High Efficient YVPO4 Luminescent Materials Activated by Europium
Abstract
:1. Introduction
2. Materials and Methods
2.1. Synthesis
2.2. Characterization
3. Results and Discussion
3.1. Pore Structure
3.2. SEM
3.3. Acid-Basic Properties of the Samples
3.4. Excitation and Luminescence
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Sample | SBET (m2/g) | Vpore (m3/g) | Monolayer Adsorption am (mmol/m2) | Adsorption Value at P/P0 = 1 (mmol/m2) |
---|---|---|---|---|
YPO4:Eu(8) | 83 | 0.13 | 0.85 | 3.7 |
YPO4:Eu(5) | 90 | 0.15 | 0.92 | 4.3 |
YVO4:Eu(5) | 6 | 0.04 | 0.07 | 1.1 |
YV0.9P0.1O4:Eu (5) | 8 | 0.05 | 0.08 | 1.3 |
YV0.8P0.2O4:Eu (5) | 9 | 0.03 | 0.09 | 0.7 |
Sample | YVO4:Eu(8) | YPO4:Eu(8) | YV0.9P0.1O4:Eu(8) | |||
---|---|---|---|---|---|---|
Elements | [norm. wt.%] | [norm. at.%] | [norm. wt.%] | [norm. at.%] | [norm. wt.%] | [norm. at.%] |
Oxygen | 17.08 | 48.41 | 17.08 | 48.41 | 18.46 | 49.75 |
Yttrium | 49.61 | 25.30 | 27.65 | 24.61 | 48.60 | 23.57 |
Vanadium | 27.65 | 24.70 | 0 | 0 | 24.35 | 20.61 |
Europium | 5.66 | 1.69 | 5.66 | 1.69 | 5.31 | 1.51 |
Phosphorous | 0 | 0 | 17.06 | 17.23 | 3.28 | 4.57 |
Sample | PH0 | pHIIS | Sample | PH0 | pHIIS |
---|---|---|---|---|---|
YPO4:Eu(0) | 6.4 | 6.1 | YVPO4(P10):Eu(0) | 6.4 | 6.8 |
YPO4:Eu(5) | 5.7 | YVPO4(P10):Eu(5) | 6.5 | ||
YPO4:Eu(8) | 6.1 | YVPO4(P10):Eu(8) | 6.9 | ||
YVO4:Eu(0) | 7.4 | YVPO4(P20):Eu(0) | 6.4 | ||
YVO4:Eu(5) | 7.5 | YVPO4(P20):Eu(5) | 6.4 | ||
YVO4:Eu(8) | 7.2 | YVPO4(P20):Eu(8) | 6.4 |
Sample | Composition | Excitation Band Peaks, nm | Emission Band Peaks, nm | ||||
---|---|---|---|---|---|---|---|
Host Material | Eu Content, mol% | λlum = 623 nm | I, a.u. | I327/I396 | λex = 328 nm | I, a.u. | |
1 | YVPO4 P10 | 8 | 327 | 799 | 14 | 623 | 781 |
396 | 58 | ||||||
2 | YVO4 | 10 | 327 | 744 | 13 | 624 | 673 |
396 | 56 | ||||||
3 | YPO4 | 10 | 322 | 13 | 0,7 | 623 | 11 |
396 | 19 |
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Minakova, T.; Mjakin, S.; Bakhmetyev, V.; Sychov, M.; Zyatikov, I.; Ekimova, I.; Kozik, V.; Chen, Y.-W.; Kurzina, I. High Efficient YVPO4 Luminescent Materials Activated by Europium. Crystals 2019, 9, 658. https://doi.org/10.3390/cryst9120658
Minakova T, Mjakin S, Bakhmetyev V, Sychov M, Zyatikov I, Ekimova I, Kozik V, Chen Y-W, Kurzina I. High Efficient YVPO4 Luminescent Materials Activated by Europium. Crystals. 2019; 9(12):658. https://doi.org/10.3390/cryst9120658
Chicago/Turabian StyleMinakova, Tamara, Sergey Mjakin, Vadim Bakhmetyev, Maxim Sychov, Ilya Zyatikov, Irina Ekimova, Vladimir Kozik, Yu-Wen Chen, and Irina Kurzina. 2019. "High Efficient YVPO4 Luminescent Materials Activated by Europium" Crystals 9, no. 12: 658. https://doi.org/10.3390/cryst9120658
APA StyleMinakova, T., Mjakin, S., Bakhmetyev, V., Sychov, M., Zyatikov, I., Ekimova, I., Kozik, V., Chen, Y. -W., & Kurzina, I. (2019). High Efficient YVPO4 Luminescent Materials Activated by Europium. Crystals, 9(12), 658. https://doi.org/10.3390/cryst9120658