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Molecules, Volume 2, Issue 5 (May 1997) – 4 articles , Pages 80-86, Articles M11-M13

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82 KiB  
Short Note
4-Amino-1-methylbenzimidazole
by Milata Viktor, Dusan Ilavsky and Josef Salon
Molecules 1997, 2(5), M13; https://doi.org/10.3390/M13 - 26 May 1997
Cited by 2 | Viewed by 3118
Abstract
Heterocyclic amines [1] can be prepared from the corresponding nitro-group containing compounds by catalytic or chemical reduction [2] [...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
81 KiB  
Short Note
1-Benzimidazolyl-1-benztriazolylmethane
by Milata Viktor and Kada Rudolf
Molecules 1997, 2(5), M12; https://doi.org/10.3390/M12 - 26 May 1997
Cited by 1 | Viewed by 3066
Abstract
Symmetrically substituted bis(azolyl)methanes are often prepared from azoles in dichloromethane under PTC conditions [1] [...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
80 KiB  
Short Note
2,2,5-Trimethylhexa-3,4-dienal Azine
by Radek Marek
Molecules 1997, 2(5), M11; https://doi.org/10.3390/M11 - 20 May 1997
Cited by 7 | Viewed by 3287
Abstract
The homoallenylaldehyde 1 was prepared according to the literature [1,2].[...] Full article
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
36 KiB  
Article
The Intramolecular Radical Cation Induced Diels-Alder Reaction in the Diene - Diene Format
by David B. Rusterholz, David B. Gorman and Paul G. Gassman
Molecules 1997, 2(5), 80-86; https://doi.org/10.3390/20500080 - 15 May 1997
Cited by 3 | Viewed by 10024
Abstract
Two 1,3,8,10-undecatetraenes were synthesized to test the viability of the intramolecular radical cation induced Diels-Alder reaction in the diene - diene format. Cyclization was successful only for the substituted tetraene with the lower oxidation potential. The major hexahydroindene product possessed a trans ring [...] Read more.
Two 1,3,8,10-undecatetraenes were synthesized to test the viability of the intramolecular radical cation induced Diels-Alder reaction in the diene - diene format. Cyclization was successful only for the substituted tetraene with the lower oxidation potential. The major hexahydroindene product possessed a trans ring juncture demonstrating a selectivity for the endo stereochemistry. Full article
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Scheme 1

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