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16 pages, 4281 KiB

Open AccessArticle

Effective Extraction of the Al Element from Secondary Aluminum Dross Using a Combined Dry Pressing and Alkaline Roasting Process

by Han Lv, Mingzhuang Xie, Zegang Wu, Lili Li, Runjie Yang, Jinshan Han, Fengqin Liu and Hongliang Zhao

Materials 2022, 15(16), 5686; https://doi.org/10.3390/ma15165686 - 18 Aug 2022

Cited by 10 | Viewed by 2088

Abstract

Secondary aluminum dross (SAD) is a hazardous solid waste discharged from aluminum electrolysis and processing and the secondary aluminum industries, which causes severe environmental pollution and public health disasters. The stable presence of the α-Al₂O₃ and MgAl₂O₄ [...] Read more.

Secondary aluminum dross (SAD) is a hazardous solid waste discharged from aluminum electrolysis and processing and the secondary aluminum industries, which causes severe environmental pollution and public health disasters. The stable presence of the α-Al₂O₃ and MgAl₂O₄ phases in SAD makes it difficult for it to be efficiently utilized. A combined dry pressing and alkaline roasting process was proposed for extracting the valuable Al element from SAD. Two alkaline additives (NaOH and Na₂CO₃) were selected as a sodium source for extracting the aluminum source from SAD in order to perform the thermodynamic analysis and roasting experiments. The phase transition behavior and the leaching performance tests were conducted using X-ray diffraction, scanning electron microscopy, X-ray fluorescence, leaching kinetics and thermal analysis. The recovery of Al and Na reached the values of 90.79% and 92.03%, respectively, under the optimal conditions (roasting temperature of 1150 °C, Na₂CO₃/Al₂O₃ molar ratio of 1.3, roasting time of 1 h, leaching temperature of 90 °C, L/S ratio of 10 mL·g⁻¹ and leaching time of 30 min). Meanwhile, the removal efficiency of N and Cl reached 98.93% and 97.14%, respectively. The leaching kinetics indicated that the dissolution of NaAlO₂ clinkers was a first-order reaction and controlled by layer diffusion process. The green detoxification and effective extraction of the Al element from SAD were simultaneously achieved without any pretreatments. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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14 pages, 4324 KiB

Open AccessArticle

Synthesise and Characterization of Cordierite and Wollastonite Glass—Ceramics Derived from Industrial Wastes and Natural Raw Materials

by Gamal A. Khater, Amany A. El-Kheshen and Mohammad M. Farag

Materials 2022, 15(10), 3534; https://doi.org/10.3390/ma15103534 - 14 May 2022

Cited by 7 | Viewed by 2220

Abstract

Industrial waste is one of the primary sources that harm the environment, and this topic has occupied many scientists on how to take advantage of these wastes or dispose of them and create a clean environment. By-pass cement dust is considered one of [...] Read more.

Industrial waste is one of the primary sources that harm the environment, and this topic has occupied many scientists on how to take advantage of these wastes or dispose of them and create a clean environment. By-pass cement dust is considered one of the most dangerous industrial wastes due to its fine granular size and its volatilization in the air, which causes severe environmental damage to human and animal health, and this is the reason for choosing the current research point. In this article, eight samples of glass–ceramics were prepared using by-pass cement dust and natural raw materials known as silica sand, magnesite, and kaolin. Then melted by using an electric furnace which was adjusted at a range of temperatures from 1550 to 1600 °C for 2 to 3 h; the samples were cast and were subjected to heat treatment at 1000 °C for 2 h based on the DTA results in order to produce crystalline materials. Various techniques were used to study the synthesized glass–ceramic samples, including differential thermal analysis (DTA), X-ray diffraction (XRD), scanning electron microscope (SEM), and thermal expansion coefficient (CTE). X-ray analysis showed that the phases formed through investigated glass–ceramic samples consisted mainly of β- wollastonite, parawollastonite, diopside, anorthite, and cordierite. It was noticed that β- the wollastonite phase was formed first and then turned into parawollastonite, and also, the anorthite mineral was formed at low temperatures before the formation of the diopside mineral. SEM showed that the formed microstructure turned from a coarse grain texture to a fine-grained texture, by increasing the percentage of cordierite. It also showed that the increase in time at the endothermic temperature significantly affected the crystalline texture by giving a fine-grained crystalline texture. The linear thermal expansion measurements technique used for the studied glass–ceramic samples gives thermal expansion coefficients ranging from 6.2161 × 10⁻⁶ to 2.6181 × 10⁻⁶ C⁻¹ (in the range of 20–700 °C), and it decreased by increasing cordierite percent. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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18 pages, 3415 KiB

Open AccessArticle

Aerobic Biostabilization of the Organic Fraction of Municipal Solid Waste—Monitoring Hot and Cold Spots in the Reactor as a Novel Tool for Process Optimization

by Sylwia Stegenta-Dąbrowska, Peter F. Randerson and Andrzej Białowiec

Materials 2022, 15(9), 3300; https://doi.org/10.3390/ma15093300 - 4 May 2022

Cited by 5 | Viewed by 1754

Abstract

The process of aerobic biostabilization (AB) has been adopted for treatment of the organic fraction of municipal solid waste (OFMSW). However, thermal gradients and some side effects in the bioreactors present difficulties in optimization of AB. Forced aeration is more effective than natural [...] Read more.

The process of aerobic biostabilization (AB) has been adopted for treatment of the organic fraction of municipal solid waste (OFMSW). However, thermal gradients and some side effects in the bioreactors present difficulties in optimization of AB. Forced aeration is more effective than natural ventilation of waste piles, but “hot and cold spots” exist due to inhomogeneous distribution of air and heat. This study identified the occurrence of hot and cold spots during the OFMSW biostabilization process at full technical scale. It was shown that the number of hot and cold spots depended on the size of the pile and aeration rate. When the mass of stabilized waste was significantly lower and the aeration rate was two-fold higher the number of anaerobic hot spots decreased, while cold spots increased. In addition, the results indicated that pile construction with sidewalls decreased the number of hot spots. However, channelizing the airflow under similar conditions increased the number of cold spots. Knowledge of the spatial and temporal distribution of process gases can enable optimization and adoption of the OFMSW flow aeration regime. Temperature monitoring within the waste pile enables the operator to eliminate undesirable “hot spots” by modifying the aeration regime and hence improve the overall treatment efficiency. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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14 pages, 4361 KiB

Open AccessArticle

Research on Dewatering Characteristics of Waste Slurry from Pipe Jacking Construction

by Libing Jiang, Liang Zhen, Jianfeng Wang, Tao Zhang and Xianwen Huang

Materials 2022, 15(6), 2242; https://doi.org/10.3390/ma15062242 - 18 Mar 2022

Cited by 9 | Viewed by 2135

Abstract

A large amount of waste slurry is produced during the construction of pipe jacking projects. To avoid the waste slurry occupying too much urban land, it needs to be rapidly reduced. Due to the complex composition of waste slurry, the existing dewatering methods [...] Read more.

A large amount of waste slurry is produced during the construction of pipe jacking projects. To avoid the waste slurry occupying too much urban land, it needs to be rapidly reduced. Due to the complex composition of waste slurry, the existing dewatering methods face the problem of low efficiency, and the soil after dewatering is difficult to recycle as soil materials due to high water content and low strength. There is currently a lack of research on dewatering and resource utilization of waste slurry from pipe jacking projects. In response to this problem, this paper studies the flocculation-settling characteristics of waste slurry and the mechanical properties of solidified sediment. It was found that the anionic polyacrylamide (APAM) 7126 obtained the best separation effect if the waste slurry contains bentonite, which increases the zeta potential, resulting in poor separation. Thus, FeCl₃·6H₂O and APAM 7126 can be used as compound conditioners. The sediment after settling was further added with 20–30% sulphate aluminum cement (SAC), and the unconfined compressive strength of the solidified sediment for 3 days could exceed 30 kPa. After flocculation-settling and solidification treatment, the waste pipe jacking slurry can be quickly dewatered into a soil material with a certain strength, which provides a reference for engineering applications. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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20 pages, 5523 KiB

Open AccessArticle

The Comparison of the Environmental Impact of Waste Mineral Wool and Mineral in Wool-Based Geopolymer

by Beata Łaźniewska-Piekarczyk, Monika Czop and Dominik Smyczek

Materials 2022, 15(6), 2050; https://doi.org/10.3390/ma15062050 - 10 Mar 2022

Cited by 5 | Viewed by 2628

Abstract

Waste generated in fine wool production is homogeneous and without contamination, which increases its chances of reuse. Waste mineral wool from demolition sites belongs to the specific group of waste. However, the storage and collection require implementing restrictive conditions, such as improper storage [...] Read more.

Waste generated in fine wool production is homogeneous and without contamination, which increases its chances of reuse. Waste mineral wool from demolition sites belongs to the specific group of waste. However, the storage and collection require implementing restrictive conditions, such as improper storage of mineral wool, which is highly hazardous for the environment. The study focuses on the leachability of selected pollutants (pH, Cl⁻, SO₄²⁻) and heavy metals (Ba, Co, Cr, Cu, Ni, Pb, Zn) from the waste mineral wool. As a solution to the problem of storing mineral wool waste, it was proposed to process it into wool-based geopolymer. The geopolymer, based on mineral wool, was also assessed regarding the leaching of selected impurities. Rock mineral wool is very good for geopolymerisation, but the glass wool needs to be completed with additional components rich in Al₂O₃. The research involved geopolymer prepared from mineral glass wool with bauxite and Al₂O₃. So far, glass wool with the mentioned additives has not been tested. An essential aspect of the article is checking the influence of wool-based geopolymer on the environment. To investigate the environmental effects of the wool-based monolith and crushed wool geopolymers were compared. Such research has not been conducted so far. For this purpose, water extracts from fragmented geopolymers were made, and tests were carried out following EN 12457-4. There is no information in the literature on the influence of geopolymer on the environment, which is an essential aspect of its possible use. The research results proved that the geopolymer made on the base of mineral wool meets the environmental requirements, except for the pH value. As mentioned in the article, the geopolymerisation process requires the dissolution of the starting material in a high pH (alkaline) solution. On the other hand, the pH minimum 11.2 value of fresh geopolymer binder is required to start geopolymerisation. Moreover, research results analysed in the literature showed that the optimum NaOH concentration is 8 M. for the highest compressive strength of geopolymer. Therefore, the geopolymer strength decreases with NaO concentration in the NaOH solution. Geopolymers glass wool-based mortars with Al₂O₃ obtained an average compressive strength of 59, the geopolymer with bauxite achieved about 51 MPa. Thus, Al₂O₃ is a better additional glass wool-based geopolymer than bauxite. The average compressive strength of rock wool-based geopolymer mortar was about 62 MPa. The average compressive strength of wool-based geopolymer binder was about 20–25 MPa. It was observed that samples of geopolymers grout without aggregate participation are characterised by cracking and deformation. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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11 pages, 3859 KiB

Open AccessArticle

Gravity and Electrostatic Separation for Recovering Metals from Obsolete Printed Circuit Board

by Camila Mori de Oliveira, Rossana Bellopede, Alice Tori, Giovanna Zanetti and Paola Marini

Materials 2022, 15(5), 1874; https://doi.org/10.3390/ma15051874 - 2 Mar 2022

Cited by 5 | Viewed by 2983

Abstract

This study proposed an evaluation of enrichment processes of obsolete Printed Circuit Boards (PCBs), by means of gravity and electrostatic separation, aiming at the recovery of metals. PCBs are the most important component in electronic devices, having high concentrations of metals and offering [...] Read more.

This study proposed an evaluation of enrichment processes of obsolete Printed Circuit Boards (PCBs), by means of gravity and electrostatic separation, aiming at the recovery of metals. PCBs are the most important component in electronic devices, having high concentrations of metals and offering a secondary source of raw materials. Its recycling promotes the reduction in the environmental impacts associated with its production, use, and disposal. The recovery method studied started with the dismantling of the PCB, followed by a comminution and granulometric classification. Subsequent magnetic, gravity, and electrostatic separations were performed. After the separations, a macroscopic visual evaluation and chemical analysis were carried out, determining the metal content in the concentrate products. The results obtained from gravity separation showed a product with metallic concentrations of 89% and 76% for particle sizes of 0.3–0.6 mm and 0.6–1.18 mm, respectively. In electrostatic separation, the product obtained was 88% for the lower particle size (<0.3 mm) and 62% for particles sizes >1.18 mm. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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22 pages, 10371 KiB

Open AccessArticle

Use of Arc Furnace Slag and Ceramic Sludge for the Production of Lightweight and Highly Porous Ceramic Materials

by Gamal A. Khater, Bassem S. Nabawy, Amany A. El-Kheshen, Manal Abdel-Baki Abdel Latif and Mohammad M. Farag

Materials 2022, 15(3), 1112; https://doi.org/10.3390/ma15031112 - 31 Jan 2022

Cited by 12 | Viewed by 2667

Abstract

The utility of recycling some intensive industries’ waste materials for producing cellular porous ceramic is the leading aim of this study. To achieve this purpose, ceramic samples were prepared utilizing both arc furnace slag (AFS) and ceramic sludge, without any addition of pure [...] Read more.

The utility of recycling some intensive industries’ waste materials for producing cellular porous ceramic is the leading aim of this study. To achieve this purpose, ceramic samples were prepared utilizing both arc furnace slag (AFS) and ceramic sludge, without any addition of pure chemicals, at 1100 °C. A series of nine samples was prepared via increasing AFS percentage over sludge percentage by 10 wt.% intervals, reaching 10 wt.% sludge and 90 wt.% AFS contents in the ninth and last batch. The oxide constituents of waste materials were analyzed using XRF. All synthesized samples were investigated using XRD to detect the precipitated minerals. The developed phases were β-wollastonite, quartz, gehlenite, parawollastonite and fayalite. The formed crystalline phases were changed depending on the CaO/SiO₂ ratio in the batch composition. Sample morphology was investigated via scanning electron microscope to identify the porosity of the prepared ceramics. Porosity, density and electrical properties were measured; it was found that all these properties were dependent on the composition of starting materials and formed phases. When increasing CaO and Al₂O₃ contents, porosity values increased, while increases in MgO and Fe₂O₃ caused a decrease in porosity and increases in dielectric constant and electric conductivity. Sintering of selected samples at different temperatures caused formation of two polymorphic structures of wollastonite, either β-wollastonite (unstable) or parawollastonite (stable). β-wollastonite transformed into parawollastonite at elevated temperatures. When increasing the sintering temperature to 1150 °C, a small amount of fayalite phase (Fe₂SiO₄) was formed. It was noticed that the dielectric measurements of the selected sintered samples at 1100 °C were lower than those recorded when sintering temperatures were 1050 °C or 1150 °C. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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17 pages, 1358 KiB

Open AccessArticle

The Influence of Low-Temperature Food Waste Biochars on Anaerobic Digestion of Food Waste

by Kacper Świechowski, Bartosz Matyjewicz, Paweł Telega and Andrzej Białowiec

Materials 2022, 15(3), 945; https://doi.org/10.3390/ma15030945 - 26 Jan 2022

Cited by 17 | Viewed by 3092

Abstract

The proof-of-the-concept of application of low-temperature food waste biochars for the anaerobic digestion (AD) of food waste (the same substrate) was tested. The concept assumes that residual heat from biogas utilization may be reused for biochar production. Four low-temperature biochars produced under two [...] Read more.

The proof-of-the-concept of application of low-temperature food waste biochars for the anaerobic digestion (AD) of food waste (the same substrate) was tested. The concept assumes that residual heat from biogas utilization may be reused for biochar production. Four low-temperature biochars produced under two pyrolytic temperatures 300 °C and 400 °C and under atmospheric and 15 bars pressure with 60 min retention time were used. Additionally, the biochar produced during hydrothermal carbonization (HTC) was tested. The work studied the effect of a low biochar dose (0.05 g_BC × g_TSsubstrate⁻¹, or 0.65 g_BC × L⁻¹) on AD batch reactors’ performance. The biochemical methane potential test took 21 days, and the process kinetics using the first-order model were determined. The results showed that biochars obtained under 400 °C with atmospheric pressure and under HTC conditions improve methane yield by 3.6%. It has been revealed that thermochemical pressure influences the electrical conductivity of biochars. The biomethane was produced with a rate (k) of 0.24 d⁻¹, and the most effective biochars increased the biodegradability of food waste (FW) to 81% compared to variants without biochars (75%). Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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18 pages, 2672 KiB

Open AccessArticle

Carbonized Solid Fuel Production from Polylactic Acid and Paper Waste Due to Torrefaction

by Kacper Świechowski, Christian Zafiu and Andrzej Białowiec

Materials 2021, 14(22), 7051; https://doi.org/10.3390/ma14227051 - 20 Nov 2021

Cited by 1 | Viewed by 2350

Abstract

The quantity of biodegradable plastics is increasing steadily and taking a larger share in the residual waste stream. As the calorific value of biodegradable plastic is almost two-fold lower than that of conventional ones, its increasing quantity decreases the overall calorific value of [...] Read more.

The quantity of biodegradable plastics is increasing steadily and taking a larger share in the residual waste stream. As the calorific value of biodegradable plastic is almost two-fold lower than that of conventional ones, its increasing quantity decreases the overall calorific value of municipal solid waste and refuse-derived fuel which is used as feedstock for cement and incineration plants. For that reason, in this work, the torrefaction of biodegradable waste, polylactic acid (PLA), and paper was performed for carbonized solid fuel (CSF) production. In this work, we determined the process yields, fuel properties, process kinetics, theoretical energy, and mass balance. We show that the calorific value of PLA cannot be improved by torrefaction, and that the process cannot be self-sufficient, while the calorific value of paper can be improved up to 10% by the same process. Moreover, the thermogravimetric analysis revealed that PLA decomposes in one stage at ~290–400 °C with a maximum peak at 367 °C, following a 0.42 reaction order with the activation energy of 160.05 kJ·(mol·K)⁻¹. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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15 pages, 9893 KiB

Open AccessArticle

Electronic Waste Low-Temperature Processing: An Alternative Thermochemical Pretreatment to Improve Component Separation

by Juliana S. S. Oliveira, Ronald R. Hacha, Felipe S. d’Almeida, Caroline A. Almeida, Francisco J. Moura, Eduardo A. Brocchi and Rodrigo F. M. Souza

Materials 2021, 14(20), 6228; https://doi.org/10.3390/ma14206228 - 19 Oct 2021

Cited by 3 | Viewed by 2711

Abstract

The production of electronic waste due to technological development, economic growth and increasing population has been rising fast, pushing for solutions before the environmental pressure achieves unprecedented levels. Recently, it was observed that many extractive metallurgy alternatives had been considered to recover value [...] Read more.

The production of electronic waste due to technological development, economic growth and increasing population has been rising fast, pushing for solutions before the environmental pressure achieves unprecedented levels. Recently, it was observed that many extractive metallurgy alternatives had been considered to recover value from this type of waste. Regarding pyrometallurgy, little is known about the low-temperature processing applied before fragmentation and subsequent component separation. Therefore, the present manuscript studies such alternative based on scanning electron microscopy characterization. The sample used in the study was supplied by a local recycling center in Rio de Janeiro, Brazil. The mass loss was constant at around 30% for temperatures higher than 300 °C. Based on this fact, the waste material was then submitted to low-temperature processing at 350 °C followed by attrition disassembling, size classification, and magnetic concentration steps. In the end, this first report of the project shows that 15% of the sample was recovered with metallic components with high economic value, such as Cu, Ni, and Au, indicating that such methods could be an interesting alternative to be explored in the future for the development of alternative electronic waste extraction routes. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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13 pages, 4075 KiB

Open AccessArticle

Dismantling of Waste Printed Circuit Boards with the Simultaneous Recovery of Copper: Experimental Study and Process Modeling

by Szabolcs Fogarasi, Árpád Imre-Lucaci and Florica Imre-Lucaci

Materials 2021, 14(18), 5186; https://doi.org/10.3390/ma14185186 - 9 Sep 2021

Cited by 3 | Viewed by 1900

Abstract

The study was carried out with the aim to demonstrate the applicability of a combined chemical–electrochemical process for the dismantling of waste printed circuit boards (WPCBs) created from different types of electronic equipment. The concept implies a simple and less polluting process that [...] Read more.

The study was carried out with the aim to demonstrate the applicability of a combined chemical–electrochemical process for the dismantling of waste printed circuit boards (WPCBs) created from different types of electronic equipment. The concept implies a simple and less polluting process that allows the chemical dismantling of WPCBs with the simultaneous recovery of copper from the leaching solution and the regeneration of the leaching agent. In order to assess the performance of the dismantling process, various tests were performed on different types of WPCBs using the 0.3 M FeCl₃ in 0.5 M HCl leaching system. The experimental results show that, through the leaching process, the electronic components (EC) together with other fractions can be efficiently dismounted from the surface of WPCBs, with the parallel electrowinning of copper from the copper rich leaching solution. In addition, the process was scaled up for the dismantling of 100 kg/h WPCBs and modeled and simulated using process flow modelling software ChemCAD in order to assess the impact of all steps and equipment on the technical and environmental performance of the overall process. According to the results, the dismantling of 1 kg of WPCBs requires a total energy of 0.48 kWh, and the process can be performed with an overall low environmental impact based on the obtained general environmental indexes (GEIs) values. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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13 pages, 2071 KiB

Open AccessArticle

Technological Characterization of PET—Polyethylene Terephthalate—Added Soil-Cement Bricks

by Tulane Rodrigues da Silva, Daiane Cecchin, Afonso Rangel Garcez de Azevedo, Izabella Valadão, Jonas Alexandre, Flavio Castro da Silva, Markssuel Teixeira Marvila, Murali Gunasekaran, Fabio Garcia Filho and Sergio Neves Monteiro

Materials 2021, 14(17), 5035; https://doi.org/10.3390/ma14175035 - 3 Sep 2021

Cited by 14 | Viewed by 3617

Abstract

The ever-growing consumption and improper disposal of non-biodegradable plastic wastes is bringing worrisome perspectives on the lack of suitable environmentally correct solutions. Consequently, an increasing interest in the circular economy and sustainable techniques is being raised regarding the management of these wastes. The [...] Read more.

The ever-growing consumption and improper disposal of non-biodegradable plastic wastes is bringing worrisome perspectives on the lack of suitable environmentally correct solutions. Consequently, an increasing interest in the circular economy and sustainable techniques is being raised regarding the management of these wastes. The present work proposes an eco-friendly solution for the huge amount of discarded polyethylene terephthalate (PET) wastes by addition into soil-cement bricks. Room temperature molded 300 × 150 × 70 mm bricks were fabricated with mixtures of clay soil and ordinary Portland cement added with up to 30 wt.% of PET waste particles. Granulometric analysis of soil indicated it as sandy and adequate for brick fabrication. As for the PET particles, they can be considered non-plastic and sandy. The Atterberg consistency limits indicated that addition of 20 wt.% PET waste gives the highest plasticity limit of 17.3%; moreover, with PET waste addition there was an increase in the optimum moisture content for the compaction and decrease in specific weight. Standard tests showed an increase in compressive strength from 0.83 MPa for the plain soil-cement to 1.80 MPa for the 20 wt.% PET-added bricks. As for water absorption, all bricks displayed values between 15% and 16% that attended the standards and might be considered an alternative for non-structural applications, such as wall closures in building construction. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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15 pages, 4216 KiB

Open AccessArticle

Phosphate Cements Based on Calcined Dolomite: Influence of Calcination Temperature and Silica Addition

by Cristina Andreea Vijan, Alina Badanoiu, Georgeta Voicu and Adrian Ionut Nicoara

Materials 2021, 14(14), 3838; https://doi.org/10.3390/ma14143838 - 9 Jul 2021

Cited by 7 | Viewed by 2819

Abstract

The aim of this study is to assess the possibility of obtaining phosphate cements based on dolomite calcined at various temperatures with/without quartz sand addition. A lower calcination temperature of dolomite (1200 °C) determines a high increase in the system temperature when calcined [...] Read more.

The aim of this study is to assess the possibility of obtaining phosphate cements based on dolomite calcined at various temperatures with/without quartz sand addition. A lower calcination temperature of dolomite (1200 °C) determines a high increase in the system temperature when calcined dolomite is mixed with KH₂PO₄ (MKP) solution and also a rapid expansion of the paste. The increase in calcination temperature up to 1400 °C reduces the oxides reactivity; however, for lower dosages of MKP, the expansion phenomenon is still recorded. The increase in MKP dosage increases the compressive strength due to the formation of K-struvite. The mixing of dolomite with sand, followed by thermal treatment at 1200 °C, modifies its composition and reactivity; the compressive strength of phosphate cements obtained by mixing this solid precursor with MKP increases up to 28 days of curing. We assessed the nature of hydrates formed in the phosphate systems studied by X-ray diffraction in order to explain the hardening processes and the mechanical properties of these systems. The microstructure and elemental composition of hardened cement pastes were assessed by scanning electronic microscopy with energy-dispersive spectroscopy. The phosphate cements based on calcined magnesite or dolomite were used to immobilize an industrial hazardous waste with high chromium content. The partial substitution of calcined magnesite/dolomite with this waste determines an important decrease in compressive strengths. Nevertheless, the leaching tests confirm an adequate immobilization of chromium in some of the matrices studied (for a waste dosage corresponding to 0.5 wt % Cr). Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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12 pages, 2137 KiB

Open AccessArticle

Chemical–Electrochemical Process Concept for Lead Recovery from Waste Cathode Ray Tube Glass

by Árpád Imre-Lucaci, Melinda Fogarasi, Florica Imre-Lucaci and Szabolcs Fogarasi

Materials 2021, 14(6), 1546; https://doi.org/10.3390/ma14061546 - 22 Mar 2021

Cited by 9 | Viewed by 2060

Abstract

This paper presents a novel approach for the recovery of lead from waste cathode-ray tube (CRT) glass by applying a combined chemical-electrochemical process which allows the simultaneous recovery of Pb from waste CRT glass and electrochemical regeneration of the leaching agent. The optimal [...] Read more.

This paper presents a novel approach for the recovery of lead from waste cathode-ray tube (CRT) glass by applying a combined chemical-electrochemical process which allows the simultaneous recovery of Pb from waste CRT glass and electrochemical regeneration of the leaching agent. The optimal operating conditions were identified based on the influence of leaching agent concentration, recirculation flow rate and current density on the main technical performance indicators. The experimental results demonstrate that the process is the most efficient at 0.6 M acetic acid concentration, flow rate of 45 mL/min and current density of 4 mA/cm². The mass balance data corresponding to the recycling of 10 kg/h waste CRT glass in the identified optimal operating conditions was used for the environmental assessment of the process. The General Effect Indices (GEIs), obtained through the Biwer Heinzle method for the input and output streams of the process, indicate that the developed recovery process not only achieve a complete recovery of lead but it is eco-friendly as well. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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Review

Jump to: Research

17 pages, 492 KiB

Open AccessReview

Applications and Properties of Hemp Stalk-Based Insulating Biomaterials for Buildings: Review

by Borja Martínez, Ernest Bernat-Maso and Lluis Gil

Materials 2023, 16(8), 3245; https://doi.org/10.3390/ma16083245 - 20 Apr 2023

Cited by 15 | Viewed by 2746

Abstract

There has been increasing interest in green and recyclable materials to promote the circular economy. Moreover, the climate change of the last decades has led to an increase in the range of temperatures and energy consumption, which entails more energy expenditure for heating [...] Read more.

There has been increasing interest in green and recyclable materials to promote the circular economy. Moreover, the climate change of the last decades has led to an increase in the range of temperatures and energy consumption, which entails more energy expenditure for heating and cooling buildings. In this review, the properties of hemp stalk as an insulating material are analyzed to obtain recyclable materials with green solutions to reduce energy consumption and reduce noise to increase the comfort of buildings. Hemp stalks are a low-value by-product of hemp crops; however, they are a lightweight material with a high insulating property. This study aims to summarize the research progress in materials based on hemp stalks and to study the properties and characteristics of the different vegetable binders that could be used to produce a bio-insulating material. The material itself and its microstructural and physical aspects that affect the insulating properties are discussed, as is their influence on durability, moisture resistance, and fungi growth. Research suggests using lignin-based or recyclable cardboard fiber to develop a bio-composite material from hemp stalk, but long-term stability requires further investigation. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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23 pages, 1441 KiB

Open AccessReview

Sustainable Use of Apple Pomace (AP) in Different Industrial Sectors

by Ewelina Gołębiewska, Monika Kalinowska and Güray Yildiz

Materials 2022, 15(5), 1788; https://doi.org/10.3390/ma15051788 - 27 Feb 2022

Cited by 56 | Viewed by 9132

Abstract

In many countries, apple pomace (AP) is one of the most produced types of agri-food waste (globally, it is produced at a rate of ~4 million tons/year). If not managed properly, such bio-organic waste can cause serious pollution of the natural environment and [...] Read more.

In many countries, apple pomace (AP) is one of the most produced types of agri-food waste (globally, it is produced at a rate of ~4 million tons/year). If not managed properly, such bio-organic waste can cause serious pollution of the natural environment and public health hazards, mainly due to the risk of microbial contamination. This review shows that AP can be successfully reused in different industrial sectors—for example, as a source of energy and bio-materials—according to the idea of sustainable development. The recovered active compounds from AP can be applied as preservatives, antioxidants, anti-corrosion agents, wood protectors or biopolymers. Raw or processed forms of AP can also be considered as feedstocks for various bioenergy applications such as the production of intermediate bioenergy carriers (e.g., biogas and pyrolysis oil), and materials (e.g., biochar and activated carbon). In the future, AP and its active ingredients can be of great use due to their non-toxicity, biodegradability and biocompatibility. Given the increasing mass of produced AP, the commercial applications of AP could have a huge economic impact in the future. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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36 pages, 2449 KiB

Open AccessReview

Materials for Production of High and Ultra-High Performance Concrete: Review and Perspective of Possible Novel Materials

by Markssuel Teixeira Marvila, Afonso Rangel Garcez de Azevedo, Paulo R. de Matos, Sergio Neves Monteiro and Carlos Maurício Fontes Vieira

Materials 2021, 14(15), 4304; https://doi.org/10.3390/ma14154304 - 31 Jul 2021

Cited by 100 | Viewed by 6775

Abstract

This review article proposes the identification and basic concepts of materials that might be used for the production of high-performance concrete (HPC) and ultra-high-performance concrete (UHPC). Although other reviews have addressed this topic, the present work differs by presenting relevant aspects on possible [...] Read more.

This review article proposes the identification and basic concepts of materials that might be used for the production of high-performance concrete (HPC) and ultra-high-performance concrete (UHPC). Although other reviews have addressed this topic, the present work differs by presenting relevant aspects on possible materials applied in the production of HPC and UHPC. The main innovation of this review article is to identify the perspectives for new materials that can be considered in the production of novel special concretes. After consulting different bibliographic databases, some information related to ordinary Portland cement (OPC), mineral additions, aggregates, and chemical additives used for the production of HPC and UHPC were highlighted. Relevant information on the application of synthetic and natural fibers is also highlighted in association with a cement matrix of HPC and UHPC, forming composites with properties superior to conventional concrete used in civil construction. The article also presents some relevant characteristics for the application of HPC and UHPC produced with alkali-activated cement, an alternative binder to OPC produced through the reaction between two essential components: precursors and activators. Some information about the main types of precursors, subdivided into materials rich in aluminosilicates and rich in calcium, were also highlighted. Finally, suggestions for future work related to the application of HPC and UHPC are highlighted, guiding future research on this topic. Full article

(This article belongs to the Special Issue Recovery and Treatment of Solid Waste)

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