Gas exchange across the air-water interface is a critical process that maintains adequate dissolved oxygen (DO) in the water column to support life. Oxygen reaeration rates can be accurately measured using deliberate gas tracers, like sulfur hexafluoride (SF
6) or xenon (Xe).
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Gas exchange across the air-water interface is a critical process that maintains adequate dissolved oxygen (DO) in the water column to support life. Oxygen reaeration rates can be accurately measured using deliberate gas tracers, like sulfur hexafluoride (SF
6) or xenon (Xe). Two continuous release experiments were conducted in different creeks in the Sierra Nevada of California: Sagehen Creek in September, 2009, using SF
6 and Martis Creek in August, 2012, using both SF
6 and Xe. Measuring gas loss along the creek, which was approximated with the one-dimensional advection-dispersion equation, allows for the estimation of the SF
6 or Xe reaeration coefficient (
KSF6, KXe), which is converted to DO reaeration (
KDO or
K2) using Schmidt numbers. Mean
KSF6 for upper and lower Sagehen and Martis Creeks were, respectively, 34 day
−1, 37 day
−1 and 33 day
−1, with corresponding
KDOs of 61 day
−1, 66 day
−1 and 47 day
−1. In Martis Creek,
KXe was slightly higher (21%) than
KSF6, but the calculated
KDO from SF
6 agreed with the calculated
KDO from Xe within about 15%; this difference may be due to bubble-enhanced gas transfer. Established empirical equations of
KDO using stream characteristics did a poor job predicting
KDO for both creeks.
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