yan Liu, Xianpeng Qin, Lin Gan, Guohong Zhou, Song Hu, Zhengjuan Wang, Juan Jiang, Tianjin Zhang and Hetuo Chen

Materials 2024, 17(2), 402; https://doi.org/10.3390/ma17020402 - 13 Jan 2024

Viewed by 1124

Abstract

Highly transparent Ho:Y₂O₃ ceramics for laser diode lighting were prepared using the vacuum sintering method with 0.3 at.% Nb₂O₅ as a sintering additive. The microstructures, transmittance, and luminescence properties of the Ho:Y₂O₃ ceramic samples [...] Read more.

Highly transparent Ho:Y₂O₃ ceramics for laser diode lighting were prepared using the vacuum sintering method with 0.3 at.% Nb₂O₅ as a sintering additive. The microstructures, transmittance, and luminescence properties of the Ho:Y₂O₃ ceramic samples were investigated in detail. The transmittance levels of all samples with various Ho³⁺ concentrations reached ~81.5% (2 mm thick) at 1100 nm. Under the excitation of 363 nm (ultraviolet) or 448 nm (blue) light, Ho:Y₂O₃ transparent ceramic samples showed that green emission peaked at 550 nm. The emission intensity was strongly affected by the concentration of Ho³⁺ ions, reaching its highest level in the sample doped with 1 at.% Ho³⁺. The CIE coordinates of the luminescence were in the green region (i.e., the CIE coordinates of the sample doped with 1 at.% Ho³⁺ were [0.27, 0.53] and [0.30, 0.69], under the excitation of 363 nm and 448 nm light, respectively). The possibility of its application as laser diode lighting was reported. Under the excitation of 450 nm blue laser, the sample doped with 0.5 at.% Ho³⁺ had the best performance: the saturated luminous flux, lumen efficiency, and the luminescence saturation power densities were 800 lm, 57.7 lm/W, and 17.6 W/mm², respectively. Furthermore, the materials have high thermal conductivity and mechanical strength due to their host of rare-earth sesquioxide. Thus, Ho:Y₂O₃ transparent ceramics are expected to be a promising candidate for green-light-emitting devices for solid-state lighting, such as laser diode lighting. Full article

(This article belongs to the Special Issue Glasses and Ceramics for Luminescence Applications (2nd Edition))

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15 pages, 6199 KiB

Open AccessEditor’s ChoiceArticle

Porous Lithium Disilicate Glass–Ceramics Prepared by Cold Sintering Process Associated with Post-Annealing Technique

by Xigeng Lyu, Yeongjun Seo, Do Hyung Han, Sunghun Cho, Yoshifumi Kondo, Tomoyo Goto and Tohru Sekino

Materials 2024, 17(2), 381; https://doi.org/10.3390/ma17020381 - 12 Jan 2024

Viewed by 1327

Abstract

Using melt-derived LD glass powders and 5–20 M NaOH solutions, porous lithium disilicate (Li₂Si₂O₅, LD) glass–ceramics were prepared by the cold sintering process (CSP) associated with the post-annealing technique. In this novel technique, H₂O vapor [...] Read more.

Using melt-derived LD glass powders and 5–20 M NaOH solutions, porous lithium disilicate (Li₂Si₂O₅, LD) glass–ceramics were prepared by the cold sintering process (CSP) associated with the post-annealing technique. In this novel technique, H₂O vapor originating from condensation reactions between residual Si–OH groups in cold-sintered LD glasses played the role of a foaming agent. With the increasing concentration of NaOH solutions, many more residual Si–OH groups appeared, and then rising trends in number as well as size were found for spherical pores formed in the resultant porous LD glass–ceramics. Correspondingly, the total porosities and average pore sizes varied from 25.6 ± 1.3% to 48.6 ± 1.9% and from 1.89 ± 0.68 μm to 13.40 ± 10.27 μm, respectively. Meanwhile, both the volume fractions and average aspect ratios of precipitated LD crystals within their pore walls presented progressively increasing tendencies, ranging from 55.75% to 76.85% and from 4.18 to 6.53, respectively. Young’s modulus and the hardness of pore walls for resultant porous LD glass–ceramics presented remarkable enhancement from 56.9 ± 2.5 GPa to 79.1 ± 2.1 GPa and from 4.6 ± 0.9 GPa to 8.1 ± 0.8 GPa, whereas their biaxial flexural strengths dropped from 152.0 ± 6.8 MPa to 77.4 ± 5.4 MPa. Using H₂O vapor as a foaming agent, this work reveals that CSP associated with the post-annealing technique is a feasible and eco-friendly methodology by which to prepare porous glass–ceramics. Full article

(This article belongs to the Special Issue Glassy Materials: From Preparation to Application)

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13 pages, 5795 KiB

Open AccessEditor’s ChoiceArticle

Characterization of Tannic Acid-Coated AZ31 Mg Alloy for Biomedical Application and Comparison with AZ91

by Jacopo Barberi, Muhammad Saqib, Anna Dmitruk, Jörg Opitz, Krzysztof Naplocha, Natalia Beshchasna, Silvia Spriano and Sara Ferraris

Materials 2024, 17(2), 343; https://doi.org/10.3390/ma17020343 - 10 Jan 2024

Cited by 3 | Viewed by 1267

Abstract

Magnesium alloys are promising materials for bioresorbable implants that will improve patient life and reduce healthcare costs. However, their clinical use is prevented by the rapid degradation and corrosion of magnesium, which leads to a fast loss of mechanical strength and the formation [...] Read more.

Magnesium alloys are promising materials for bioresorbable implants that will improve patient life and reduce healthcare costs. However, their clinical use is prevented by the rapid degradation and corrosion of magnesium, which leads to a fast loss of mechanical strength and the formation of by-products that can trigger tissue inflammation. Here, a tannic acid coating is proposed to control the degradation of AZ31 and AZ91 alloys, starting from a previous study by the authors on AZ91. The coatings on the two materials were characterized both by the chemical (EDS, FTIR, XPS) and the morphological (SEM, confocal profilometry) point of view. Static degradation tests in PBS and electrochemical measurements in different solutions showed that the protective performances of the tannic acid coatings are strongly affected by the presence of cracks. The presence of fractures in the protective layer generates galvanic couples between the coating scales and the metal, worsening the corrosion resistance. Although degradation control was not achieved, useful insights on the degradation mechanisms of coated Mg surfaces were obtained, as well as key points for future studies: it resulted that the absence of cracks in protective coatings is of uttermost importance for novel biodegradable implants with proper degradation kinetics. Full article

(This article belongs to the Special Issue Biocompatible and Bioactive Materials for Medical Applications)

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22 pages, 8943 KiB

Open AccessEditor’s ChoiceArticle

Possibilities of Increasing the Durability of Dies Used in the Extrusion Process of Valve Forgings from Chrome-Nickel Steel by Using Alternative Materials from Hot-Work Tool Steels

by Marek Hawryluk, Marta Janik, Maciej Zwierzchowski, Marzena Małgorzata Lachowicz and Jakub Krawczyk

Materials 2024, 17(2), 346; https://doi.org/10.3390/ma17020346 - 10 Jan 2024

Cited by 1 | Viewed by 1128

Abstract

This study refers to an analysis of the dies used in the first operation of producing a valve forging from chromium-nickel steel NC3015. The analyzed process of manufacturing forgings of exhaust valves is realized in the co-extrusion technology, followed by forging in closed [...] Read more.

This study refers to an analysis of the dies used in the first operation of producing a valve forging from chromium-nickel steel NC3015. The analyzed process of manufacturing forgings of exhaust valves is realized in the co-extrusion technology, followed by forging in closed dies. This type of technology is difficult to master, mainly due to the increased adhesion of the charge material to the tool substrate as well as the complex conditions of the tools’ operations, which are caused by the cyclic thermo-mechanical loads and also the hard tribological conditions. The average durability of tools made from tool steel WLV (1.2365), subjected to thermal treatment and nitriding, equals about 1000 forgings. In order to perform an in-depth analysis, a complex analysis of the presently realized technology was conducted in combination with multi-variant numerical simulations. The obtained results showed numerous cracks on the tools, especially in the cross-section reduction area, as well as sticking of the forging material, which, with insufficient control of the tribological conditions, can cause premature wear of the dies. In order to increase the durability of forging dies, alternative materials made of hot work tool steels were used: QRO90 Supreme, W360, and Unimax. The preliminary tests showed that the best results were obtained for QRO90, as the average durability for the tools made of this steel equaled about 1200 forgings (with an increase in both the minimal and maximal values), with reference to the 1000 forgings for the material applied so far. Full article

(This article belongs to the Special Issue Enhancing In-Use Properties of Advanced Steels)

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22 pages, 4577 KiB

Open AccessEditor’s ChoiceReview

Challenges for Field-Effect-Transistor-Based Graphene Biosensors

by Takao Ono, Satoshi Okuda, Shota Ushiba, Yasushi Kanai and Kazuhiko Matsumoto

Materials 2024, 17(2), 333; https://doi.org/10.3390/ma17020333 - 9 Jan 2024

Cited by 10 | Viewed by 3721

Abstract

Owing to its outstanding physical properties, graphene has attracted attention as a promising biosensor material. Field-effect-transistor (FET)-based biosensors are particularly promising because of their high sensitivity that is achieved through the high carrier mobility of graphene. However, graphene-FET biosensors have not yet reached [...] Read more.

Owing to its outstanding physical properties, graphene has attracted attention as a promising biosensor material. Field-effect-transistor (FET)-based biosensors are particularly promising because of their high sensitivity that is achieved through the high carrier mobility of graphene. However, graphene-FET biosensors have not yet reached widespread practical applications owing to several problems. In this review, the authors focus on graphene-FET biosensors and discuss their advantages, the challenges to their development, and the solutions to the challenges. The problem of Debye screening, in which the surface charges of the detection target are shielded and undetectable, can be solved by using small-molecule receptors and their deformations and by using enzyme reaction products. To address the complexity of sample components and the detection mechanisms of graphene-FET biosensors, the authors outline measures against nonspecific adsorption and the remaining problems related to the detection mechanism itself. The authors also introduce a solution with which the molecular species that can reach the sensor surfaces are limited. Finally, the authors present multifaceted approaches to the sensor surfaces that provide much information to corroborate the results of electrical measurements. The measures and solutions introduced bring us closer to the practical realization of stable biosensors utilizing the superior characteristics of graphene. Full article

(This article belongs to the Special Issue Research Progress on Two-Dimensional Materials)

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36 pages, 2816 KiB

Open AccessEditor’s ChoiceReview

Polymersomes as the Next Attractive Generation of Drug Delivery Systems: Definition, Synthesis and Applications

by Mariana Fonseca, Ivana Jarak, Francis Victor, Cátia Domingues, Francisco Veiga and Ana Figueiras

Materials 2024, 17(2), 319; https://doi.org/10.3390/ma17020319 - 8 Jan 2024

Cited by 7 | Viewed by 3937

Abstract

Polymersomes are artificial nanoparticles formed by the self-assembly process of amphiphilic block copolymers composed of hydrophobic and hydrophilic blocks. They can encapsulate hydrophilic molecules in the aqueous core and hydrophobic molecules within the membrane. The composition of block copolymers can be tuned, enabling [...] Read more.

Polymersomes are artificial nanoparticles formed by the self-assembly process of amphiphilic block copolymers composed of hydrophobic and hydrophilic blocks. They can encapsulate hydrophilic molecules in the aqueous core and hydrophobic molecules within the membrane. The composition of block copolymers can be tuned, enabling control of characteristics and properties of formed polymersomes and, thus, their application in areas such as drug delivery, diagnostics, or bioimaging. The preparation methods of polymersomes can also impact their characteristics and the preservation of the encapsulated drugs. Many methods have been described, including direct hydration, thin film hydration, electroporation, the pH-switch method, solvent shift method, single and double emulsion method, flash nanoprecipitation, and microfluidic synthesis. Considering polymersome structure and composition, there are several types of polymersomes including theranostic polymersomes, polymersomes decorated with targeting ligands for selective delivery, stimuli-responsive polymersomes, or porous polymersomes with multiple promising applications. Due to the shortcomings related to the stability, efficacy, and safety of some therapeutics in the human body, polymersomes as drug delivery systems have been good candidates to improve the quality of therapies against a wide range of diseases, including cancer. Chemotherapy and immunotherapy can be improved by using polymersomes to deliver the drugs, protecting and directing them to the exact site of action. Moreover, this approach is also promising for targeted delivery of biologics since they represent a class of drugs with poor stability and high susceptibility to in vivo clearance. However, the lack of a well-defined regulatory plan for polymersome formulations has hampered their follow-up to clinical trials and subsequent market entry. Full article

(This article belongs to the Special Issue Novel Nanosystems Composed of Amphiphilic Copolymers: Synthesis, Properties and Some Applications)

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20 pages, 3054 KiB

Open AccessEditor’s ChoiceReview

A Short Overview on Graphene and Graphene-Related Materials for Electrochemical Gas Sensing

by Mallikarjun Madagalam, Mattia Bartoli and Alberto Tagliaferro

Materials 2024, 17(2), 303; https://doi.org/10.3390/ma17020303 - 7 Jan 2024

Cited by 3 | Viewed by 1630

Abstract

The development of new and high-performing electrode materials for sensing applications is one of the most intriguing and challenging research fields. There are several ways to approach this matter, but the use of nanostructured surfaces is among the most promising and highest performing. [...] Read more.

The development of new and high-performing electrode materials for sensing applications is one of the most intriguing and challenging research fields. There are several ways to approach this matter, but the use of nanostructured surfaces is among the most promising and highest performing. Graphene and graphene-related materials have contributed to spreading nanoscience across several fields in which the combination of morphological and electronic properties exploit their outstanding electrochemical properties. In this review, we discuss the use of graphene and graphene-like materials to produce gas sensors, highlighting the most relevant and new advancements in the field, with a particular focus on the interaction between the gases and the materials. Full article

(This article belongs to the Special Issue Advanced Graphene and Graphene Oxide Materials)

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16 pages, 4184 KiB

Open AccessEditor’s ChoiceArticle

The Combined Effects on Human Dental Pulp Stem Cells of Fast-Set or Premixed Hydraulic Calcium Silicate Cements and Secretome Regarding Biocompatibility and Osteogenic Differentiation

by Yun-Jae Ha, Donghee Lee and Sin-Young Kim

Materials 2024, 17(2), 305; https://doi.org/10.3390/ma17020305 - 7 Jan 2024

Viewed by 1551

Abstract

An important part of regenerative endodontic procedures involving immature permanent teeth is the regeneration of the pulp–dentin complex with continuous root development. Hydraulic calcium silicate cements (HCSCs) are introduced for the pulpal treatment of immature permanent teeth. The stem-cell-derived secretome recently has been [...] Read more.

An important part of regenerative endodontic procedures involving immature permanent teeth is the regeneration of the pulp–dentin complex with continuous root development. Hydraulic calcium silicate cements (HCSCs) are introduced for the pulpal treatment of immature permanent teeth. The stem-cell-derived secretome recently has been applied for the treatment of various damaged tissues. Here, we evaluated the biocompatibility and osteogenic differentiation of HCSCs combined with secretome on human dental pulp stem cells. In the Cell Counting Kit-8 test and wound healing assays, significantly higher cell viability was observed with secretome application. In alkaline phosphatase analysis, the activity was significantly higher with secretome application in all groups, except for RetroMTA on day 2 and Endocem MTA Premixed on day 4. In an Alizarin Red S staining analysis, all groups with secretome application had significantly higher staining values. Quantitative real-time polymerase chain reaction results showed that the day 7 expression of OSX significantly increased with secretome application in all groups. SMAD1 and DSPP expression also increased significantly with secretome addition in all groups except for Biodentine. In conclusion, HCSCs showed favorable biocompatibility and osteogenic ability and are predicted to demonstrate greater synergy with the addition of secretome during regenerative endodontic procedures involving immature permanent teeth. Full article

(This article belongs to the Special Issue Advanced Materials and Technologies in Endodontics and Restorative Dentistry)

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14 pages, 2515 KiB

Open AccessEditor’s ChoiceArticle

Influence of Carbon-Based Fillers on the Electromagnetic Shielding Properties of a Silicone-Potting Compound

by Rafael Seidel, Konrad Katzer, Jakob Bieck, Maurice Langer, Julian Hesselbach and Michael Heilig

Materials 2024, 17(2), 280; https://doi.org/10.3390/ma17020280 - 5 Jan 2024

Cited by 2 | Viewed by 1150

Abstract

The effect of carbon-based additives on adhesives and potting compounds with regard to electrical conductivity and electromagnetic interference (EMI) shielding properties is of great interest. The increasing power of wireless systems and the ever-higher frequency bands place new demands on shielding technology. This [...] Read more.

The effect of carbon-based additives on adhesives and potting compounds with regard to electrical conductivity and electromagnetic interference (EMI) shielding properties is of great interest. The increasing power of wireless systems and the ever-higher frequency bands place new demands on shielding technology. This publication gives an overview of the effect of carbon-based fillers on electrical conductivity, electromagnetic shielding properties, and the influence of different fillers and filler amounts on rheological behavior. This work focuses on carbon black (CB), recycled carbon fibers (rCF), carbon nanotubes (CNTs), and complex nanomaterials. Therefore, silicon samples with different fillers and filler amounts were prepared using a dual asymmetric centrifuge and a three-roll mill. It has been found that even with small filler amounts, the electromagnetic shielding properties were drastically raised. The filler content as well as the dispersion technique have a significant influence on most of the fillers. It has also been found that the complex viscosity is strongly influenced by the dispersion technique as well as by the choice and amount of filler. In the experiments carried out, shielding values of over 20 dB were achieved with several fillers, whereby even 43 dB were reached with complex, pre-crosslinked fillers. This signal reduction of up to 99.99% enables almost complete shielding of the related frequency. Full article

(This article belongs to the Section Carbon Materials)

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34 pages, 2194 KiB

Open AccessEditor’s ChoiceReview

Designing Composite Stimuli-Responsive Hydrogels for Wound Healing Applications: The State-of-the-Art and Recent Discoveries

by Anna Michalicha, Anna Belcarz, Dimitrios A. Giannakoudakis, Magdalena Staniszewska and Mariusz Barczak

Materials 2024, 17(2), 278; https://doi.org/10.3390/ma17020278 - 5 Jan 2024

Cited by 9 | Viewed by 3057

Abstract

Effective wound treatment has become one of the most important challenges for healthcare as it continues to be one of the leading causes of death worldwide. Therefore, wound care technologies significantly evolved in order to provide a holistic approach based on various designs [...] Read more.

Effective wound treatment has become one of the most important challenges for healthcare as it continues to be one of the leading causes of death worldwide. Therefore, wound care technologies significantly evolved in order to provide a holistic approach based on various designs of functional wound dressings. Among them, hydrogels have been widely used for wound treatment due to their biocompatibility and similarity to the extracellular matrix. The hydrogel formula offers the control of an optimal wound moisture level due to its ability to absorb excess fluid from the wound or release moisture as needed. Additionally, hydrogels can be successfully integrated with a plethora of biologically active components (e.g., nanoparticles, pharmaceuticals, natural extracts, peptides), thus enhancing the performance of resulting composite hydrogels in wound healing applications. In this review, the-state-of-the-art discoveries related to stimuli-responsive hydrogel-based dressings have been summarized, taking into account their antimicrobial, anti-inflammatory, antioxidant, and hemostatic properties, as well as other effects (e.g., re-epithelialization, vascularization, and restoration of the tissue) resulting from their use. Full article

(This article belongs to the Section Biomaterials)

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38 pages, 8389 KiB

Open AccessEditor’s ChoiceReview

Materials Nanoarchitectonics at Dynamic Interfaces: Structure Formation and Functional Manipulation

by Katsuhiko Ariga

Materials 2024, 17(1), 271; https://doi.org/10.3390/ma17010271 - 4 Jan 2024

Cited by 6 | Viewed by 2902

Abstract

The next step in nanotechnology is to establish a methodology to assemble new functional materials based on the knowledge of nanotechnology. This task is undertaken by nanoarchitectonics. In nanoarchitectonics, we architect functional material systems from nanounits such as atoms, molecules, and nanomaterials. In [...] Read more.

The next step in nanotechnology is to establish a methodology to assemble new functional materials based on the knowledge of nanotechnology. This task is undertaken by nanoarchitectonics. In nanoarchitectonics, we architect functional material systems from nanounits such as atoms, molecules, and nanomaterials. In terms of the hierarchy of the structure and the harmonization of the function, the material created by nanoarchitectonics has similar characteristics to the organization of the functional structure in biosystems. Looking at actual biofunctional systems, dynamic properties and interfacial environments are key. In other words, nanoarchitectonics at dynamic interfaces is important for the production of bio-like highly functional materials systems. In this review paper, nanoarchitectonics at dynamic interfaces will be discussed, looking at recent typical examples. In particular, the basic topics of “molecular manipulation, arrangement, and assembly” and “material production” will be discussed in the first two sections. Then, in the following section, “fullerene assembly: from zero-dimensional unit to advanced materials”, we will discuss how various functional structures can be created from the very basic nanounit, the fullerene. The above examples demonstrate the versatile possibilities of architectonics at dynamic interfaces. In the last section, these tendencies will be summarized, and future directions will be discussed. Full article

(This article belongs to the Special Issue Nanoarchitectonics in Materials Science)

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11 pages, 3428 KiB

Open AccessEditor’s ChoiceArticle

Study on the Crystallization Behavior of Neodymium Rare-Earth Butadiene Rubber Blends and Its Effect on Dynamic Mechanical Properties

by Xiaohu Zhang, Wenbin Zhu, Xiaofan Li, Xinzheng Xie, Huan Ji, Yanxing Wei and Jifu Bi

Materials 2024, 17(1), 256; https://doi.org/10.3390/ma17010256 - 3 Jan 2024

Cited by 1 | Viewed by 1174

Abstract

Utilizing neodymium-based butadiene rubber as a baseline, this study examines the effect of eco-friendly aromatic TDAE oil, fillers, and crosslinking reactions on neodymium-based rare-earth butadiene rubber (Nd-BR) crystallization behavior. The findings suggest that TDAE oil hinders crystallization, resulting in decreased crystallization temperatures and [...] Read more.

Utilizing neodymium-based butadiene rubber as a baseline, this study examines the effect of eco-friendly aromatic TDAE oil, fillers, and crosslinking reactions on neodymium-based rare-earth butadiene rubber (Nd-BR) crystallization behavior. The findings suggest that TDAE oil hinders crystallization, resulting in decreased crystallization temperatures and heightened activation energies (E_a). The crystallization activation energies for 20 parts per hundreds of rubber (PHR) and 37.5 PHR oil stand at −116.8 kJ/mol and −48.1 kJ/mol, respectively, surpassing the −264.3 kJ/mol of the unadulterated rubber. Fillers act as nucleating agents, hastening crystallization, which in turn elevates crystallization temperatures and diminishes E_a. In samples containing 20 PHR and 37.5 PHR oil, the incorporation of carbon black and silica brought the E_a down to −224.9 kJ/mol and −239.1 kJ/mol, respectively. Crosslinking considerably restricts molecular motion and crystallization potential. In the examined conditions, butadiene rubber containing 37.5 PHR oil displayed no crystallization following crosslinking, albeit crystallization was discernible with filler inclusion. Simultaneously, the crystallinity level sharply declined, manifesting cold crystallization behavior. The crosslinking process elevates E_a, while the equilibrium melting point (

T_{m}^{0}

) noticeably diminishes. For instance, the

T_{m}^{0}

of pure Nd-BR is approximately −0.135 °C. When blended with carbon black and silica, the

T_{m}^{0}

values are −3.13 °C and −5.23 °C, respectively. After vulcanization, these values decrease to −21.6 °C and −10.16 °C. Evaluating the isothermal crystallization kinetics of diverse materials via the Avrami equation revealed that both the oil and crosslinking process can bring about a decrease in n values, with the Avrami index n for various samples oscillating between 1.5 and 2.5. Assessing the dynamic mechanical attributes of different specimens reveals that Nd-BR crystallization notably curtails its glass transition, marked by a modulus shift in the transition domain and a decrement in loss factor. The modulus in the rubbery state also witnesses a substantial augmentation. Full article

(This article belongs to the Section Polymeric Materials)

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21 pages, 4123 KiB

Open AccessEditor’s ChoiceArticle

Nanoscale and Tensile-Like Properties by an Instrumented Indentation Test on PBF-LB SS 316L Steel

by Giovanni Maizza, Faisal Hafeez, Alessandra Varone and Roberto Montanari

Materials 2024, 17(1), 255; https://doi.org/10.3390/ma17010255 - 3 Jan 2024

Viewed by 1587

Abstract

The mechanical properties of a defect-free laser melting (PBF-LB) deposit of an AISI 316L steel alloy were assessed by means of an instrumented indentation test (IIT), at both the macro- and nano-scales. The inherent non-equilibrium microstructure of the alloy was chemically homogenous and [...] Read more.

The mechanical properties of a defect-free laser melting (PBF-LB) deposit of an AISI 316L steel alloy were assessed by means of an instrumented indentation test (IIT), at both the macro- and nano-scales. The inherent non-equilibrium microstructure of the alloy was chemically homogenous and consisted of equiaxed grains and large-elongated grains (under the optical microscope) with irregular outlines composed of a much finer internal cell structure (under the scanning electron microscope). Berkovich and Vickers indenters were used to assess the indentation properties across individual grains (nano) and over multiple grains (macro), respectively. The nano-indentation over the X-Y plane revealed nearly constant indentation modulus across an individual grain but variable on average within different grains whose value depended on the relative orientation of the individual grain. The macro-indentation test was conducted to analyze the tensile-like properties of the polycrystalline SS 316L alloy over the X-Y and Y-Z planes. The macro-indentation test provided a reliable estimate of the ultimate tensile strength (UTS-like) of the alloy. Other indentation properties gave inconsistent results, and a post factum analysis was, therefore, conducted, by means of a new approach, to account for the presence of residual stresses. The already existing indentation data were supplemented with new repeated indentation tests to conduct a detailed analysis of the relaxation ability of compressive and tensile residual stresses. The developed methodology allows the effect of residual stresses and the reliability of measured macro-indentation properties to be examined as a function of a small group of indentation parameters. Full article

(This article belongs to the Special Issue Instrumented Indentation Test: An Aiding Tool for Materials Science and Industry)

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13 pages, 2529 KiB

Open AccessEditor’s ChoiceArticle

Design, Synthesis, and Spectral Properties of Novel 2-Mercaptobenzothiazole Derivatives

by Agnieszka Skotnicka and Janina Kabatc-Borcz

Materials 2024, 17(1), 246; https://doi.org/10.3390/ma17010246 - 2 Jan 2024

Cited by 1 | Viewed by 1522

Abstract

This paper is focused on the optimalization of methods for the synthesis, isolation, and purification of 2-mercaptobenzothiazole-based acrylic and methacrylic monomers. The structures of the newly synthesized compounds were confirmed through infrared (IR) and nuclear magnetic resonance spectroscopy (NMR). Spectroscopic properties of the [...] Read more.

This paper is focused on the optimalization of methods for the synthesis, isolation, and purification of 2-mercaptobenzothiazole-based acrylic and methacrylic monomers. The structures of the newly synthesized compounds were confirmed through infrared (IR) and nuclear magnetic resonance spectroscopy (NMR). Spectroscopic properties of the resulting 2-mercaptobenzothiazole derivatives were determined based on their absorption spectra and molar absorption coefficients in solvents with varying polarities. A correlation was established between the calculated density functional theory (DFT) energies and Frontier Molecular Orbitals and the experimental observations, confirming their consistency. The practical utility of the synthesized compounds, particularly in future polymerization processes, hinges on a thorough understanding of these properties. Full article

(This article belongs to the Special Issue Feature Paper in the Section 'Polymeric Materials' (2nd Edition))

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47 pages, 7700 KiB

Open AccessEditor’s ChoiceReview

On the Durability of Icephobic Coatings: A Review

by Andrés Nistal, Benjamín Sierra-Martín and Antonio Fernández-Barbero

Materials 2024, 17(1), 235; https://doi.org/10.3390/ma17010235 - 31 Dec 2023

Cited by 7 | Viewed by 2925

Abstract

Ice formation and accumulation on surfaces has a negative impact in many different sectors and can even represent a potential danger. In this review, the latest advances and trends in icephobic coatings focusing on the importance of their durability are discussed, in an [...] Read more.

Ice formation and accumulation on surfaces has a negative impact in many different sectors and can even represent a potential danger. In this review, the latest advances and trends in icephobic coatings focusing on the importance of their durability are discussed, in an attempt to pave the roadmap from the lab to engineering applications. An icephobic material is expected to lower the ice adhesion strength, delay freezing time or temperature, promote the bouncing of a supercooled drop at subzero temperatures and/or reduce the ice accretion rate. To better understand what is more important for specific icing conditions, the different types of ice that can be formed in nature are summarized. Similarly, the alternative methods to evaluate the durability are reviewed, as this is key to properly selecting the method and parameters to ensure the coating is durable enough for a given application. Finally, the different types of icephobic surfaces available to date are considered, highlighting the strategies to enhance their durability, as this is the factor limiting the commercial applicability of icephobic coatings. Full article

(This article belongs to the Special Issue Surface Modifications and Coatings: Processing, Characterization, and Applications)

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13 pages, 3193 KiB

Open AccessEditor’s ChoiceArticle

High Emissivity MoSi₂-SiC-Al₂O₃ Coating on Rigid Insulation Tiles with Enhanced Thermal Protection Performance

by Xukun Yang, Yange Wan, Jiancun Li, Jiachen Liu, Mingchao Wang and Xin Tao

Materials 2024, 17(1), 220; https://doi.org/10.3390/ma17010220 - 30 Dec 2023

Cited by 3 | Viewed by 1614

Abstract

High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder [...] Read more.

High emissivity coatings with sol as the binder have the advantages of room temperature curing, good thermal shock resistance, and high emissivity; however, only silica sol has been used in the current systems. In this study, aluminum sol was used as the binder for the first time, and MoSi₂ and SiC were used as emittance agents to prepare a high emissivity MoSi₂-SiC-Al₂O₃ coating on mullite insulation tiles. The evolution of structure and composition at 1000–1400 °C, the spectral emissivity from 200 nm to 25 μm, and the insulation performance were studied. Compared with the coating with silica sol as a binder, the MoSi₂-SiC-Al₂O₃ coating has better structural uniformity and greater surface roughness and can generate mullite whiskers at lower temperatures. The total emissivity is 0.922 and 0.897, respectively, at the wavelength range of 200–2500 nm and 2.5–25 μm, and the superior emissivity at a low wavelength (<10 μm) is related to a higher surface roughness and reduced feature absorption. The emissivity reduction related to the oxidation of emittance agents at a high temperature (−10.2%) is smaller than that of the silica-sol-bonded coating (−18.6%). The cold surface temperature of the coated substrate is 215 °C lower than the bare substrate, suggesting excellent thermal insulation performance of the coating. Full article

(This article belongs to the Special Issue Advanced Ceramic and Glass Materials: Preparation, Characterization and Applications—2nd Edition)

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14 pages, 6311 KiB

Open AccessFeature PaperEditor’s ChoiceArticle

Rapid Growth of Metal–Metal Oxide Core–Shell Structures through Joule Resistive Heating: Morphological, Structural, and Luminescence Characterization

by Juan Francisco Ramos-Justicia, Ana Urbieta and Paloma Fernández

Materials 2024, 17(1), 208; https://doi.org/10.3390/ma17010208 - 30 Dec 2023

Cited by 1 | Viewed by 1168

Abstract

The aim of this study is to prove that resistive heating enables the synthesis of metal/metal oxide composites in the form of core–shell structures. The thickness and morphology of the oxide layer depends strongly on the nature of the metal, but the influences [...] Read more.

The aim of this study is to prove that resistive heating enables the synthesis of metal/metal oxide composites in the form of core–shell structures. The thickness and morphology of the oxide layer depends strongly on the nature of the metal, but the influences of parameters such as the time and current profiles and the presence of an external field have also been investigated. The systems chosen for the present study are Zn/ZnO, Ti/TiO₂, and Ni/NiO. The characterization of the samples was performed using techniques based on scanning electron microscopy (SEM). The thicknesses of the oxide layers varied from 10 μm (Zn/ZnO) to 50 μm (Ni/NiO). In the case of Zn- and Ti-based composites, the growth of nanostructures on the oxide layer was observed. Micro- and nanoneedles formed on the ZnO layer while prism-like structures appeared on the TiO₂. In the case of the NiO layer, micro- and nanocrystals were observed. Applying an external electric field seemed to align the ZnO needles, whereas its effect on TiO₂ and NiO was less appreciable, principally affecting the shape of their grain boundaries. The chemical compositions were analysed using X-ray spectroscopy (EDX), which confirmed the existence of an oxide layer. Structural information was obtained by means of X-ray diffraction (XRD) and was later checked using Raman spectroscopy. The oxide layers seemed to be crystalline and, although some non-stoichiometric phases appeared, the stoichiometric phases were predominant; these were wurtzite, rutile, and cubic for Zn, Ti, and Ni oxides, respectively. The photoluminescence technique was used to study the distribution of defects on the shell, and mainly visible bands (2–2.5 eV), attributed to oxygen vacancies, were present. The near-band edges of ZnO and TiO₂ were also observed around 3.2–3.3 eV. Full article

(This article belongs to the Special Issue Advantages and Perspectives of ZnO Nanostructured Materials)

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20 pages, 15729 KiB

Open AccessEditor’s ChoiceArticle

Atomistic-Continuum Study of an Ultrafast Melting Process Controlled by a Femtosecond Laser-Pulse Train

by Yu Meng, An Gong, Zhicheng Chen, Qingsong Wang, Jianwu Guo, Zihao Li and Jiafang Li

Materials 2024, 17(1), 185; https://doi.org/10.3390/ma17010185 - 29 Dec 2023

Cited by 3 | Viewed by 1379

Abstract

In femtosecond laser fabrication, the laser-pulse train shows great promise in improving processing efficiency, quality, and precision. This research investigates the influence of pulse number, pulse interval, and pulse energy ratio on the lateral and longitudinal ultrafast melting process using an experiment and [...] Read more.

In femtosecond laser fabrication, the laser-pulse train shows great promise in improving processing efficiency, quality, and precision. This research investigates the influence of pulse number, pulse interval, and pulse energy ratio on the lateral and longitudinal ultrafast melting process using an experiment and the molecular dynamics coupling two-temperature model (MD-TTM model), which incorporates temperature-dependent thermophysical parameters. The comparison of experimental and simulation results under single and double pulses proves the reliability of the MD-TTM model and indicates that as the pulse number increases, the melting threshold at the edge region of the laser spot decreases, resulting in a larger diameter of the melting region in the 2D lateral melting results. Using the same model, the lateral melting results of five pulses are simulated. Moreover, the longitudinal melting results are also predicted, and an increasing pulse number leads to a greater early-stage melting depth in the melting process. In the case of double femtosecond laser pulses, the pulse interval and pulse energy ratio also affect the early-stage melting depth, with the best enhancement observed with a 2 ps interval and a 3:7 energy ratio. However, pulse number, pulse energy ratio, and pulse interval do not affect the final melting depth with the same total energies. The findings mean that the phenomena of melting region can be flexibly manipulated through the laser-pulse train, which is expected to be applied to improve the structural precision and boundary quality. Full article

(This article belongs to the Section Materials Physics)

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23 pages, 5067 KiB

Open AccessEditor’s ChoiceArticle

Green Synthesis of Silver Nanoparticles Using the Cell-Free Supernatant of Haematococcus pluvialis Culture

by Maria G. Savvidou, Evgenia Kontari, Styliani Kalantzi and Diomi Mamma

Materials 2024, 17(1), 187; https://doi.org/10.3390/ma17010187 - 29 Dec 2023

Cited by 3 | Viewed by 1441

Abstract

The green synthesis of silver nanoparticles (AgNPs) using the cell-free supernatant of a Haematococcus pluvialis culture (CFS) was implemented in the current study, under illumination conditions. The reduction of Ag⁺ to AgNPs by the CFS could be described by a pseudo-first-order kinetic [...] Read more.

The green synthesis of silver nanoparticles (AgNPs) using the cell-free supernatant of a Haematococcus pluvialis culture (CFS) was implemented in the current study, under illumination conditions. The reduction of Ag⁺ to AgNPs by the CFS could be described by a pseudo-first-order kinetic equation at the temperature range tested. A high reaction rate during synthesis and stable AgNPs were obtained at 45 °C, while an alkaline pH (pH = 11.0) and a AgNO₃ aqueous solution to CFS ratio of 90:10 (v/v) proved to be the most effective conditions in AgNPs synthesis. A metal precursor (AgNO₃) at the concentration range tested (1–5 mM) was the limited reactant in the synthesis process. The synthesis of AgNPs was accomplished under static and agitated conditions. Continuous stirring enhanced the rate of reaction but induced aggregation at prolonged incubation times. Zeta potential and polydispersity index measurements indicated stable AgNPs and the majority of AgNPs formation occurred in the monodisperse phase. The X-ray diffraction (XRD) pattern revealed the face-centered cubic structure of the formed AgNPs, while TEM analysis revealed that the AgNPs were of a quasi-spherical shape with a size from 30 to 50 nm. The long-term stability of the AgNPs could be achieved in darkness and at 4 °C. In addition, the synthesized nanoparticles showed antibacterial activity against Escherichia coli. Full article

(This article belongs to the Special Issue Eco-Nanotechnology in Materials)

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24 pages, 11690 KiB

Open AccessEditor’s ChoiceArticle

Crashworthiness of Additively Manufactured Auxetic Lattices: Repeated Impacts and Penetration Resistance

by Paolo Franzosi, Ivan Colamartino, Alessandro Giustina, Marco Anghileri and Marco Boniardi

Materials 2024, 17(1), 186; https://doi.org/10.3390/ma17010186 - 29 Dec 2023

Cited by 2 | Viewed by 1318

Abstract

Auxetic materials have recently attracted interest in the field of crashworthiness thanks to their peculiar negative Poisson ratio, leading to densification under compression and potentially being the basis of superior behavior upon impact with respect to conventional cellular cores or standard solutions. However, [...] Read more.

Auxetic materials have recently attracted interest in the field of crashworthiness thanks to their peculiar negative Poisson ratio, leading to densification under compression and potentially being the basis of superior behavior upon impact with respect to conventional cellular cores or standard solutions. However, the empirical demonstration of the applicability of auxeticity under impact is limited for most known geometries. As such, the present work strives to advance the investigation of the impact behavior of auxetic meta-materials: first by selecting and testing representative specimens, then by proceeding with an experimental and numerical study of repeated impact behavior and penetration resistance, and finally by proposing a new design of a metallic auxetic absorber optimized for additive manufacturing and targeted at high-performance crash applications. Full article

(This article belongs to the Special Issue Mechanical Performance of Advanced Composite Materials and Structures)

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17 pages, 3801 KiB

Open AccessEditor’s ChoiceArticle

A Machine Learning Approach for Modelling Cold-Rolling Curves for Various Stainless Steels

by Julia Contreras-Fortes, M. Inmaculada Rodríguez-García, David L. Sales, Rocío Sánchez-Miranda, Juan F. Almagro and Ignacio Turias

Materials 2024, 17(1), 147; https://doi.org/10.3390/ma17010147 - 27 Dec 2023

Cited by 2 | Viewed by 1384

Abstract

Stainless steel is a cold-work-hardened material. The degree and mechanism of hardening depend on the grade and family of the steel. This characteristic has a direct effect on the mechanical behaviour of stainless steel when it is cold-formed. Since cold rolling is one [...] Read more.

Stainless steel is a cold-work-hardened material. The degree and mechanism of hardening depend on the grade and family of the steel. This characteristic has a direct effect on the mechanical behaviour of stainless steel when it is cold-formed. Since cold rolling is one of the most widespread processes for manufacturing flat stainless steel products, the prediction of their strain-hardening mechanical properties is of great importance to materials engineering. This work uses artificial neural networks (ANNs) to forecast the mechanical properties of the stainless steel as a function of the chemical composition and the applied cold thickness reduction. Multiple linear regression (MLR) is also used as a benchmark model. To achieve this, both traditional and new-generation austenitic, ferritic, and duplex stainless steel sheets are cold-rolled at a laboratory scale with different thickness reductions after the industrial intermediate annealing stage. Subsequently, the mechanical properties of the cold-rolled sheets are determined by tensile tests, and the experimental cold-rolling curves are drawn based on those results. A database is created from these curves to generate a model applying machine learning techniques to predict the values of the tensile strength (Rm), yield strength (Rp), hardness (H), and elongation (A) based on the chemical composition and the applied cold thickness reduction. These models can be used as supporting tools for designing and developing new stainless steel grades and/or adjusting cold-forming processes. Full article

(This article belongs to the Special Issue Machine Learning Techniques in Materials Science and Engineering)

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19 pages, 2944 KiB

Open AccessEditor’s ChoiceArticle

Particleboards with Recycled Material from Hemp-Based Panels

by Electra Papadopoulou, Iouliana Chrysafi, Konstantina Karidi, Andromachi Mitani and Dimitrios N. Bikiaris

Materials 2024, 17(1), 139; https://doi.org/10.3390/ma17010139 - 27 Dec 2023

Cited by 1 | Viewed by 1877

Abstract

This research addresses the current need for sustainable solutions in the construction and furniture industries, with a focus on environmentally friendly particleboard. Particleboards were made from a mixture of virgin wood chips and hemp shives, which were then mechanically recycled and used to [...] Read more.

This research addresses the current need for sustainable solutions in the construction and furniture industries, with a focus on environmentally friendly particleboard. Particleboards were made from a mixture of virgin wood chips and hemp shives, which were then mechanically recycled and used to make new lightweight particleboards. Phenol–formaldehyde resin with 25% w/w phenol replacement by soybean flour (PFS) was used as the binder for the lignocellulosic materials. Laboratory analyses determined the resin properties, and FTIR confirmed the structure of the experimental PFS resin. The thermal properties of all the resins were evaluated using thermogravimetric analysis (TGA). The panels were manufactured using industrial simulation and tested for mechanical and physical properties in accordance with European standards. The FTIR study confirmed good adhesion, and the TGA showed improved thermal stability for the recycled biomass panels compared to virgin biomass panels. The study concludes that lightweight particleboards can be successfully produced from recycled hemp shive-based panels, providing a sustainable alternative to traditional materials in the construction industry. Full article

(This article belongs to the Special Issue Towards a Sustainable and Recyclable Future with Wood and Wood-Based Composites)

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35 pages, 6148 KiB

Open AccessEditor’s ChoiceReview

Titanium Alloy Implants with Lattice Structures for Mandibular Reconstruction

by Khaled M. Hijazi, S. Jeffrey Dixon, Jerrold E. Armstrong and Amin S. Rizkalla

Materials 2024, 17(1), 140; https://doi.org/10.3390/ma17010140 - 27 Dec 2023

Cited by 3 | Viewed by 1916

Abstract

In recent years, the field of mandibular reconstruction has made great strides in terms of hardware innovations and their clinical applications. There has been considerable interest in using computer-aided design, finite element modelling, and additive manufacturing techniques to build patient-specific surgical implants. Moreover, [...] Read more.

In recent years, the field of mandibular reconstruction has made great strides in terms of hardware innovations and their clinical applications. There has been considerable interest in using computer-aided design, finite element modelling, and additive manufacturing techniques to build patient-specific surgical implants. Moreover, lattice implants can mimic mandibular bone’s mechanical and structural properties. This article reviews current approaches for mandibular reconstruction, their applications, and their drawbacks. Then, we discuss the potential of mandibular devices with lattice structures, their development and applications, and the challenges for their use in clinical settings. Full article

(This article belongs to the Section Biomaterials)

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14 pages, 6019 KiB

Open AccessEditor’s ChoiceArticle

Multiscale Analysis of Composite Structures with Artificial Neural Network Support for Micromodel Stress Determination

by Wacław Kuś, Waldemar Mucha and Iyasu Tafese Jiregna

Materials 2024, 17(1), 154; https://doi.org/10.3390/ma17010154 - 27 Dec 2023

Cited by 4 | Viewed by 1373

Abstract

Structures made of heterogeneous materials, such as composites, often require a multiscale approach when their behavior is simulated using the finite element method. By solving the boundary value problem of the macroscale model, for previously homogenized material properties, the resulting stress maps can [...] Read more.

Structures made of heterogeneous materials, such as composites, often require a multiscale approach when their behavior is simulated using the finite element method. By solving the boundary value problem of the macroscale model, for previously homogenized material properties, the resulting stress maps can be obtained. However, such stress results do not describe the actual behavior of the material and are often significantly different from the actual stresses in the heterogeneous microstructure. Finding high-accuracy stress results for such materials leads to time-consuming analyses in both scales. This paper focuses on the application of machine learning to multiscale analysis of structures made of composite materials, to substantially decrease the time of computations of such localization problems. The presented methodology was validated by a numerical example where a structure made of resin epoxy with randomly distributed short glass fibers was analyzed using a computational multiscale approach. Carefully prepared training data allowed artificial neural networks to learn relationships between two scales and significantly increased the efficiency of the multiscale approach. Full article

(This article belongs to the Special Issue Computational Modelling and Design of Novel Engineering Materials (Second Edition))

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14 pages, 5431 KiB

Open AccessEditor’s ChoiceArticle

Advanced Integration of Glutathione-Functionalized Optical Fiber SPR Sensor for Ultra-Sensitive Detection of Lead Ions

by Jiale Wang, Kunpeng Niu, Jianguo Hou, Ziyang Zhuang, Jiayi Zhu, Xinyue Jing, Ning Wang, Binyun Xia and Lei Lei

Materials 2024, 17(1), 98; https://doi.org/10.3390/ma17010098 - 24 Dec 2023

Cited by 4 | Viewed by 1427

Abstract

It is crucial to detect Pb²⁺ accurately and rapidly. This work proposes an ultra-sensitive optical fiber surface plasmon resonance (SPR) sensor functionalized with glutathione (GSH) for label-free detection of the ultra-low Pb²⁺ concentration, in which the refractive index (RI) sensitivity of [...] Read more.

It is crucial to detect Pb²⁺ accurately and rapidly. This work proposes an ultra-sensitive optical fiber surface plasmon resonance (SPR) sensor functionalized with glutathione (GSH) for label-free detection of the ultra-low Pb²⁺ concentration, in which the refractive index (RI) sensitivity of the multimode-singlemode-multimode (MSM) hetero-core fiber is largely enhanced by the gold nanoparticles (AuNPs)/Au film coupling SPR effect. The GSH is modified on the fiber as the sensing probe to capture and identify Pb²⁺ specifically. Its working principle is that the Pb²⁺ chemically reacts with deprotonated carboxyl groups in GSH through ligand bonding, resulting in the formation of stable and specific chelates, inducing the variation of the local RI on the sensor surface, which in turn leads to the SPR wavelength shift in the transmission spectrum. Attributing to the AuNPs, both the Au substrates can be fully functionalized with the GSH molecules as the probes, which largely increases the number of active sites for Pb²⁺ trapping. Combined with the SPR effect, the sensor achieves a sensitivity of 2.32 × 10¹¹ nm/M and a limit of detection (LOD) of 0.43 pM. It also demonstrates exceptional specificity, stability, and reproducibility, making it suitable for various applications in water pollution, biomedicine, and food safety. Full article

(This article belongs to the Section Materials Chemistry)

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33 pages, 5643 KiB

Open AccessEditor’s ChoiceReview

Research Progress in Special Engineering Plastic-Based Electrochromic Polymers

by Yixuan Liu, Zhen Xing, Songrui Jia, Xiangfu Shi, Zheng Chen and Zhenhua Jiang

Materials 2024, 17(1), 73; https://doi.org/10.3390/ma17010073 - 22 Dec 2023

Cited by 8 | Viewed by 1625

Abstract

SPECPs are electrochromic polymers that contain special engineering plastic structural characteristic groups (SPECPs). Due to their high thermal stability, mechanical properties, and weather resistance, they are also known as high-performance electrochromic polymer (HPEP or HPP). Meanwhile, due to the structural characteristics of their [...] Read more.

SPECPs are electrochromic polymers that contain special engineering plastic structural characteristic groups (SPECPs). Due to their high thermal stability, mechanical properties, and weather resistance, they are also known as high-performance electrochromic polymer (HPEP or HPP). Meanwhile, due to the structural characteristics of their long polymer chains, these materials have natural advantages in the application of flexible electrochromic devices. According to the structure of special engineering plastic groups, SPECPs are divided into five categories: polyamide, polyimide, polyamide imide, polyarylsulfone, and polyarylketone. This article mainly introduces the latest research on SPECPs. The structural design, electrochromic properties, and applications of these materials are also introduced in this article, and the challenges and future development trends of SPECPs are prospected. Full article

(This article belongs to the Section Polymeric Materials)

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22 pages, 7099 KiB

Open AccessEditor’s ChoiceArticle

Reprocessing Possibilities of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)–Hemp Fiber Composites Regarding the Material and Product Quality

by Wiesław Frącz, Andrzej Pacana, Dominika Siwiec, Grzegorz Janowski and Łukasz Bąk

Materials 2024, 17(1), 55; https://doi.org/10.3390/ma17010055 - 22 Dec 2023

Viewed by 1080

Abstract

An important issue addressed in research on the assessment of the quality of polymer products is the quality of the polymer material itself and, in accordance with the idea of waste-free management, the impact of its repeated processing on its properties and the [...] Read more.

An important issue addressed in research on the assessment of the quality of polymer products is the quality of the polymer material itself and, in accordance with the idea of waste-free management, the impact of its repeated processing on its properties and the quality of the products. In this work, a biocomposite, based on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) with short hemp fibers, was obtained and repeatedly processed, which is a continuation of the research undertaken by the team in the field of this type of biocomposites. After subsequent stages of processing, the selected mechanical, processing and functional properties of the products were assessed. For this purpose, microscopic tests were carried out, mechanical properties were tested in static tensile and impact tests, viscosity curves were determined after subsequent processing cycles and changes in plastic pressure in the mold cavity were determined directly during processing. The results of the presented research confirm only a slight decrease in the mechanical properties of the produced type of biocomposite, even after it has been reprocessed five times, which gives extra weight to arguments for its commercialization as a substitute for petrochemical-based plastics. No significant changes were found in the used parameters and processing properties with the stages of processing, which allows for a predictable and stable manufacturing process using, for example, the injection molding process. Full article

(This article belongs to the Special Issue Qualitative-Environmental Aspects to Improve Materials and Processes of Their Formation)

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14 pages, 8542 KiB

Open AccessEditor’s ChoiceArticle

Electrophysical Properties of the Three-Component Multiferroic Ceramic Composites

by Dariusz Bochenek, Przemysław Niemiec, Dagmara Brzezińska, Grzegorz Dercz and Marcin Wąs

Materials 2024, 17(1), 49; https://doi.org/10.3390/ma17010049 - 22 Dec 2023

Cited by 1 | Viewed by 890

Abstract

Using the free (pressureless) sintering method, multiferroic ceramic composites based on two ferroelectric materials, i.e., BaTiO₃ (B) and Pb_0.94Sr_0.06 (Zr_0.46Ti_0.54)_0.99Cr_0.01O₃ (P), and magnetic material, i.e., zinc–nickel ferrite (F) were obtained. [...] Read more.

Using the free (pressureless) sintering method, multiferroic ceramic composites based on two ferroelectric materials, i.e., BaTiO₃ (B) and Pb_0.94Sr_0.06 (Zr_0.46Ti_0.54)_0.99Cr_0.01O₃ (P), and magnetic material, i.e., zinc–nickel ferrite (F) were obtained. Three composite compositions (BP-F) were obtained with a constant 90/10 content (ferroelectric/magnetic) and a variable content of the ferroelectric component (B/P), i.e., 70/30, 50/50, and 30/70. Crystalline structure, microstructural, DC electrical conductivity, dielectric, and ferroelectric properties of multiferroic composites were investigated. The concept of a composite consisting of two ferroelectric components ensures the preservation of sufficiently high ferroelectric properties of multiferroic composites sintered by the free sintering method. Research has shown that the percentage of individual ferroelectric components in the composite significantly affects the functional properties and the entire set of physical parameters of the multiferroic BP-F composite. In the case of the dielectric parameters, the best results were obtained for the composition with a more significant amount of BaTiO₃; i.e., permittivity is 1265, spontaneous polarization is 7.90 µC/cm², and remnant polarization is 5.40 µC/cm². However, the most advantageous set of performance parameters shows the composite composition of 50BP-F. Full article

(This article belongs to the Special Issue Advanced Materials and Technologies for Thermal Sprayed Coatings)

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16 pages, 4984 KiB

Open AccessEditor’s ChoiceArticle

N-Doped Carbon Nanowire-Modified Macroporous Carbon Foam Microbial Fuel Cell Anode: Enrichment of Exoelectrogens and Enhancement of Extracellular Electron Transfer

by Ke Liu, Zhuo Ma, Xinyi Li, Yunfeng Qiu, Danqing Liu and Shaoqin Liu

Materials 2024, 17(1), 69; https://doi.org/10.3390/ma17010069 - 22 Dec 2023

Cited by 4 | Viewed by 1431

Abstract

Microbial fuel cell (MFC) performance is affected by the metabolic activity of bacteria and the extracellular electron transfer (EET) process. The deficiency of nanostructures on macroporous anode obstructs the enrichment of exoelectrogens and the EET. Herein, a N-doped carbon nanowire-modified macroporous carbon foam [...] Read more.

Microbial fuel cell (MFC) performance is affected by the metabolic activity of bacteria and the extracellular electron transfer (EET) process. The deficiency of nanostructures on macroporous anode obstructs the enrichment of exoelectrogens and the EET. Herein, a N-doped carbon nanowire-modified macroporous carbon foam was prepared and served as an anode in MFCs. The anode has a hierarchical porous structure, which can solve the problem of biofilm blockage, ensure mass transport, favor exoelectrogen enrichment, and enhance the metabolic activity of bacteria. The microscopic morphology, spectroscopy, and electrochemical characterization of the anode confirm that carbon nanowires can penetrate biofilm, decrease charge resistance, and enhance long-distance electron transfer efficiency. In addition, pyrrolic N can effectively reduce the binding energy and electron transfer distance of bacterial outer membrane hemin. With this hierarchical anode, a maximum power density of 5.32 W/m³ was obtained, about 2.5-fold that of bare carbon cloth. The one-dimensional nanomaterial-modified macroporous anodes in this study are a promising strategy to improve the exoelectrogen enrichment and EET for MFCs. Full article

(This article belongs to the Special Issue Nanoarchitectonics in Materials Science)

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30 pages, 7029 KiB

Open AccessEditor’s ChoiceReview

Development and Future Trends of Protective Strategies for Magnesium Alloy Vascular Stents

by Dexiao Liu, Ke Yang and Shanshan Chen

Materials 2024, 17(1), 68; https://doi.org/10.3390/ma17010068 - 22 Dec 2023

Cited by 6 | Viewed by 1862

Abstract

Magnesium alloy stents have been extensively studied in the field of biodegradable metal stents due to their exceptional biocompatibility, biodegradability and excellent biomechanical properties. Nevertheless, the specific in vivo service environment causes magnesium alloy stents to degrade rapidly and fail to provide sufficient [...] Read more.

Magnesium alloy stents have been extensively studied in the field of biodegradable metal stents due to their exceptional biocompatibility, biodegradability and excellent biomechanical properties. Nevertheless, the specific in vivo service environment causes magnesium alloy stents to degrade rapidly and fail to provide sufficient support for a certain time. Compared to previous reviews, this paper focuses on presenting an overview of the development history, the key issues, mechanistic analysis, traditional protection strategies and new directions and protection strategies for magnesium alloy stents. Alloying, optimizing stent design and preparing coatings have improved the corrosion resistance of magnesium alloy stents. Based on the corrosion mechanism of magnesium alloy stents, as well as their deformation during use and environmental characteristics, we present some novel strategies aimed at reducing the degradation rate of magnesium alloys and enhancing the comprehensive performance of magnesium alloy stents. These strategies include adapting coatings for the deformation of the stents, preparing rapid endothelialization coatings to enhance the service environment of the stents, and constructing coatings with self-healing functions. It is hoped that this review can help readers understand the development of magnesium alloy cardiovascular stents and solve the problems related to magnesium alloy stents in clinical applications at the early implantation stage. Full article

(This article belongs to the Special Issue Advances in the Corrosion and Protection of Metals (Second Volume))

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20 pages, 1543 KiB

Open AccessEditor’s ChoiceReview

Production, Recycling and Economy of Palladium: A Critical Review

by Tomasz Michałek, Volker Hessel and Marek Wojnicki

Materials 2024, 17(1), 45; https://doi.org/10.3390/ma17010045 - 21 Dec 2023

Cited by 6 | Viewed by 4020

Abstract

Platinum group metals (PGMs), including palladium, play a pivotal role in various industries due to their unique properties. Palladium is frequently employed in technologies aimed at environmental preservation, such as catalytic converters that reduce harmful emissions from vehicles, and in the production of [...] Read more.

Platinum group metals (PGMs), including palladium, play a pivotal role in various industries due to their unique properties. Palladium is frequently employed in technologies aimed at environmental preservation, such as catalytic converters that reduce harmful emissions from vehicles, and in the production of clean energy, notably in the hydrogen evolution process. Regrettably, the production of this vital metal for our environment is predominantly centered in two countries—Russia and South Africa. This centralization has led to palladium being classified as a critical raw material, emphasizing the importance of establishing a secure and sustainable supply chain, as well as employing the most efficient methods for processing materials containing palladium. This review explores techniques for palladium production from primary sources and innovative recycling methods, providing insights into current technologies and emerging approaches. Furthermore, it investigates the economic aspects of palladium production, including price fluctuations influenced by emission regulations and electric vehicle sales, and establishes connections between palladium prices, imports from major producers, as well as copper and nickel prices, considering their often co-occurrence in ores. Full article

(This article belongs to the Special Issue Advanced Metallurgy Technologies: Physical and Numerical Modelling)

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45 pages, 10823 KiB

Open AccessEditor’s ChoiceReview

Progress in Gallium Oxide Field-Effect Transistors for High-Power and RF Applications

by Ory Maimon and Qiliang Li

Materials 2023, 16(24), 7693; https://doi.org/10.3390/ma16247693 - 18 Dec 2023

Cited by 2 | Viewed by 3229

Abstract

Power electronics are becoming increasingly more important, as electrical energy constitutes 40% of the total primary energy usage in the USA and is expected to grow rapidly with the emergence of electric vehicles, renewable energy generation, and energy storage. New materials that are [...] Read more.

Power electronics are becoming increasingly more important, as electrical energy constitutes 40% of the total primary energy usage in the USA and is expected to grow rapidly with the emergence of electric vehicles, renewable energy generation, and energy storage. New materials that are better suited for high-power applications are needed as the Si material limit is reached. Beta-phase gallium oxide (β-Ga₂O₃) is a promising ultra-wide-bandgap (UWBG) semiconductor for high-power and RF electronics due to its bandgap of 4.9 eV, large theoretical breakdown electric field of 8 MV cm⁻¹, and Baliga figure of merit of 3300, 3–10 times larger than that of SiC and GaN. Moreover, β-Ga₂O₃ is the only WBG material that can be grown from melt, making large, high-quality, dopable substrates at low costs feasible. Significant efforts in the high-quality epitaxial growth of β-Ga₂O₃ and β-(Al_xGa_1−x)₂O₃ heterostructures has led to high-performance devices for high-power and RF applications. In this report, we provide a comprehensive summary of the progress in β-Ga₂O₃ field-effect transistors (FETs) including a variety of transistor designs, channel materials, ohmic contact formations and improvements, gate dielectrics, and fabrication processes. Additionally, novel structures proposed through simulations and not yet realized in β-Ga₂O₃ are presented. Main issues such as defect characterization methods and relevant material preparation, thermal studies and management, and the lack of p-type doping with investigated alternatives are also discussed. Finally, major strategies and outlooks for commercial use will be outlined. Full article

(This article belongs to the Special Issue Ultra-Wide Bandgap Semiconductor Materials and Devices)

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14 pages, 5786 KiB

Open AccessEditor’s ChoiceArticle

Nitrogen- and Sulfur-Codoped Strong Green Fluorescent Carbon Dots for the Highly Specific Quantification of Quercetin in Food Samples

by Kandasamy Sasikumar, Ramar Rajamanikandan and Heongkyu Ju

Materials 2023, 16(24), 7686; https://doi.org/10.3390/ma16247686 - 17 Dec 2023

Cited by 8 | Viewed by 1573

Abstract

Carbon dots (CDs) doped with heteroatoms have garnered significant interest due to their chemically modifiable luminescence properties. Herein, nitrogen- and sulfur-codoped carbon dots (NS-CDs) were successfully prepared using p-phenylenediamine and thioacetamide via a facile process. The as-developed NS-CDs had high photostability against photobleaching, [...] Read more.

Carbon dots (CDs) doped with heteroatoms have garnered significant interest due to their chemically modifiable luminescence properties. Herein, nitrogen- and sulfur-codoped carbon dots (NS-CDs) were successfully prepared using p-phenylenediamine and thioacetamide via a facile process. The as-developed NS-CDs had high photostability against photobleaching, good water dispersibility, and excitation-independent spectral emission properties due to the abundant amino and sulfur functional groups on their surface. The wine-red-colored NS-CDs exhibited strong green emission with a large Stokes shift of up to 125 nm upon the excitation wavelength of 375 nm, with a high quantum yield (QY) of 28%. The novel NS-CDs revealed excellent sensitivity for quercetin (QT) detection via the fluorescence quenching effect, with a low detection limit of 17.3 nM within the linear range of 0–29.7 μM. The fluorescence was quenched only when QT was brought near the NS-CDs. This QT-induced quenching occurred through the strong inner filter effect (IFE) and the complex bound state formed between the ground-state QT and excited-state NS-CDs. The quenching-based detection strategies also demonstrated good specificity for QT over various interferents (phenols, biomolecules, amino acids, metal ions, and flavonoids). Moreover, this approach could be effectively applied to the quantitative detection of QT (with good sensing recovery) in real food samples such as red wine and onion samples. The present work, consequently, suggests that NS-CDs may open the door to the sensitive and specific detection of QT in food samples in a cost-effective and straightforward manner. Full article

(This article belongs to the Special Issue State-of-the-Art Nanomaterials in Energy and Environmental Applications)

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