1. Introduction
Surface functionalization through surface topography adaption is applied in a variety of applications as, e.g., to control tribological properties [
1], in biomedical applications [
2], to improve wettability characteristics [
3] or for bonding between different materials [
4].
Functionalization of a surface consists in adapting the surface properties. New properties can be established by changing the chemical and phase composition of the surface, as well as changing the surface morphology.
Researchers have various surface treatment methods at their disposal to adapt the surface properties. They can be divided into low-scale methods, where high-selectivity of the process is required (e.g., micro-milling [
5], electron beam processing [
6], and various laser-based methods), and large-scale methods, where a significant part of the area can be treated in the uniform manner (for example, sandblasting [
7], electrical discharge machining (EDM) [
8], or electrochemical etching [
9]). Despite a wide variety of processing purposes, surface treatment methods are mainly based on the removal of material up to predetermined spatial properties. Moreover, regular structures with repeating patterns are largely created by local processing methods.
Laser-based material structuring technologies are often associated with laser ablation. This approach requires high intensity laser radiation provided by pulsed laser sources. The spatial sizes of the structures produced by ablation can vary from submicron structures created with DLIP (Dual Laser Interference Patterning) [
10,
11] or LIPSS (Laser-Induced Periodic Surface Structures) [
12] technologies to relatively large sizes using LST (Laser Surface Texturing) [
13], as well as scanning strategies, over a large area [
14].
2. State of the Art
A different approach to surface topography adaption is laser remelting technologies. These processes generally require less power density for the absence or a low rate of vaporisation. Laser polishing is a remelting-based process designed to remove surface roughness. Depending on the initial surface and the material, both continuous wave (CW) and pulsed laser sources can be used [
15]. Furthermore, the remelting approach can be applied to various materials. Weingarten [
16] applied it to remove roughness from glass, in Reference [
17] remelting was applied to a ceramic material for roughness reduction. By References [
18,
19,
20], laser polishing was applied for treatment of steel and titanium.
The structuring technology WaveShape (see
Figure 1) is based on laser remelting and was first introduced by Temmler [
21]. During this process, regular surface structures are generated by the redistribution of material in the molten state. The resulting structure height is linearly dependent on the laser power amplitude and can be adjusted from a few microns up to several hundreds microns.
By laser processing with the beam diameter
, a molten pool is created on the metal surface, which moves along the scanning direction with a scan speed
. The scanning speed is generally varied from 10 to 200 mm/s. Using constant laser power
in the order of a few hundred watts, the direction of solidification is parallel to the initial surface in the direction of the beam movement. However, a change of the laser power leads to a change of the direction of the solidification front following the change of the molten pool size. Therefore, when the melt pool volume increases, the direction of solidification shifts upwards and when the volume of the molten pool decreases, it moves downwards [
23].
During solidification, a texture is formed on the surface which has one to one correspondence to the laser power modulation signal. In order to obtain harmonic structures, the average laser power is modulated during the process with a laser power amplitude in the order of several tens of watts at a predetermined spatial wavelength .
The nature of the process lies in the behavior of the molten pool driving forces. For the WaveShape process, Temmler [
22] considers spontaneous shape change due to volume expansion as a main principle of the structuring. Sharma [
24] provides a 2D-process simulation of the WaveShape process by COMSOL Multiphysics and considers the Marangoni force as the main force.
The technology can be applied to adapt the surface morphology. According to Bordatchev [
25], potential applications of the technology are the structuring of moulds for the production of light guides and texturing metal surfaces. An approach for removing waviness was considered by Oreshkin Reference [
26]; the principle is called destructive interference.
This paper focuses on the creation of harmonic structures, although the generation of structures with complex shapes using WaveShape is a promising area of research.
3. Problem Statement
Surface structures created with the laser structuring by remelting normally have a one to one correspondence of the resulting surface structure and the modulation signal. However, even for harmonic structures, shape deviations can be observed. When the power modulation signal is, e.g., given as
, the resulting surface profile can mathematically be described as:
where
is the phase shift (see
Figure 2),
is a deviation component, presumably depending on the laser power amplitude
and the spatial wavelength
.
Temmler [
23] considered this issue and divided it into two parts. The first is the phase shift between the modulation signal and the generated structures
presented in
Figure 2, the second is the so-called asymmetry. The asymmetry of the structures was measured as the asymmetry angle
:
where
is the peak deviation from the symmetry position in the lateral direction, and
is the height amplitude of the structure (peak). An example of structures with asymmetry is displayed in
Figure 3.
The approach of Temmler [
23] to reduce asymmetry is the double structuring of a track: first in one direction and then in the opposite direction, so that the deviation caused by the first pass is compensated. This method can reduce the shape deviation but requires twice as much processing time.
It might be more accurate to describe the shape deviation of structures rather than their asymmetry because, although the structures on the surface might be symmetrical, they could still exhibit a deviation from a predetermined shape.
Shape deviation is a key factor for the inverse laser structuring problem: the generation of a laser power modulation signal to generate a predetermined structure on the surface. Thus, if the power modulation signal does not allow the generation of a given structure, it is necessary to modify the modulation signal (see
Figure 4). This paper describes research towards finding such a modulation signal modification.
4. Materials and Methods
4.1. Materials and Surface Preparation
Commercially available Ti6Al4V alloy was used as a base material for this research. The probes with flat surface were mechanically grinded with grinding wheels up to grit size P500 according to ISO-6344. The measured residual arithmetical mean roughness after probe preparation was lower than 0.1 m. Before laser processing, the surface was cleaned with isopropanol.
4.2. Experimental Set-Up
The experimental set-up is presented on the
Figure 5.
In the scope of this study, the laser processing was done with the CW fiber laser IPG LS-2 (IPG Photonics, Fryasino, Russia, legacy model of YLS-2000) with maximum laser power up to 2 kW. In addition, a 3D-Laser scanner (IPG Photonics, Oxford, MA, USA) was used. The scanning speed was fixed on = 25 mm/s. The power modulation signal was created with a Control Cell (Blackbird Robotersysteme GmbH, Garching—Hochbrück, Germany). An industrial robot ABB IRB 4600 (ABB, Zürich, Switzerland) was used for the alignment of the laser scanner. The process gas chamber was filled with inert gas (Argon) to a residual oxygen concentration of 1000 ppm. Glass with anti-reflection coating was used to reduce back reflection. The oxygen concentration during the processing was measured with the gas analyzer AKPM-1-01 (Alfa Bassens, Moscow, Russia).
The structures were obtained by scanning single tracks with a length of six times the spatial wavelength but no less than 20 mm. The power modulation was provided as a periodic function:
with
defined as
and
defined as
where the
is the laser power at which the melting process starts, and
the laser power at which a plasma torch is visible above the molten pool. The laser power amplitude
was calculated with a coefficient of
to remain within the safe limits of the processing window.
Table 1 shows the laser power parameters which are determined for the scanning velocity
= 25 mm/s and laser beam diameters
= 250
m and
= 500
m.
4.3. Surface Measurement and Data Processing
For the measurement of the longitudinal profiles of the generated structures, a Dektak 150 stylus profilometer (Veeco Instruments Inc., Plainview, NY, USA) was used.
The result of the measurement is a two-dimensional structure profile . A Fourier transformation was performed on the profile with rectangular windowing. The width of the rectangle window can be determined from the analysis of the fundamental frequency of the obtained profiles. The following parameters was determined:
Power spectrum magnitude on the first spatial frequency () and the second spatial frequency (). Further, in order to avoid confusion, the term “harmonic” is used to indicate certain frequencies or wavelengths. The first spatial frequency (first harmonic) corresponds to the main spatial wavelength of the power modulation signal ; the second harmonic is . The spatial frequency is inverse to the spatial wavelength .
The ratio of the magnitudes on the second and first harmonics . The ratio of harmonics is used as a measure of structure deviation.
The phase shift of the second harmonic relative to the first harmonic is measured as: , where —shift of the first harmonic, and —shift of the second harmonic.
5. Results and Discussion
5.1. Determination of Process Parameter Sets
In order to investigate different types of deviations, laser processing was done for two fixed beam diameters with a variation of the spatial wavelength. For selected spatial wavelengths and beam diameters, the power modulation amplitude
is varied in five steps to the maximal
measured during preliminary experiments: for
= 250
m,
is varied from 20 to 52 W; for
= 500
m,
is varied from 30 to 176 W. The magnitudes of the second and first harmonics, as well as their ratio as a function of the spatial wavelength, is presented in
Figure 6. For both beam diameters, the maximum structure height of the first harmonic is reached at a spatial wavelength of approximately four times the beam diameter. This dependence is close results observed by Temmler [
23]. However, additional analysis was done to examine the deviation of the signal from the power modulation signal.
The minimum of the ratio can be determined to for a beam diameter of = 250 m and for a beam diameter of = 500 m, respectively. Thus, the symmetric structures with low shape deviation can only be generated in a small region of wavelengths. For regions of small and large wavelengths, the shape of the structure differs from the symmetric structure. Furthermore, general structure heights are lower for these ranges. One approach to adapt the shape of the structures in regions of small and large wavelengths to the symmetric target shape was investigated in this study.
Three regions of wavelengths were determined: a small wavelength region (1–2
), a medium wavelength region (3–5
) and a large wavelength region (>5
). For the following experiments, one main spatial wavelength
1 from each region is selected (see
Table 2).
Temmler [
27] investigated structuring by remelting for the Ti6Al4V alloy. The structure height was used as a parameter of the processing quality. For
= 25 mm/s, structure heights of up to 20
m for a beam diameter of
= 250
m and up to 40
m for a beam diameter
= 500
m were generated. The maximum of the structure height is also observed in the region of medium spatial wavelengths. The deviation of the structure shape has not been investigated. In this study, the processing is carried out with lower power density: for a beam diameter
= 250
m,
= 92.5 W and
= 52.5 W were determined, and, for a beam diameter
= 500
m,
= 130 W and
= 105 W were determined. Presumably, this inconsistency is caused by the different distribution of the power density in the in the beam spot.
The nature of the structure height distribution of the as a function of the ratio
is consistent with earlier studies of both the titanium alloy Ti6Al4V [
27] and steel H11 [
23]. The existence of an extremum in the medium wavelength region can presumably be explained by the coordinated motion of the three-phase line of the solidification front with the expansion-compression cycle of the molten pool during structuring by remelting. Further research is needed to confirm or refute this hypothesis.
Furthermore, it can be observed that the range of the ratios
for different beam diameters is the same for different magnitudes of the first harmonics (see
Figure 6). This indicates that the ratio
is a suitable measure to compare the quality of different harmonic structures.
5.2. Linearity of Laser Power Amplitude on Structure Shape Deviation
It is known that the structure heights linearly increase with the increase of laser power amplitude
[
23] for various materials. In this study the influence of the laser power amplitude
to structure shape deviation was investigated. For selected spatial wavelengths and beam diameters, the laser power amplitude
was varied in five steps to the maximal
measured during preliminary experiments: for
= 250
m,
was varied from 20 to 52 W; for
= 500
m
was varied from 30 to 176 W. The ratio of the second and first harmonics is shown in
Figure 7.
The tendency for structuring with lower shape deviation in the medium wavelength range is more noticeable at higher
. The reason is presumably the low amplitude of the first harmonic, since as a consequence even a small variation of the amplitude results in an increase of the ratio of harmonics. The graphs in
Figure 7 show the predominant trend of an increase of
and, therefore, shape deviations with an increase of the laser power amplitude
excluding the lowest values. A presumable reason might be an increase in the unevenness of the three-phase line movement at higher laser power gradients
.
5.2.1. Direction of Phase Shift
For chosen spatial wavelengths and laser power parameters described in
Section 5.1, the phase shift of the second harmonic relative the first harmonic
were measured (see the
Figure 8).
For small spatial wavelengths
> 0°, this indicates that structure peaks are shifted to the left from the symmetrical position. For the large spatial wavelengths
< 0°, the peak is shifted to the right from the symmetrical position. These findings are consistent with the data obtained on the steel 1.2343 [
23]. For the medium spatial wavelengths, the spatial shifts are located between the extreme values. The sign of the phase shift
in both the low wavelength and large wavelength range is consistent with the previous investigation of shape deviation on steel 1.2343.
5.2.2. Compensation of Laser Power Amplitude
In order to improve the structure quality by reducing the surface shape deviation, a compensation signal has been added to the signal of laser power amplitude. Since the majority of the deviation is caused by the second harmonic, the compensation signal is a harmonic wave with the doubled frequency with a phase shift relative to the first harmonic. As a result, the Formula (
3) of the laser power signal changes to the following:
The laser power amplitude of the compensation signal was chosen based on the ratio
for the corresponding laser beam diameter and spatial wavelength:
The process parameters for every parameter set are shown in
Table 3.
For each parameter set, the phase shift
is varied from −180° to 180°. The results of the structuring with the compensation signal are shown in
Figure 9. The influence of the compensation signal is compared to the reference structure with
= 0 W.
From the graphs in
Figure 9, it can be seen that adding the compensation signal to the laser modulation signal has an influence on the structure shape deviation. For each parameter, there is a value of the phase shift
, where the ratio of harmonics is minimal. For small spatial wavelengths, the minimal value is in the range of −30° to 60°; for large spatial wavelengths, this range is approximately 120° to 150°. For the medium spatial wavelengths, no trend in the location of the extremum could be determined as general for both beam diameters. Additionally, the magnitude of
is much lower in the medium spatial wavelength range, so the reference structures are more symmetrical than they are in the other ranges. Thus, the influence of phase shift on shape deviation in the medium spatial wavelength range is lower than in the other ranges.
Moreover, the graphs in
Figure 10 show the correlation between the phase shift of the structures obtained with the compensation signal and the position of the ratio extrema. The phase shift of the structure obtained with the compensation signal corresponds to the phase shift of the reference signal at the points of the extrema. This implies that the phase shift of the second harmonic does not change at the extreme points. For the maximum of the ratio of harmonics
, a positive interference occurred, and, for the minimum of the ratio of harmonics
, a negative interference appeared.
5.2.3. Finding the Optimal Value of Laser Power Amplitude
After finding the extreme points by variation of the phase shift
, the investigations of the amplitude of the compensation signal is performed. The process parameters from the
Table 3 are used, but the laser power amplitude of the compensation signal
is varied in twelve steps. The results of the investigations are displayed in
Figure 11.
For each parameter set, the dependence of the ratio of harmonics
on the laser power amplitude of the compensation signal
is investigated. The local minima show the optimum value of the amplitude
for a given phase shift
. A further increase of the laser power amplitude will lead to a decrease in the structure quality due to overstructuring at the second harmonic. As a result,
Table 4 shows the parameter sets for each beam diameter
and spatial wavelength
, where the harmonics ratio is minimal. The harmonics ratio for the reference structure and the structure after processing with the compensation signal is also presented.
Examples of the reference structure and the structure after processing with compensation are shown in
Figure 12 for comparison. For the structures in the small wavelength range, the peak of the reference structure is shifted to the left. For the large wavelength range, the peak of the structure is shifted to the right. After processing with the compensation signal, both structures show no visible signs of a shift.
6. Summary and Outlook
Laser structuring by remelting (WaveShape) enables the generation of harmonic structures on metal surfaces. The structures are formed due to the kinematics of the three-phase line of the melt pool. In this study, the maximum structure heights were achieved at = 4 for = 250 and 500 m, which is in good agreement with other studies. Additionally, shape deviations of the generated sinusoidal structure were systematically investigated for the first time.
It was found that the majority of the shape deviation are concentrated at a spatial wavelength corresponding to half the spatial wavelength of the structuring. Therefore, shape deviation was estimated using, inter alia, the amplitude ratio of the first harmonic (structuring wavelength) and second harmonic (half structuring wavelength) . It was observed that the shape deviations for medium spatial wavelengths ( = 3–5) are significantly smaller than for small ( = 1–2) or large ( > 5) spatial wavelengths. Thus, at wavelengths in the medium wavelength range, not only the highest structure heights but also the smallest shape deviations are obtained. However, a linear increase in the amplitude ratio (i.e., shape deviation) was observed with increasing laser power amplitude , especially for longer spatial wavelengths. In general, the larger the laser power amplitude , the higher the structural heights achieved. Therefore, reducing the shape deviation at large laser power amplitudes is of particular importance.
Therefore, in this study, an approach to reduce the shape deviation by superimposing a compensation signal on the harmonic structuring signal was specifically investigated. In this approach, a compensation signal with half the spatial wavelength (/2) was varied in phase shift () and amplitude () and superimposed on the structuring signal. For all parameter combinations investigated, superposition with the compensation signal leads to a change in the amplitude ratio , which depends, in particular, on the phase shift . Thereby, the minimum of the amplitude ratio lies at a phase shift in the range of = −30° to −60° for small spatial wavelengths, and in the range of = 120° to 150° for large spatial wavelengths. Furthermore, the phase shift extremes of the second harmonic coincide with the phase shift of the reference signal. This indicates effective interference between the compensation signal and the processes that significantly affect the shape deviation. Additional adjustment of the power amplitude reduced the overall amplitude ratio by up to 91%, resulting in a significant reduction of the shape deviation.
In summary, this work has demonstrated that shape deviation in the WaveShape process can be effectively corrected over a wide range of spatial wavelengths ( = 2–8). The correction is achieved by superimposing a wavelength-, amplitude-, and phase-corrected compensation signal on the structuring signal. An application of this approach could particularly improve the quality when generating more complex regular structures. Moreover, the implementation of compensation signal can extend the process limits to a wide range of spatial wavelengths without the need to change the laser beam diameter. Further planned investigations of shape deviation correction have the goal to realize a transfer from single tracks to surface processing (considering the track overlap).
Within the scope of this research, shape deviation was mainly considered from a signal processing perspective. The development of effectively adapted compensation algorithms will require a study of the physical correlations, especially taking into account the thermal properties of the material. In addition, this approach will be used, among others, for an active elimination of ripples and waviness on a metal surface.
Author Contributions
Conceptualization, O.O. and D.P.; methodology, D.P. and O.O.; software, D.P. and A.P.; validation, O.O. and D.P.; formal analysis, D.P.; investigation, D.P. and A.P.; data curation, D.P. and L.K.; writing—original draft preparation, O.O., D.P., L.K. and A.T.; writing—review and editing, O.O., D.P., L.K. and A.T.; supervision, A.T.; project administration, O.O. and L.K. All authors have read and agreed to the published version of the manuscript.
Funding
The authors gratefully acknowledge the financial support of the RFBR (grant number 19-58-12006) and the Deutsche Forschungsgemeinschaft (DFG) (grant number SCHL2189/6-1) for the project “Structuring by laser remelting for removing waviness or generation of structures on metallic surfaces (DeConStruc)”.
Conflicts of Interest
The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript, or in the decision to publish the results.
Abbreviations
The following abbreviations are used in this manuscript:
CW | Continuous wave |
EDM | electrical discharge machining |
DLIP | Dual Laser Interference Patterning |
LIPSS | Laser-Induced Periodic Surface Structures |
LST | Laser Surface Texturing |
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Figure 1.
Schematic diagram of laser structuring by remelting (WaveShape) [
22].
Figure 1.
Schematic diagram of laser structuring by remelting (WaveShape) [
22].
Figure 2.
Schematic diagram of the relative position of the laser power amplitude signal and generated structure along the x-axis.
Figure 2.
Schematic diagram of the relative position of the laser power amplitude signal and generated structure along the x-axis.
Figure 3.
Single track structures on steel 1.2343 with: asymmetry of peaks shifted to the left (
a), symmetrical in longitudinal direction (
b), asymmetry of peaks shifted to the right (
c); the 3D-profiles generated with a white light interferometer (1) and cross-sections along the longitudinal profile (2). Processing parameters:
= 115 W,
= 50 W,
= 250
m,
= 50 mm/s, (
a)
= 0.5 mm, (
b)
= 1.0 mm, (
c)
= 2.0 mm [
23].
Figure 3.
Single track structures on steel 1.2343 with: asymmetry of peaks shifted to the left (
a), symmetrical in longitudinal direction (
b), asymmetry of peaks shifted to the right (
c); the 3D-profiles generated with a white light interferometer (1) and cross-sections along the longitudinal profile (2). Processing parameters:
= 115 W,
= 50 W,
= 250
m,
= 50 mm/s, (
a)
= 0.5 mm, (
b)
= 1.0 mm, (
c)
= 2.0 mm [
23].
Figure 4.
Schematic diagram of the Waveshape process chain with signal compensation.
Figure 4.
Schematic diagram of the Waveshape process chain with signal compensation.
Figure 5.
Experimental set-up for laser surface processing with process gas chamber for the avoiding oxidation of samples.
Figure 5.
Experimental set-up for laser surface processing with process gas chamber for the avoiding oxidation of samples.
Figure 6.
Structure height of the first and second harmonics for = 250 m (a) and 500 m (c) and the ratio of the second and first harmonics (b,d), respectively.
Figure 6.
Structure height of the first and second harmonics for = 250 m (a) and 500 m (c) and the ratio of the second and first harmonics (b,d), respectively.
Figure 7.
Ratio of the second and first harmonics in dependence of the amplitude of laser power modulation: (a) = 250 m, (b) = 500 m.
Figure 7.
Ratio of the second and first harmonics in dependence of the amplitude of laser power modulation: (a) = 250 m, (b) = 500 m.
Figure 8.
The phase shifts of reference structures.
Figure 8.
The phase shifts of reference structures.
Figure 9.
Ratio of the second and first harmonics depending on the phase shift of the compensation signal for = 250 m (a) and 500 m (b).
Figure 9.
Ratio of the second and first harmonics depending on the phase shift of the compensation signal for = 250 m (a) and 500 m (b).
Figure 10.
Phase shift accordance to the extremum of the harmonics ratio (a,b) = 250 m, = 500 m, (c,d) = 500 m, = 4000 m.
Figure 10.
Phase shift accordance to the extremum of the harmonics ratio (a,b) = 250 m, = 500 m, (c,d) = 500 m, = 4000 m.
Figure 11.
Ratio of the second and first harmonics depending on the laser power amplitude of the compensation signal: (a): = 250 m, = 500 m, (b): = 500 m, = 4000 m.
Figure 11.
Ratio of the second and first harmonics depending on the laser power amplitude of the compensation signal: (a): = 250 m, = 500 m, (b): = 500 m, = 4000 m.
Figure 12.
Reference and corrected surfaces: (a): = 250 m, = 500 m, (b): = 500 m, = 4000 m.
Figure 12.
Reference and corrected surfaces: (a): = 250 m, = 500 m, (b): = 500 m, = 4000 m.
Table 1.
Process parameters for single tracks.
Table 1.
Process parameters for single tracks.
| | | |
---|
250 | 25 | 135 | 52 |
500 | 25 | 410 | 176 |
Table 2.
Chosen spatial wavelengths from the small (), medium (), and large () wavelength regions.
Table 2.
Chosen spatial wavelengths from the small (), medium (), and large () wavelength regions.
[m] | [m] | [m] | [m] |
---|
250 | 500 | 1000 | 2000 |
500 | 1000 | 2000 | 4000 |
Table 3.
Process parameter sets for processing with the compensation signal.
Table 3.
Process parameter sets for processing with the compensation signal.
[m] | [m] | [mm/s] | [W] | [W] | [W] | |
---|
250 | 500 | 25 | 135 | 52 | 8.84 | 0.17 |
250 | 1000 | 25 | 135 | 52 | 2.6 | 0.05 |
250 | 2000 | 25 | 135 | 52 | 10.92 | 0.21 |
500 | 1000 | 25 | 410 | 176 | 21.12 | 0.12 |
500 | 2000 | 25 | 410 | 176 | 17.6 | 0.10 |
500 | 4000 | 25 | 410 | 176 | 21.12 | 0.12 |
Table 4.
Process parameter sets for laser processing with optimized parameters of the compensation signal.
Table 4.
Process parameter sets for laser processing with optimized parameters of the compensation signal.
, [m] | , [m] | , [mm/s] | , [W] | , [W] | , [W] | , [°] | | |
---|
250 | 500 | 25 | 135 | 52 | 16.6 | –50 | 0.17 | 0.02 |
250 | 1000 | 25 | 135 | 52 | 0.26 | 160 | 0.05 | 0.03 |
250 | 2000 | 25 | 135 | 52 | 5.2 | 160 | 0.21 | 0.02 |
500 | 1000 | 25 | 410 | 176 | 72.6 | –50 | 0.12 | 0.09 |
500 | 2000 | 25 | 410 | 176 | 17.6 | –110 | 0.10 | 0.08 |
500 | 4000 | 25 | 410 | 176 | 14.4 | 140 | 0.12 | 0.01 |
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