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State-of-the-Art Polymer Science and Technology in Canada

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Innovation of Polymer Science and Technology".

Deadline for manuscript submissions: closed (15 November 2024) | Viewed by 6845

Special Issue Editors


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Guest Editor
Department of Chemical Engineering, Université Laval, 1065 Avenue de la Médecine, Quebec, QC G1V 0A6, Canada
Interests: characterization; modeling; optimization; polymers; processing; recycling; rheology

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Guest Editor
Department of Chemical Engineering Ecole Polytechnique Montreal, Quebec, QC, Canada
Interests: rheology; gels; synthetic and natural polymers; composites and nanocomposites; fabrication of porous membranes by electrospinning

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Guest Editor
Department of Chemical Engineering, Queen's University, 19 Division Street, Kingston, ON K7L 3N6, Canada
Interests: graphene foams polypropylene composites

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Guest Editor
Department of Mechanical Engineering, École de Technologie Supérieure, Montréal, QC H3C 1K3, Canada
Interests: polymer blends; polymer nanocomposites; rheology; electrospinning; blowspinning process; functional polymer systems
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Special Issue Information

Dear Colleagues,

Research and development activities related to plastics have seen unprecedented growth throughout the world over the last century. The entire spectrum of activities includes the production (polymerization), processing (additive manufacturing, blowing, casting, electrospinning, extrusion, injection molding, rotomolding, etc.) and characterization (chemical, electrical, mechanical, morphological, physical, rheological, thermal, etc.) of different resins and structures. However, research and development, in both experimental and theoretical areas, must be combined to achieve successful large-scale (industrial) production and reach commercial success. Furthermore, in recent years the widespread environmental concerns related to plastics production and disposal have shifted public policy and consumer attitudes, which resulted in a shift in activities towards more sustainable products and technologies. 

The research and development landscape is especially strong in Canada which always had, and continues to develop, a strong industrial component in the general field of polymers including biobased macromolecules (extraction and modification), complex structures (blends, composites, foams, multi-layers, hybrid systems), characterization and modeling (equipment, methods, software, tools,) and recycling (thermoplastics, thermosets, elastomers, etc.). 

Based on 2021 statistics, the Canadian plastics sectors includes over 1750 establishments directly involved in the production of different plastics products, while over 750 companies are indirectly involved [1]. Globally, the industry generates USD 2.1 Bn in net revenues with USD 26 Bn in total shipments. So, this industry is highly important for the country. 

A long tradition of important results has its origin from investigations carried out in Canada alone or in collaboration with other countries. One example is the famous Bagley correction for the analysis of rheological data obtained from capillary rheometry [2]. This method is still used today and represents an important contribution from the industrial sector since all the work was done inside a company (ICI Chemicals). Another example is the studies performed by the group of Prof. Musa Kamal on polymer crystallization kinetics and injection molding leading to the predictions of morphological structures and transition temperatures [3]. These pioneering works are still the basis for new development all around the world and several more important results can be found in the scientific literature. 

On the industrial side, two important companies were originally involved in the polymer business in Canada. The Polymer Corporation Ltd. was founded in 1942 to help in the war effort by producing synthetic rubber-based materials [4,5]. This institution led to major developments in organic and polymer chemistry leading to the Polysar corporation [6]. The other main area was associated with the Xerox research center working on different types of polymerization reactions [7]. These results led to several opportunities in industrial chemistry, especially radical polymerization. A more specific overview on the history of the Canadian plastics industrial sector can be found in the book of R. Zarboni (Canadian Plastics Pioneers 1950-2000) [8]. Today, Nova Chemicals is at the forefront of technological development in the production of polymer resins (mainly polyolefins) [9].

In this Special Issue, we gathered innovative current developments from the most prominent investigators working in Canada. The subjects are very wide and include most of the aspects of polymers/plastics in today’s applications.

We hope that you will enjoy reading this Special Issue that we have put together. 

Prof. Dr. Denis Rodrigue
Prof. Dr. Marie-Claude Heuzey
Prof. Dr. Marianna Kontopoulou
Prof. Dr. Nicole Demarquette
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • plastics polymerization
  • polymer processing
  • polymer characterization
  • polymer resins and structures
  • modeling
  • recycling

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Published Papers (4 papers)

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Research

15 pages, 2189 KiB  
Article
Bulk Free Radical Terpolymerization of Butyl Acrylate, 2-Methylene-1,3-Dioxepane and Vinyl Acetate: Terpolymer Reactivity Ratio Estimation
by Maryam Movafagh, Kelly M. Meek, Alison J. Scott, Alexander Penlidis and Marc A. Dubé
Polymers 2024, 16(10), 1330; https://doi.org/10.3390/polym16101330 - 9 May 2024
Viewed by 1209
Abstract
This investigation introduces the first estimation of ternary reactivity ratios for a butyl acrylate (BA), 2-methylene-1,3-dioxepane (MDO), and vinyl acetate (VAc) system at 50 °C, with an aim to develop biodegradable pressure-sensitive adhesives (PSAs). In this study, we applied the error-in-variables model (EVM) [...] Read more.
This investigation introduces the first estimation of ternary reactivity ratios for a butyl acrylate (BA), 2-methylene-1,3-dioxepane (MDO), and vinyl acetate (VAc) system at 50 °C, with an aim to develop biodegradable pressure-sensitive adhesives (PSAs). In this study, we applied the error-in-variables model (EVM) to estimate reactivity ratios. The ternary reactivity ratios were found to be r12 = 0.417, r21 = 0.071, r13 = 4.459, r31 = 0.198, r23 = 0.260, and r32 = 55.339 (BA/MDO/VAc 1/2/3), contrasting with their binary counterparts, which are significantly different, indicating the critical need for ternary system analysis to accurately model multicomponent polymerization systems. Through the application of a recast Alfrey–Goldfinger model, this investigation predicts the terpolymer’s instantaneous and cumulative compositions at various conversion levels, based on the ternary reactivity ratios. These predictions not only provide crucial insights into the incorporation of MDO across different initial feed compositions but also offer estimates of the final terpolymer compositions and distributions, underscoring their potential in designing compostable or degradable polymers. Full article
(This article belongs to the Special Issue State-of-the-Art Polymer Science and Technology in Canada)
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12 pages, 989 KiB  
Article
Photopolymerization of Limonene Dioxide and Vegetable Oils as Biobased 3D-Printing Stereolithographic Formulation
by Mégane Clerget, Eric Gagnon and Jerome P. Claverie
Polymers 2024, 16(7), 965; https://doi.org/10.3390/polym16070965 - 2 Apr 2024
Viewed by 1174
Abstract
Epoxidized vegetable oils and limonene dioxide, a bis-epoxide derived from the terpene limonene, are photo-copolymerized to yield highly crosslinked networks with high conversion of all epoxide groups at ambient temperature. However, the slow polymerization of such biobased formulation polymerizes is not compatible for [...] Read more.
Epoxidized vegetable oils and limonene dioxide, a bis-epoxide derived from the terpene limonene, are photo-copolymerized to yield highly crosslinked networks with high conversion of all epoxide groups at ambient temperature. However, the slow polymerization of such biobased formulation polymerizes is not compatible for a use in a commercial SLA 3D printer. Adding an acrylated epoxidized vegetable oil to the bis-epoxide leads to a decrease of curing time and an increase in LDO conversion to polymer. For example, in a 60:40 wt:wt mixture of LDO and epoxidized soybean oil, the conversions of both exocyclic and endocyclic epoxide groups of LDO are ≥95%. These formulations were successfully used in SLA 3D printers, leading to generation of hard and dry complex objects using biobased formulations. Full article
(This article belongs to the Special Issue State-of-the-Art Polymer Science and Technology in Canada)
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21 pages, 19103 KiB  
Article
From Waste to Value Added Products: Manufacturing High Electromagnetic Interference Shielding Composite from End-of-Life Vehicle (ELV) Waste
by Roxana Moaref, Shaghayegh Shajari and Uttandaraman Sundararaj
Polymers 2024, 16(1), 120; https://doi.org/10.3390/polym16010120 - 29 Dec 2023
Cited by 2 | Viewed by 1371
Abstract
The use of plastics in automobiles is increasing dramatically due to their advantages of low weight and cost-effectiveness. Various products can be manufactured by recycling end-of-life vehicle (ELV) plastic waste, enhancing sustainability within this sector. This study presents the development of an electromagnetic [...] Read more.
The use of plastics in automobiles is increasing dramatically due to their advantages of low weight and cost-effectiveness. Various products can be manufactured by recycling end-of-life vehicle (ELV) plastic waste, enhancing sustainability within this sector. This study presents the development of an electromagnetic interference (EMI) shield that can be used for protecting electronic devices in vehicles by recycling waste bumpers of ethylene propylene diene monomer (EPDM) rubber from ELVs. EPDM waste was added to a unique combination of 40/60: PP/CaCO3 master batch and conductive nanofiller of carbon nanotubes using an internal melt mixing process. This nanocomposite was highly conductive, with an electrical conductivity of 5.2×101S·cm1 for 5 vol% CNT in a 30 wt% EPDM/70 wt% PP/CaCO3 master batch and showed a high EMI shielding effectiveness of 30.4 dB. An ultra-low percolation threshold was achieved for the nanocomposite at 0.25 vol% CNT. Waste material in the composite improved the yield strain by about 46% and strain at break by 54% in comparison with the same composition without waste. Low cost and light-weight fabricated composite from ELV waste shows high EMI SE for application in electronic vehicles and opens a new path to convert waste to wealth. Full article
(This article belongs to the Special Issue State-of-the-Art Polymer Science and Technology in Canada)
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19 pages, 4590 KiB  
Article
Optimization of the Electrospray Process to Produce Lignin Nanoparticles for PLA-Based Food Packaging
by Rodrigue Daassi, Kalvin Durand, Denis Rodrigue and Tatjana Stevanovic
Polymers 2023, 15(13), 2973; https://doi.org/10.3390/polym15132973 - 7 Jul 2023
Cited by 13 | Viewed by 2365
Abstract
The development of new processing methods is required in order to meet the continuous demand for thinner films with excellent barrier properties for food packaging and other applications. In this study, rice husk organosolv lignin nanoparticles were prepared using the electrospray method, which [...] Read more.
The development of new processing methods is required in order to meet the continuous demand for thinner films with excellent barrier properties for food packaging and other applications. In this study, rice husk organosolv lignin nanoparticles were prepared using the electrospray method, which were applied to produce polylactic acid (PLA)-based films for food packaging. The effect of the following electrospray parameters has been investigated: lignin concentration (LC) ranging from 5–50 mg/mL, flow rate (FR) from 0.5–1 mL/min, applied voltage from 10–30 kV, and tip-to-collector distance (TCD) from 10–25 cm, on the morphology, size, polydispersity index (PDI), and Zeta potential (ZP) of lignin nanoparticles (LNPs). The response surface methodology with a Box-Behnken design was applied to optimize these parameters, while dynamic light scattering (DLS) and scanning electron microscopy (SEM) analyses were used to characterize the controlled LNPs. The results showed that the LNPs shape and sizes represent a balance between the solvent evaporation, LC, applied voltage, TCD and FR. The application of optimal electrospray conditions resulted in the production of LNPs with a spherical shape and a minimal size of 260 ± 10 nm, a PDI of 0.257 ± 0.02, and a ZP of −35.2 ± 4.1 mV. The optimal conditions were achieved at LC = 49.1 mg/mL and FR = 0.5 mL/h under an applied voltage of 25.4 kV and TCD = 22 cm. Then, the optimized LNPs were used to improve the properties of PLA-based films. Three types of PLA-lignin blend films were casted, namely lignin/PLA, LNPs/PLA and PLA-grafted LNPs. PLA-grafted LNPs exhibited a more uniform dispersion in PLA for lignin contents of up to 10% than other composite samples. Increasing the lignin content from 5% to 10% in PLA-grafted LNPs resulted in a significant increase in elongation at break (up to four times higher than neat PLA). The presence of PLA-grafted lignin led to a substantial reduction in optical transmittance in the UV range, dropping from 58.7 ± 3.0% to 1.10 ± 0.01%, while maintaining excellent transparency to visible light compared to blends containing lignin or LNPs. Although the antioxidant capacity of unmodified lignin is well-known, a substantial increase in antioxidant capacity was observed in LNPs and PLA-grafted LNP films, with values exceeding 10 times and 12 times that of neat PLA, respectively. These results confirm the significant potential of using studied films in food packaging applications. Full article
(This article belongs to the Special Issue State-of-the-Art Polymer Science and Technology in Canada)
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