1. Introduction
The Universe starts chemically simple and evolves into chemical complexity due to the evolution of galaxies and stars. The metallicity of galaxies carries the signature of their chemical evolution through cosmic time and is mainly affected by stellar evolution, e.g., see [
1]. Stellar evolution occurs through two major stellar mass channels, determined by initial mass: (1) the low- and intermediate-mass stars (LIMSs), with initial mass below
, and the high-mass stars, with
.
Planetary nebulae (PNe) are the ejected, illuminated envelopes of those LIMSs that evolve through the asymptotic giant branch (AGB) phase, i.e., those with initial mass in the
range. Stellar evolution predictions for Galactic PN progenitors [
2] indicate that the abundances of their
-elements, such as O, S, Ne, and Ar, are not expected to vary significantly during their lifetime. On the other hand, other elements, notably C and N, vary during the progenitor’s evolution, in different ways depending on their initial mass and metallicity. LIMS may contribute to C and N in galaxies at the 50% level or more. Furthermore, it has been observed that some metals (notably Fe) are mostly in gaseous form in the stars and tend to condense into small dust grains at the post-AGB and PN stages. The seamless comparison between PNe and their progenitor abundances of the relevant elements provides excellent constraints to elemental enrichment and depletion, and consequently to stellar and Galactic evolution.
A detailed comparison of PN abundances with those of the progenitors has not been performed recently. The seminal paper by Smith & Lambert [
3] shows PNe enriched in C/O concerning the underlying progenitor population for a relatively modest sample of red giants (32) and PNe (100). Comparative studies of PNe and progenitor stars have been attempted, limited to the
-elements, in M31 [
4] and other spirals [
5]. In the epoch of APOGEE and GAIA, there is a purpose in gleaning the tens-of-thousand abundance results of the APOGEE DR17 to select the PN progenitor populations for PN abundance comparison.
2. Our Study
The unified catalog of Galactic PNe Parker et al. [
6] includes very detailed explanations on what is considered a
True PN, based on spectroscopic and imaging information. In this paper, we based our analysis only on True|Galactic PNe in the Parker et al. [
6] catalog. Furthermore, we selected those whose elemental abundances have been measured. Abundance analyses have been unified in several recent catalogs. For this project, we use the PN abundances given in Bucciarelli & Stanghellini [
7]. Nebular parameters such as distances and radii are also taken from this paper, where distances are measured from the Gaia DR3 calibration of the Galactic PN distance scale. For the stellar sample, we select red giant targets in the APOGEE DR17 [
8], by limiting the stellar temperature and surface gravity appropriately to cover red giant branch (RGB) and asymptotic giant branch (AGB) stars [
9]. Both the nebular and stellar selected samples are disk populations, based on their Galactic radius (
kpc) and altitude (
kpc).
We used [O/H] as an indication of the stellar and nebular metallicity, since we know a priori that iron is depleted in PNe; thus, the usual [Fe/H] or [Fe/O] stellar indicators could not be applied here since they vary during AGB and post-AGB evolution. [O/H] is broadly used as a metal indicator, although it may fail in some extreme cases. We assessed that [O/H] in the observed PNe variation is well within the abundance error bars, but only complete population synthesis could discover the exceptions.
In
Figure 1, we show an example of the nebular and stellar samples that can be used for our project. Compatible samples of PNe and red giants (RGB and AGB, hereafter RGs) used for the analysis were built from the initial samples as follows: (1) We selected all PNe with at least one abundance measurement, other than oxygen, in the literature. (2) We then drew an RG sample with metallicity and spatial distributions similar to that of the PN sample in (1), with a given tolerance. (3) Finally, we ran the Kolgomorov–Smirnov (KS) test between the stellar and nebular metallicity and spatial distributions and discard RG samples whose distribution test against the null hypothesis (
p < 0.05). Any surviving RG sample could be used for the subsequent analysis. In
Figure 1, we show, as an example, the [Fe/H] sample used for the subsequent analysis.
3. Elemental Depletion
We studied the nebular and stellar samples to detect the depletion of certain elements in the nebular sample with respect to the underlying stellar population, due to condensation into dust grains. LIMS may contribute up to 90% of the total dust in galaxies [
10,
11,
12]; in PNe, dust content depends on progenitor mass and initial composition [
13]. We expect atomic condensation to depend on condensation temperature T
c [
14]. The condensation temperatures of the elements studied in this paper are T
c (C) = 77 K, T
c (N) = 131 K, T
c (O) = 181 K, T
c (S) = 693 K, and T
c (Fe) = 1351 K; thus, Fe is expected to be found mostly in dust grains at the PN stage, and sulfur could also show some depletion. [Fe/H] depletion in PNe has been observed before Delgado-Inglada & Rodríguez [
15], but has not yet been studied against the underlying progenitor population (i.e., the observed RGs), not related to the PN metallicity. In
Figure 2, we show the observed depletions of [Fe/H] and [S/H] in the studied populations. Both elements are depleted by dust formation in the PNe with respect to the underlying stellar population, given that the oxygen abundances are similarly distributed (see
Figure 1).
We quantified the [Fe/H] and [S/H] depletion by measuring their running median for the stellar sample and subtracting the value of each PN at the same [O/H]. We found, for the first time, a measure of the depletions of these elements directly compared with the [O/H] values. In
Figure 3, we plot [Fe/H] versus [O/H] in RGs and PNe, and we indicate a running median for the RGs. We measured depletion for each PN to the RG median of the same [O/H] value, and we found an average [Fe/H] depletion is <D[Fe/H]> = 1.741 ± 0.486 dex. We also disclose a mild correlation of the depletion with [O/H]. If [O/H] is a measure of the target metallicity, we can say that depletion is higher at high metallicity.
Sulfur depletion is milder and more uncertain, <D[S/H]
dex, with no correlation between sulfur depletion and metallicity. The sulfur depletion value for the ISM at solar metallicity, 0.45 ± 0.28 dex [
16], is compatible with the average PNe depletion, within the uncertainties. This is interesting, indicating that sulfur condensation at a similar environmental metallicity has similar efficiency in the two environments.
4. Elemental Enrichment
PNe are major sources of C and N in the Universe. According to Kobayashi & Taylor [
17], 45% of carbon and 74% of nitrogen originates in LIMS nucleosynthesis. We compared [C/H] and [C/O] to [O/H] in RGs and PNe, and noted qualitative enrichment of both elements including when the metallicity effect is removed from the distributions. In
Figure 4, we show the [C/H] versus [O/H] plot of RGs and PNe. Similarly to depletion, we measure carbon and nitrogen enrichment in our sample of PNe with reference to the RG median line at the same [O/H] value. We found an average [C/H] enrichment of PNe with reference to the underlying progenitor population of <E[C/H]> = 0.332 ± 0.460 dex, and an average [N/H] enrichment of <E[N/H]> = 0.393 ± 0.421 dex. If we limit our analysis to the PNe that have gone through the hot-bottom burning (HBB) during their progenitor evolution, we note an enhancement in the [N/H] enrichment of these PNe with respect to the underlying stellar population, with <E[N/H]> = 0.980 ± 0.243.
5. Radial Metallicity Gradients
Radial metallicity gradient evolution is a powerful tool to constrain galaxy evolution, and it is based on the [O/H] observation of galaxies at different redshifts, i.e., cosmic ages. Curti et al. [
18] and others have shown that most observed galaxies follow the inside-out spiral formation with enhanced feedback, based on their radial abundance gradients. To determine radial metallicity gradient evolution, one could compare gradients of presumably similar galaxies at different redshifts, or use populations of different ages in the same galaxy. PNe and evolved stars in the galaxy can be used to determine gradient evolution more accurately than other pairs of stellar populations, since the radial migration/age difference between the two is minimal. The underlying assumption is that the observed [O/H] distribution in PNe is the same of the original progenitor formation cloud, back to redshift z ≤ 2.
In
Figure 5, we show the radial oxygen gradients of the RG and PN populations described above. Distances for the PNe are from the Gaia DR3 Galactic PN distance scale by Bucciarelli & Stanghellini [
7]. PNe and RGs have similar, flat radial metallicity gradients, with marginal slope difference, within the scatter of the distributions.
To test gradient evolution for RGs, we could use ages
predicted from APOGEE stellar spectra, via a Bayesian convolutional neural network model, trained on asteroseismological stellar ages [
19], but we would face large relative uncertainties, especially for young populations; thus, gradient evolution measured with those ages would be rather uncertain.
6. Conclusions and Future Endeavors
We performed a comparative analysis of abundances of Galactic PNe in the Parker et al. [
6] catalog, and RG stars from the APOGEE DR17 survey, based on sample pairs with compatible metallicity ([O/H]) and spatial (RG and z) distributions. We found that iron is depleted in PNe, with <D[Fe/H]> = 1.74 ± 0.49. This means that, on average, only 2% of the iron that is present on the RG atmospheres is observed in PNe in gaseous form, while most of it is in solid-state compounds. The depletion amount slightly increases with PN metallicity. We also found that sulfur is also depleted in PNe at a much lesser degree than iron.
We also found that the median [C/H] enrichment is ∼0.3, and the median [N/H] enrichment is ∼0.4, with respect to the median underlying RG population of the same metallicity. Furthermore, PNe whose progenitors have gone through the HBB have extreme [N/H] enrichment. We examined the radial metallicity gradients of PN and RG populations that are compatible in metallicity and space distributions. Both gradients were flat and comparable within the error bars.
In the future, we plan to examine the radial gradients in more detail with compatible samples of PNe and RGs that have different ages, possibly based on improved ages determined from asteroseismology.
Author Contributions
All authors participated in the research project and collaborated for the final results. All authors have read and agreed to the published version of the manuscript.
Funding
This research received no external funding.
Data Availability Statement
No new data were created or analyzed in this study. Data sharing is not applicable to this article.
Acknowledgments
L.S. thanks Paolo Ventura and Flavia Dell’Agli, and all other meeting organizers, for a very constructive meeting and discussion.
Conflicts of Interest
The authors declare no conflicts of interest.
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