2.3.2. Emission Inventory
To establish the emission inventory, it is essential to identify the primary sources contributing to CEs within the defined system boundary. We systematically assessed key environmental impact stages associated with rice production, encompassing (1) carbon dioxide (CO
2) resulting from the production, transportation, and utilization of various agricultural inputs; (2) methane (CH
4) emissions from paddy fields during rice cultivation; and (3) direct and indirect nitrous oxide (N
2O) emissions arising from nitrogen application [
12,
27,
28,
29,
30]. It is pertinent to note that straw burning can also contribute to CEs. However, based on our field investigations, we confirmed that Chinese farmers do not engage in straw burning due to stringent government regulations, hence, it was not factored into the CE calculation. Consequently, the pollution emission inventory related to rice production encompassed CO
2, CH
4, and N
2O.
Below are the calculation methods for CEs:
CO
2 emissions. The calculation of CO
2 emissions primarily considered agricultural inputs such as fertilizers, pesticides, diesel fuel consumption by agricultural machinery (tillage, planting/transplanting, and harvesting), and electricity consumption for irrigation. The most authoritative method for estimating CO
2 from these agricultural inputs is the CE factor approach provided by the IPCC [
27,
31], which was also employed in this analysis. The specific formula is as follows:
Here, indicates the CO2 emission from the production, transportation and utilization of various agricultural inputs; denotes total amount of the th agricultural input throughout the entire life cycle of rice production; is the coefficient factor for the th agricultural input; and , , and correspond to CO2 from the production, transportation, and utilization of the th agricultural input, respectively. The CO2 produced from input utilization primarily originates from diesel combustion.
Given the diversity of fertilizer types, which is influenced by factors such as regional geography, climate conditions, crop growth characteristics, and farmer operational habits, accurate statistics on their usage can be challenging. We convert various fertilizers into their active components (N, P
2O
5, K
2O) for unified measurement [
22,
26,
27], and the corresponding carbon emission coefficients we used are based on [
26]. Given the diversity of pesticides and their varying active components, precise calculations of their CO
2 emissions are challenging. Therefore, we employed a unified comprehensive factor to estimate the emissions resulting from the various pesticides used by farmers [
26]. Additionally, we considered diesel fuel consumption, including the use of farm machinery both owned and rented by farmers. This calculation accounted for the diesel expenditure, diesel price, machinery operating time, and the unit fuel consumption, converting these into diesel fuel consumption based on a diesel density of 0.84 kg/L [
32]. Furthermore, we estimated the electricity consumption for irrigation by considering the irrigation fees paid by farmers and the corresponding agricultural electricity prices in the region. Notably, during the survey period, poverty-stricken counties in Hunan Province implemented discounted electricity prices for agricultural irrigation and drainage. Consequently, we matched the relevant irrigation and drainage electricity prices based on whether the sample household was located in a poverty-stricken county.
CH
4 emissions. The CH
4 emissions were calculated using the methodologies detailed in the literature [
33,
34,
35] and in accordance with the ISO/TS14067 [
36] accounting standard. To account for variations in the reproductive characteristics among different rice varieties and the operational disparities during production, we adjusted the calculation method and conventional parameter values. The specific formula is as follows:
In Equation (8),
represents the CH
4 emissions within the system boundary of rice production (kg);
is the daily CH
4 emission factor (kg/(ha × d)), where
denote factors affecting CH
4 emissions from rice fields, such as ecosystems, water conditions, and organic matter input;
is the harvest area of the rice field (ha); and
is the total number of days in the rice growth period. In Equations (9) and (10),
is the baseline CH
4 emission factor, representing the CH
4 emissions during the continuous irrigation of rice fields without organic matter input, with a default value of 1.3 kg/(ha × d);
and
are the conversion factors for water conditions during the planting and pre-planting periods, respectively;
is the conversion factor for the type and quantity of organic matter input; and
is the conversion coefficient for different varieties of soil organic matter input. The values of
,
and
for different rice cultivation techniques in different growing seasons were derived from [
12] to highlight the disparities among various rice production methods. Finally,
is the input density (t/ha) of organic matter, primarily referring to the amount of straw return, and its calculation formula is as follows:
where
represents the yield of rice (kg/ha);
denotes the straw-to-grain ratio of rice;
indicates the straw return rate of rice; and 0.85 reflects the proportion of dry weight to fresh weight of rice straw. To accurately capture the heterogeneity in rice production processes, we calculated the value of
based on the harvest index
specific to different rice-cropping systems, as opposed to using conventional uniform values, following the methodology outlined by [
12]. Additionally, considering the unique harvesting characteristics of the RR system during the main season, we estimated the straw return rate of RR during the main season by comparing the stubble height between RR and conventional rice.
N
2O emissions. N
2O emissions from paddy fields encompass both direct and indirect emissions. Direct N
2O emissions occur from the soil due to the nitrification and denitrification of nitrogen sources. Indirect N
2O emissions result from the deposition of ammonia volatilized in the forms of NH
3-N and NOx-N, as well as nitrate leaching and runoff. The quantity of N
2O emissions, denoted as
, can be calculated as follows:
where
indicates the direct emissions and
represents the indirect emissions. The formula for calculating direct N
2O emissions is as follows:
Based on the research findings, fertilizers and straw are the primary nitrogen sources contributing to N
2O emissions during rice cultivation. Therefore, in Equation (14),
and
represent the nitrogen inputs from fertilizers and straw to the rice field, respectively.
denotes the direct N
2O emission factor (kg N
2O-N/kg × N). The value of
is derived from the active components in the fertilizers, while
comprises the nitrogen from straw returned to the field
and the root nitrogen content
. Equation (15) outlines the calculation method for
. Here,
,
, and
retain their previously defined meanings;
is the root-to-shoot ratio taken from the Guidelines for Provincial Greenhouse Gas Inventories compiled by research institutions under the Climate Change Department of the National Development and Reform Commission of China; and
and
represent the nitrogen content of straw and roots, respectively, based on the values documented in [
12].
The formula for calculating the indirect N
2O emissions is as follows:
Equation (16) describes the two main contributors to indirect N2O emissions: nitrogen volatilization leading to atmospheric deposition, , and nitrogen leaching or runoff, . In Equation (17), represents the rate of nitrogen volatilization, and denotes the N2O emission factor (kg N2O-N/kg × N) that results from atmospheric nitrogen deposition. Equation (18) defines as the nitrogen leaching and runoff rate, and as the indirect N2O emission factor (kg N2O-N/kg × N) resulting from nitrogen leaching and runoff losses. The values of the emission factors and used in the above equations were sourced from the Guidelines for Provincial Greenhouse Gas Inventories.
After quantifying the CEs originating from agricultural inputs, as well as CH
4 and N
2O emissions associated with rice cultivation, the quantity of CEs from rice production, denoted as
, was computed using the following formula:
where CH
4 and N
2O emissions were converted to CO
2 equivalents (CO
2 eq) according to their respective GWP (kg ha
−1). The GWP values utilized in this study accorded with the latest 100-year GWP coefficients of CO
2, CH
4, and N
2O (1:28:265) recommended by the IPCC [
22].