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Article

Study of the Improvement of Disintegration Efficiency and Antibacterial Properties of Disposable Toilet Seat Cover Sheet Made of Cellulose Fibers

by
Ju-Hyun Park
1,
Chul-Hwan Kim
1,*,
Hyeong-Hun Park
1,
Tae-Gyeong Lee
1,
Min-Sik Park
2 and
Jae-Sang Lee
2
1
Department of Forest Products, Institute of Agriculture and Life Sciences (IALS), Gyeongsang National University, Jinju 52828, Republic of Korea
2
Department of Environmental Materials Science, Gyeongsang National University, Jinju 52828, Republic of Korea
*
Author to whom correspondence should be addressed.
Appl. Sci. 2024, 14(16), 7431; https://doi.org/10.3390/app14167431
Submission received: 30 July 2024 / Revised: 16 August 2024 / Accepted: 20 August 2024 / Published: 22 August 2024
(This article belongs to the Section Applied Industrial Technologies)
Browse Figures
Versions Notes

Abstract

:
The growing prevalence of disposable toilet seat covers in public restrooms stems from concerns about personal hygiene, given the direct contact between the seat and various users’ skin. To enable these disposable cover sheets to be flushed down the toilet instead of being discarded in the trash, they must possess specific properties. These include rapid water absorption for quick disintegration, strength to endure user movement or moisture on the toilet seat surface, and a comfortable texture. To address these challenges, the study investigated the disintegration characteristics of flushable cover sheets prepared under different refining conditions. Alkyl ketene dimer (AKD) was also employed to enhance water resistance, while an organic antibacterial agent was used to impart antimicrobial properties. The findings revealed that adding 0.2% AKD and 1% organic antibacterial agent to pulp stock with a freeness of about 650 mL CSF was suitable for manufacturing disposable cover sheets with disintegration characteristics like toilet tissue paper.

1. Introduction

The COVID-19 pandemic has demonstrably increased public awareness of personal hygiene and its role in preventing the spread of infectious diseases [1]. This heightened awareness is reflected in the increased use of personal protective equipment such as disposable masks, gloves, and hand sanitizers [2]. For example, one survey documented an almost 9000% increase in the proportion of face masks found in litter within a year of the pandemic’s start [3]. Additionally, the demand for multipurpose disposable wet wipes has surged globally since the recent pandemic [4]. For instance, the occurrence of these wipes on beaches increased by 94% in 2016 alone, marking a 400% rise over the past decade. On a single stretch of the Thames shoreline in the UK, over 23,000 wet wipes were collected [5,6,7].
While these practices significantly contribute to reducing viral transmission and protecting public health, it is crucial to acknowledge that the disposable products market was already experiencing growth before the pandemic due to various factors such as increased urbanization, rising disposable income, and changing lifestyles.
A survey conducted by Evey at the California State Science Fair in 2015 [8] indicated that 51 percent of respondents used a paper toilet seat cover, with an average usage of 14 sheets of toilet paper per flush. It is worth noting that one toilet seat cover is approximately equivalent to seven sheets of toilet paper. Concerning the impact of the COVID-19 pandemic, the global disposable toilet seat cover sheet market size was estimated to be USD 525.7 million in 2022, and it is projected to reach a revised size of USD 602.5 million by 2028, with a compound annual growth rate of 2.3 percent during the review period, as demonstrated by 360 Research Reports [9].
The increased use of disposable toilet seat covers after the pandemic can be attributed to several factors: firstly, the pandemic heightened awareness about the importance of maintaining cleanliness and hygiene to prevent the spread of infectious diseases. Toilet plumes could play a contributory role in the transmission of enteric diseases. Common toilet hygiene measures include handwashing, hand drying, disinfecting, or covering the toilet seat surface before use, and flushing the toilet with the lid closed [10]. In addition, it was recognized that outpatients were sharing toilet facilities with other patients, potentially staff and visitors, in some areas of the hospital. This raised the possibility that vector transmission could occur due to contact with the toilet seat [11]. As such, disposable toilet seat covers offer individuals a convenient way to protect themselves from potential contaminants in public restrooms, thus addressing heightened hygiene concerns. Secondly, disposable toilet seat covers are convenient and easy to use. They offer a quick and hassle-free solution for individuals who prefer not to make direct contact with toilet seats in public restrooms. The convenience factor likely plays a significant role in their widespread adoption. Thirdly, the pandemic has spurred cultural shifts towards a greater emphasis on personal hygiene and cleanliness. Public toilets are a potential source of infection because they are contaminated with microbes from the gut every time they are used for going to the bathroom. Being wet provides ideal conditions for the survival and growth of microbes, these microbes are clear vectors for disease transmission [12]. As a result, individuals may be more inclined to use disposable toilet seat covers as part of their efforts to maintain hygiene standards in public settings. Therefore, the combined effect of the pandemic-induced hygiene awareness and pre-existing growth trends likely led to the widespread use of disposable toilet seat covers observed after the pandemic.
While flushing disposable toilet seat covers might seem ideal, it is not recommended due to the materials they are made of. These seat covers typically consist of paper or non-woven fabric [13]. Non-woven fabric is extensively used in the medical field and in protection against biological agents in other sectors [14]. Even though paper is hydrophilic, it may not disintegrate quickly enough in water to avoid clogging, especially without additional aggressive treatment. Non-woven materials with improved liquid-repellent, virus-proof, and bacterial-resistance finishes have been developed for applications such as surgical masks, gowns, drapes, etc. [14]. On the other hand, non-woven fabric is relatively hydrophobic and non-wettable with water [15], does not break down in water at all, and can contribute significantly to plumbing problems. Therefore, discarding disposable toilet seat covers in a designated waste receptacle is better than flushing them down the toilet [16].
Disposing the toilet cover in a separate waste receptacle after use could worsen the environmental impact by increasing household waste. A more sustainable solution is to use toilet covers made from biodegradable cellulose fibers rather than non-degradable materials. Furthermore, the most desirable option is to flush the used toilet cover paper, minimizing both waste and environmental impact.
For disposable toilet cover paper to be discarded with water and avoid clogging, it must possess specific properties. Like toilet paper, the cover sheet must absorb water fast enough and disintegrate well in water, ensuring an effective breakdown during flushing and preventing blockages in the toilet or pipes. Additionally, it should possess sufficient physical strength to withstand the weight and movement of toilet users on the toilet cover. ISO 12625-17 [17,18] describes a standard test method for evaluating the disintegration rate of tissue products by placing the tissue product in deionized water under specified conditions, agitating it, and then pouring it onto a sieve of specified size to measure the weight of the residue [19].
This study aimed to develop a flushable toilet seat cover sheet as a more environmentally friendly alternative to disposable covers, replacing both non-biodegradable plastic and paper options requiring separate waste disposal. To achieve this, it was necessary to enhance the water absorption capability and the durability of the paper material compared to current products on the market. By doing so, the intention is to reduce the volume of waste generated from toilet seat covers that cannot be disposed of via flushing, thereby minimizing the environmental impact by ensuring the covers can be safely and conveniently disposed of within the restroom facilities.

2. Materials and Methods

2.1. Raw Materials

Bleached hardwood kraft pulp (Hw-BKP) of Moorim P&P Co., Ltd. Jinju, in Korea was used to make a base paper for a disposable toilet cover sheet. Hw-BKP was beaten to 300–500 mL CSF using a laboratory single disk refiner (KOS1 Co., Gimhae, Republic of Korea) at 800 rpm. During the stock preparation stage, the chemicals and antibacterial agents (refer to Table 1) were added to a 1 L beaker containing the pulp suspension at 1% consistency and stirred at 1100 rpm for 180 s. According to ISO 5269-1, laboratory handsheets with a basis weight of 22 ± 2 g/m2 were prepared in 25 × 25 cm and about 30 μm in thickness using the pulp stock for physical and antibacterial testing. The types and amounts of chemicals used to improve the water resistance, antibacterial properties, and retention of pulp fibers and an antibacterial agent are summarized in Table 1.

2.2. Test for Antibacterial Test

Antimicrobial testing of cover sheets was conducted according to the guidelines of the CLSI document M02 [20]. Specimens with a diameter of 1 cm were collected from the antibacterial cover sheets. The specimens were sterilized through autoclaving at a temperature of 121 °C for 15 min to ensure the elimination of any potential contaminants. A loopful of the E. coli culture was inoculated into a suitable broth and incubated at 37 °C for a period of 18 to 24 h, allowing the bacteria to proliferate in the incubator (NB-205Q, N-BIOTEK, Bucheon, Republic of Korea). The cover sheet disks were then placed on agar previously inoculated with the test bacterium Escherichia coli (E. coli) using sterile forceps. The inoculated agar plates containing the cover sheet disks were incubated at 37 °C for 18 to 24 h.
If the disks of the cover sheets have high antibacterial activity, a transparent zone or ring will form around them. The larger the zone of inhibition, the greater the antibacterial effect of the cover sheet.

2.3. Water Resistance Test

A self-developed device (Water Resistance Tester, Gyeongsang National University, Jinju, Republic of Korea) that simultaneously measures sizing degree and contact angle was used to evaluate the water resistance of disposable toilet seat covers [21,22]. As shown in Figure 1, this automatic device helps assess the liquid penetration into the specimens and the hydrophobic properties of the surfaces of the specimens.
The device comprises a specimen stage, a liquid droplet dispenser, a digital camera, and analysis software. The dispenser was used to drop around 18.5 mg of 6% FeCl3 (II) onto the surface of the toilet seat cover sheet that was on the 6% NH4SCN solution. The digital camera was used to record the change in the color of the liquid droplet. The software records and analyzes the change in the droplet’s contact angle and the end point at which the droplet turns reddish-brown when two reagents react [23].

2.4. SEM Image

To observe the surface structure of the cover sheet made from refined pulp fibers, images were captured using a Field-Emission Scanning Electron Microscope (FE-SEM, JSM-7610F, JEOL, Tokyo, Japan). The FE-SEM was operated under optimized conditions to achieve high-resolution imaging, allowing for detailed visualization of the fiber morphology. Specifically, the images illustrated how the refining process enhances the bonding between fibers, thereby increasing the cover sheet’s inter-fiber connectivity and overall structural integrity. This detailed examination using FE-SEM was crucial for understanding the microstructural changes induced by the refining process and their impact on the material properties of the cover sheet.

2.5. Testing Methods for Physical Properties

Tensile strength, tear strength, and surface roughness were measured according to the standard methods including ISO 1924-3, ISO 1974, and ISO 8791-4.
To evaluate the suitability of a disposable toilet cover sheet for disposal via flushing, an 11.4 cm × 10 cm sample was placed in 500 mL of distilled water within a beaker. The water was agitated at 600 revolutions per minute (rpm) using a three-winged propeller. Subsequently, the disintegration rate of the toilet cover sheet was determined and compared to that of conventional toilet paper under identical conditions.

3. Results and Discussion

3.1. Disintegration Rate

The disintegration rate of disposable toilet seat cover sheets is a critical parameter influencing both user comfort and the environmental impact of the product [24]. Figure 2 illustrates how the disintegration rate varies with different levels of freeness and the addition of AKD (alkyl ketene dimer). This study investigates the effects of refining and AKD addition on the disintegration rate, aiming to optimize the balance between product performance and user convenience.
The study examined disposable toilet seat cover sheets prepared with varying levels of pulp freeness and AKD addition. AKD was incorporated into the pulp stock to enhance the hydrophobic properties of the cover sheets, thereby preventing liquids from being readily absorbed and improving user comfort [25]. The disintegration rate was measured as the time taken for the sheets to fully break down in water, compared to standard toilet tissue paper.
The results indicate that the non-sized cover sheets (without AKD) disintegrated in approximately 23 s, which is about 10 s longer than the disintegration time for standard toilet tissue paper (13 s). The refining process, which subjects the fibers to compression and shear forces, appears to impact the disintegration rate negatively. The morphological changes in pulp fibers during refining enhance inter-fiber bonding, making the cover sheets more resistant to disintegration. Interestingly, the difference in freeness after refining did not significantly affect the disintegration rate of the cover sheets. The addition of AKD was found to be a more significant factor. Increased levels of AKD led to slower disintegration rates, as the cover sheets became more resistant to water absorption [26,27]. However, when AKD was added to the unrefined pulp stock, there was a slight improvement in the disintegration rate, although this effect was not substantial compared to the impact on refined pulp stocks.
The findings highlight the complex interplay between fiber morphology, refining, and chemical additives in determining the disintegration rate of disposable toilet cover sheets. Non-sized cover sheets, while quicker to disintegrate, do not provide the same level of user comfort due to their higher water absorption. On the other hand, cover sheets with higher levels of AKD, while more comfortable, disintegrate more slowly, posing potential issues for disposal in toilets.
As shown in Figure 3, the SEM image displaying the surface structure of the cover sheet made from refined pulp fibers illustrates how the refining process increases inter-fiber bonding [28]. This enhancement contributes to the durability and structural integrity of the cover sheets but comes at the expense of disintegration efficiency [29]. This emphasizes the need for a balanced production approach, where the benefits of refining and AKD addition are carefully weighed against the disintegration requirements.

3.2. Sizing Degree and Contact Angle

Figure 4 compares the Stöckigt sizing degree and the contact angle of the disposable toilet cover sheets based on different levels of freeness and AKD addition. The Stöckigt sizing degree measures how long it takes for a specific solution to penetrate the paper. A higher sizing degree indicates that the paper takes longer to absorb the solution, making it more water-resistant. On the other hand, the contact angle is a direct measure of the wettability of the material surface. A high contact angle (above 90°) typically indicates that the surface is hydrophobic (water repellent), whereas a low contact angle suggests that the surface is hydrophilic (water attractive).
The cover seat must immediately resist the absorption or penetration of moisture from the toilet seat surface but must not maintain this resistance for too long after being submerged in water within the plumbing system. Without a sizing agent, liquid readily penetrated the cover sheets irrespective of the freeness levels like the toilet paper in Figure 4. Thus the sizing degree and contact angle for the toilet paper could not be measured due to fast absorption. As AKD was added, the time it took for the liquid to penetrate the cover sheet began to lengthen, and when more than 0.4% AKD was added, the penetration time took over 100 s [30,31]. Therefore, to alleviate users’ discomfort caused by moisture absorption in the cover sheet, adding 0.2% AKD or less was found to be ideal to sufficiently delay absorption or penetration. This is because AKD forms covalent bonds with the cellulose fibers, creating a durable hydrophobic layer. Several studies have also shown that AKD can retain its sizing efficiency for several years under normal storage conditions, except when exposed to extreme environmental conditions [32,33,34,35].
The contact angles of disposable toilet cover sheets made of disintegrated pulp fibers were lower (85–95°) than those made from refined pulp fibers [36,37]. The difference in contact angles between cover sheets made from disintegrated and refined pulp fibers could also be linked to fixing AKD onto the cellulose fibers. AKD, which imparts hydrophobicity to paper, more significantly adhered to the refined pulp fibers with more fibrils, resulting in a greater contact angle [38]. Variations in AKD retention levels between the two types of pulp fibers could affect the surface wettability and hydrophobicity of the cover sheets, leading to differences in contact angles.
In conclusion, the disposable toilet cover sheets prepared from disintegrated pulp fibers displayed lower contact angles, signifying a slightly greater affinity for water interaction than those from refined pulp fibers. This attribute suggests that they may be better suited for disposal through a toilet system when compared to cover sheets made from refined pulp fibers. The enhanced water interaction implies easier disintegration in water, as shown in Figure 2, potentially leading to more efficient disposal and reduced environmental impact. At the same time, the cover sheet with only 0.2% AKD will not readily absorb moisture from the toilet cover surface, contributing to lowering the discomfort of toilet users caused by contact with moisture. When the cover sheet is flushed down the toilet, AKD is considered relatively safe for the environment when used in controlled amounts. This can be confirmed by the fact that there have been no reports indicating that discarded paper and paperboard in the soil hurt the soil environment.

3.3. Physical Properties

The surface roughness and tensile strength of toilet seat cover sheets containing 0.2% AKD, which exhibited a disintegration rate comparable to toilet paper and water-repellent properties, were compared under different freeness conditions.
Surface roughness is a critical attribute of toilet seat cover sheets that directly affects user comfort. This study investigates the impact of pulp freeness on the surface roughness of toilet seat cover sheets containing 0.2% AKD (alkyl ketene dimer). Figure 5 illustrates the surface roughness of these sheets prepared under different freeness conditions.
Toilet seat cover sheets were prepared by incorporating 0.2% AKD into pulp stocks with varying levels of freeness. The surface roughness of the sheets was measured to assess the tactile smoothness perceived by users. Freeness, a measure of the drainage rate of a pulp slurry, was adjusted through refining processes, which fibrillate the fibers and potentially alter the surface characteristics of the final product.
The results indicate that refining slightly improved the surface roughness of the toilet seat cover sheets, making them marginally smoother. However, no significant difference in surface roughness was observed based on changes in freeness levels. This suggests that the tactile smoothness of the cover sheets, as perceived by users, remains almost identical regardless of the freeness of the pulp used. The slight improvement in surface roughness with refining can be attributed to the mechanical processing of fibers, which creates a more uniform and less coarse fiber network. Refining causes fibers to undergo compression and shear forces, leading to fibrillation and the creation of finer fiber elements that contribute to a smoother surface. Despite this, the study found that variations in freeness did not significantly impact the surface roughness. The consistent tactile smoothness across different freeness levels suggests that users will have a similar sensory experience with the toilet seat cover sheets, irrespective of the processing variations in pulp freeness. This uniformity in surface roughness is beneficial from a manufacturing perspective, as it allows for flexibility in the refining process without compromising user comfort.
It is necessary to note that rough surfaces provide more area for bacteria to attach than smooth surfaces [39]. Moreover, disposable cover sheets are manufactured from biodegradable cellulose fibers and have many voids, making them more susceptible to bacterial contamination. Therefore, considering the rough surface structure, the presence of many voids, and the characteristics of cellulose fibers, it is essential to recognize that disposable cover sheets require antimicrobial treatment to prevent bacterial contamination.
These findings have practical implications for the production of toilet seat cover sheets. Manufacturers can achieve the desired surface smoothness without heavily focusing on adjusting freeness levels. This can streamline the production process, reduce costs associated with extensive refining, and ensure consistent product quality. The slight improvements in surface roughness due to refining are beneficial but not critical, allowing for greater flexibility in manufacturing parameters.
Tensile strength is a key mechanical property that determines the durability and performance of toilet seat cover sheets. This study investigates the impact of pulp freeness on the tensile strength of these sheets [40,41]. Toilet seat cover sheets were prepared from pulp stocks with different levels of freeness, which were adjusted through refining processes. Freeness, measured as the drainage rate of a pulp slurry, influences the extent of fiber bonding and network cohesion [42]. Refining involves mechanical processing that fibrillates the fiber surfaces, increasing their surface area and creating a more entangled and interconnected fiber network. As shown in Figure 6, the results indicated that cover sheets made from unrefined fibers exhibited fewer contact points and entanglements between neighboring fibers, resulting in weaker bonds and a less cohesive network. Consequently, the tensile strength of these unrefined sheets was similar to that of 2-ply toilet tissue paper with a basis weight of 28 g/m2, approximately 0.13 kN/m. In contrast, refining significantly enhanced the tensile strength of the cover sheets. The mechanical processing during refining increased the fiber surface area and created a more uniform, entangled, and interconnected fiber network. This enhanced bonding capability resulted in a much stronger and more cohesive fiber network, leading to a meaningful increase in tensile strength.
The study highlights the crucial role of refining in improving the tensile strength of toilet seat cover sheets. Unrefined fibers, with their limited contact points and weak bonding, result in lower tensile strength, comparable to standard 2-ply toilet tissue paper. The lack of sufficient fiber entanglement and bonding leads to a less cohesive fiber network, reducing the mechanical robustness of the cover sheets. Refining significantly alters the fiber morphology by applying compression and shear forces that fibrillate the fibers [43,44]. This increases their surface area and creates a more interconnected and entangled network, enhancing the bonding capability between fibers and resulting in a stronger and more cohesive fiber network [45,46]. The improved tensile strength of the refined cover sheets demonstrates the effectiveness of refining in enhancing the mechanical properties of the product.
From a practical standpoint, refining is a critical step in the production of high-strength toilet seat cover sheets. Manufacturers can optimize the refining process to achieve the desired tensile strength, ensuring that the cover sheets are durable and capable of withstanding the mechanical stresses encountered during use. The enhanced tensile strength also contributes to user satisfaction by providing a more reliable and robust product.

3.4. Antibacterial Test

The incorporation of antibacterial agents into toilet seat cover sheets can provide significant hygiene benefits, particularly in public or high-traffic restrooms where the risk of bacterial contamination is higher [47]. Figure 7 highlights the antibacterial properties of toilet seat cover sheets containing 0.2% AKD (alkyl ketene dimer) and an organic antibacterial agent. The organic antibacterial agent (Zinc Omadine™, zinc pyrithione, Ahsung Fine Chemical Co., Ltd., Pyeongtaek, Korea) easily blends with cellulose fibers. Pyrithione-based agents exert antibacterial activity in the cover sheets by destroying cell membranes.
A powder-type organic antibacterial agent was chosen to enhance the retention and efficacy of the antibacterial properties within the fiber network. To attach organic antibacterial agents to cellulose fibers, cationic retention aids were used. The cationic retention aid acts as a bridging agent to attach organic antibacterial agents to cellulose fibers. It works by neutralizing the negative charges on both the fibers and the antibacterial agents, forming stable complexes that ensure the antibacterial agents are effectively retained in the paper. The toilet seat cover sheets were prepared with varying concentrations of the antibacterial agent to determine the minimum effective concentration.
The findings indicate that toilet seat cover sheets made solely from pulp fibers or with antibacterial agents added at concentrations below 1% showed no noticeable antibacterial effect. The antibacterial activity was significant only when the added antibacterial agent constituted at least 1.0% of the total dry weight of the pulp fibers. This threshold concentration is crucial for ensuring the effectiveness of the antibacterial properties in practical applications.
The results underscore the importance of the concentration of antibacterial agents in achieving significant antibacterial activity. At concentrations below 1%, the antibacterial agents are insufficient to provide any noticeable effect, likely due to inadequate coverage and interaction with bacteria. However, when the concentration reaches or exceeds 1%, the antibacterial agents are more effectively retained within the fiber network, providing a robust antibacterial effect. The use of powder-type organic antibacterial agents is particularly advantageous for this application. The powder form enhances the retention of the agent within the fiber network, ensuring sustained antibacterial efficacy [48]. This is essential for maintaining the hygiene benefits of the toilet seat cover sheets over time.
The incorporation of antibacterial agents in toilet seat cover sheets offers additional hygiene benefits in environments with high bacterial contamination risks. Public and high-traffic restrooms, in particular, can benefit from this added layer of protection. The antibacterial properties help reduce the spread of germs, promoting a cleaner environment and providing peace of mind for users with health concerns or heightened awareness of hygiene. However, it is also true that strict restrictions on usage are necessary, as there are reports indicating that even low concentrations of antimicrobial agents can cause disruptions in aquatic systems [49,50].

4. Conclusions

Disposable toilet seat covers for public restrooms must be flushable, durable, water-resistant, and soft. This study optimized a stock preparation by varying pulp freeness, adding 0.2% AKD for water resistance, and incorporating a 1% organic antibacterial agent. Non-sized cover sheets disintegrate more slowly than toilet tissue. Refining enhances inter-fiber bonding but impairs disintegration, while increased AKD levels improve water resistance but slow disintegration. A balance between refining and AKD levels is crucial. Refining slightly smooths the surface and significantly enhances tensile strength by creating a more entangled fiber network. Optimal preparation includes a freeness of 650 mL CSF, 0.2% AKD, and 1% antibacterial agent, ensuring flushability, strength, water resistance, and hygiene. Lower concentrations or the absence of the antibacterial agent showed no noticeable antibacterial effect, underscoring its necessity for significant hygiene benefits in public restrooms.
Future research should explore the environmental impact of AKD and antibacterial agents in flushable products. Additionally, studies could investigate alternative, eco-friendly antibacterial agents and their effects on disintegration and strength. Understanding the long-term biodegradability of refined fibers and AKD-treated sheets in various wastewater treatment conditions is also essential. Developing methods to enhance surface smoothness without compromising disintegration could further optimize user comfort and product performance.

Author Contributions

Research and investigation, C.-H.K., J.-H.P., H.-H.P., T.-G.L., M.-S.P. and J.-S.L.; tables and figures preparation, J.-H.P. and H.-H.P.; data curation, T.-G.L., M.-S.P. and J.-S.L.; writing—review and editing, J.-H.P. and C.-H.K. All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by the Basic Science Research Program via the National Research Foundation of Korea (NRF), funded by the Ministry of Education (Grant No. 2022R1I1A3053045). It was also supported by the Korea Basic Science Institute (National Research Facilities and Equipment Center) grant funded by the Ministry of Education (Grant No. 2022R1A6C101B724).

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The original contributions presented in the study are included in the article, further inquiries can be directed to the corresponding author.

Conflicts of Interest

The authors declare no conflicts of interest.

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Applsci 14 07431 g001
Figure 1. Simultaneous measurement device for the Stöckigt sizing degree and contact angle: (a) automatic sizing tester; (b) contact angle on the cover sheet.
Figure 1. Simultaneous measurement device for the Stöckigt sizing degree and contact angle: (a) automatic sizing tester; (b) contact angle on the cover sheet.
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Figure 2. Comparison of disintegration rate of the disposable toilet cover sheets according to varying freeness and AKD addition levels.
Figure 2. Comparison of disintegration rate of the disposable toilet cover sheets according to varying freeness and AKD addition levels.
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Figure 3. The SEM image of the surface structure of the cover sheet made from refined pulp fibers.
Figure 3. The SEM image of the surface structure of the cover sheet made from refined pulp fibers.
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Figure 4. Comparison of sizing degrees and contact angles of the disposable toilet seat cover sheets according to varying freeness and AKD addition levels: (a) sizing degree; (b) contact angle.
Figure 4. Comparison of sizing degrees and contact angles of the disposable toilet seat cover sheets according to varying freeness and AKD addition levels: (a) sizing degree; (b) contact angle.
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Figure 5. Comparison of surface roughness of toilet cover sheets made from pulp stocks with different freeness.
Figure 5. Comparison of surface roughness of toilet cover sheets made from pulp stocks with different freeness.
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Figure 6. Tensile strength and surface roughness of toilet seat cover sheets made from pulp stocks with different freeness.
Figure 6. Tensile strength and surface roughness of toilet seat cover sheets made from pulp stocks with different freeness.
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Figure 7. Comparison of the antibacterial effect of the toilet seat cover sheets.
Figure 7. Comparison of the antibacterial effect of the toilet seat cover sheets.
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Table 1. Chemicals used for preparing disposable toilet cover sheet.
Table 1. Chemicals used for preparing disposable toilet cover sheet.
Chemical TypesBrand NameAddition Level (%) 1Company
Alkyl ketene dimerHercon WI0, 0.2, 0.4, 0.6, 0.8., 1.0Solenis Korea, Gimcheon, Republic of Korea
Retention aidSR-17000.2Dongjin Industry Co., Ltd., Daegu, Republic of Korea
Organic antibacterial agentZinc Omadine™0, 0.5, 1, 1.5, 1.5, 2, 2.5Ahsung Fine Chemical Co., Ltd., Pyeongtaek, Republic of Korea
1 Based on the oven-dried weight of pulp fibers.
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MDPI and ACS Style

Park, J.-H.; Kim, C.-H.; Park, H.-H.; Lee, T.-G.; Park, M.-S.; Lee, J.-S. Study of the Improvement of Disintegration Efficiency and Antibacterial Properties of Disposable Toilet Seat Cover Sheet Made of Cellulose Fibers. Appl. Sci. 2024, 14, 7431. https://doi.org/10.3390/app14167431

AMA Style

Park J-H, Kim C-H, Park H-H, Lee T-G, Park M-S, Lee J-S. Study of the Improvement of Disintegration Efficiency and Antibacterial Properties of Disposable Toilet Seat Cover Sheet Made of Cellulose Fibers. Applied Sciences. 2024; 14(16):7431. https://doi.org/10.3390/app14167431

Chicago/Turabian Style

Park, Ju-Hyun, Chul-Hwan Kim, Hyeong-Hun Park, Tae-Gyeong Lee, Min-Sik Park, and Jae-Sang Lee. 2024. "Study of the Improvement of Disintegration Efficiency and Antibacterial Properties of Disposable Toilet Seat Cover Sheet Made of Cellulose Fibers" Applied Sciences 14, no. 16: 7431. https://doi.org/10.3390/app14167431

APA Style

Park, J. -H., Kim, C. -H., Park, H. -H., Lee, T. -G., Park, M. -S., & Lee, J. -S. (2024). Study of the Improvement of Disintegration Efficiency and Antibacterial Properties of Disposable Toilet Seat Cover Sheet Made of Cellulose Fibers. Applied Sciences, 14(16), 7431. https://doi.org/10.3390/app14167431

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