Thermomechanical Behavior of Textile Reinforced Cementitious Composites Subjected to Fire
Abstract
:1. Introduction
2. Materials and Methods
2.1. Matrix
2.2. Textile Reinforcement
2.3. Specimens
- Thickness of the concrete cover
- Time/temperature of exposure to fire
- Material of fibers
- Moisture content
- Face 2 is the face that was exposed to the fire during the fire test (also referred to as “surface” for the fire test). It is also the face that was subjected to tension during the bending test.
- Effective depth refers to the level of the most stressed fibers (starting from face 1) during the bending test. Thus, it is also the level of fibers which were closer to the exposed to fire surface, which are the fibers that were exposed to the highest temperature.
- Fiber volume fraction (Vf) was calculated only in the longitudinal direction of the specimens, in the direction of the tensile stresses during the bending test.
2.4. Fire Tests Set-up
2.5. Mechanical Tests Set-up
3. Results and Discussion
3.1. Fire-Testing Results
- Fire test 1: Series A was tested for a duration of 30 min.
- Fire test 2: Series B, C, D and F were tested for a duration of 30 min.
- Fire test 3: Series E was tested for a duration of 15 min.
3.2. Results from Coating Burn-off Tests
- The equipment that was used was a small electrical furnace with the capacity to reach 1000 °C.
- Apart from the temperature, the time of exposure also plays a significant role. The heating rate in the middle of the specimens (closest measurement to the level of the effective depth, thus, the fibers that are of interest) was almost the same in both the 15-min and the 30-min fire tests, equal to 18–19 °C/min. Therefore, the heating time was decided each time according to the target temperature and a standard heating rate of 18 °C/min.
- The cooling down of the specimens, after reaching the maximum temperature, was performed with a rate of 1.5 °C/min until a temperature of 200 °C, which is also a good approach of the cooling down rate that was measured at the 15-min fire test.
- The initial mass of the coating was calculated based on the weight of the textiles before and after coating, as provided by the technical datasheets.
3.3. Results from TRC Heating and Compression Tests
3.4. Bending Tests Results
3.4.1. Results from 15-Minute Fire Tests
- The mass loss of the coating is in the order of 20% or lower (see Figure 7); therefore, since most of the coating is still in place, the bond between the textiles and the mortar will not be completely lost as in Series A, B, C, D and F.
- Even though it is well-known that glass fibers lose their strength after being exposed to temperatures higher than 300 °C, it is also well known that carbon fibers maintain their capacity to even higher temperatures if they are not in oxidizing atmosphere [31]. Therefore, even though the glass fibers within the specimens of Series E do not provide significant load bearing capacity, the carbon fibers do.
- The matrix was exposed to a maximum temperature of 477 °C at the surface (face 2), while at the bottom side (face 1, which is subjected in compression at the flexural test, thus, it is the most contributing part of the mortar) the maximum temperature reached 317 °C. According to Table 4, the degradation of the mortar is also not critical. The loss of compressive strength is close to 20% (interpolation between 5% and 36%), while the reduction of the elastic modulus is close to 48% (interpolation between 23% and 72%).
3.4.2. Results from 30-Minute Fire Tests
- The temperature stability of the coating of the textiles seems to be the most decisive parameter regarding the residual strength of the TRC specimens, since it directly affects the bond between the matrix and the reinforcement. Thus, extra care must be given when thermoplastic coatings are used in applications with fire safety requirements.
- The increased concrete cover could potentially protect the reinforcement better than a thinner cover; however, it is suggested that the same cover be applied symmetrically, so that a high geometrical eccentricity is avoided.
4. Conclusions
- The most critical parameter that defines the residual strength of the TRC specimens after heating is the coating of the textiles. After the 15-min long fire test, where the temperature at the effective depth did not exceed 400 °C, the degradation was less severe, since the coating was not completely lost (less than 30%). The specimens in this case contained hybrid reinforcement of glass and carbon textiles and they suffered reductions of 74% and 48% in the initial and the post-cracking stiffness, respectively. The maximum force also dropped by 25%, while the corresponding maximum displacement increased by 68%.
- The textiles that were coated with a thermoplastic material retained a practically negligible residual strength after being subjected to a 30-min fire test, where the temperature at the level of the effective depth (most stressed fibers during the bending test) exceeded 500 °C. This corresponds to a mass loss of 90% or higher and is explained by the fact that the loss of the coating, which is an intermediate layer between the fibers and the matrix, leads to failure of the bond between the fibers and the matrix. The same result was observed regardless of the fiber material (glass or carbon), the thickness of the concrete cover (8 mm or 12 mm) and the moisture saturation of the specimens (0% or 50%).
- The degradation of the mortar due to the high temperature was also significant and could be another dominant parameter. Regarding the compressive strength and the elastic modulus, it was observed that the latter dropped faster with respect to the temperature of exposure. However, in both cases the degradation was not severe until 200 °C (5% and 23%, respectively), while it became critical at 500 °C (63% and 82% loss, respectively).
- The temperature profile within the cross section of the one-sided exposed specimens of TRC was not uniform. Specifically, the temperature reduction through the top part of the specimens appeared to be higher due to the lower thermal conductivity of the top, hotter, layers. Thus, the concrete cover is also a potential critical parameter that could determine the residual strength of the heated specimens. The effect of the concrete cover, though, was not quantified in this study.
- Finally, it was concluded that a highly asymmetrical design scheme can be disastrous for the case of one-sided exposure to fire, since the double asymmetry (in heating and in axial stiffness) can lead to premature failure of the specimens solely due to thermal stresses.
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Type of Textile | Roving Distance (mm) | Weight before Finishing (gr/m2) | Nominal Thickness (mm) | Yarn Failure Stress (MPa) | Yarn Stiffness (GPa) | ||||
---|---|---|---|---|---|---|---|---|---|
warp | weft | warp | weft | warp | weft | ||||
Two-dimensional (2D) glass | 12 | 12 | 284 | 284 | 0.106 | 0.106 | 526 | 67 | |
Three-dimensional (3D) glass styrene-butadiene (SBR) coated | Face 1 | 10 | 10 | 229.3 | 229.3 | 0.171 | 0.171 | 496 | 67 |
Face 2 | 18 | 9 | 229.3 | 229.3 | 0.171 | 0.171 | |||
2D carbon SBR coated | 12.7 | 12.7 | 258 | 258 | 0.143 | 0.143 | 814 | 93 |
Fire Test | Series | Type of Reinforcement | Cover Thickness (mm) | Total Thickness (mm) | Effective Depth (mm) | Time of Exposure (min) | Moisture Saturation (%) | Fiber Volume Fraction (%) | |
---|---|---|---|---|---|---|---|---|---|
Face 1 | Face 2 | ||||||||
TEST 1 | A | Glass | 4 | 8 | 28 | 20 | 30 | 0 | 2.17 |
TEST 2 | B | Glass + carbon | 4 | 8 | 28 | 20 | 30 | 0 | 1.47 |
C | Carbon | 2 | 12 | 24 | 12 | 30 | 0 | 1.82 | |
D | Glass + carbon | 4 | 8 | 28 | 20 | 30 | 50 | 1.47 | |
F | Glass + carbon | 4 | 12 | 32 | 20 | 30 | 0 | 1.29 | |
TEST 3 | E | Glass + carbon | 4 | 8 | 28 | 20 | 15 | 0 | 1.47 |
Fire Test | Duration (min.) | Series | Temperature at the End of the Fire Test (°C) | ||
---|---|---|---|---|---|
surface | middle | bottom | |||
1 | 30 | A | 638 | 525 | 437 |
2 | 30 | B | 648 | 526 | 343 |
C | - | - | - | ||
D | 650 | 530 | 343 | ||
F | 666 | 524 | 385 | ||
3 | 15 | E | 477 | 302 | 192 |
Temperature (°C) | Reduction of Compressive Strength | Reduction of Elastic Modulus |
---|---|---|
20 | - | - |
200 | 5% | 23% |
400 | 36% | 72% |
500 | 63% | 82% |
700 | 71% | 85% |
Mechanical Properties | Not Exposed Specimens (E1, E2) | Exposed Specimens (E4, E5) | Difference (%) |
---|---|---|---|
k1 (kN/m) | 1.58 | 0.41 | −74% |
k2 (kN/m) | 0.20 | 0.10 | −48% |
Fmax (kN) | 1.86 | 1.39 | −25% |
δmax (mm) | 14.1 | 23.6 | +68% |
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Kapsalis, P.; El Kadi, M.; Vervloet, J.; De Munck, M.; Wastiels, J.; Triantafillou, T.; Tysmans, T. Thermomechanical Behavior of Textile Reinforced Cementitious Composites Subjected to Fire. Appl. Sci. 2019, 9, 747. https://doi.org/10.3390/app9040747
Kapsalis P, El Kadi M, Vervloet J, De Munck M, Wastiels J, Triantafillou T, Tysmans T. Thermomechanical Behavior of Textile Reinforced Cementitious Composites Subjected to Fire. Applied Sciences. 2019; 9(4):747. https://doi.org/10.3390/app9040747
Chicago/Turabian StyleKapsalis, Panagiotis, Michael El Kadi, Jolien Vervloet, Matthias De Munck, Jan Wastiels, Thanasis Triantafillou, and Tine Tysmans. 2019. "Thermomechanical Behavior of Textile Reinforced Cementitious Composites Subjected to Fire" Applied Sciences 9, no. 4: 747. https://doi.org/10.3390/app9040747
APA StyleKapsalis, P., El Kadi, M., Vervloet, J., De Munck, M., Wastiels, J., Triantafillou, T., & Tysmans, T. (2019). Thermomechanical Behavior of Textile Reinforced Cementitious Composites Subjected to Fire. Applied Sciences, 9(4), 747. https://doi.org/10.3390/app9040747