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Development, Validation, and Application of Methods for the Multi-Element Analysis of Samples with Different Matrices Using Spectrometric Techniques

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Analytical Chemistry".

Deadline for manuscript submissions: closed (28 February 2023) | Viewed by 5833

Special Issue Editors


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Guest Editor
Division of Analytical Chemistry and Chemical Metallurgy, Faculty of Chemistry, Wroclaw University of Science and Technology, Wroclaw, Poland
Interests: trace element analysis using spectrometric methods (ICP OES, ICP MS, FAAS, and ETAAS); speciation and fractionation analysis of metals and metalloids using chromatographic separation; application of chemical vapor generation (CVG) techniques for analytical atomic and mass spectrometry; analytical and spectroscopic characteristics of cold atmospheric pressure plasmas (CAPPs); application of CAPPs in biology, medicine, and technology
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Division of Analytical Chemistry and Chemical Metallurgy, Faculty of Chemistry, Wroclaw University of Science and Technology, 50-370 Wroclaw, Poland
Interests: multi-element analysis of samples with different matrices using spectrometric methods of detection; development and validation of new sample preparation procedures before spectrometric measurements; speciation, fractionation, and trace analysis of elements in food and environmental samples; bioavailability and bioaccessibility of elements
Special Issues, Collections and Topics in MDPI journals
Division of Analytical Chemistry and Chemical Metallurgy, Faculty of Chemistry, Wroclaw University of Science and Technology, 50370 Wroclaw, Poland
Interests: hydride generation (HG) technique; determination of hydride- and non-hydride-forming elements using spectrometric methods; elemental and speciation analysis; non-chromatographic speciation and fractionation of As via HG; samples and their preparation before analysis
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Elemental characterization of various matrices, such as food, industrial, environmental, or biological samples, using spectrometric techniques, such as ICP OES, ICP MS, FAAS, and ETAAS, arouses a constant research interest, particularly because of the possibility to evaluate the quality and safety of these materials and their suitability for direct applications. Multi-element analysis of samples, especially those of a complex composition, is not an easy task, and causes a permanent necessity to develop and use valid methods that guaranty reliable and dependable results. One of the most important and demanding steps in the analytical process is sample preparation before measurements, depending on the composition of the sample matrix, the type and concentration of analytes, and the detection technique used for the quantification of these analytes. In a traditional approach, samples are decomposed by wet acidic digestion procedures in the presence of concentrated oxidizing acids; however, followed the idea of simplifying the analytical proceeding, alternative methodologies at the stage of sample preparation that fit in with the principles of “green chemistry” are also currently being developed. In view of this, this Special Issue is addressed to all analytical chemists dealing with the determination of major, minor, and trace elements is various samples using spectrometric techniques, with special attention to the development and validation of new methods of element analysis. Scientific areas to be covered by this Special Issue may include (but are not limited to) the following topics:

i) multi-element analysis of samples with different matrices, including food, environmental, industrial, or biological materials;
ii) speciation and/or fractionation of elements;
iii) sample preparation procedures before spectrometric measurements;
iv) method validation, verification, and application.

Prof. Dr. Pawel Pohl
Dr. Anna Szymczycha-Madeja
Dr. Maja Welna
Guest Editors

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Keywords

  • samples
  • sample preparation
  • multi-element analysis
  • spectrometric techniques
  • analytical characteristic
  • validation
  • application

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Published Papers (2 papers)

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Research

24 pages, 2646 KiB  
Article
Application of Inductively Coupled Plasma Spectrometric Techniques and Multivariate Statistical Analysis in the Hydrogeochemical Profiling of Caves—Case Study Cloșani, Romania
by Anamaria Iulia Torok, Erika Andrea Levei, Silviu Constantin, Oana Teodora Moldovan, Marin Senila, Oana Cadar, Dorina Casoni, Simion Bogdan Angyus, Claudiu Tanaselia, Eniko Covaci and Tiberiu Frentiu
Molecules 2021, 26(22), 6788; https://doi.org/10.3390/molecules26226788 - 10 Nov 2021
Cited by 5 | Viewed by 2310
Abstract
The aim of the study was to develop the hydrogeochemical profiling of caves based on the elemental composition of water and silty soil samples and a multivariate statistical analysis. Major and trace elements, including rare earths, were determined in the water and soil [...] Read more.
The aim of the study was to develop the hydrogeochemical profiling of caves based on the elemental composition of water and silty soil samples and a multivariate statistical analysis. Major and trace elements, including rare earths, were determined in the water and soil samples. The general characteristics of water, anions content, inorganic and organic carbon fractions and nitrogen species (NO3 and NH4+) were also considered. The ANOVA—principal component analysis (PCA) and two-way joining analysis were applied on samples collected from Cloșani Cave, Romania. The ANOVA-PCA revealed that the hydrogeochemical characteristics of Ca2+-HCO3 water facies were described by five factors, the strongest being associated with water-carbonate rock interactions and the occurrence of Ca, Mg and HCO3 (43.4%). Although organic carbon fractions have a lower influence (20.1%) than inorganic ones on water characteristics, they are involved in the chemical processes of nitrogen and of the elements involved in redox processes (Fe, Mn, Cr and Sn). The seasonal variability of water characteristics, especially during the spring, was observed. The variability of silty soil samples was described by four principal components, the strongest influence being attributed to rare earth elements (52.2%). The ANOVA-PCA provided deeper information compared to Gibbs and Piper diagrams and the correlation analysis. Full article
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15 pages, 280 KiB  
Article
Development and Validation of an Analytical Method for Determination of Al, Ca, Cd, Fe, Mg and P in Calcium-Rich Materials by ICP OES
by Anna Szymczycha-Madeja, Maja Welna, Monika Zabłocka-Malicka, Pawel Pohl and Włodzimierz Szczepaniak
Molecules 2021, 26(20), 6269; https://doi.org/10.3390/molecules26206269 - 16 Oct 2021
Cited by 2 | Viewed by 2846
Abstract
Four procedures based on closed-vessel microwave-assisted wet digestion with different oxidative reagents, including HNO3 (P1), HNO3 + H2O2 (P2), aqua regia (P3) and Lefort aqua regia (P4), for preparation of calcium (Ca)-rich materials prior to determination of total [...] Read more.
Four procedures based on closed-vessel microwave-assisted wet digestion with different oxidative reagents, including HNO3 (P1), HNO3 + H2O2 (P2), aqua regia (P3) and Lefort aqua regia (P4), for preparation of calcium (Ca)-rich materials prior to determination of total concentrations of Al, Ca, Cd, Fe, Mg and P by inductively coupled optical emission spectrometry (ICP OES) were compared. It was found that digestion with Lefort aqua regia (P4) provided the best results for all examined elements, i.e., precision of 0.30–4.4%, trueness better than 2%, recoveries of added elements between 99.5–101.9%, and limits of detection within 0.08–1.8 ng g−1. Reliability of this procedure was verified by analysis of relevant certified reference materials (CRMs), i.e., Natural Moroccan Phosphate Rock—Phosphorite (BCR-O32). Additionally, selection of appropriate analytical lines for measurements of element concentrations, linear dynamic ranges of calibration curves and matrix effects on the analyte response were extensively investigated. Finally, the selected procedure was successfully applied for routine analysis of other Ca-rich materials, i.e., CRMs such as NIST 1400 (Bone Ash), CTA-AC-1 (Apatite Concentrate Kola Peninsula) and NCS DC70308 (Carbonate Rock), and six natural samples, such as a dolomite, a phosphate rock, an enriched superphosphate fertilizer, pork bones, pork bones after incineration, and after steam gasification. Full article
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