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Multiple Applications for Ceramic Materials

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Materials Physics".

Deadline for manuscript submissions: closed (10 July 2022) | Viewed by 5158

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Guest Editor
Istituto di Fisica Applicata “N. Carrara”, IFAC, Consiglio Nazionale delle Ricerche, CNR, Via Madonna del Piano 10C, I-50019 Sesto Fiorentino, Florence, Italy
Interests: solid-state-laser; laser material characterizations; trasparent policrystalline ceramics; laser crystals; non-linear optics; LED thecnology
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Special Issue Information

Dear Colleagues,

In the last decade, many efforts have been focused on the fabrication and development of transparent polycrystalline ceramics because they can be used as host materials for solid-state lasers (SSL). Ceramics doped with rare-earth elements (RE) such as Yb3+, Nd3+, Tm3+, Dy3+, etc, has been considered a promising and attractive way to build up efficient and high-power diode-pumped SSL with short duration pulses.

If compared with single crystals, ceramic fabrication processes make it possible to obtain samples with a more uniform dopant distribution, high levels of doping, excellent thermo-mechanical and optical properties. Moreover, they are more economically advantageous than crystals due to lower processing temperatures and shorter processing times. Since the first laser oscillations many relevant experimental results have been obtained by RE:(Y2O3, YAG, LuAG, Lu2O3, Sc2O3, exc) in terms of laser output power, efficiency, tuning range, duration pulses. It is mainly due to the continuous improvement of sintering methods which have allowed us to manufacture increasingly performing ceramics.    

This Special Issue is aimed to cover the recent research work on fabrication, development e characterization of transparent polycrystalline ceramic materials, so as to provide an insight into the current status and future prospects in this field. Topics can include, but are not limited to, the following:

  • Methods and technique of fabrication of transparent ceramics (i.e vacuum sintering, high-pressure sintering, hot pressing (HP), hot isostatic pressing (HIP), Spark plasma sintering, exc);
  • Microstructural characterizations (i.e X-Ray Diffraction (XRD), Energy Dispersive X-ray Analysis (EDX), exc);
  • Optical characterization (i.e. refraction index, absorption coefficient, transmittance, exc);
  • Spectroscopic investigation (i.e emission and absorption cross-sections, photoluminescence spectra, exc);
  • Mechanical properties (i.e fracture toughness, Young's modulus, exc);
  • Characterization/Simulation of thermal effects (i.e thermal lens, thermal conductivity, temperature gradients, exc);
  • Laser tests (laser output powers, slope efficiencies, tunability, exc) ;
  • Applications

It is my great pleasure to invite colleagues to submit a manuscript for this Special Issue. Full papers, communications, and reviews on any aspect of transparent ceramic materials are all welcome as well as new results obtained in luminescent laser material field.

Dr. Angela Pirri
Guest Editor

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Keywords

  • Polycristalline ceramics
  • Sesquioxides
  • Oxides
  • Mixed garnets
  • Fabrication of ceramic materials
  • Microstructure characterization
  • Thermal effects
  • Optical properties
  • Solid-state-laser
  • Applications

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Published Papers (2 papers)

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Research

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18 pages, 41152 KiB  
Article
In Situ Investigation of Strain Localization in Sintered, Porous Segmented Alumina
by Vladimir Kibitkin, Mikhail Grigoriev, Alexander Burlachenko, Andrey Solodushkin, Nickolai Savchenko, Valery Rubtsov and Sergei Tarasov
Materials 2021, 14(13), 3720; https://doi.org/10.3390/ma14133720 - 2 Jul 2021
Cited by 5 | Viewed by 1767
Abstract
Evaporation of paraffin and ultra-high-molecular-weight polyethylene admixed with alumina powder for the slip casting and sintering process allowed the obtainment of segmented porous alumina ceramics with 50% total porosity, whose deformation behavior we studied. Structurally, these ceramic materials were composed of large and [...] Read more.
Evaporation of paraffin and ultra-high-molecular-weight polyethylene admixed with alumina powder for the slip casting and sintering process allowed the obtainment of segmented porous alumina ceramics with 50% total porosity, whose deformation behavior we studied. Structurally, these ceramic materials were composed of large and small pores, and a system of discontinuities subdividing the samples into segments. Using digital image correlation (DIC), strain distribution maps were obtained that allowed the observation of strain localization zones, where primary cracks propagated along the interblock discontinuities. Two stages were revealed to be responsible for different mechanisms that provided the sample with damage tolerance under compression loading: the first stage was crack propagation along the block boundaries, which was followed by the second stage of microcracking and fragmentation, consisting of filling of the free spaces with fragments, compaction band generation, and stabilization of the crack. Both stages comprise a cycle that is repeated again and again until the full volume of the sample is occupied by the compaction bands. Full article
(This article belongs to the Special Issue Multiple Applications for Ceramic Materials)
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Review

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20 pages, 2045 KiB  
Review
Achievements and Future Perspectives of the Trivalent Thulium-Ion-Doped Mixed-Sesquioxide Ceramics for Laser Applications
by Angela Pirri, Roman N. Maksimov, Jiang Li, Matteo Vannini and Guido Toci
Materials 2022, 15(6), 2084; https://doi.org/10.3390/ma15062084 - 11 Mar 2022
Cited by 24 | Viewed by 2874
Abstract
This paper is devoted to reviewing the latest results achieved in solid-state lasers based on thulium-doped mixed-sesquioxide ceramics, i.e., (Lu,Sc,Y)2O3. The near- and mid-infrared regions are of interest for many applications, from medicine to remote sensing, as they match [...] Read more.
This paper is devoted to reviewing the latest results achieved in solid-state lasers based on thulium-doped mixed-sesquioxide ceramics, i.e., (Lu,Sc,Y)2O3. The near- and mid-infrared regions are of interest for many applications, from medicine to remote sensing, as they match molecular fingerprints and cover several atmospheric transparency windows. These matrices are characterized by a strong electron–phonon interaction—which results in a large splitting of the ground state—and by a spectral broadening of the optical transition suitable for developing tunable and short-pulse lasers. In particular, the manuscript reports on the trivalent thulium laser transitions at 1.5, 1.9, and 2.3 µm, along with the thermal and optical characteristics of the (Lu,Sc,Y)2O3 ceramics, including the fabrication techniques, spectroscopic and optical properties, and laser performances achieved in different pumping regimes, such as continuous-wave (CW), quasi-CW, and pulsed modes. A comparison of the performance obtained with these mixed-sesquioxide ceramics and with the corresponding crystals is reported. Full article
(This article belongs to the Special Issue Multiple Applications for Ceramic Materials)
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