2. Thermodynamic Process Design
The turbine, which could be used in addition to the throttle valve for conditioning the steam can be characterized with two process parameters, namely its expansion ratio
and its efficiency
. Typical stage expansion ratios are up to
4–5 with acceptable efficiency [
10]. If the required expansion ratio is larger than
, more than one stage could be connected in series. The turbine efficiency has typical values in the range
. For the sake of simplicity, the following assumptions in the analysis are made: the isentropic efficiency is used to characterize the turbine, the expansion is considered adiabatic and the kinetic and potential energy changes of the steam are assumed to be negligible during the conversion from thermal to mechanical energy.
To assess the use of a turbine in a given steam conditioning application, a generalized expansion process can be used. This expansion process can be represented by an expansion line in a TS diagram, shown in
Figure 2 and is constructed as follows: from the initial conditions (state 1), the steam is expanded by isenthalpic throttling (h = cst) to the turbine inlet pressure
, (state
) in
Figure 2. Contrary to conventional approaches for turbine calculations, the temperatures and pressures are not all known
a priori, as they depend on the locus of state 3, which defines the turbine outlet conditions and the turbine efficiency
. The unknown turbine inlet pressure
can be determined from the given turbine outlet pressure
at state 3 and the efficiency of the turbine
. Based on the definition of the isentropic turbine efficiency [
11], Equation (
2), the turbine outlet state
for a reversible adiabatic expansion is calculated using Equation (
3). The calculations are included here for completeness.
In the next step, the corresponding entropy
is determined using an equation of state. If the turbine outlet state
after the adiabatic isentropic expansion is located in the wet steam area (
Figure 2), the entropy
, Equation (
4), can be computed by means of the steam quality x, Equation (
5).
Because
, the entropy at state
is known. Finally, the turbine inlet pressure can be calculated:
The analysis shown here is only valid if the turbine exit pressure is located on the saturated vapor line. However, if this is not the case, an analogous procedure can be established to determine the turbine inlet pressure
. The knowledge of the turbine inlet pressure
enables calculation of the total expansion ratio
. Thus the number of stages needed to match the total expansion ratio can be determined as the product of
N stages in series.
where
is the pressure ratio of the single stage
i.
The generalized expansion curve is obtained by varying the turbine inlet state
at fixed turbine outlet state
and given constant turbine efficiency
. In
Figure 2, these states are connected by a straight line, termed the expansion line. The slope
of the expansion line in a TS diagram is related to the turbine efficiency. At an isentropic expansion, the slope becomes
, i.e., a vertical line. This design method reveals an interesting feature, namely that the work output of the turbine is independent of the efficiency, because enthalpy difference remains constant considering state 3 is invariant.
Conversely, the expansion ratio between turbine inlet and outlet increases with decreasing turbine efficiency and vice versa. This allows prediction of the financial benefit from the application without knowing detailed turbine specifications at an early project phase.
Using the expansion line and the saturated vapor pressure line, three different scenarios of steam conditioning using a turbine can be distinguished, depending on the initial state of the steam leaving the steam generator.
In the first scenario, the initial state of the steam corresponds to a location within the two-phase region (I). The reduction of the initial temperature of the steam to the required process temperature can be achieved directly by an expansion at constant enthalpy using the Joule-Thomson effect. Further conditioning of the steam is not necessary and heat is not rejected to the environment. Moreover, the amount of heat that can be transferred in the process is increased by the expansion, since the entropy rises . In this case, the use of a turbine is inappropriate. This scenario is unlikely to occur in an industrial setting as steam is typically distributed at superheated conditions to avoid condensation and reduce heat losses in the distribution network.
In the second scenario (II), left side of
Figure 3, the initial state of the steam is situated between the saturated steam line and the expansion line. The desired turbine inlet condition can be reached by first expanding the steam by isenthalpic throttling to the expansion line
. Further expansion of the steam is then carried out by the turbine until it reaches the state on the saturated steam line
. In the TS-diagram, the expansion line is added to illustrate the concept for the process designer. The two process steps above can be interchanged, whereby the turbine has to operate at higher pressure and temperature. Expansion by the turbine is carried out into the two-phase region until that pressure is reached from which it can be further expanded at constant enthalpy down to the saturated state. It is assumed that the same turbine efficiency is used, i.e., that the expansion line is shifted parallel to the left. Expansion in a turbine can continue to the required condensation temperature; however, this penalizes the amount of available heat. Furthermore, such operation increases the risk of wear of the flow-guiding components of the turbine from erosion, which should be avoided. This emphasizes the importance of properly selecting the turbine outlet state
. The closer state (3) is to the saturated vapor pressure line, the more work (Equation (
8)) can be extracted from the process. However, to reduce the risk of expansion into the two-phase region, a superheating margin of the steam would be of advantage.
The third scenario (III) is characterized by an initial state of the steam that is located to the right of the expansion line, shown on the right side of
Figure 3. The required target state on the saturated vapor pressure line cannot be achieved solely by a turbine. Enabling the use of turbine in this scenario requires a certain amount of thermal energy to be released as heat. In a first step
, the temperature of the steam is lowered at constant pressure to the corresponding turbine outlet temperature while releasing heat. In the second step
, the steam is expanded to the final state by the turbine. As discussed in the previous case, the two process steps are interchangeable. Graphically, this is done by a parallel shifting of the expansion line in
Figure 3 to the right until the initial state of the steam is reached (state 1). After expansion in a turbine
, the turbine outlet temperature is obtained as the intersection point with the isobaric pressure corresponding to the condensation pressure. In the second step
, the superheated steam is cooled to the saturation temperature after entering the heat exchanger. If
is small, the process heat exchanger will transfer heat initially in the superheated steam region to reach saturation conditions and thus modification of the design would not be necessary.
3. Design Challenges for Small-Scale Turbines
Recently, small-scale turbomachinery supported on gas lubricated bearings have been tested successfully in a variety of applications such as heat pumps [
5], air conditioning systems, fuel cells [
12] and organic Rankine cycles [
8]. This work focuses on the use of small-scale turbines with gas-lubricated journal bearings, which operate with superheated steam close to the saturated vapor pressure and for which the working fluid directly serves as the bearing lubricant, thus offering a hermetic system. However, this introduces additional challenges, because of the risk of condensation in the journal bearings, as recently highlighted by Guenat and Schiffmann [
13].
Progress in research makes it possible to use gas-lubricated bearings in such turbomachines for applications in the power range of
kW], see [
14]. As the lubrication is provided by the working fluid, they are inherently oil-free, thus eliminating concerns of contamination of the working fluid by lubricants or vice versa. This feature is advantageous, since it prevents premature deterioration of both the working fluid and lubricant properties and simplifies the design of the turbomachine. Both factors significantly reduce the operational and investment costs.
Conversely, this means that the operating point of the turbomachine, thus thermodynamic state of the working medium in the turbine imposes design constraints upon the other parts of the machine. Special care must be taken in the design of the main components such as:
as shown in
Figure 4. A comprehensive discussion about the design of single components is given by Schiffmann et al. [
14].
In the steam conditioning process, the turbine operates close to the vapor saturation pressure; therefore, special care must be taken to avoid condensation in the bearings to avoid a reduction in load capacity and rotor dynamic stability [
13]. Due to the functional principle of a fluid dynamic bearing, an isothermal pressure increase occurs inside the bearing. Hence, the vapor temperature surrounding the bearings has be high enough that the maximum bearing pressure is lower than the saturation vapor pressure to prevent condensation. Furthermore, with a low pressure of the steam in the motor, the windage loss between rotor and stator is reduced [
14].
As a consequence, it is necessary to separate the turbine rotor backspace from the rest of the spindle, which can be done with a labyrinth seal. It acts mainly as a throttle and therefore limit leakage bypassing the turbine rotor. Details on the design of these seals with a special focus on small-scale turbomachines can be found in the work of Katuwal Chhetri [
15].
Therefore, the remaining leakage flow across the seal still has a higher temperature than the steam at the turbine exit. This steam temperature must not exceed the Curie temperature of the permanent magnet, else the magnetic properties are lost and the generator fails. For the stator of the generator including the end-winding, its insulation class determines the temperature limit. Class E is commonly used for cost reasons and has a limit temperature of K. In case a physical separation of the stator from the rotor and bearing can be applied, the stator can be cooled separately and high steam temperatures in the motor can be tolerated. However, any condensate that forms on the cold separation surface must be removed such that it cannot penetrate into the bearings. Purging of the motor housing with conditioned steam originating from the turbine inlet could be an option to address this.
The single-stage machine shown in
Figure 4 has an overhung radial turbine on one side and the generator on the other with the bearings located in between. Multi-stage turbines are also possible. As indicated in
Section 2, the working fluid is superheated steam and the process should be managed to avoid wet steam at the turbine exhaust to avoid droplet erosion. However, due to the proximity to the saturated steam line, droplet formation may occur locally.
4. Evaluation of Steam Conditioning Based on Test Cases
In addition to the thermodynamics of the process and the design aspects of using an oil-free, small-scale turbine for the steam conditioning, the commercial perspectives of such an application have to be considered as well. This requires realistic test cases from the industry and cost estimates for the necessary investment and operational costs, including benefits from generated electricity. From the 20 available cases (
Appendix A:
Table A1 and
Table A2), four are selected and summarised in
Table 1, representing typical examples for steam conditioning processes as they occur in industry [
1,
16].
The mass flow through the turbine is in a range of
kg/s]. This suggests selection of mixed-flow turbines offering a less expensive alternative to axial machines [
10], especially at small mass flowrates, where the axial machine tends to be fragile due to the necessarily large number of blades. For the mass flow range and pressure ratios, the turbine radius
is in a range of
mm] and the rotational shaft speed lies between
[51,000, ..., 400,000 rpm], (refer to
Table A3 in
Appendix A). For the given turbine radius, the application of gas bearings proposed in the previous section are particularly suitable and inexpensive for the high rotational speeds required. In addition, the nozzle ring can be omitted on radial machines, if the required expansion ratio is small. Generally, radial or mixed-flow turbines are more compact in axial direction. From a rotordynamic perspective, a mixed-flow turbine is preferable, because the rotor tends to be shorter than its axial counterpart, thus its Eigenfrequency involving lateral bending is higher, which is beneficial for gas bearing supported rotors [
9]. For cases 1–3 listed in
Table 1, the expansion ratio of the turbine necessary to expand from
for a turbine efficiency
is given. It is significantly smaller than the expansion ratio by throttling at constant enthalpy only
.
In the TS diagram shown in
Figure 5, the expansion using a turbine with different efficiencies
is shown for Case 1. The negative slope of the expansion line (see
Section 2) increases with increasing turbine efficiency
, whereas the turbine inlet pressure
and inlet temperature
decreases for reaching the same state (state 3) from
Table 2. Consequently, in most practical applications, a single-stage or two-stage turbine would be sufficient to cover the process requirements, which simplifies the overall design and therefore reduces the investment cost. Moreover, lower turbine inlet pressures simplify the design of the turbine casing and the labyrinth seal needed to maintain low pressures in the bearing and generator housing. The fourth case in
Table 1 represents scenario III, where the energy output is dependent on the turbine efficiency. However, inlet and outlet pressure of the turbine are very high, i.e., the opposite of cases 1–3 with the corresponding consequences concerning the casing and sealing.
The turboexpander system cost
depends on (i) the power of the machine, (ii) the pressure and temperature level at which the machine is operated and (iii) the turbine specification (mass flow, expansion ratio, efficiency, number of stages, etc.). However, the key parameter to estimate costs remains the power rating of the machine. Thus, a linear relationship is selected to estimate the system costs as a function of the generated power P, shown in Equation (
9), which represents the cost of the machine under conditions of large-scale manufacturing leveraging the economies of scale for production.
where
and
. The currency used for the analysis is the Swiss Franc (CHF), considered here due to the location of equipment manufacturers and related economic parameters.
The authors are aware of the fact that other methods are commonly used to estimate the scaling sensitivity. In the chemical industry for example, the change of investment costs caused by scaling effects are often described by a power function with the exponent of
, see Williams [
17] and Peters [
18]. However, the linear fit proposed here is obtained by assessing the prototyping costs for several similar machines tested by the research group of the authors [
19].
The presented cost estimate is used to determine the investment costs for the turbine in the case studies, shown in
Table 3, with the payback period (PbP) modeled related to the electricity price (EPE):
Rearranging Equation (
10) yields
with an average electricity cost in Switzerland of EPE = 0.2 CHF/kWh [
20] as a basis, a turbine output of
= 7.27 kW (Case 1 in
Table 1) results in economic break-even after ca. t = 3500 h. If the electrical energy is fed back into the public grid, the compensation is around
= 0.07 CHF/kWh, tripling the payback time,
= 10,000 h. If the system is operated continuously for 11 months per year (approx. 8000 h), the investment cost is returned after 4.4 months in case of internal consumption and after 1.25 years in the case of re-injection into the electricity grid. As the machines are maintenance-free, no additional operating costs are considered.
In
Figure 6, the PbP is shown as a function of the generated electrical power for 20 industrial cases. The pressure of the steam from the steam generator is the same for all cases (
MPa). The investigated cases differ in the final pressure (state 3) to be achieved, which is in the range of
MPa with steam mass flowrate in the range of
kg/s. To investigate the effect of the initial enthalpy on the generated power and the PbP, the analysis is performed for two initial temperatures T1 = [535, 550] K.
The graph shows the PbP required for a machine working 8000 working hours per year as a function of the generated power. For low electrical power the PbP is high. With increasing power, it approaches a constant value asymptotically. This means that the power-dependent term (Equation (
11)) dominates. With increasing power generation, the function approaches a constant value given by the first term in Equation (
11). The difference of
K causes a doubling of the generated power and consequently a significant reduction of the PbP. Considering an uncertainty of 50% in the cost estimate, the PbP of these single stage turbines with an electrical output power <200 kW is less than two years, therefore offering an interesting perspective from an industrial point of view.
5. Multi-Stage Expansion with Intermediate Super-Heating
As shown in
Section 2, due to the turbine efficiency, which has a typical range of
, it is often impossible to use the entire available pressure difference in a single expansion process. However, by intermediate re-heating, several expansion processes can be carried out in succession and thus the entire pressure difference can be exploited to generate electrical energy. Using Case 1 from the previous section, the potential from multiple expansion stages is examined and shown in
Figure 7.
The expansion and intermediate re-heating take place between the saturated steam line
and the enthalpy of the superheated steam from the steam generator
. The total number of expansion processes N has to be determined iteratively, with the turbine efficiency
as parameter,
. This results in four expansions
and three intermediate heating steps
where
denotes the stages, as shown in the TS diagram in
Figure 7. The corresponding turbine efficiencies are
.
The total electrical power that can be obtained from the multi-stage expansion yields
The turbine mass flow
depends on the type of heat source
used for intermediate heating. If an external heat source can be used, the turbine mass flow is equal to the mass flow coming from the steam generator, yielding the upper limit for electricity generation. Another option is to split the steam from the steam generator into two separate flows
, one to generate electrical energy and the other as heat source for the reheat processes. The resulting mass flow ratio can be calculated from the energy balance between the generated electrical power and the heat supplied as follows:
This ratio depends on whether (i) either only the sensible heat of the partial mass flow
is used, or (ii) both latent and sensible heat of the steam. Since the latent heat is significantly higher than the sensible heat in the analysed case, it follows that the turbine mass flow and thus the electrical power generated is also higher, as suggested by the comparison summarized in
Table 4.
However, the electrical power is only 18% lower than the maximum value achievable with an external heat source used for intermediate superheating. When only sensible heat is used, the generated electrical power decreases to 50% of the maximum and represents the lower limit. The values of the multi-stage expansion presented in
Table 4 are normalized with the respective values of the single-stage expansion.
In the case under investigation, four turbines and three heat exchangers (re-heaters) are required. For the turbine it is assumed that two stages can be combined in one machine, which halves the constant costs in Equation (
9). It is assumed that the intermediate superheating is realized by generic shell and tube heat exchangers. Their cost can be calculated using the following equation proposed by Mounier et al. [
21]:
where
A is the surface area of the heat exchanger,
and
n = 0.9119. To obtain a power-based relationship, the heat exchanger surface area is substituted by
where
U is the thermal transmittance and
the logarithmic mean temperature difference LMTD.
For a shell and tube heat exchanger, the thermal transmittance and the driving temperature difference have to be estimated in order to determine the required heat exchanger area A. The steam to be heated flows through the tubes, while the hot steam flows around them and thereby condenses. In this configuration, the heat transfer from the inner tube wall into the superheated steam (cold side) dominates the overall heat transfer, since the heat transfer coefficient for condensation around the tubes (hot side) is two orders of magnitude larger [
22]. The following relation for turbulent superheated steam is used [
23] to compute the heat transfer coefficient
where
is the bulk temperature of the steam, c the average velocity in the tubes and d the hydraulic tube diameter. Setting
, a value of
is used in Equation (
15) and the LMTD is estimated from the data, yielding the extended model for the multi-stage payback period
as follows:
where
N is the number of stages.
Table 4 shows the
normalized with the single-stage expansion case. In spite of the higher complexity of the entire system, i.e., four turbine stages and three heat exchangers, the additional cost is more than compensated by the higher electrical power generated. Since the individual components of the system become smaller as the mass flow ratio increases, their cost decrease and so does the normalised
. In general, the situation does not change significantly with the number of turbine stages to exploit the entire pressure range. By generating electrical energy, as an embodiment of exergy, this process moves toward making the best possible use of available energy sources. The authors are aware that multi-stage expansion with intermediate heating significantly increases the complexity and thus potential problems of such a system compared to simple throttling or single-stage expansion. However, it is important to highlight the potential for such systems and for well-informed decisions.
For the 20 available cases,
Figure 8 shows the
for multi-stage expansion as a function of the generated electrical power. Both quantities are standardized with their respective values of the single expansion. For both initial temperatures T = 535 K (circles) and T = 550 K (triangles), the number of expansion stages N required to use the full pressure range are color-coded in the legend. Note that an external heat source is assumed in the present analysis. The graph reveals that the generated power can be increased by up to 3.3 times by means of multi-stage expansion with reheat compared to a single-stage expansion combined with a throttling device. However, this requires a large number of turbine stages and heat exchangers, leading to higher system complexity. Under the given assumptions, the values of the
of multi-stage systems are at most 1.5 times higher compared to systems with only one expansion stage. Increasing future energy costs would give rise to decreasing PbP for multi-stage expansion systems, and make them more attractive from an economic perspective.