5.1. Groundwater Vulnerability
Groundwater vulnerability refers to the possibility of groundwater pollution under the action of natural conditions or human activities [
26]. Groundwater vulnerability evaluation can classify the groundwater vulnerability in different regions and identify the potential of groundwater pollution, which is an important basic work for rational development, utilization, and protection of groundwater resources and an important basis for prevention and control measures of groundwater pollution [
27,
28,
29,
30]. The evaluation methods of groundwater vulnerability mainly include the overlay index method, process simulation method, and statistical methods [
30,
31,
32]. Among them, the overlay index method is a commonly used method with advantages such as simplicity and easy acquisition of data [
30,
31]. The DRASTIC model is the most widely applied and mature model in the overlay index method [
33,
34]. It selects seven representative indicators (depth of groundwater (D), net recharge (R), aquifer media (A), soil media (S), topography (T), impact of vadose zone (I), and hydraulic conductivity of aquifer (C), and their weights are 5, 4, 3, 2, 1, 5, 3, respectively. Different categories of each evaluation indicator are rated on a scale of 1–10. The smaller the rating, the lower the groundwater vulnerability [
27]. Then, groundwater vulnerability index is calculated to evaluate the groundwater vulnerability.
Usually, net recharge is replaced by rainfall because data are difficult to obtain [
35,
36]. Among the seven indicators, D determines the shortest path for pollutants to enter the groundwater from the surface. The deeper the depth of the groundwater is, the harder it is for pollutants to reach the groundwater, that is, the lower the groundwater vulnerability is. R and T determine the infiltration amount of water from the surface. As the carrier of pollutants, the infiltration amount of water determines that of pollutants. The smaller the R is and the larger the topographic slope is, the smaller the pollutant infiltration is and the lower the groundwater vulnerability is. S, I, and A affect the transport rate of pollutants from the surface, mainly through the type and size of media particles, thus affecting the groundwater vulnerability. The finer the particles are, the smaller the rate of pollutants passing through, and the longer they stay in the surface water, the more likely they are to be degraded. As a result, the groundwater is less susceptible to pollution, that is, the lower the groundwater vulnerability. C is considered to be an important factor affecting the diffusion of pollutants in groundwater. The smaller C is, the less easily the pollutants in groundwater diffuse, that is, the lower the groundwater vulnerability.
Based on the situation of the study area and referring to the relevant literature [
28,
35,
37,
38], each evaluation indicator of the DRASTIC model is rated as 1, 3, 5, and 7, corresponding to different categories of indicators. The greater the rating, the greater the contribution to groundwater vulnerability (
Table 7). The groundwater vulnerability indexes calculated by the comprehensive index method (Equation (4)) are 47–145 for the DRASTIC model, which is divided into four classes from low to high, corresponding to extremely low, low, moderate, and high vulnerability. It can be seen from the groundwater vulnerability map (
Figure 9) that the extremely low vulnerability areas are distributed in the northeast of Jiyuan City, Lushan County, the areas from Xin’an County to Mengjin County, and the areas near the mountains in the middle of CPUA, with an area of 365.2 km
2, accounting for 1.0% of the study area. The low vulnerability areas are distributed in the areas from Fengqiu County to Changyuan County and the areas near mountains, with an area of 5773.3 km
2, accounting for 15.0% of the study area. The moderate vulnerability areas are distributed in Xinxiang City, Luoyang City, Xuchang City, Jiaozuo City, and Luohe City, with an area of 23,321.3 km
2, accounting for 60.6%. The high vulnerability areas are distributed in the east and south of Kaifeng City, northeast of Luoyang City, south of Xuchang City, north of Luohe City, east of Zhengzhou City, and southeast of Pingdingshan City, covering an area of 9004.8 km
2, accounting for 23.4%.
Single indicator sensitivity can indicate the contribution of a single indicator to the evaluation result using an effective weight, and judge the importance of the indicator’s accuracy to the evaluation. The effective weight
of indicator
is calculated using Equation (5). Sensitivity analysis of single indicators for the DRASTIC model (
Table 8) show that the effective weights of A, S, T, and I (18.49%, 8.87%, 7.01%, and 25.14%, respectively) are higher than the theoretical weights (13.04%, 8.70%, 4.35%, and 21.74%, respectively). The effective weights of other indicators are lower than their theoretical weights. The theoretical and effective weights of D, A, and I are high, indicating that these indicators have a great influence on the groundwater vulnerability, and their accuracy is more important for the groundwater vulnerability evaluation.
5.2. Human Activities, Groundwater Vulnerability, and Groundwater Function Zoning
Groundwater vulnerability indicates the possibility of groundwater pollution, while land use types indicate certain human activities and possible pollution sources. Combining groundwater vulnerability, land use types, and groundwater function zoning can manage and utilize groundwater more reasonably.
Geological-disaster-prone areas are widely distributed, and in these areas possible geological disasters include ground subsidence, land desertification, and other groundwater-related disasters. Therefore, in these areas, special attention should be paid to the exploitation of groundwater, and groundwater cannot be allowed to be overexploited to form groundwater depression cones. Measures should be taken to improve the situation in areas where groundwater depression cones have formed, such as saving water and collecting precipitation during the rainy season. The groundwater vulnerability in the geological-disaster-prone areas is mainly low, moderate, and high. In these areas, the land types are mainly urban construction land and agricultural land. The low vulnerability of groundwater does not mean that it will not be polluted, and attention should also be paid to preventing groundwater pollution when paying attention to preventing geological disasters.
The ecology of ecologically vulnerable areas is relatively vulnerable, and the main land used type is agricultural land. During agricultural irrigation, more water should be saved, and attention should be paid not to cause ecological damage when developing and utilizing groundwater. The groundwater vulnerability in these areas is moderate or high. While protecting the ecology from damage, it is necessary to strictly control the discharge of pollutants to avoid causing groundwater pollution.
Reservation areas are areas where the current level of groundwater development is not high and are reserved for the sustainable use of water resources in the future. In these areas, the land use types are agricultural land and industrial land, and the groundwater vulnerability is low, moderate, and high, attention should be paid to the use of fertilizers, and the discharge of industrial pollutants.
The development and utilization areas are designed to meet industrial and agricultural production, urban life, etc. The land use types in these areas are mainly garden land and agricultural land. Despite the low groundwater vulnerability in this area, attention should be paid to the use of fertilizers, etc.
Conservation areas are areas where groundwater development is restricted in order to maintain a certain amount of gushing water from important springs or to conserve water sources. In these areas, the land use type is agricultural land and the groundwater vulnerability classes are moderate and high; attention should be paid to the use of fertilizers and pesticides.