3.1. Basic Design of the Red Plasmonic Filter
In a metallic hole array, the spectral position of transmittance peaks (
λmax) corresponds to the SP resonance orders, following [
13,
22]
where
P is the period of the array and
εm and
εd are the permittivity values of the metal and dielectric material, respectively. Optical resonance originates from the periodicity. The smallest periodic unit generates the fundamental resonance mode, and more modes appear corresponding to the periodic dimensions. The periodicity is calculated using (
i,j) numbers in Equation (1) corresponding to the reciprocal vectors of the array. Among the multiple transmittance peaks, the highest transmittance occurs in the largest wavelength region corresponding to the first order of resonance [
15]. If the pass band is to be positioned in red light, i.e.,
λmax(1,0) or
λmax(0,1) lies between 600 nm and 700 nm, the second order peak (
λmax(1,1)) appears within the range 420–500 nm, as expected from Equation (1). Therefore, the hole arrays for a red PCF inevitably introduce additional disturbances in the form of undesirable transmission peaks in the lower wavelength region. This leads to the deterioration of the color purity performance.
In this paper, a design method is proposed to suppress undesirable transmittance by combining PhCs with the conventional PCF structure. As atoms are periodically repeated in a solid crystal, PhCs consist of a structure in which optically different material compositions are regularly repeated. Such periodic structures make it possible to control the dispersion and velocity of light. One of the most interesting properties of PhCs is the PBG, which is a specific wavelength range in which the existence of optical modes is inhibited, similar to the electron energy band gap of crystal lattices. Based on the photonic band theory [
23,
24], the development of various device applications with PBGs is being actively researched [
25,
26]. If different dielectric constants are repeated in a certain direction, light is scattered at the interfaces of layers, resulting in destructive interference in the direction of the repeated change of dielectric constants. Therefore, light of specific energy levels cannot propagate in that direction.
In the proposed structure, the spectral range of the PBG is adjusted at the wavelength of the second order peak of a red PCF.
Figure 1 shows the schematic diagram of the PCF structure for filtering red light. The reference PCF structure shown in
Figure 1a has hole arrays in a 150-nm-thick aluminum (Al) film on a glass substrate. The diameter of the holes is 240 nm, and the period of the square array is 370 nm. Lithium fluoride (LiF) layers cover the top and bottom of the Al film; the thickness of the top and bottom LiF layers are 150 nm and 50 nm, respectively. These thicknesses are selected to obtain effectively the same SP modes [
27].
The proposed filter is shown in
Figure 1b. One-dimensional (1D) periodicity is the simplest structure adopted to form a PBG; it allows us to simplify the modified structure in terms of both design and fabrication. Two different dielectric materials are stacked alternatively on the top of the reference PCF, forming a 1DPhC structure. The periodic interval in the direction orthogonal to the surface of the structure generates a PBG during normal transmission. In a previous experimental study, the reference structure exhibited optimized transmittance with the quasi-plane surface [
15]. Thus, the surface of each layer of 1DPhC can be assumed to be flat.
3.2. Design Photonic Bandgap in the Stop Band of the Plasmonic Filter
First, the spectral characteristics of 1DPhCs with a finite number of multilayers were examined. The optical properties of 1DPhCs were engineered to provide high reflection and low transmission at PBG with the central wavelength of 400 nm. Since infinite repetition is not practically possible, the constructed PBG is expected to have a low quality factor (Q-factor). Thus, the transmittance curve of the PhC may result in a wide and shallow valley. In addition, the finite number of interfaces within the multilayers is the main cause of the ripples beyond the PBG range in the transmission spectrum. These ripples originate from the constructive and destructive interferences between various reflection modes. Smaller numbers of interfaces result in larger amplitude and wider shape of the ripples. The transmittance spectrum of the optimized PhC to be integrated on a red PCF should have a valley in the cutoff band (approximately 400–600 nm) and a peak only in the red wavelength range. In addition, the shape of the spectral valley should not be symmetrical about the center wavelength of PBG and should be wider on the longer wavelength side. Considering these requirements, the designed PhCs have a PBG with a central wavelength of 400 nm, which is less than the range of λmax(1,1) of the red PCF.
The transmission spectra of 1DPhCs were calculated for various combinations of dielectric materials according to the number of stacked pairs. For all cases, two different dielectric materials were laid in sequence on the glass substrate, and the PhCs contain LiF along with the following three dielectric materials: (a) silicon dioxide (SiO
2); (b) aluminium oxide (Al
2O
3); and (c) zinc sulfide (ZnS). The thickness of each material in the PhC is designed according to the following equation [
28]:
where
d and
nd are the thickness and refractive index of each material, respectively, and
λPBG is the central wavelength of the PBG (400 nm in this study). The refractive index values are not constant in the spectral range of interest. For defining
d, the real value of
nd at 400 nm was used. The refractive index value and thickness of each material layer were as follows: (i) n
LiF = 1.38, d
LiF = 72.5 nm; (ii) n
SiO2 = 1.55, d
SiO2 = 64.5 nm; (iii) n
Al2O3 = 1.83, d
Al2O3 = 54.6 nm; and (iv)
nZnS = 2.38,
dZnS = 42.0 nm.
Figure 2 shows the transmittance spectra of each 1DPhC laid on the glass substrate. Since a finite set of two materials were stacked in each 1DPhC, a perfect bandgap at 400 nm could not be realized. The strength of the PBG effect resulted in either a transmission or reflection spectrum around 400 nm. Since the PBG was used to restrict the second order peak (
λmax(1,1)) of the red PCF, the effects of PBG were interpreted by reducing the transmittance at
λPBG. As shown in
Figure 2, as the number of layers increased, the disallowed band developed more readily. In all cases, at least two pairs of materials were required to form a distinct valley around 400 nm. The valley deepened as the number of layers increased. In addition, as the number of layers increased, the valley became narrower, and the central wavelength of the valley showed a blue-shift.
For the LiF/SiO
2 composition shown in
Figure 2a, the minimum transmittance of two pairs was 0.914 at 406.7 nm. The transmittance of the spectral valley reduced by 0.097 (~10.6%) and reached 0.817 at 394.5 nm, showing a spectral shift of 12.2 nm to the shorter range. The valley is not exactly symmetric with respect to the minimum transmittance position. Further, the filtering performance is measurable only in the visible range. Hence, in order to examine the broadness of the transmittance valley, the spectral distance (
λbroad) was confirmed from the wavelength of minimum transmittance near 400 nm to the first maximum transmittance on the right side. In the case of the LiF/SiO
2 structure, the use of five pairs resulted in a narrower transmittance valley with 67.2 nm
λbroad, while for the structure with two pairs,
λbroad was 193.5 nm.
The larger the contrast ratio of the refractive indexes between two materials of the PhC (
n1/
n2), the more distinct the PBG; consequently, lower transmittance was observed around 400 nm. In contrast, in the case with five pairs, the minimum transmittance was 0.817 for the smallest contrast ratio (1.087 in
Figure 2a) and 0.152 for the case with the largest contrast ratio (1.725 in
Figure 2c). In addition, when the contrast ratio of the index values was large, the valley became narrower and deeper and more distinct corresponding to the use of more layers. In
Figure 2b, for LiF/Al
2O
3 with
n1/
n2 of 1.3, the minimum transmittance of the two pair structure was 0.62 (412.2 nm), and it reduced to 0.292 (at 401.4 nm) for five pairs. For the LiF/ZnS structure shown in
Figure 2c, the minimum transmittance showed a reduction in 72.9%, decreasing from 0.561 to 0.152 when the number of stacked layers increased from two pairs to five pairs. In addition, the valley became narrower, resulting in a change in
λbroad from 120.6 nm to 97.8 nm under identical conditions.
Meanwhile, ripples were observed in the longer wavelength range. The ripples become clearer and their amplitude increases as the ratio n1/n2 increases or as more layers are stacked. The ripples are the result of the interferences of the reflected light modes from various interfaces. In other words, in the dielectric layer that forms the interfaces with the other materials (of different optical constants), multiple reflections occur between the two interfaces. These light modes have a regular optical path difference, resulting in constructive and destructive interference, and finally showing repeating maxima and minima in the spectral range. This phenomenon is well known and forms the basis of the Fabry–Perot interferometer (FPI). The PhC structure has multiple interfaces, and hence, various reflected modes generate complex interference effects.
On the other hand, the entire PhC can be considered as an FPI that has the interfaces with the glass substrate at the bottom and with the air on the other side. The spectral distance between multiple transmittance peaks (
λFSR: free spectral range) is affected by the thickness of the FPI structure. It is calculated as [
29]
where
λ0 is the central wavelength of the transmittance peak;
n, the average refractive index value; and
d, the thickness of the FPI. The greater the number of stacks in PhC, the thicker the FPI, the smaller is the value of
λFSR, and thus, more ripples are created within the wavelength range of interest. A larger average refractive index of FPI yields similar results. Therefore, the case of the structure with five pairs of LiF/ZnS layers resulted in the most distinct and frequently positioned ripples. Thus, the transmittance curves could be designed. In order to improve the spectral selectivity of the filter by using the PhC, the transmittance of the PhC should be high in the pass band and low in the other wavelength bands. For example, three or five pairs of LiF/ZnS layers is acceptable over the four-pair structure, which has a weak transmittance valley in the red wavelength range.
Next, let us consider the optimized design of the red PCF combined with a PhC (PhC-PCF). As shown in
Figure 2, the use of more layers resulted in low transmittance, close to zero, at the PBG. However, infinite repetition of layers is not practically possible. Further, multiple additionally deposited layers are inefficient in terms of mass production, even though a one-dimensionally repeated stack is very simple and can be achieved without any complex pattering techniques. In this regard, the proposed PhC-PCF was designed to reduce the number of the layers of PhC.
Previously, the fabrication process of the reference PCFs in
Figure 1a has been reported, which adopted the laser interference lithography (LIL) method [
15]. First, the coherent laser lights produce periodic patterns. Then, the photoresistive thin film is exposed by the interference patterns, and the following steps are the same as conventional photolithography, which is widely used in the industry. Compared to the conventional nano-patterning technologies such as electron-beam lithography and focused ion beam methods, the process revealed the possibility of the PCF fabrication in large area within short time. For comprising the proposed PhC-PCF in
Figure 1b, the PhC consisted of LiF and tungsten trioxide (WO
3) layers. Both materials can be deposited by thermal evaporation in the same chamber. The in situ process is also advantageous for large-area fabrication and cost effectiveness. The refractive indices were experimentally obtained from the thermally evaporated thin film. The LiF and WO
3 layers were 72.5 nm and 45 nm thick, respectively, when calculated using (2) to achieve
λPBG = 400 nm. The contrast ratio of the refractive indices of these two materials is 1.61, which is quite similar to that in the case shown in
Figure 2c.
Figure 3a shows the transmission spectra of pairs of LiF and WO
3 thin layers in free space. The glass substrate shows low loss in light transmission and does not have any spectral dependency. Therefore, the spectral responses of the multilayer stacks regardless of the presence or absence of the glass substrate are quite similar. The transmittance curves of the multi-layered stack were calculated to interpret only the effects of PhC by excluding the PCF in the final structure shown in
Figure 1b. Similar to the results shown in
Figure 2, more pairs of LiF/WO
3 layers resulted in a more distinct valley, and thus showed low transmittance around 400 nm. Here, the structures composed of at least three pairs of LiF/WO
3 layers revealed a distinct valley in the 400 nm wavelength band and ripples in the longer wavelength range. The transmittance at 400 nm was 0.181 for the three-pair structure, and it was reduced to 0.066 for the four-pair structure.
The refractive indices of LiF and WO
3 are shown in
Figure 3b,c, respectively. The measured optical constant of the WO
3 thin film showed resonance characteristics near 230 nm. The maximum value of the imaginary part of the refractive index (
k) was 0.918 at 233 nm. It reduced gradually, and
k became zero at wavelengths greater than 390 nm. The imaginary part contributes to optical absorption, and the absorption resonance can be interpreted by the Lorentz oscillation model. The real part of the susceptibility, centered on the resonance frequency, oscillates between the positive and negative values, resulting in the curvature of the real part of the refractive index (
nR), as shown in
Figure 3b. At wavelengths longer than the resonance wavelength, the maximum value of
nR for WO
3 was 2.57 at 298 nm. This value is much larger than that in the wavelength range from 400 nm (2.18) to 700 nm (1.99).
The observed resonance characteristics resulted in high transmission loss in the 300 nm wavelength range and consequently led to the formation of an asymmetrical valley at λPBG. The broadness of the valley (λbroad) was defined as that from the target PBG band (λPBG, 400 nm) to the first peak position on the right side. The values of λbroad were 202.0 nm and 143.5 nm for the three-pair and four-pair structures, respectively. As the number of the stacked layers increased, the transmittance curve of the 4-pair structure showed ripples, and a shallow valley appeared between 500 nm and 700 nm. The minimum transmittance in this wavelength range was 0.736 at 641 nm. For LiF/WO3, the three-pair structure, with the smallest number of layers, was the most suitable for enhancing the spectral selectivity of the PCF.
3.3. Adjusting Spectral Response of PCF Using 1D-Phcs
To investigate the effect of PBG on the whole structure, the transmittance spectra of the PhC-PCFs were simulated. The simulation was performed to determine the most efficient way to handle PhC. The proposed structures have different orders of the position of the PhC: (i) glass/PCF/PhD and (ii) glass/PhC/PCF.
Figure 4 summarizes the change in the spectral response when the PhC was used in the reference PCF structure.
Figure 4a–d shows the results for glass/PCF/PhC structures, and
Figure 4e–h shows the transmission spectra for structures containing PhC, i.e., for glass/PhC/PCF structures. The transmittance curves of the PhC-PCFs were compared to the optical response of the reference PCF (
Figure 2a). In all graphs, dashed lines show the transmission calculated as a simple product of the transmittance of PhC in
Figure 3a and that of the reference PCF.
As expected, the use of three pairs of LiF/WO
3 layers helps suppress the transmission in the spectral range from 400 nm to 600 nm while maintaining transmission in the range of
λ1 of the PCF. These trends can be observed in
Figure 4c,g. The spectra of the PhC-PCF structure resulted in a transmittance peak at
λ1 similar to that of the PCF. Although transmittance in the wavelength range below 600 nm decreased, more peaks appeared randomly. For all cases shown in
Figure 4, the spectral shapes at
λ1 well corresponded to that of the calculated shapes. However, for two curves in the shorter wavelength range, the difference between the calculation and the simulated data was quite large.
In the first case, (i), the peak value of the PhC-PCF structure at
λ1 was smaller than that of the calculated value for structures with two pairs or four pairs of PhC (
Figure 4b,d). On the other hand, the peak value is larger than the calculated value in
Figure 4a,c. The most similar case between the calculated and simulated results is shown in
Figure 4c—the case of three pairs of layers, which results in a peak shift of 7 nm and a difference of 6.6% in peak transmittance (0.407 at 616 nm for the simulation and 0.434 at 623 nm for the calculation). In the short wavelength range below 600 nm, the simulation results show additional sharp peaks. These ripples affect the peak at
λ1 when the PhC is composed of more than three pairs of layers.
In case (ii), in which PhC is inserted between the glass substrate and the metallic hole arrays, the transmittance peak of the PhC-PCF at
λ1 is larger than the calculated value. In this case, the additional ripples appeared even in the peak at
λ1 with more than two pairs of PhC layers. The greatest similarity between the simulation and calculation is shown in
Figure 4e, i.e., for the one-pair structure. The peak transmittance was 0.332 at 618 nm in the simulation and 0.365 at 620 nm as per the calculation. The difference between the simulated and calculated values is smaller than that in case (i).
In order to analyze the effect of PhC quantitatively, the difference between the simulated and calculated values according to the wavelength (
Figure 5) were considered. The results for glass/PCF/PhC structures are shown in
Figure 5a–d, and those for glass/PhC/PCF structures are shown in
Figure 5e–h, according to the numbers of PhCs. The numbers in each graph represent the average values of the differences in the spectral range from 300 nm to 800 nm. The difference between the calculated and simulated results decreased as the number of layers of the PhC increased. Additionally, a comparison of the structures with the same PhC composition (for example,
Figure 5b,f or
Figure 5d,h) showed that additional PhC layers between the substrate and the PCF led to a reduction in the difference between the calculated and simulated results. The smallest average difference was 0.0201 in case (i) and 0.0125 in case (ii); the value for case (ii) is 1.6 times smaller than that for case (i).
The calculated spectra indicate a situation in which the optical functions of the PCF and the PhC are separated. The effect of the additional dielectric layers on enhancing SPR and other possible optical effects through the multiple interfaces were not considered. In this regard, the smaller average difference between the calculations and the simulated results implies that the two components work more independently. In addition, the effect of PhC is more dominant than that of the complex optical interactions between the light modes generated from the additionally introduced interfaces. A comparison of the calculated and simulated results shows that the PhC inserted in the medium of the PCF provides more PBG-like effects.
Meanwhile, in terms of PBG formation with a finite numbers of layers, case (ii), i.e., glass/PhC/PCF structures, may be more effective. In these structures, light first undergoes PBG and then encounters the metallic surface of the PCF before passing through the PCF. Although the metal film enhances SP modes and scattering at the holes, the dominantly film-like shape results in high reflection. Thus, the round trip between the glass substrate and the metal film results in a larger number of effective layers for PhCs. In this regard, PhCs can be used for adjusting the transmission spectra of the reference PCF. The handling of PhCs in types of case (ii) is a more efficient way to control the spectra of the PCF with less layers. Compared to case (i), the optical response of case (ii) was closer to the expected value by considering only the PCF and PhCs and not any complex phenomena. In this work, the spectral response of the three pairs of LiF/WO3 layer was suitable to adjust the main transmittance peak as well as to suppress the minor transmittance peaks of the red PCF.
Although the reflective type of color filters is widely applicable in e-paper and various sensor devices, most imaging devices such as displays and CMOS image sensors adapt the transmissive type of color filters. These industrial devices demonstrate the full color image by the combination of red, green, and blue sub-pixels. From this perspective, the main goal of this study is to design a transmissive color filter as simple as possible. Since PBG from PhCs also provide the spectral selectivity, it can be also possible to form color filters by utilize PhC by itself. PBG works as an obstacle for light passing through the PhC structure; thus, it provides the band stop range in the spectra in terms of transmission. Referring the spectral selectivity of PBG in
Figure 2, it could be possible to realize cyan, yellow, and magenta as primary colors for the transmissive type of color filter. It can also be inferred that high reflectivity with spectral selectivity is obtained by PBG (a reflective type of color filter) and, in this case, realize red, green, and blue primary color. Photonic crystals can also be used to make transmissive filters with a high wavelength selectivity. In this case, two-dimensional or three-dimensional photonic crystals are often used [
30,
31].
In addition, the plasmonic filters could expand the use of color filter device due to active controllability [
32,
33]. The SP resonance condition is affected by both the refractive index values of materials and the dimensions of the structure. By reversing the refractive index change from dielectric materials such as phase change materials (from thermal energy), liquid crystals with electrical, and optical anisotropy, there is a polymerization state in the conducting polymers. Especially, the plasmonic structure consists of a novel metal with high conductivity, and the SP structure provides active spectral controllability without any additional component when using the electrical tuning method. In these regards, the simple guideline to design the transmissive plasmonic color filter with high selectivity will help to enlarge the use of nano-optic phenomena in practical applications.