3.1. Cone Calorimeter Analysis
Time to ignition (TTI) measures the time required for a material to transition from the start of heating to sustain combustion under a certain intensity of incident heat flux. A longer TTI implies better fire resistance of the material. Experimental data (
Table 4) show that the TTI for elm, pine, and poplar wood is 80 s, 61 s, and 52 s, respectively. Therefore, among these three types of wood samples, poplar is the most flammable, while elm wood exhibits the best fire resistance. In addition, wood samples treated with modern surface treatments demonstrate significant improvements in fire resistance, with TTI values for elm, pine, and polar increasing to 145 s, 128 s, and 103 s, representing percentage increases of 81.3%, 109.8%, and 98.2%, respectively. The results have been confirmed by previous studies on the fire performance of surface treatments on pine and beech wood [
33]. Compared to modern surface treatments, traditional treatments (Yi-ma-wu-hui) are equally effective, resulting in TTI values for elm, pine, and polar increasing to 131 s, 127 s, and 102 s, with percentage increases of 63.8%, 108.2%, and 96.2%, respectively. Although slightly less effective than modern treatments, both surface treatments significantly enhance the fire resistance of timber structural components.
Heat release rate (HRR) is a measure of the amount of heat released per unit area during the combustion process of a material under a certain heat flux, used to assess fire intensity. The peak heat release rate (pkHRR) reflects the maximum heat release of the material during combustion and is an important indicator of a fire hazard. As shown in
Figure 5, the HRR curves of pine and elm wood exhibit two peaks, with the second peak higher than the first peak. In contrast, the HRR curve of poplar wood initially shows a more gradual increase without a distinct first peak. This difference may be related to the moisture content of the different types of wood. During the initial stages of combustion, moisture in the wood evaporates and produces hydrogen gas (H
2) as a combustible material that participates in the combustion process, leading to differences in the initial peaks of heat release.
Different surface treatment methods have a significant impact on the pkHRR of wood, effectively reducing the peak heat release rate and decreasing the potential danger of flame spread. Modern surface treatment methods have led to a decrease in the pkHRR of elm, pine, poplar, and wood by 31.4%, 19.9%, and 26.4%, respectively (
Table 5). The effects of traditional surface treatment methods for elm, pine, and poplar are even more significant, with reductions of 35.3%, 18.1%, and 29.0%, respectively. Additionally, both surface treatment methods suppress heat release in the initial stages of combustion, delaying the occurrence of peaks and prolonging the duration of wood components in a fire, with the traditional method showing a more pronounced delay effect. This indicates that both traditional and modern surface treatment techniques can effectively enhance the safety properties of wood in fire scenarios, especially in terms of delaying flame development and reducing peak heat release, which helps increase response time at the fire scene.
Mass loss rate (MLR) refers to the rate of change in sample mass over time during the combustion process, reflecting the extent of volatilization and combustion of the material under a certain fire intensity. The MLR of the three types of wood samples is shown in
Figure 6, where it can be observed that the mass of the specimens changes slowly within the first 100 s of combustion, sharply decreases between 100 and 250 s, and then stabilizes after 250 s. In contrast, the mass loss of the samples applied with surface treatments is not as pronounced after 200 s, and the change in mass loss is similar for both modern and traditional surface treatment methods. This result was confirmed in previous investigations of the fire performance of different types of cedar after surface treatment [
34]. To provide a clearer representation of the rate of mass loss and understand the variation in mass loss during the combustion process, this study also recorded the mass loss rate curves for the wood samples at different time points and plotted their fitting curves (
Figure 7). Due to the nonlinear variation in the mass loss rate with time curve, a polynomial curve fitting was performed to combine the actual variation in the curve and the fitting effect. In addition, since the mass change curves of the three types of wood are similar, the analysis will focus on the fitting curve of the mass loss rate over time for elm wood. The results generally show an initial trend of decrease, followed by an increasing trend, and returning back to a decreasing trend. This indicates that wood samples undergo rapid mass loss in the early stages of combustion, with the mass loss rate gradually increasing, reaching a peak before decreasing again. In addition, it is evident that the peak time for the rate of mass loss in wood samples is significantly delayed after using modern and traditional surface treatments, with the effect being more pronounced in the traditional surface treatments.
Surface treatment alters the rate of the charring of wood, resulting in lower mass loss for untreated wood compared to wood that has undergone surface treatment within the same burning time. Although there is no consistent pattern in the total mass loss of wood samples after complete combustion, wood that has been surface-treated tends to have a longer burning time, with the peak mass loss rate occurring significantly later than in untreated wood samples (
Table 6). The results confirm that surface treatments can effectively delay the rate of wood combustion, thereby increasing its durability in a fire, and that traditional surface treatments are more effective.
Smoke production rate (SPR) is an indicator of the speed at which smoke is generated in a fire, typically expressed as the ratio of the mass of smoke produced per unit of time to the mass of the burning material. The curves show the variation in the smoke production rate for wood samples with different surface treatments (
Figure 8). It can be observed that after undergoing modern and traditional surface treatments, the time span for smoke generation significantly increases for elm, pine, and poplar wood, with wood samples treated using traditional methods showing a longer duration of smoke production.
According to
Table 7, it could be found that the total oxygen consumption, total smoke production, total smoke release, total CO release, and total CO
2 release are correlated during wood combustion. The production of CO
2 was higher when the wood was sufficiently combusted, while the production of CO and smoke was lower. CO
2 was positively correlated with oxygen consumption, while CO was negatively correlated with oxygen consumption. In addition, the smoke release is also negatively correlated with CO
2, implying that incomplete combustion results in a relative decrease in CO
2 production. Furthermore, it is evident that the total smoke released during the combustion process significantly increases for various types of wood after modern and traditional surface treatments, with the traditional surface treatment showing the most significant increase. The smoke release totals for elm, pine, and poplar wood increased by 49.3%, 62.2%, and 14.4%, respectively. Furthermore, the completeness of combustion can be assessed by calculating the ratio of carbon monoxide (CO) to carbon dioxide (CO
2) emissions. It can be observed that compared to poplar and elm wood, pine wood releases more CO after application of modern or traditional surface treatments, indicating incomplete combustion and higher fire resistance, with the effect being more pronounced after traditional surface treatment.
Overall, among the three types of wood samples without surface treatment, the fire resistance properties from highest to lowest are elm wood, pine wood, and poplar wood. After surface treatment, the fire resistance properties of these three types of wood remain consistent. In the experiment, poplar wood is more prone to combustion compared to the other two types of wood and releases more smoke during the combustion process. Although poplar wood’s average heat release rate falls between pine and elm wood, it releases more total heat due to its shorter burning time.
Both modern and traditional surface treatment methods can effectively improve the fire resistance properties of wood samples, as shown in
Table 8, where a positive value (“+”) indicates a positive effect on the fire resistance properties and a negative value (“−”) indicates a negative effect. The combustion property parameters are reflected in the prolonged ignition time, reduced heat release rate, and slowed mass loss rate, which help mitigate the loss of the mechanical properties of wood and the effects of temperature fields during a fire. However, especially with the traditional treatment method, although it delays the peak time of the heat release rate, it also leads to the generation of a large amount of smoke and incomplete combustion of the wood. In contrast, the modern treatment method produces less smoke and demonstrates a more significant advantage in increasing ignition time.
3.2. Fire Dynamics Simulation Analysis
To further explore the fire resistance properties of buildings under different surface treatment methods, the fire development process of the Xianqing Temple building was simulated using FDS, and the changes in temperature at three monitoring points were recorded, as shown in
Figure 9. During the simulation, the temperature at these monitoring points gradually increased, with monitoring point 3 (at 8.3 m) reaching the highest temperature, followed by monitoring point 2 (at 5.9 m), and monitoring point 1 showing the lowest temperature (at 1.8 m). This temperature distribution reflects the behavioral characteristics of smoke and flames in the early stages of a fire in ancient buildings, where temperatures at higher positions inside the building rise earlier and faster compared to lower positions. This is mainly because flames spread along the surface of the combustible material, and due to the upward trend of hot air and thermal currents, flames are more likely to expand upwards. Additionally, the flames heat the surrounding air, creating thermal currents. As the thermal currents rise, cold air is replenished from below, creating a cyclic convection process. Natural convection further promotes the upward diffusion of flames and thermal currents.
Furthermore, the highest temperatures at the three monitoring points reached 760 °C, 653 °C, and 680 °C, respectively. The temperature on the roof rafter quickly reaches 200 °C and stabilizes at around 330 °C, which is the typical charring temperature of wood. When the fire temperature reaches 335 s, the internal temperature of the building rapidly increases, indicating a flashover phenomenon occurring at that time.
Flashover is the most unfavorable scenario in a fire, indicating a sudden full-scale combustion inside the building. In firefighting, it is generally recognized that the period before flashover occurs in a building is the prime time to extinguish the fire to preserve the overall structure of the building. To clearly determine the timing of flashover in a building, the trend of temperature differentials at each moment compared to the previous moment was further plotted to observe the rate of temperature change over time (
Figure 10). The moment when the temperature change rate rapidly accelerates can be identified as the time when the building experiences flashover in a fire.
As shown in
Figure 10a, the flashover time of the Xianqing Temple roof rafter is approximately 370 s. After 500 s, the temperature differentials at each monitoring point change from positive to negative, indicating the highest temperatures in the building and rapid cooling in the later stages. Based on this phenomenon, it can be inferred that the building collapses at this time, with heat dissipating outward, and the temperatures at each measurement point gradually decrease to 100 °C. Combining the above analysis results, it is confirmed that when a fire breaks out at the Xianqing Temple due to the careless use of fire for sacrificial purposes, the fire should be quickly extinguished within 300 s to preserve the overall building structure.
To visually illustrate the temperature distribution of the Xianqing Temple roof rafter more intuitively, temperature distribution maps at three profiles over time were plotted (
Figure 11,
Figure 12 and
Figure 13). In order to facilitate the demonstration of the analyses and findings, during the initial stages of the fire when the temperature was slowly increasing, recordings were taken at intervals of 100 s. However, due to the rapid temperature changes in the later stages when the building experienced flashover, recordings were taken every 20 s.
From
Figure 11,
Figure 12 and
Figure 13, it can be observed that smoke initially accumulates at the top of the roof rafter inside the building and then gradually spreads to the sides and downward, eventually enveloping the entire building in a high-temperature field. This result further confirms that during a fire at the Xianqing Temple, the roof collapsed first due to the flashover.
After understanding the combustion and temperature changes in the Xianqing Temple, based on the ignition time, heat release rate, mass loss rate, and smoke production of pine, poplar, and elm wood with different surface treatments, the combustion properties of poplar wood with the worst fire resistance were selected as simulation conditions to further study the fire properties of buildings with different surface treatments. The temperature changes at different monitoring points in buildings with different surface treatments are shown in
Figure 14.
It can be observed that the Xianqing Temple main hall model without surface treatment collapsed at 492 s. However, modern and traditional surface treatment methods kept the temperature around 330 °C, with the modern treatment maintaining the collapsed temperature until 500 s after the fire started, while the traditional treatment stabilized at 330 °C until 640 s (monitoring points 3 and 2). At the same time, the temperature change at monitoring point 1, located at a lower position, remained below 200 °C. This result confirms that both modern and traditional surface treatment methods effectively prolong the time before the building ignites. Furthermore, no flashover or collapse occurred within the simulated 800 s, indicating that both modern and traditional treatment methods extended the optimal rescue time for the building by approximately 300 s.
Table 9 records the time taken for monitoring point 3 to reach the wood combustion charring temperature (300 °C). Under the no-treatment scenario, 300 °C charring temperature is reached at 91 s after the fire started, while the traditional and modern surface treatment delayed reaching the charring temperature by 37 s and 43 s, respectively. In summary, both modern and traditional surface treatment methods not only provide good fire resistance properties but also help to delay the destruction of the building and provide a longer rescue time for evacuation and firefighting in case of a fire.