1. Introduction
The traditional injection molding manufacturing process is still the mainstream processing method in the plastics industry due to its low processing cost, fast production speed, large production volume, and formable products with complex shapes.
The molding principle is to plasticize plastic pellet particles, transforming the raw materials into a molten state by the action of external heat and the sheer heat generated by screw rotation. The molten polymer is injected into a pre-designed mold cavity through screw advancement and molded into the shape of the mold design. The output product quality [
1] is a function of the processing conditions, melt quality, material property, mold design, and machine parameter setting; any changes in the above will deliver a defective product with short shot, flash, air bubbles, silver streaks, warpage, shrinkage, etc.
In an injection molding process, factors [
2] that affect the final quality of the product include the quality of the plastic pellets, the injection speed, the injection pressure, the packing pressure [
3], the melt temperature, and the mold temperature. Among the many variable factors, plastic pellets determine the mechanical properties of the product [
4].
Most plastics can absorb moisture from the air before production. This ability is influenced by the type of plastic material used, environmental conditions, drying temperature and time, and so on. Hygroscopic materials [
5] such as polyurethane, acrylonitrile butadiene styrene, polycarbonate, and others, can absorb moisture even after drying when exposed to the atmosphere. If the plastic pellets contain moisture even after drying, the absorbed moisture will cause many difficulties in the molding and processing of the product part. Furthermore, the internal quality [
6] of plastic products will significantly deteriorate, resulting in polymer degradation [
7]; product quality is reflected in the appearance of silver streaks [
8], scorch marks, air bubbles, and poor surface finish, and a decrease in product surface transparency [
9] that can be observed with the naked eye. Consequently, the effect of moisture produces additional plastic waste in an injection molding process, affecting the sustainability of the production process. Research scholars have conducted studies to improve the surface quality. For example, Heinzler [
10] proposed a method to compensate for the influence of moisture content in plastic pellets on molded parts quality by combining the pressure controller with a switching point and feedback control of the injection pressure during the injection stage. Dong G and Zhao G [
11] “investigated the morphology evolution and elimination mechanism of bubble marks on the surface of microcellular injection-molded parts with dynamic mold temperature control”. Dyi-Cheng Chen and Tse-Hsi Chen [
12] explored the effect of gate design on the surface finish of thin-film components according to process parameter injection pressure and injection rate. These methods help to improve the surface finish of product parts and reduce the appearance of air bubbles in the final product part. However, these studies did not determine the effect on injection molding parameters of moisture content or propose a method to regulate the generation of air bubbles in the plasticization stage in an injection molding process.
The materials are affected by moisture factors, so it is necessary to use a dryer to reduce the moisture content in the material to ensure consistency in the process and product quality. However, using a traditional 50 kg drying machine with a daily power consumption of 4.5 kilowatt hours and a required drying time of 2 to 4 h before production, the accumulated power consumption is very great. In large-scale plastic molding processing plants, a larger number of dryer machines are required to cooperate with each other to maintain an uninterrupted supply of production materials. Moreover, high electricity consumption not only does not meet green production standards, but also increases the company’s economic expenditure on dryer machine purchases. Therefore, the objective of this study is to investigate the influence of plasticization parameters on moisture content and to assess if the moisture in the pellets can be removed directly during the plasticizing stage; this will enable reduction in the drying time, avoid possible problems with absorbed moisture, and power-saving to achieve green production standards.
In injection molding, the maximum allowable moisture content is typically low [
13], which can be adjusted based on material properties. If the pellet has an excessive moisture content, then some plastic materials will react with the water vapor at high temperature, and air bubbles will be generated [
14] by mixing with the molten material during the plasticization process. These air bubbles are injected into the mold cavity during the injection phase, resulting in an air bubble defect in the output product part as nearby air bubbles fuse together to form one big bubble form. The size and number of air bubbles that appear in the final product part vary throughout the process based on the melt temperature, screw rotation rate, melt pressure, and melt state of the melt resin. D.V. Rosato and Marlene G. Rosato [
15] proposed that surface defects, such as splay marks and silver streaks, are most often caused by bubbles in the melt coming from moisture, trapped air, etc. They suggest that appearance properties are heavily influenced by the plasticization variables of screw rotation, back pressure, and melt temperature and suggest that higher screw rotation and melt temperature cause more bubble formation since the melt is less viscous, while M. Joseph Gordon [
16] suggested that back pressure removes trapped air, gases, and moisture from the pellet. All these exemplify that the generation of air bubbles, splay marks, and silver streaks, due to material moisture, is heavily influenced by the plasticization variables, melt quality, and melt temperature. According to Amano and Utsugi [
17], plasticization melt quality and melt temperature is determined by the processing operating conditions, such as screw speed rotation, barrel temperature, barrel resident time, and the effect of shear heating and heat absorption rate on the molten resin. Dontula [
18] successfully assessed the impact of screw speed, back pressure, and injection stroke on melt temperature distribution using infrared sensors. Similarly, Jian-Yu Chen [
19] assessed the online quality monitoring of melt resin variation by placing a pressure sensor on the load cell, nozzle, and mold cavity and by attaching four strain gauges on the tie bars of the machine. He repeated the experiment with different back pressure, barrel temperature, and screw speed rotation level, and assessed pressure, viscosity, and energy quality indexes. Many of these studies indicate that variation in melt temperature and melt quality at the plasticization stage is heavily dependent on the effect of screw rotation, back pressure, and melt temperature. Furthermore, the melt temperature and melt quality of the polymer plays a key role in the generation of bubbles in the injection molding plasticization process. Thus, the effects of plasticization variables, the impact of material moisture content, and resin melt state quality are inextricably linked with each other and an experimental study is required to analyze the output response.
For this purpose, factorial design analysis has proven to be an effective, reliable, and cost-effective solution in investigating the effect of each parameter variable with the influence of moisture content on the output response. Factorial designs [
20] are experimental studies that use more than one independent variable to study the effect on the output response. The factorial design of the experiment (DOE) table provides a very simple way to run an experiment with multiple factors and levels in an effective manner to analyze the output response with multivariate statistics. When it is essential to define which factor is statistically significant for an output response, a factorial design approach is frequently used [
21]. In this study, the hygroscopic material used to conduct the experiments was thermoplastic polyurethane. Thermoplastic polyurethane (TPU) [
22] is a class of thermoplastic elastomers that have the material properties of both plastic and rubber. Because of their excellent tensile strength, high elongation at break, and good load-bearing capacity, TPU has been found useful in a wide range of indoor, outdoor, underwater, and biomedical applications. It also has exceptional mechanical, physical, and chemical properties, as well as biocompatibility. Moreover, the hydrolysis resistance property [
23] of TPU helps to identify the most significant plasticization parameters. By comparison, the appearance of splay marks, silver streaks, etc., due to material moisture, is most often found to occur with transparent hygroscopic polycarbonate material.
5. Conclusions
The experimental work in this paper supports a new innovative method to reduce the required drying time of plastic resin material, thereby promoting green production standards in the injection molding manufacturing process. Moreover, this study provides an alternative approach to minimize the appearance of moisture-induced defects, such as air bubble formation, silver streaks, etc., in the molded sample, by optimizing plasticization parameters instead of using a dryer. A factorial design multivariate statistical analysis with polyurethane material was used to determine the influence of plasticization parameters that have a significant effect on the moisture content at a 95% confidence interval (α = 0.05). Experimental analysis using polycarbonate material revealed that the plasticization parameters, screw speed, back pressure, and barrel temperature had a significant influence in controlling the effect of moisture. It is possible to suppress the formation of air bubbles, silver lines, etc., on the molded part by optimizing the plasticization parameters, by lowering the barrel temperature and screw speed and by increasing the back pressure. Comparing the glossiness measurement value of the product part produced with a moisture content of 600 ppm, 98.1 GU with the properly dried material with 100 ppm, 98.4 GU, shows that, through reasonable plasticization parameter correction, the standard deviation of the gloss data with moisture content was 0.6, which meets the gloss requirements of qualified products. Accordingly, the surface quality of the product part produced with moisture content can be improved and it is possible to reduce the drying time by changing the plasticization parameter. Furthermore, this study provides an alternative approach to reduce the impact of moisture-oriented air bubble formation, and other defects in the molded sample, even after drying and changing climatic conditions.