1. Introduction
The burning of fossil fuels is one of the main contributors to global warming and climatic changes. Many countries with rich fossil resources highly depend on fossil fuels for the industrial sector, and the continuous increase in energy demand will likely increase fossil fuel consumption, resulting in a further increase in CO
2 emissions [
1]. Therefore, governments across the world have been taking initiatives to address this issue by encouraging the promotion and implementation of renewable energy (RE); renewable and alternative energy has great potential to replace the dependency on fossil fuels by reducing product costs and improving energy conversion efficiency [
2].
Solar energy, as an eco-friendly excellent candidate and a continuous and stable renewable energy resource, has enormous under-utilized potential to reduce CO
2 emissions and slow down the trend of global warming, which can significantly change local energy policy and energy structure and contribute to the low-carbon and carbon-neutral ambitions under the 2015 Paris Agreement [
3].
A large amount of incident solar energy is dissipated into the environment in the form of low-grade heat during solar energy use, which greatly reduces the performance of PV cells [
4]. At the same time, the heat buildup within conventional PV systems causes an increase in internal temperature within the cells, resulting in a drastic decrease in energy conversion efficiency. Only 5–25% of the solar radiation received by traditional solar photovoltaic panels is converted into electricity. The rest of the energy (75–95% of the solar radiation) would be stored as thermal energy in the photovoltaic cell, which results in a temperature increase and energy conversion efficiency decrease [
5]. The solar conversion efficiency of PV modules decreases due to an increase in the internal charge carrier complex rate at high temperatures, which reduces system power output [
6]. Solar energy accounts for only 0.5% of total primary energy demand, while the proportion of energy supplied by solar PV is only 0.04%, it is indicated that there is huge potential for improvement in solar PV technology and thermal use [
7].
The heat collection module from PVT generates both electricity and thermal energy separately, eliminating the heat buildup issues that plague conventional PV systems. The heat gathered by the PV cells after absorbing solar radiation is the primary heat source of the collector system. As a result, the PV cell coverage of the PV module has a significant impact on the amount of light and heat. The PVT system can achieve a comprehensive light and heat efficiency of 68% and can effectively heat to water by optimizing the PV cell coverage, and it is a feasible way to improve the light and heat performance and practicality of the PVT system [
8]. Kazem et al. summarized the effects of solar irradiance and ambient temperature on the electrical performance of water-based PVT systems [
9]. The power of the PV panels is determined by the amount of solar irradiance, while the cooling water flow and temperature affect the power output characteristics of the PV panels [
10]. Gaur et al. proposed a PV system model to investigate the performance of a commercial PV module and showed that the electrical efficiency of the system with and without water cooling is 7.36% and 6.85%, respectively [
11]. Singh et al. conducted an experiment to compare the effect of the presence or absence of water flow on the temperature of PV panels. The PVT system was shown to have a lower temperature than conventional PV panels. The PV panel temperature decreased by 15.23% when the water mass flow rate was 0.0166 kg/s [
12]. The efficiency of the PVT system at high mass flow rates is also worth considering when compared to low flow rates of water. When the water flow rate exceeds 0.15 kg/s, the temperature of the PV panel gradually decreases and the output power increases, whereas the mass flow rate follows an opposite trend for the temperature. Furthermore, the collector installation angle has little effect on the system’s electrical efficiency while having a significant impact on its thermal efficiency [
13]. At low Reynolds numbers, the heat transfer coefficient increases with the depth of the cooling channels, which results in increasing the electrical and thermal efficiency of the system. However, at higher Reynolds numbers (Re1000), the channel depth has no significant effect on heat transfer efficiency [
14]. Al-Waeli et al. propose four evaluation criteria for new hybrid PV/T collectors, each of which can be used to serve different PV/T configurations and designs for comparing the operating performance of different PV/T systems [
15]. In winter, the performance of the dual-fluid PVT system was improved compared to the single-fluid PVT system, with a 20% increase in heat gain from the fluid mass and a 15.3% increase in total solar energy conversion, but a 0.2% loss in power output. In the summer, dual-fluid systems do not improve collector performance [
16]. Three different materials, aluminum, copper, and TPT (Tedlar/PET/Tedlar), are used as heat-absorbing substrates for the PVT system. It was shown that the PVT system with TPT substrate has the lowest average temperature and higher photovoltaic efficiency, and the PVT system with copper as the substrate has the highest photothermal efficiency and COP(Coefficient Of Performance) [
17].
Because solar energy is intermittent, there is a large gap between energy supply and demand in PVT systems, with plenty of heat available during the day but none at night. In addition to increasing energy efficiency, the use of PCM increases the timing and flexibility of heat supply to the PVT modules [
18]. The melted PCM is used as a heat source to heat the water overnight until the next morning, resulting in a higher water temperature than in the absence of PCM [
19]. However, the collector may cause overheating of the PCM after a long period of operation. A relatively low conditioning temperature of the cooling mass can enhance the heat exchange with the PCM, and the use of appropriate intermittent conditioning can significantly improve the conversion efficiency of the system to solar energy, where the PVT-PCM system with 45 °C indirect conditioning has a better performance compared to full-time conditioning [
20]. Preet et al. investigated the output of three different PV systems, natural convection, water-based PVT, and water-based PVT-PCM, in terms of open circuit voltage (V
oc) and short circuit current (I
sc) at different operating flows [
21]. When compared to the PV system, the PVT-PCM system reduces the temperature of the heat-absorbing panels and solar cells by 15 °C and 20 °C, respectively, resulting in a 21% increase in solar thermal efficiency. At the same time, the temperature of the heat-absorbing panels in the PVT-PCM system is lower than that of the PV panels, avoiding the impact of the heat-absorbing panels on the efficiency of the PV panels [
22]. Yuan et al. investigate the performance of water-based PVT systems and PVT-PCM systems during the daytime and at nighttime. The experiments revealed that the use of PCM could improve the system’s photovoltaic efficiency by 1.7% during the daytime. Furthermore, the temperature of the PVT-PCM system is significantly higher at night in winter, whereas increasing the PCM thickness improved the anti-freeze function of the water-based PVT system [
23]. Yang et al. found that sensible and latent heat can be stored in the PCM layer, and the PCM releases the absorbed heat energy into the water, maintaining the water temperature in the tank for a longer period of time by comparing the water temperature in the storage tank of PVT and PVT-PCM systems [
24]. Modjinou found that PCM improves the performance of photovoltaic cells, and the thickness and density of the PCM can further improve the working performance of PVT systems [
25].
The efficiency of the photovoltaic cells is primarily influenced by factors such as solar radiation intensity, photovoltaic cell temperature, and the cell’s own material properties. According to the literature above, water-based PVT collectors have been investigated in terms of various structures and operating parameters. The research aims to 1. Explore the daily energy performance (choosing from a typical day condition) of the plate-and-tube water-based PVC collectors; 2. Study the use/adoption of thermal energy storage technology by PCM to improve the overall energy conversion utilization efficiency.
However, the performance comparison of PV, PVT, and PVT-PCM under the same conditions and the applicability of the water-based PVT-PCM system have not been investigated extensively. Therefore, in this study, Firstly, the water-based PVT-PCM collector is designed with an air layer between the photovoltaic cells and the glass cover plate to reduce the system’s heat loss, optimize the structure and minimize the negative impact of temperature on photovoltaic cells by using a plate-and-tube. Secondly, PCM is selected and integrated into the water-based PVT collector to further improve the heat transfer inside the collector and enhance the overall efficiency of the system. Finally, based on the water-based plate-and-tube PVT-PCM collector, a simulation study was conducted to compare the photovoltaic panel temperature and photothermal performance of PV/T-PCM, PV/T, and PV systems under different conditions, and the influence of water flow rate, presence of PCM and different PCM layer thicknesses on the collector’s performance is also evaluated.
3. Simulation Results and Analysis
The variation of solar irradiance and ambient temperature during a typical summer day in the Lhasa area, which has a rich solar resource, is shown in
Figure 7 [
40]. It is found that the simulation results show that solar irradiance reached an all-day maximum of 976.59 W at 13:00 and the ambient temperature reached an all-day maximum of 20.7 °C at 15:00 from 8:00 to 18:00. The environmental wind speed is assumed to be a constant average value, and the inlet water temperature is assumed to be equal to the ambient temperature. The solar radiation is converted to an internal heat source for the PV panels by Equation (33) [
41] compiled into Fluent in the form of UDF for ease of calculation. The various design parameters of the collector are shown in
Table 1,
Table 2 and
Table 3. A series of simulation results including thermal-electric efficiency, photovoltaic cell temperature, and electrical power will be analyzed in detail.
3.1. The Effect of Water Flow Rate on the Electrical Performance of PVT System
Figure 8 shows the hourly variations of PV panel temperature and the photoelectric efficiency at different water flow rates in the range from 0.004 to 0.1 m/s, with the operating hours from 8:00 am to 18:00. It is found that the temperatures of the PV panels gradually decrease and the photoelectric efficiency significantly increases with the increase in the water flow rate from 0.004 to 0.1 m/s. The influences of the water flow rates on the effectiveness and the temperature of PV panels are obvious in the range of the water flow rate from 0.004 to 0.1 m/s for the recorded time between 8:00–16:00. It is shown that when water flow rates increase from 0.004 to 0.1 m/s, the PV panel temperatures are respectively increased from 327.89 K to 297.92 K and the photoelectric efficiency is decreased from 12.1% to 10.1% at 13:30. Simultaneously, it is observed that the maximum temperature of PV panels occurs from 13:00 to 14:00, but the temperature of PV panels decreases rapidly once recorded time exceeds 14:00.
The simulation results indicate that continuously increasing the mass flow rate of cooling water can effectively improve the photoelectric efficiency and reduce the temperature of the solar cell because the excessive flow rate enhances the heat exchange efficiency within the photovoltaic panel and reduces the heat exchange time.
3.2. The Effect of Water Flow Rate on the Thermal Performance of PVT Systems
The hourly variation of the temperature difference between the water flow inlet and outlet is shown in
Figure 9. The water temperature difference between the flow inlet and outlet is inversely proportional to the water flow rate and corresponds to the solar irradiance trend. It is observed that the temperature difference reaches a peak at 13:00 and then gradually deceases. Simultaneously, it is found that when the water mass rate is 0.004 kg/s, the maximum water difference between the flow inlet and outlet reaches 16.5 °C at 13:00, whereas when the water mass rate is 0.1 kg/s, the maximum water difference between the flow inlet and outlet is only 0.81 °C at 13:00. The simulation results indicate that the effect of increasing the water flow rate continuously on the inlet and outlet temperature difference is very significant.
The photothermal efficiency of the water-based PV/T collectors is evaluated at the different water mass flow rates, depending on the various hours, as shown in
Figure 10. It is found that the Photothermal efficiency of the water-based PVT-PCM collectors gradually increases with the increase in the mass flow rates from 0.004–0.01 kg/s and operating hours from 8:00 to 18:00 on a typical working day. However, once the mass flow rate exceeds 0.1 kg/s, the photothermal efficiency of the water-based PVT-PCM collectors will significantly decrease instead, so there is an optimal range for the mass flow rate, which is between 0.015–0.02. Simultaneously, it is observed that the photothermal efficiency maintains a steady increase with increasing solar intensity in the operating time range from 8:00–16:00. The influence of the water mass flow rate and operating times on the photothermal efficiency is obvious for the water-based PV/T collectors operated on a typical day. Therefore, there is a combined effect of mass flow and temperature difference on solar thermal efficiency, which has the best thermal effect when the water mass flow rate is 0.02 kg/s. The main reason for the increase in photothermal efficiency is that increasing the flow rate enhances internal heat transfer within the collector, however, when the flow rate is too high, the temperature rise of water decreases significantly due to the short heat transfer time, leading to a decrease in efficiency. Therefore, there exists an optimal operating flow rate with maximum efficiency.
Figure 11 shows the variations of the thermal power at different mass flow rates, ranging from 0.004 to 0.1 kg/s, with the operating time between 8:00 and 18:00. It is found that the thermal power increases significantly with the increase in the operating time from 8:00 to 12:30. Simultaneously, it is observed that the thermal power decreases rapidly once the operating time exceeds 13:00, and the thermal power increases up to 398.94 W when the mass flow rates reach 0.02 kg/s but it drops sharply when the mass flow exceeds 0.02 kg/s.
Figure 9 shows that increasing the water flow rate can improve the thermal power of the system, but the thermal power reaches a limit as the water flow rate increases.
The influence of the water mass flow rate and solar irradiance on the effectiveness of the thermal power is obvious for the water-based PV/T collector in a range of water mass flow rates between 0.004–0.1kg/s. It is difficult to achieve a large water temperature rise with the same heat amount because of the large heat capacity and high flow rate of water. As a result, the temperature of the photovoltaic panels is well regulated under high water flow rate conditions, while the temperature rise of the cooling water is relatively small.
3.3. Effect of the Presence of PCM on the Performance of PVT Systems
The temperature of a solar cell and the photoelectric efficiency of the three systems (PV, PVT, and PVT-PCM) are compared under the hourly operating conditions shown in
Figure 10. It is indicated that the temperature of solar cell rises and then declines, but the photoelectric efficiency declines and then rises for the three systems (PV, PVT, and PVT-PCM), due to constant absorption of heat from hourly sufficient irradiance resulting in increased temperature and decreased efficiency.
As shown in
Figure 12, the solar cell temperature gradually increases as the operating hours gradually go up to 13:00, at which time, the PVT-PCM system has the largest difference in cell temperature compared to the PV/T and PV systems, decreasing by 26.7% and 55.4%, respectively. The photovoltaic efficiency gradually decreases as the operating hours gradually go up to 13:00, at which time, the difference in electrical output capacity is the largest, and the PVT-PCM system has the largest difference in photovoltaic efficiency compared to the PV/T and PV. The PVT-PCM system has a 3.06% and 16.15 increase in photovoltaic efficiency compared to the PV/T and PV systems, respectively. With the operating time after 15:00 gradually rising, the difference in the temperature of the solar cell and the photoelectric efficiency of the above three systems gradually decreases. After 17:00, the PV/T-PCM system PV panel temperature starts to be higher than the PV/T system due to the PCM phase change exotherm, and this heat is eventually used mainly to extend the heating of water. The main reason for the increase in thermal efficiency is that the temperature of the PVT-PCM system remains at the lowest level among the three operating systems, which is due to the fact that the sensible and latent heat absorption of the melting PCM and heat of the water takes away part of the heat within the PV plate.
The simulation results indicate that there is an important impact on reducing the temperature inside the shell and improving the efficiency of the system by using PCM materials inside solar panels.
Figure 13 shows the hourly variation of the electrical power. It is observed that the PVT-PCM system always has a higher electrical power output than the PVT and PV systems from 8:00 to 18:00, and the electrical power difference between them increases and then decreases, which is due to the variation of the solar irradiation intensity. The electrical power output of all three systems obtains its maximum value at 13:00 at 42.74 W, 40.19 W, and 34.06 W, respectively, while their power output difference also has its maximum value for the whole day at that time at 2.55 W and 8.68 W, respectively. Then, the difference between them decreases as the irradiance starts to decrease. The presence of PCM can, therefore, improve the effectiveness of the system’s electrical power output, especially at high irradiance levels. The average electrical power output for the three systems’ operating time periods is 28.59 W, 27.47 W, and 24.00 W, respectively, with a performance increase of 4.08% and 19.13% compared to PV/T and PV systems.
It is found that photoelectric efficiency gains obvious improvements and the temperature of solar cells significantly decreases with the application of PCM to the solar cell, which is due to the fact that absorbed heat from solar irradiance by melting PCM is in the form of latent heat and hence the temperature within the solar cell obviously decreases. Therefore, there is an obvious advantage to using PCM solar cells to reduce the temperature of the solar cell and improve photoelectric efficiency.
3.4. Effect of PCM Thickness
In order to derive the effect of PCM on system performance, the collector performance is calculated and analyzed for different PCM layer thicknesses “h”.
Figure 14 indicates the PV panel temperature and photovoltaic efficiency, with respect to the operating time between 8:00 to 18:00 and PCM thicknesses ranging from 0.02 to 0.04 m. It is observed that the temperature of solar energy decreases and the photovoltaic efficiency increases when the PCM thickness increasingly ranges from 0.02 to 0.03 m within the operating time, and then the temperature hardly increases and the photovoltaic efficiency decreases when the PCM thickness exceeds 0.03 m. While the thickness of the PCM had a negative effect on the effectiveness when exceeding 0.03 m.
As shown in
Figure 14, the maximum temperature of the solar cell respectively decreased by 1.6%, 3.5%, and 3.6% as the thickness of the PCM gradually went up to 0.04m. The maximum photovoltaic efficiency respectively increased by 0.18%, 0.42%, and 0.44% and the photoelectric efficiency respectively increased by 0.05%, 0.18%, and 0.12% compared to the PCM thickness of 0.02 m based on the operating conditions.
Figure 15 indicates the photothermal efficiency, with respect to the operating time between 8:00 to 18:00 and PCM thicknesses ranging from 0.02 to 0.04 m. It is observed that photothermal efficiency increases in the operating time from 8:00 to 14:30, and then the photovoltaic efficiency hardly decreases when the operating time exceeds 14:30.
As shown in
Figure 15, the maximum photothermal efficiency respectively increased by 5.8%, 2.9%, and 4.7% as the thickness of the PCM gradually went up to 0.04mm in the operating time from 8:00 to 11:30. The maximum photovoltaic efficiency respectively increased by 0.18%, 0.42%, and 0.44% and the photothermal efficiency respectively increased by 0.13% and decreased by 0.16% and 0.66% as the thickness of the PCM gradually went up to 0.04 m compared the PCM thickness of 0.02 m when the operating time exceeds 14:30.
It is found that photovoltaic efficiency and photothermal efficiency see a slight improvement, but the effect is not obvious as with the thickness of PCM, which is due to the fact that PV panel temperature by solar irradiance rises to the melting temperature of the PCM, the PCM absorbs heat in the form of latent heat, and gradually liquefies and maintains the temperature constant. Therefore, it is recommended that the thickness of the PCM should be kept between 0.02–0.03 m to effectively reduce the temperature of the solar cell and improve photoelectric efficiency.
Figure 16 shows the heat absorption rate of the PCM based on different thicknesses of PCM, with respect to the operating time between 8:00 to 18:00 and PCM thicknesses ranging from 0.02 to 0.04 m. It is observed that the heat absorption rate of different thicknesses of PCM slowly increases until 10:30, it sharply increases between 10:30 and 12:30, and starts to obviously decrease after 13:00, which is due to variable solar irradiance in the given operating time.
Figure 17 shows the liquid phase rate of different thicknesses of PCM, with respect to the operating time between 8:00 to 18:00 and PCM thicknesses ranging from 0.02 to 0.04 m. It is observed that the liquid phase rate of PCM is almost constant until 10:30, the heat absorption rate of PCM sharply increases between 10:30 and 16:00, and then the liquid phase rate of PCM starts to slowly decrease after 16:00, which is due to variable solar irradiance in the given operating time.
It is observed that there is no phase change of PCM in all working conditions before 10:30, and the liquid phase rate of PCM is slow due to not absorbing enough heat to melt. The heat absorption rate of PCM sharply increases between 10:30 and 16:00 due to the fact the PCM starts to absorb heat and melt to generate a phase change and the liquid phase rate starts to rise. The temperature inside the collector reaches its peak as the irradiance starts to decrease after 13:00, while the liquid phase rate of the PCM starts to decrease but the temperature of the PV panel is still higher than the melting temperature of the PCM, so the liquid phase rate also continues to increase. The liquid phase rate of the PCM reaches its maximum value of the day around 16:00, while the heat absorption rate of the PCM drops to 0, the collector temperature is lower and the melting temperature of the PCM is reached again, the PCM starts to solidify and becomes exothermic, the liquid phase rate then drops and the heat absorption rate of the PCM is negative. In all operating conditions, the heat absorption rate of the PCM is highest at h = 0.04 m, when the mass of the PCM is the largest and the internal potential energy and heat saturation are low, so the heat exchange with the collector is the most effective, and the heat absorption rate of the PCM reaches its maximum value of 120.2 J/s for the whole day at 12:30. The 0.02 m thick PCM layer has the lowest rate of heat absorption with a maximum value of 103.1 J/s throughout the day.
Based on the analysis above, it can be concluded that increasing the water flow rate can significantly improve the electrical efficiency of the system but at the cost of a decrease in temperature rise, leading to a decrease in thermal efficiency. The optimal operating flow rate exists at a maximum value when the flow rate is too high, causing a significant decrease in efficiency due to the reduced heat transfer time. The best overall performance is achieved when the water flow rate is 0.02 kg/s. Compared to the worst operating conditions, the thermal-electric efficiency increased by 40.7% and 4.1%, respectively. In the three systems (PVT-PCM, PVT, and PV), the PVT-PCM system’s photovoltaic efficiency increased by 3.06% and 16.15% while the electrical output increased by 4.08% and 19.13%. When the collector height was 0.03 m, the PVT-PCM system’s photovoltaic efficiency improved the most, with an increase of 0.18% compared to a height of 0.02 m. As the PCM thickness exceeded 0.03 m, the collector’s photothermal performance improvement was not significant. Therefore, it is recommended to choose a PCM thickness of 0.03 m to ensure good performance.
4. Conclusions
In this study, a plate-and-tube water-based PV/T-PCM collector with an air gap was proposed to reduce energy losses and mitigate the negative impact of temperature rise on PV cells. A numerical investigation is conducted in this work to examine the effect of water flow rates, the presence of PCM, and PCM thickness on the power output and efficiency of the solar collector. The interactions between the studied input factors and their combined impact on the power output and efficiency of the solar collector are observed. The optimal values of some important parameters of the PVT-PCM at the maximum efficiency are also calculated. Moreover, the performances of the PVT-PCM, PVT, and single PV cell are compared. The application of PCM significantly improves the power generation capacity of the system and enhances the solar energy utilization efficiency of the plate-and-tube water-based PVT collector. It is vital to find the optimal values of some key parameters, which will be of great guiding significance for the design and operation of solar energy systems and can be determined through theoretical calculation. In addition, the application of the PCM can improve the shortcomings of PVT systems with fluctuating photothermal efficiency due to irradiance and keep the stability of the thermal power output. Other findings are as follows:
(1) The water flow rate has a maximum value of m = 0.02 kg/s for system performance improvement. The thermal-electric efficiency increased by 40.7% and 4.1% compared to m = 0.004 kg/s. However, as the flow rate continues to increase to m = 0.1 kg/s, the electrical efficiency increased by 5.55%, but the thermal efficiency decreased by 13.4% due to the higher flow rate and the resulting lower temperature rise of the water.
(2) Compared to the system without PCM, the electrical power output at 13:00 increased by 2.55 W and 8.68 W, and the average photoelectric efficiency increased by 3.06% and 16.15%, respectively. In the calculation time, the maximum temperature differences of the respective PV cells in the three systems are 25.67 °C, 34.32 °C, and 57.11 °C, respectively, which, to some extent, improves their service life.
(3) For the water-based plate-and-tube PV/T-PCM collector, the results show that the 0.03 m thickness of PCM has the best selection value compared to other thicknesses of the PCM.