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Morphology, Properties and Application of Flake Graphene-Based Composite Materials

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Composites".

Deadline for manuscript submissions: closed (20 March 2023) | Viewed by 6191

Special Issue Editor


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Guest Editor
Department of Chemical Synthesis and Flake Graphene, Łukasiewicz Research Network, Institute of Microelectronics and Photonics, Aleja Lotników 32/46, 02-668 Warsaw, Poland
Interests: flake graphene; biomaterials; atomic force microscopy; regenerative medicine; surface-related phenomena

Special Issue Information

Dear Colleagues,

Flake graphene and its derivatives are some of the most fascinating materials in modern science. They can be implemented in materials or used as an external layer, creating novel composite materials characterized by superior mechanical or surface-related properties. In addition, flake graphene can be embroidered with other materials due to the presence of manifold functional groups on its surface. These possibilities enable the fabrication of composite materials with strictly designed properties and functions. Such composites have many applications in areas including tissue engineering and regenerative medicine as drug carriers, energy storage materials, sensors, barrier coatings, anticorrosive coatings, materials to reduce friction wear, and materials with enhanced mechanical performance, etc.

This Special Issue, “Morphology, Properties and Application of Flake Graphene-based Composite Materials,” focuses on the development and characterization of novel composite materials and the publication of research papers, short communications, and review papers advancing knowledge on the properties and applications of such composites.

This Special Issue aims to create an interdisciplinary, international forum for researchers for sharing their experience and latest findings in the field of flake graphene and composite materials.

Dr. Adrian Chlanda
Guest Editor

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Keywords

  • flake graphene
  • composites
  • nanomaterials
  • biomaterials
  • polymers
  • fibers
  • surface
  • mechanical properties

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Published Papers (3 papers)

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Research

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16 pages, 8439 KiB  
Article
Study on the Preparation and Optical Properties of Graphene Oxide@Fe3O4 Two-Dimensional Magnetically Oriented Nanocomposites
by Song Yin, Tiantian Zhang, Yinfeng Yu, Xiaotong Bu, Zepeng Zhang, Junming Geng, Xueling Dong and Haibing Jiang
Materials 2023, 16(2), 476; https://doi.org/10.3390/ma16020476 - 4 Jan 2023
Cited by 9 | Viewed by 2076
Abstract
In this work, graphene oxide@Fe3O4 (GO@Fe3O4) two-dimensional magnetically oriented nanocomposites were prepared through the co-precipitation approach using graphene oxide as the carrier and FeCl3·6H2O and FeSO4·7H2O as iron [...] Read more.
In this work, graphene oxide@Fe3O4 (GO@Fe3O4) two-dimensional magnetically oriented nanocomposites were prepared through the co-precipitation approach using graphene oxide as the carrier and FeCl3·6H2O and FeSO4·7H2O as iron sources. The samples were characterized and tested by X-ray diffraction, a transmission electron microscope, Fourier-transform infrared spectroscopy, a vibrating-specimen magnetometer, a polarized optical microscope, an optical microscope, etc. The effects of material ratios and reaction conditions on the coating effects of Fe3O4 on the GO surface were investigated. The stable GO@Fe3O4 sol system was studied and constructed, and the optical properties of the GO@Fe3O4 sol were revealed. The results demonstrated the GO@Fe3O4 two-dimensional nanocomposites uniformly coated with Fe3O4 nanoparticles were successfully prepared. The GO@Fe3O4 two-dimensional nanocomposites exhibited superparamagnetic properties at room temperature, whose coercive force was 0. The stable GO@Fe3O4 sol system could be obtained by maintaining 1 < pH < 1.5. The GO@Fe3O4 sol showed magneto-orientation properties, liquid crystalline properties, and photonic crystal properties under the influence of the external magnetic field. The strength and direction of the magnetic field and the solid content of the GO@ Fe3O4 sol could regulate the aforementioned properties. The results suggest that GO@Fe3O4 two-dimensional magnetically oriented nanocomposites have potential applications in photonic switches, gas barriers, and display devices. Full article
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19 pages, 5951 KiB  
Article
Influence of Graphene Sheets on Compaction and Sintering Properties of Nano-Zirconia Ceramics
by Elena A. Trusova, Dmitrii D. Titov, Asya M. Afzal and Sergey S. Abramchuk
Materials 2022, 15(20), 7342; https://doi.org/10.3390/ma15207342 - 20 Oct 2022
Cited by 2 | Viewed by 1697
Abstract
The use of a nanostructured graphene-zirconia composite will allow the development of new materials with improved performance properties and a high functionality. This work covers a stepwise study related to the creation of a nanostructured composite based on ZrO2 and graphene. A [...] Read more.
The use of a nanostructured graphene-zirconia composite will allow the development of new materials with improved performance properties and a high functionality. This work covers a stepwise study related to the creation of a nanostructured composite based on ZrO2 and graphene. A composite was prepared using two suspensions: nano-zirconia obtained by sol-gel synthesis and oxygen-free graphene obtained sonochemically. The morphology of oxygen-free graphene sheets, phase composition and the morphology of a zirconia powder, and the morphology of the synthesized composite were studied. The effect of the graphene sheets on the rheological and sintering properties of a nanostructured zirconia-based composite powder has been studied. It has been found that graphene sheets in a hybrid nanostructure make it difficult to press at the elastic deformation stage, and the composite passes into the plastic region at a lower pressure than a single nano-zirconia. A sintering mechanism was proposed for a composite with a graphene content of 0.635 wt%, in which graphene is an important factor affecting the process mechanism. It has been determined that the activation energy of the composite sintering is more than two times higher than for a single nano-zirconia. Apparently, due to the van der Waals interaction, the graphene sheets partially stabilize the zirconia and prevent the disordering of the surface monolayers of its nanocrystals and premelting prior to the sintering. This leads to an increase in the activation energy of the composite sintering, and its sintering occurs, according to a mixed mechanism, in which the grain boundary diffusion predominates, in contrast to the single nano-zirconia sintering, which occurs through a viscous flow. Full article
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Review

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24 pages, 4373 KiB  
Review
Flake Graphene as an Efficient Agent Governing Cellular Fate and Antimicrobial Properties of Fibrous Tissue Engineering Scaffolds—A Review
by Aleksandra Izabela Banasiak, Adrian Racki, Marcin Małek and Adrian Chlanda
Materials 2022, 15(15), 5306; https://doi.org/10.3390/ma15155306 - 2 Aug 2022
Cited by 5 | Viewed by 2006
Abstract
Although there are several methods for fabricating nanofibrous scaffolds for biomedical applications, electrospinning is probably the most versatile and feasible process. Electrospinning enables the preparation of reproducible, homogeneous fibers from many types of polymers. In addition, implementation of this technique gives the possibility [...] Read more.
Although there are several methods for fabricating nanofibrous scaffolds for biomedical applications, electrospinning is probably the most versatile and feasible process. Electrospinning enables the preparation of reproducible, homogeneous fibers from many types of polymers. In addition, implementation of this technique gives the possibility to fabricated polymer-based composite mats embroidered with manifold materials, such as graphene. Flake graphene and its derivatives represent an extremely promising material for imparting new, biomedically relevant properties, functions, and applications. Graphene oxide (GO) and reduced graphene oxide (rGO), among many extraordinary properties, confer antimicrobial properties of the resulting material. Moreover, graphene oxide and reduced graphene oxide promote the desired cellular response. Tissue engineering and regenerative medicine enable advanced treatments to regenerate damaged tissues and organs. This review provides a reliable summary of the recent scientific literature on the fabrication of nanofibers and their further modification with GO/rGO flakes for biomedical applications. Full article
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