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Article

Resonance Transitions in the Spectra of the Ag6+–Ag8+ Ions

by
Alexander Ryabtsev
* and
Edward Kononov
Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow 108840, Russia
*
Author to whom correspondence should be addressed.
Atoms 2017, 5(1), 11; https://doi.org/10.3390/atoms5010011
Submission received: 16 January 2017 / Revised: 14 February 2017 / Accepted: 21 February 2017 / Published: 4 March 2017
(This article belongs to the Special Issue Spectra of Ionized Atoms: From Laboratory to Space)
Browse Figures
Versions Notes

Abstract

:
The spectrum of silver, excited in a vacuum spark, was recorded in the region 150–350 Å on a 3-m grazing incidence spectrograph. The resonance 4dk–(4dk−15p + 4dk−14f + 4p54dk+1) was studied in the Ag6+–Ag8+ spectra (Ag VII–Ag IX) with k = 5–3, respectively. Several hundred lines were identified with the aid of the Cowan code and orthogonal operator technique calculations. The energy levels were found and the transition probabilities were calculated.

1. Introduction

Six- through eight-times ionized silver atoms are the members of the isonuclear sequence of the silver ions with the unfilled 4dk (k = 5–3) ground-state configuration. The spectra of these ions have not been investigated previously. The excitation of the 4d electron leads to the lowest odd configurations 4dk−15p and 4dk−14f. The third odd configuration 4p54dk+1 is formed by the excitation of the inner shell 4p electron. The resonance transitions are represented by the transitions from these odd configurations to the ground-state configuration. Out of all resonance transitions only the 4dk–4dk−14p (k = 9–6) ones were previously studied in the silver spectra of the lower ionization stages: Ag III [1], Ag IV [2], Ag V [3] and Ag VI [4]. On the other hand, all three resonance transition arrays were investigated in rather simple spectra of ions having 4d and 4d2 ground-state configurations: Ag XI [5,6] and Ag X [7]. In this article we report the results of the study of the Ag VII, Ag VIII and Ag IX to fill the gap between the Ag VI and Ag X isonuclear spectra.
This study is part of a project to get atomic data for the ions of lighter than tin chemical elements isoelectronic with Sn IX–Sn XIV which are relevant to a development of bright source for projection lithography at the 135 Å wavelength. The results for the palladium isonuclear spectra were recently published (see [8] and references therein). Such isoelectronic data are necessary for validation of previously reported analyses of the corresponding tin ion spectra [9,10]. Research on these spectra is also of general interest to atomic physics for improving of theoretical methods of calculations of multi-electron heavy atom spectra.

2. Experiment

The experimental technique and the theoretical approaches for spectrum calculations were the same as in our previous publications [7,8]. Briefly, the light source was a low-inductance vacuum spark operated with an additional inductance up to 2.5 μH. A 150 or 12 μF capacitor was charged up to 4.5 kV resulting in the spark peak current in a range of ~10–20 kA. Ionization stages were distinguished by comparing the intensities of the lines at various peak currents. A 3 m grazing incidence spectrograph (85° angle of incidence) equipped with a gold coated holographic grating having 3600 lines/mm was used for taking the spectra. A plate factor of the spectrograph in the region 160–350 Å was 0.32–0.46 Å mm−1 respectively. The spectra were recorded on Kodak SWR photographic plates (Eastman Kodak Company, Rochester, NY, USA) and measured on an EPSON EXPRESSION 10000XL scanner (Seiko Epson Corporation, Suwa, Japan). Wavelengths were calibrated using titanium ion lines [11] as the standards. The titanium spectrum was superimposed on some silver exposures. The measured wavelength uncertainty is estimated as ±0.005 Å for the unperturbed lines of moderate intensity. General view of the silver spectrum in the region 150–350 Å is shown in Figure 1, where the lines identified in this work, previously identified, and remaining unidentified are marked by different colours depending on particular spectrum.
The relative line intensities were obtained as described in our previous article [8] “from the measured optical densities using an approximate photoplate response curve estimated from different experiments. They should be considered mostly as qualitative ones because of some uncertainty of used photoplate response curve and neglect of the wavelength dependence of the spectrograph efficiency and photoplate sensitivity. Also the saturation effects resulting from the photoplate response nonlinearity can significantly influence the intensity ratios of the weak to strong lines.” The intensity I = 1000 was attributed to the strongest line of the 4dk–4dk−15p transition array in each ion spectrum.
The program IDEN [12] was used for the spectrum identification. As in [8], ab initio calculations were performed with the use of the Dirac–Fock (DF) code of Parpia et al. [13], or by the Hartree–Fock method with relativistic corrections (HF) with the use of the Cowan code (Cowan programs RCN, RCN2, RCG, and RCE) [14]. Semiempirical correction of ab initio values of Slater parameters was made with the RCE Cowan code or by using a technique of orthogonal operators [15,16,17,18].
The energies derived after the identification of spectral lines were optimized using the program LOPT [19].

3. Results

In the following, the results of the analyses of silver ions in the charge states Ag6+, Ag7+ and Ag8+ are presented. Line identifications are summarized in Table A1, Table A2, Table A3 and Table A4 (see Appendix A at the end of the document) and energy levels are collected in Table A5, Table A6, Table A7, Table A8, Table A9, Table A10 and Table A11. The data were interpreted using semi-empirical orthogonal parameters and Cowan code calculations resulting in calculated values for the energy levels, wave-function composition, transition probabilities and energy parameters. The semi-empirical energy parameters and their comparison with the corresponding ab initio values are shown in Table A12, Table A13 and Table A14.

3.1. Ag VII

A diagram of the low lying configurations of Ag VII with the ground-state configuration 4d5 is shown in Figure 2. As in the case of silver ions in lower stages of ionization (Ag III–Ag VI) we were able to make the analysis of only the 4d5–4d45p transition array (Table A1). The lines of these transitions are represented by a compact group in the region 271–343 Å mostly isolated from the other transitions in Ag VII as well as in the neighboring ions (see Figure 1). Three hundred and seventy-eight lines were identified in this transition array, 47 of them were doubly and one trebly identified. Eight lines are probably blended with previously identified Ag VI transitions. Thirty-four levels out of 37 possible 4d5 ones were found (Table A5) and 142 levels of the 4d45p configurations were located out of 180 possible levels (Table A6). The relative uncertainty of the level energies given by least-squares optimization [19] ranges from 1 to 4 cm−1 for 4d5 levels and from 3 to 8 cm−1 for 4d45p depending on the number of lines used for the level optimization and on their wavelength uncertainties. Identification was performed with the help of the semi-empirical calculations based on the orthogonal operators. The initial orthogonal energy parameters were extrapolated along the sequence Ag IV–Ag V. Final energy parameters of Ag VII after a fitting of the calculated levels to the found levels are listed in Table A12 and Table A13. They are compared with the values from the Parpia et al. code [13]. Only the parameters of the 4d5 and 4d45p configurations are listed in the tables although the matrixes of the interacting 4d5 + 4d45s + 4d35s2 (even) and 4d45p + 4d35s5p + 4d25s25p (odd) configurations were used in the fittings. The parameters of the unknown configurations were fixed on extrapolated values; the interaction parameters were fixed on values obtained with scaling by 0.85 of the ab initio integrals.
In a treatment of the 4d5 shell (as well as of the other 4dk shells) by the orthogonal parameter technique O2, O2′, Ea′ and Eb′ are the orthogonal counterparts of the traditional parameters F2(4d,4d,), F4(4d,4d), α and β. The one-electron magnetic (spin-orbit) operator ζ(4d) and the effective 3-particle electrostatic operators T1 and T2 are the same as in Cowan code and (Ac...A0) are additional 2-body magnetic parameters. The 4d45p configuration and the other 4dk−15p configurations contain additional parameters: C1dp–C3pd are the orthogonal counterparts of the Slater exchange integrals G1(4d,5p)–G3(4d,5p); S1dp, S2dp are the effective electrostatic 2-body dp-parameters; Sd.Lp…SS(dp)20 are magnetic 2-body dp-parameters [15], and T16 to T35 are the electrostatic 3-body ddp-parameters. In case of Ag VII 2-body magnetic parameters were varied at the fitting on one bunch keeping the ratios of the corresponding ab initio values. Root mean square deviations of the fitting σ were 14 and 19 cm−1 in even and odd configurations, respectively.
Almost all levels of the 4d5 configuration can be well designated with the leading member of their eigenvector composition. Only 48,086 cm−1 (J = 3/2) and 47119 cm−1 (J = 5/2) were designated with the second term. For 4d45p configuration, in many cases two wave functions have the same first component leading to non-unique labels for the energy levels. Therefore, the level energies are listed in Table A6 along with the level designations to avoid the ambiguities.
According to our predictions the most intense lines of the 4d5–(4d44f + 4p54d6) transitions are expected in the 170–240 Å wavelength range. As it is seen in Figure 1 there are many unknown lines in this region but we were not able to make reliable identification of these lines.

3.2. Ag VIII

The low lying configurations of Ag VIII are shown in Figure 3. The transitions from all low odd configurations decaying to the ground-state 4d4 configuration are identified in this spectrum. The 4d4–4d35p transitions are overlapped with some unknown lines of moderate intensity. But nevertheless, 118 lines were identified in this transition array (Table A2). Twenty-one lines were doubly and two lines trebly identified. Twenty-nine (out of 34 possible) 4d4 levels were found with the relative uncertainty from 3 to 7 cm−1 and collected in Table A7. The levels of the 4d35p configurations are contained in Table A8. It was possible to locate 83 out of 110 possible levels of this configuration. Their uncertainties are from 4 to 14 cm−1. As in Ag VII the identification of the 4d4 4d35p transitions was performed with by means of the semi-empirical calculations based on the orthogonal operators.
The energy parameters obtained in the final fitting are collected in Table A12 for 4d4 and Table A13 for 4d35p. For the meaning of the energy parameters and the procedure of the calculations see Section 3.1. Root mean square deviations of the fitting were 26 and 47 cm−1 in the 4d4 and 4d35p configurations, respectively. In case of the 4d35p configuration the fitting is affected by the interaction with the levels of the 4p54d5 configuration. The 4d35p levels above ~424,000 cm−1 overlap with the low lying 4p54d5 levels. Their interaction cannot be taken into account in the orthogonal operator code. The LS-coupling scheme is good approximation for the 4d4 levels. The value of the first component of the eigenvector composition for all levels is not less than 50%, thus a unique label by the name of the first component can be assigned to all energy levels. To differentiate 4d4 terms with the same LS values (recurring terms) the seniority numbers are used in the orthogonal operator code, whereas the Nielson and Koster sequential indices [20] are employed in the Cowan code [14]. Both labels are retained in Table A7 for the 4d4 levels because the 4d4–(4d35p + 4d34f + 4p54d5) transitions were analyzed with the aid of the Cowan code as described below. Contrary to 4d4, the percentage of the first component of the eigenvector composition is less than 50% for many of the 4d35p levels. It goes down to 16%. It makes LS-labeling of many levels meaningless in many cases. Therefore, the energy level values are listed in Table A2 along with the LSJ labels for the wavelength identification.
The identification of the 4d4–(4d35p + 4d34f + 4p54d5) transitions using the Cowan code resulted in 118 classified lines in the region 162–189 Å (Table A3). Seventeen lines were doubly classified. The wavelengths and intensities of 10 lines are affected by blending with the Ag IX lines. Table A9 contains the (4d34f + 4p54d5) levels above 556,000 cm−1. It was possible to find 58 levels of these configurations with the uncertainties from 7 to 19 cm−1. Cowan’s calculations of the odd level system were performed for a matrix of interacting configurations 4d35p + 4d36p + 4d25s5p + 4d5s25p + 4d3(4f-6f) + 4p54d5 + 4p54d45s. Starting energy parameters for the 4d35p, 4d34f and 4p54d5 configurations in Ag VIII were estimated by extrapolation of the scaling factors (the ratios of the fitted to the corresponding Hartree - Fock energy parameters) from Pd VII [21] and Pd VIII [8]. The ab initio electrostatic parameters in the unknown configurations were multiplied by 0.85 scaling factor. The configuration interaction parameters were scaled by 0.8 and the average energies along with the spin-orbit parameters were fixed at the corresponding HF values. Final energy parameters for the 4d35p, 4d34f and 4p54d5 configurations obtained in the fitting of the calculated energy levels to the experimental ones using the Cowan code are presented in Table A14. Standard deviation of the fitting σ was 213 cm−1. It should be noted, that for the 4d3 levels alone, the fitting by the Cowan code results in σ = 129 cm−1 what is 2.7 times larger than at the fitting using the orthogonal parameter code (see Table A13).
All found levels belong to the upper part of configurations (“emissive zone” [22]) from 557,000 to 669,000 cm−1. Only the levels for this energy range are listed in Table A9. According to our calculations full spread of the 4d34f + 4p54d5 levels cover the range up to 424,000 cm−1 overlapping with the 4d35p levels. Because of significant uncertainty in prediction of the low lying 4d34f + 4p54d5 levels they are omitted from Table A9.
Examination of Table A9 shows that the percentage contribution of the leading eigenvector component never exceeds 41% and can be as low as 9%. Moreover, the 4d34f wave function can be found as the leading component only at 13 levels with the largest contribution 31%, second component being mostly 4p54d5. Therefore, not only LS-assignment of many levels in Table A3, but also configuration attributions are arbitrary in many cases. Therefore, in Table A9, the upper levels of the transitions are designated by their energies and J values, whereas for convenience, a configuration name and LS-label are given according to the output files from the Cowan code in spite of possible ambiguity in many cases.

3.3. Ag IX

The scheme of the 4d3, 4d25p, 4d24f and 4p54d4 levels for Ag IX is shown in Figure 4. It shows that in comparison with Ag VII and Ag VIII the 4d25p levels are almost fully imbedded within the widely spread 4d24f + 4p54d4 levels. The levels of all odd configurations strongly interact. Their initial prediction in the framework of the Cowan code was performed by cross-extrapolation of the scaling factors and effective parameters from isonuclear Ag VIII (this work) and isoelectronic Pd VIII [8]. The 4d3 energies were calculated in the framework of the orthogonal parameters by extrapolation from Ag VII and Ag VIII (Table A12) and used as an input to Cowan’s calculations of the 4d3–(4d25p + 4d24f + 4p54d4) transition probabilities. Thus predicted energy levels and transition probabilities were then used for the spectrum analysis by the IDEN code [12].
As a result, 132 lines were identified in the 4d3–(4d25p + 4d24f + 4p54d4) transition array (Table A4). Nine lines were doubly classified and one line was trebly classified. The 4d3–4d25p part of this transition array lying in the 221–244 Å region is overlapped by unidentified lines (see Figure 1) discussed in Section 3.1. Nevertheless, it was possible to select the majority of the Ag IX lines by observation of their intensities with the change of the vacuum spark excitation conditions. The other 4d3–(4d24f + 4p54d4) part falls in the middle of the region where the spectrum consists of many overlapping lines in Ag VIII–Ag XII. Therefore 10 lines of Ag IX are found to be blended with Ag VIII and 8 with Ag X. In total, 17 levels of the 4d3 configuration and 78 levels of the 4d25p + 4d24f + 4p54d4 configurations were established and collected in Table A10 and Table A11, respectively. The uncertainty of relative positions of the levels after optimization by LOPT [19] ranges from 4 to 17 cm−1 for the ground-state configuration and from 6 to 19 cm−1 for the excited configurations.
As was mentioned above the energy levels of the 4d3 configuration were treated by orthogonal operator technique. As in Ag VII and Ag VIII calculated matrix consisted of three interacting configurations: 4d3 + 4d25s + 4d5s2 with similar scaling of the energy parameters for unknown configurations. The levels of the 4d3 configuration are presented in Table A10 along with the eigenvector compositions and deviations from the orthogonal parameter calculations. Standard deviation of the fitting was 27 cm−1. The resulting energy parameters of this configuration are collected in Table A12 in comparison with those of 4d4 (Ag VIII) and 4d5 (Ag VII). Table A12 shows regular behavior of the parameters and scaling factors along this part of the isonuclear sequence of silver ions. The labeling of the 4d3 energy levels by the fist component of their eigenvectors is unambiguous.
Table A11 contains all 306 levels of the 4d25p + 4d24f + 4p54d4 configurations. Because of the numerous blends only 78 levels were found. Similar to Ag VIII, a set of the interacting configurations (4d25p + 4d26p + 4d5s5p + 5s25p + 4d2(4f − 6f) + 4p54d4 + 4p55d35s) with the same treatment of the unknown configurations was used in the Cowan code calculations. The energy parameters for these configurations in Ag IX are listed in Table A14. The standard deviation of the fitting σ was 327 cm−1, to be compared with σ = 213 cm−1 in Ag VIII. It should be noted that in Ag IX more energy parameters than in Ag VIII were fixed on the estimated values for stability of the fitting. Similar considerations are applied to the eigenvector composition of the Ag IX odd levels. There are ambiguities in the LS- labeling and configuration assignment of the levels. Only the level energy and J value can serve as unique label, what is used in the list of the identified lines in Table A4.

4. Discussion

The spectra reported in this article are relevant to the verification of the identifications of the EUV spectra of Sn ions [9,10] which are used as a “fuel” in the radiation sources for the projection lithography at the 135 Å wavelength. The previous analyses in [9,10] were performed without any isoelectronic or isoionic support. The isoelectronic sequence Rh VIII–Cd XI was recently studied in [7]. It was found by extrapolation to Sn XIII that the identification of this spectrum should be revised. Similar conclusion was made after the identification of the M1 transitions between the levels of ground-state configurations in Sn XIII and other ions with open 4d- shell [23]. More data on the VUV spectra of the neighboring to Sn elements are needed. The analyses of Ag VII, Ag VIII and Ag IX were performed in this work for the first time and all Ag ion spectra with the 4dk (k = 1–10) ground-state configuration now became known. After the studies of spectra of the 4d- palladium ions ([8] and references therein) the present work on Ag ion spectra is the next step in the study of the ion spectra isoelectronic with Sn IX–Sn XIII. The work on Cd- and In- ion spectra is in progress at this laboratory.

Author Contributions

A.R. recorded the spectra, performed their analyses and wrote the paper; E.K. made spectrum measurements and wrote the paper.

Conflicts of Interest

The authors declare no conflict of interest.

Appendix A

Table
Table A1. Identified lines of the 4d5−4d45p transitions in the spectrum of Ag6+.
Table A1. Identified lines of the 4d5−4d45p transitions in the spectrum of Ag6+.
λ (Å) ao-c, (Å) bν (cm−1)I cgA, (108 s−1)5d55d45p
Term eE (cm−1)Term eE (cm−1)
271.9100.000367,768.8363154G11/230,662(23F)4F9/2398,431
277.7060.003360,092.8114254G11/230,662(41F)2G9/2390,759
277.852−0.001359,904.2193754G5/229,390(23F)4F3/2389,293
277.9690.003359,752.2135154D7/236,485(23P)4D7/2396,241
280.155−0.002356,944.6121154D5/239,299(23P)4D7/2396,241
280.8260.000356,092.154832H9/253,797(21G)2F7/2409,889
281.791−0.003354,872.4134756S5/20(45D)4D7/2354,869
283.3870.002352,874.394434F3/253,796(23F)4D1/2406,673
284.236−0.003351,820.26251832H11/257,962(21G)2G9/2409,779
284.511−0.001351,479.9129332H11/257,962(21G)2H11/2409,441
285.168−0.003350,670.33027652G9/259,223(21G)2F7/2409,889
285.7270.002349,984.1615352F7/259,792(21G)2G9/2409,779
285.7850.004349,912.955534F9/249,104(23F)4G11/2399,022
286.212 349,391.33237732G9/279,131(21D)2F7/2428,522
286.254−0.010349,339.53015932H9/253,797(23F)4D7/2403,133
286.2760.011349,313.3237634F9/249,104(23F)4F9/2398,431
286.411−0.002349,148.682834F7/248,712(23F)4G7/2397,858
286.7440.009348,743.41513234F9/249,104(23F)4G7/2397,858
287.9500.001347,282.91511332F7/253,353(41F)2D5/2400,637
288.0740.003347,133.0108834F9/249,104(23P)4D7/2396,241
288.8060.002346,253.7163654G9/230,907(43D)4F7/2377,163
288.9700.003346,057.0123356S5/20(45D)4F7/2346,061
289.2260.005345,750.6162554G11/230,662(41I)2I13/2376,419
289.4310.001345,506.053654G9/230,907(43G)4G11/2376,414
289.5750.002345,334.0189534F7/248,712(23F)4F5/2394,049
289.665−0.001345,225.972832H9/253,797(23F)4G11/2399,022
289.9440.000344,894.11811452G9/259,223(23F)2F7/2404,117
290.1690.006344,626.64732632H9/253,797(23F)4F9/2398,431
290.203−0.003344,586.392434F7/248,712(23F)4G7/2393,295
290.265−0.006344,512.5127232F7/253,353(23F)4G7/2397,858
290.4150.002344,335.1185352D3/248,086(23P)4D1/2392,424
291.2630.003343,332.2523956S5/20(45D)4F5/2343,336
291.3100.002343,277.01511332G7/279,705(21D)2F5/2422,985
291.8170.003342,680.2147934F7/248,712(23F)4G5/2391,396
291.862−0.002342,627.81913234F7/248,712(23F)4F7/2391,338
291.915−0.004342,565.63213834F5/251,049(41D)2P3/2393,610
292.0190.001342,443.34639032H9/253,797(23P)4D7/2396,241
292.2600.000342,160.64423554G11/230,662(43G)4H13/2372,822
292.7000.007341,647.25345034F9/249,104(41F)2G9/2390,759
292.860−0.002341,460.2378056S5/20(45D)6D7/2341,458
293.0020.001341,294.3174354G7/230,378(43G)4G7/2371,673
293.0770.000341,206.8318952D3/248,086(23F)4F3/2389,293
293.201−0.002341,062.723032H11/257,962(23F)4G11/2399,022
293.3880.000340,845.31722552F7/259,792(41F)2D5/2400,637
293.4570.001340,764.882754G9/230,907(43G)4G7/2371,673
293.516−0.001340,696.83220132F7/253,353(23F)4F5/2394,049
293.681−0.002340,506.13312634F5/251,049(23P)4D3/2391,553
293.711−0.001340,470.61417832H11/257,962(23F)4F9/2398,431
293.8220.004340,342.253134F5/251,049(23F)4G5/2391,396
293.865−0.003340,292.7410134F5/251,049(23F)4F7/2391,338
293.954−0.001340,189.493554G5/229,390(43F)2F5/2369,578
294.467−0.002339,596.6244354G9/230,907(43G)2H9/2370,501
294.526−0.001339,529.1184452I11/244,011(41I)2H11/2383,539
294.551−0.001339,499.61310932H9/253,797(23F)4G7/2393,295
294.798−0.006339,214.92611952G9/259,223(23F)4F9/2398,431
294.834−0.002339,174.319734256S5/20(45D)6D5/2339,172
294.8720.003339,130.23720232F7/253,353(23F)4G9/2392,486
294.932−0.002339,061.62311734F9/249,104(41F)2G7/2388,163
294.980 d0.004339,006.04319934F5/251,049(23F)4F5/2390,060
294.980 d−0.006339,006.04313454G11/230,662(41I)2I11/2369,661
295.0910.002338,878.2193454D7/236,485(43G)2G7/2375,365
295.253−0.003338,692.6226132H9/253,797(23F)4G9/2392,486
295.3040.001338,633.84720352G9/259,223(23F)4G7/2397,858
295.304−0.005338,633.84715934F3/253,796(23P)4D1/2392,424
295.537−0.001338,367.69065752I11/244,011(41I)2H9/2382,377
295.6480.004338,240.1123234F5/251,049(23F)4F3/2389,293
295.8010.001338,064.9203552F7/259,792(23F)4G7/2397,858
295.9440.002337,901.3228534F7/248,712(41F)2G7/2386,615
295.9800.003337,861.1107954D5/239,299(43D)4F7/2377,163
296.056−0.006337,773.4225554G11/230,662(43G)4H9/2368,429
296.5790.005337,177.8148754G5/229,390(43F)4F3/2366,573
296.716 d0.004337,023.2185254D1/238,685(43D)4D3/2375,706
296.716 d−0.004337,023.21811752G9/259,223(23P)4D7/2396,241
296.7790.003336,950.91211632D5/272,934(21G)2F7/2409,889
296.892−0.001336,822.63716054G11/230,662(43F)4G11/2367,483
296.9100.001336,802.81710354D1/238,685(43D)4P1/2375,489
296.944−0.008336,763.91710354D3/239,788(43D)4F5/2376,543
297.106−0.004336,580.1225554G9/230,907(43F)4G11/2367,483
297.1240.004336,559.4223534P5/232,005(43F)4D3/2368,569
297.216−0.002336,456.22917434P3/232,994(43D)4P3/2369,448
297.251−0.008336,415.8125454D5/239,299(43D)4D3/2375,706
297.324 336,333.830756556S5/20(45D)6P3/2336,333
297.504−0.004336,130.184454D1/238,685(43P)2P1/2374,810
297.702−0.007335,906.6367954G9/230,907(43F)4F7/2366,806
297.882−0.002335,702.91618854D3/239,788(43D)4P1/2375,489
297.911−0.002335,670.55529934F9/249,104(41D)2F7/2384,772
297.951−0.003335,625.91814352G7/255,773(23F)4G5/2391,396
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314.212−0.001318,256.62219734F3/253,796(43H)4G5/2372,051
314.298 d−0.006318,169.61820612D3/2104,821(21D)2F5/2422,985
314.298 d0.000318,169.61822052G9/259,223(43F)2G9/2377,393
314.370−0.003318,096.9197534F7/248,712(43F)4F7/2366,806
314.4000.002318,065.886952I13/245,546(43H)4I13/2363,614
314.5450.000317,919.31918434F5/251,049(43P)4D7/2368,968
314.650−0.010317,813.5911352G7/255,773(43F)4D7/2373,577
314.712−0.001317,750.9238154D7/236,485(45D)4D5/2354,235
314.7490.002317,713.48923654G11/230,662(45D)6D9/2348,377
314.7970.000317,665.52310934P1/234,605(45D)4D1/2352,270
314.856−0.005317,605.822 VI15652F7/259,792(43F)2G9/2377,393
315.100−0.012317,359.31414552G7/255,773(43G)4G9/2373,120
315.192−0.003317,266.6117932H9/253,797(43H)2H9/2371,061
315.264 d0.001317,194.88318132H9/253,797(43F)2F7/2370,993
315.264 d−0.004317,194.88331052G9/259,223(43G)4G11/2376,414
315.327 d−0.001317,130.83728434F7/248,712(43F)2G7/2365,842
315.327 d−0.005317,130.83712532D5/272,934(23F)4F5/2390,060
315.5520.001316,905.21611952D5/247,119(43D)2D5/2364,025
315.751−0.002316,705.61112432H9/253,797(43G)2H9/2370,501
315.758−0.007316,698.2189732H9/253,797(43G)4H11/2370,488
315.9880.003316,467.344152I11/244,011(43H)4I11/2360,481
316.2910.000316,164.31814852F5/257,413(43F)4D7/2373,577
316.3840.010316,071.5910632H9/253,797(43P)4D7/2369,878
316.5480.006315,907.64424834F9/249,104(43H)4H11/2365,017
316.588−0.004315,867.81210332H9/253,797(41I)2I11/2369,661
316.780−0.009315,676.92114934F9/249,104(43F)4G9/2364,772
316.804−0.001315,652.9292634F3/253,796(43D)4P3/2369,448
316.8430.002315,613.88324952G9/259,223(43H)4G7/2374,839
317.044−0.002315,413.384632F5/259,954(43G)2G7/2375,365
317.146−0.008315,312.541854G5/229,389(45D)4F5/2344,697
317.305−0.001315,154.612636254G9/230,907(45D)4F7/2346,061
317.408−0.005315,051.91420052F7/259,792(43H)4G7/2374,839
317.5720.000314,889.0153152D3/248,086(43P)4D5/2362,975
317.594−0.003314,867.0266554D1/238,685(45D)4D3/2353,549
317.710−0.001314,752.3206232D3/271,517(41D)2D5/2386,268
317.7350.000314,728.1249152G7/255,773(43G)2H9/2370,501
317.823−0.008314,640.23113532H9/253,797(43G)4H9/2368,429
318.013−0.005314,452.330 VI15654D3/239,788(45D)4D5/2354,235
318.1740.001314,293.43012552D3/248,086(43H)4G5/2362,381
318.202−0.003314,265.9199234F7/248,712(43P)4D5/2362,975
318.3070.001314,162.51722432G9/279,131(23F)4G7/2393,295
318.411−0.004314,059.9113734P5/232,005(45D)4F7/2346,061
318.791 d−0.004313,685.3920032D5/272,934(41F)2G7/2386,615
318.791 d0.001313,685.395332H9/253,797(43F)4G11/2367,483
318.8320.003313,645.32613532D5/272,934(41S)2P3/2386,582
319.143 d−0.005313,338.91412632D5/272,934(41D)2D5/2386,268
319.143 d0.004313,338.91418434F9/249,104(43G)4F9/2362,447
319.273−0.002313,211.9144652D3/248,086(43F)4F5/2361,296
319.5340.002312,955.910225654G7/230,378(45D)4F5/2343,336
319.902−0.003312,595.66519454G5/229,390(45D)4F3/2341,983
320.035−0.001312,465.5125752F5/257,413(43P)4D7/2369,878
320.2510.004312,255.5143052F7/259,792(43H)4G5/2372,051
320.3660.000312,142.8184352I13/245,546(43H)4G11/2357,689
320.6250.001311,891.2288954D7/236,485(45D)6D9/2348,377
320.752 d0.003311,767.4146252G9/259,223(43F)2F7/2370,993
320.752 d−0.005311,767.4924832D3/271,517(43D)2D3/2383,280
320.823 d0.000311,698.5258232H11/257,962(41I)2I11/2369,661
320.823 d−0.008311,698.52521632G7/279,705(23F)4G5/2391,396
320.9000.003311,623.96016354G11/230,662(45D)6D9/2342,289
321.1540.001311,377.515 VI6634F9/249,104(43F)4G9/2360,482
321.198−0.003311,334.32613634P5/232,005(45D)4F5/2343,336
321.2570.001311,277.1171952G9/259,223(43G)2H9/2370,501
321.312−0.004311,224.0184232H9/253,797(43H)4H11/2365,017
322.007−0.001310,552.4419154G9/230,907(45D)6D7/2341,458
322.338 310,233.12957912D5/2103,996(23F)2D5/2414,230
322.6120.002309,969.485734P5/232,005(45D)4F3/2341,976
322.8520.006309,739.4137452G9/259,223(43P)4D7/2368,968
323.5980.007309,025.312 VI11832G9/279,131(41F)2G7/2388,163
323.6260.000308,998.811552G7/255,773(43F)4G9/2364,772
323.721−0.001308,907.5178752D3/248,086(43F)2D3/2356,993
323.897−0.002308,740.02220432H9/253,797(43H)2I11/2362,535
324.055−0.005308,589.82519934F9/249,104(43H)4G11/2357,689
324.4040.003308,257.626 VI7952G9/259,223(43F)4G11/2367,483
324.427−0.003308,235.7825934P3/232,994(45D)6D1/2341,227
324.4580.003308,206.7388754D7/236,485(45D)4F5/2344,695
324.7180.002307,959.31919432D3/271,517(43G)2F5/2379,478
325.135−0.005307,564.459232D3/271,516(41F)2F5/2379,077
325.1700.003307,531.5157432D5/272,934(41F)2F7/2380,468
325.319−0.001307,390.23216134F9/249,104(43F)4D7/2356,493
325.8290.001306,909.155132G7/279,705(41F)2G7/2386,615
325.9430.008306,802.013432H11/257,962(43F)4G9/2364,772
326.1390.004306,618.0171934P1/234,605(45D)6D1/2341,227
326.204−0.001306,556.626 VI12232H11/257,962(43H)2I13/2364,518
326.519−0.004306,260.7912932G7/279,705(43D)2F5/2385,962
326.6090.002306,176.4131234P3/232,994(45D)6D5/2339,172
326.915 d0.000305,890.1244132H9/253,797(43G)4G7/2359,687
326.915 d0.003305,890.12431812D5/2103,996(21G)2F7/2409,889
327.004−0.003305,806.4112054D7/236,485(45D)6D9/2342,289
327.0480.000305,765.23921934F9/249,104(45D)4D7/2354,869
327.307−0.001305,523.838 VI11934F7/248,712(45D)4D5/2354,235
327.438−0.002305,401.03113354D5/239,299(45D)4F5/2344,697
327.8500.001305,017.182034F9/249,104(43H)4H9/2354,122
328.5550.002304,362.831 VI22812D3/2104,821(21G)2F5/2409,186
329.7120.003303,295.2123654D1/238,685(45D)4F3/2341,983
329.8300.000303,186.1219434F5/251,049(45D)4D5/2354,235
330.3910.000302,672.11620232G7/279,705(41I)2H9/2382,377
330.5600.004302,516.8155032H11/257,962(43F)4G9/2360,482
332.140−0.006301,077.9126532H9/253,797(45D)4D7/2354,869
332.353−0.003300,885.1116932F7/253,353(45D)4D5/2354,235
332.485 d−0.003300,765.31213332G7/279,705(41F)2F7/2380,468
332.485 d0.004300,765.3127632F7/253,353(43H)4H9/2354,122
333.198−0.001300,121.8426612D5/2103,996(23F)2F7/2404,117
334.140−0.003299,275.8125234F9/249,104(45D)6D9/2348,377
334.911−0.001298,587.115332G9/279,131(41G)2H11/2377,717
338.225−0.001295,661.2159232G7/279,705(43G)2G7/2375,365
341.0890.008293,178.3203034F9/249,104(45D)6D9/2342,289
342.6280.000291,861.730932G9/279,131(43F)2F7/2370,993
a Observed wavelengths, d—doubly identified, t—trebly identified; b Difference between the observed wavelength and the wavelength derived from the final level energies (Ritz wavelength). A blank value indicates that the upper level is derived only from that line; c Relative intensity; VI—line is also identified as Ag VI; e The number preceding the terms is seniority number.
Table
Table A2. Identified lines of the 4d4–4d35p transitions in the spectrum of Ag7+.
Table A2. Identified lines of the 4d4–4d35p transitions in the spectrum of Ag7+.
λ (Å) ao-c, (Å) bν (cm−1)I cgA, (108 s−1)5d45d35p
Term eE (cm−1)Term fE (cm−1)
247.539−0.005403,976.85615043H628,185(32F)3G5432,154
253.534−0.002394,424.45411443H423,302(32H)3G3417,724
253.6270.001394,279.89838323F460,980(12D)3F4455,261
253.737−0.001394,108.96028445D35292(34P)5P3399,399
254.226−0.003393,350.82017441G443,104(32F)1F3436,451
254.4510.001393,003.0237543H628,185(32H)1I6421,189
254.6410.000392,709.8174123F362,552(12D)3F4455,261
255.1310.000391,955.5550130745D47443(34P)5P3399,399
255.214 391,828.014059623F460,980(12D)3D3452,808
255.5700.001391,282.2289945D00(34P)5P1391,283
255.8910.000390,791.4387823F362,552(12D)1D2453,343
255.891 390,791.43821043G326,967(32D)3D2417,758
255.919 390,748.611545545D35292(34P)5P2396,041
256.069 390,519.86143521G469,584(12D)1F3460,104
256.1380.002390,414.54923145D23212(34P)5P2393,630
256.446−0.002389,945.77032045D11,340(34P)5P1391,283
256.757 389,473.318034743H628,185(32H)3I7417,658
257.391−0.001388,514.011035445D47443(34F)5F5395,955
257.505−0.003388,342.05731445D35292(34P)5P2393,630
257.6030.003388,194.33519443G326,967(34P)3D3415,165
257.6270.006388,158.1160d11443H423,302(32D)3D3411,469
257.6270.007388,158.1160d56743F429,555(32H)3G3417,724
257.645−0.004388,131.08348243G432,698(32H)3G4420,822
257.6850.000388,070.726043745D23212(34P)5P1391,283
257.7400.001387,987.93323043P232,134(32F)3F3420,123
257.796−0.002387,903.64317245D35292(34F)5F4393,193
257.947−0.001387,676.56828945D23212(34F)5F3390,887
258.3320.004387,098.82616543F332926(32P)3P2420,031
258.3470.002387,076.32910743H526,250(32G)1H5413,329
258.5830.003386,723.012049243H526,250(32F)1G4412,977
258.855 386,316.7228245D00(34F)5F1386,317
259.104−0.001385,945.417094443G535,077(32H)3G5421,021
259.1920.000385,814.413032043H628,185(32H)3I6413,999
259.2390.000385,744.460d41243G535,077(32H)3G4420,822
259.2390.004385,744.460d25945D47443(34F)5F4393,193
259.283−0.001385,679.05610621G469,584(12D)3F4455,261
259.3420.001385,591.271d16343P126,526(32D)3D1412,118
259.3420.011385,591.271d12543H423,302(32G)3H5408,910
259.4320.002385,457.53912045D11340(34F)5F2386,800
259.6430.000385,144.212067243H628,185(32G)1H5413,329
259.878−0.001384,795.9110d15543G432,698(32D)3F4417,492
259.8780.001384,795.9110d68043F332,926(32H)3G3417,724
259.9780.003384,647.913055445D35292(34F)3G3389,944
260.1150.001384,445.33733741F352,004(32F)1F3436,451
260.2800.002384,201.618074643H423,302(32G)3F3407,506
260.3760.005384,060.03217243F228,051(32D)3D1412,118
260.4430.001383,961.28139845D11340(34F)5D2385,302
260.5750.000383,766.74130223F362,552(12D)3D3446,318
260.695−0.001383,590.017019845D23212(34F)5F2386,800
260.709−0.001383,569.413031945D00(34F)5D1383,568
260.989−0.004383,157.95922043D336,879(32P)3P2420,031
261.0860.000383,015.629056145D47443(34F)5G5390,458
261.1730.000382,888.03220723F261,644(12D)3D2444,532
261.2470.002382,779.5267543G326,967(32G)1F3409,750
261.323−0.001382,668.21000173543H628,185(32G)3H6410,851
261.3280.000382,660.9958156843H526,250(32G)3H5408,910
261.400 382,555.59448643G326,967(32D)3F2409,522
261.458−0.002382,470.69954743G432,698(34P)3D3415,165
261.4960.000382,415.0590165543G535,077(32D)3F4417,492
261.6250.001382,226.53726745D11340(34F)5D1383,568
261.7180.000382,090.725072045D23212(34F)5D2385,302
261.752−0.003382,041.0490112145D35292(34F)5F3387,329
261.7930.000381,981.265d26423F362,552(12D)3D2444,532
261.7930.003381,981.265d39943H526,250(34P)5D4408,236
261.836−0.003381,918.416069543F429,555(32D)3D3411,469
262.106−0.003381,525.042095045D47443(34F)5F4388,964
262.160−0.001381,446.4670188641I639,744(32H)1I6421,189
262.276−0.001381,277.8620205541I639,744(32H)3G5421,021
262.3230.000381,209.411039743P232,134(32P)3P1413,344
262.340 381,184.710046845D11340(34F)5D0382,525
262.520−0.004380,923.3280d35943G535,077(32H)1H5415,995
262.520 380,923.3280d49243H526,250(34P)5D4407,173
262.535 380,901.6490150241G443,104(32P)3D3424,006
262.653−0.004380,730.52716243H628,185(32G)3H5408,910
262.7870.002380,536.35124043G326,967(32G)3F3407,506
262.910 380,358.3250d55343F228,051(32G)3F2408,409
262.910−0.002380,358.3250d68845D23212(34F)5D1383,568
262.9660.001380,277.35039243G432,698(32F)1G4412,977
263.020−0.003380,199.28726943F429,555(32G)1F3409,750
263.150−0.001380,011.413068745D35292(34F)5D2385,302
263.2120.003379,921.9370125845D35292(34F)5D4385,218
263.2400.003379,881.57330645D47443(34F)5F3387,329
263.303 379,790.64626741G443,104(32F)3F3422,895
263.3360.001379,743.03530343P126,526(32D)3D2406,270
263.510−0.004379,492.3250111443F332,926(32P)3D2412,412
263.8110.001379,059.3520189443H628,185(32H)3I5407,246
263.914−0.012378,911.3500t37243H526,250(32H)3H5405,144
263.9140.007378,911.3500 t27943G535,077(32H)3I6413,999
263.9140.001378,911.3500 t114543H526,250(32G)3G4405,162
264.072−0.003378,684.68462743F429,555(34P)5D4408,236
264.159 378,559.914033843P021,309(32P)3P1399,869
264.2930.000378,367.9470125245D23212(34F)5D3381,580
264.3740.000378,252.05038443G535,077(32G)1H5413,329
264.409−0.005378,201.93313043G326,967(32G)3G4405,162
264.546−0.001378,006.12320843P126,526(32P)3D1404,530
264.581−0.004377,956.19640643F429,555(32G)3F3407,506
264.705−0.003377,779.0680203345D47443(34F)5D4385,218
264.7520.004377,712.06575341G443,104(32H)3G4420,822
264.7690.002377,687.718041543F429,555(32H)3I5407,246
264.802 377,640.77328821D288,586(12D)1P1466,227
265.169−0.006377,118.08346743H526,250(32H)3H6403,359
265.2830.002376,955.934093643H628,185(32H)3H5405,144
265.439 376,734.4320d140543G432,698(32D)3F3409,432
265.4390.000376,734.4320d31721G469,584(12D)3D3446,318
265.6200.001376,477.77836643F228,051(32P)3D1404,530
265.728−0.002376,324.739072545D11340(34F)3D2377,661
265.7820.002376,248.2500179041I639,744(32H)1H5415,995
265.9480.001376,013.326039443D336,879(34P)3D2412,894
265.977−0.007375,972.3440d141343H423,302(32G)1G4399,265
265.9770.008375,972.3440d29145D47443(34F)5G5383,426
266.2380.002375,603.817081643F429,555(32G)3G4405,162
266.2850.001375,537.514029243G432,698(34P)5D4408,236
266.3840.003375,397.9420141043H423,302(32G)3G3398,704
266.5450.002375,171.232083143H628,185(32H)3H6403,359
266.744 374,891.37734545D00(34F)3D1374,891
266.9640.006374,582.3430t92143D336,879(32D)3D3411,469
266.964 374,582.3430t52943D336,879(34P)5S2411,461
266.964−0.002374,582.3430t76243F332,926(32G)3F3407,506
267.1970.000374,255.712027741I639,744(32H)3I6413,999
267.281−0.001374,138.1250d60243P232,134(32D)3D2406,270
267.281−0.001374,138.1250d32645D47443(34F)5D3381,580
267.4260.001373,935.213046243G326,967(34P)5D2400,904
267.676−0.001373,586.0460d157941I639,744(32G)1H5413,329
267.676−0.003373,586.0460d31043H526,250(34F)3G5399,831
267.9420.004373,215.12822243D139,191(32P)3D2412,412
268.145−0.004372,932.64832443D139,191(32D)3D1412,118
268.201−0.001372,854.78141243F228,051(34P)5D2400,904
268.3470.001372,651.812033243H423,302(34F)5F5395,955
268.362 372,631.0250122841F352,004(32D)1D2424,635
268.487−0.008372,457.548d27443G432,698(32H)3H5405,144
268.4870.005372,457.548d20543G432,698(32G)3G4405,162
268.5530.002372,366.02411045D35292(34F)3D2377,661
268.597−0.005372,305.02810943G326,967(32G)1G4399,265
268.6480.001372,234.32930843F332,926(32G)3G4405,162
268.691−0.004372,174.73127043G535,077(32H)3I5407,246
269.0090.002371,734.87161843G326,967(32G)3G3398,704
269.0740.001371,645.0390124943H628,185(34F)3G5399,831
269.4200.004371,167.72420123F460,980(32F)3G5432,154
269.4650.001371,105.74116441I639,744(32G)3H6410,851
269.790−0.004370,658.73336443F228,051(32G)3G3398,704
270.1020.001370,230.5350d99543H526,250(34F)3G4396,481
270.102−0.004370,230.5350d28141G443,104(32G)1H5413,329
270.2270.006370,059.35025543G535,077(32H)3H5405,144
270.265 370,007.23735643D238,402(32G)3F2408,409
270.358 369,879.9290d39523F362,552(32F)3D2432,431
270.358−0.005369,879.9290d85841G443,104(32F)1G4412,977
270.518 369,661.23233023F460,980(32F)3D3430,642
270.958 369,060.911038223P163,371(32F)3D2432,431
271.5360.005368,275.33720543G535,077(32H)3H6403,359
271.933 367,737.7270108921G469,584(32F)1G4437,322
272.3810.000367,132.85033643G432,698(34F)3G5399,831
272.5790.001366,866.1150113121G469,584(32F)1F3436,451
272.743−0.003366,645.59947343H423,302(34F)3G3389,944
272.8080.007366,558.28150043G432,698(32G)1G4399,265
273.0550.000366,226.64830743G326,967(34F)5F4393,193
273.8660.000365,142.120059543G535,077(34F)3F4400,219
273.912 365,080.84332543G432,698(34F)3F3397,779
273.967 365,007.51510943P021,309(34F)5F1386,317
274.155−0.002364,757.2160 d41543G535,077(34F)3G5399,831
274.1550.000364,757.2160 d66321D288,586(12D)1D2453,343
274.7050.000364,026.93120043H423,302(34F)5F3387,329
275.061−0.001363,555.72729243F332,926(34F)3G4396,481
275.2240.000363,340.44145443D336,879(34F)3F4400,219
275.408 363,097.72430123P163,371(34P)3S1426,468
275.7020.003362,710.53524343H526,250(34F)5F4388,964
275.902 362,447.52222923F362,552(32F)3F4424,999
276.3250.000361,892.71817543F228,051(34F)3G3389,944
276.7540.000361,331.72225143F429,555(34F)5F3390,887
277.091−0.001360,892.32414041F352,004(34P)3D2412,894
277.7490.003360,037.3110 d37623F460,980(32H)3G5421,021
277.749 360,037.3110 d59441F352,004(32H)1G4412,041
278.440 359,143.824 d39021D288,586(12D)3F2447,730
278.440−0.001359,143.820 d23723F460,980(32F)3F3420,123
279.5170.000357,760.0173443G432,698(34F)5G5390,458
280.308−0.005356,750.42228523F460,980(32H)3G3417,724
280.7750.003356,157.11718841G443,104(32G)1G4399,265
281.5010.002355,238.52713043H628,185(34F)5G5383,426
284.3330.000351,700.3127323F261,644(32P)3P1413,344
284.7910.000351,134.71714743P126,526(34F)3D2377,661
287.065−0.003348,353.2187343G535,077(34F)5G5383,426
287.4680.000347,864.81722721D288,586(32F)1F3436,451
a Observed wavelengths, d—doubly identified, t—trebly identified; b Difference between the observed wavelength and the wavelength derived from the final level energies (Ritz wavelength). A blank value indicates that the upper level is derived only from that line; c Relative intensity; e The number preceding the terms is seniority number; f Term attribution is arbitrary in a few cases (see text) for the level composition, see Table A8. The number preceding the terms of the 5d3 configuration is seniority number.
Table
Table A3. Identified lines of the 4d4–(4d34f + 4p54d5) transitions in the spectrum of Ag7+.
Table A3. Identified lines of the 4d4–(4d34f + 4p54d5) transitions in the spectrum of Ag7+.
λ, Å ao-c, (Å) bν (cm−1)I cgA, (109 s−1)4d4(4d34f + 4p54d5)
Term eE (cm−1)Config. fTerm fE (cm−1)
162.5280.001615,277323943G432,6984p54d5(4F)3F3647,982
162.554−0.001615,182265643G535,0784p54d5(4F)3F4650,256
164.321−0.001608,5645412603H526,2494p54d5(4G)3G4634,810
164.5420.001607,749534 IX42473H628,1854p54d5(4G)3G5635,935
165.1580.004605,4821225673F4229,5554p54d5(4G)3G3635,050
165.481 604,30029451221I639,7444p54d5(2H)1H5644,043
166.7440.003599,721355 IX28213G535,0784p54d5(4G)3G4634,810
166.9170.006599,0997219661G4169,5854p54d5(2G1)1F3668,708
167.156−0.005598,24469314293F4229,5554p54d5(4P)3D3627,779
167.460 597,158190 IX28885D47,4424p54d5(6S)5P3604,600
167.7310.000596,1931112751I639,7444p54d5(4G)3G5635,935
167.835−0.003595,8248312613H526,2494p54d5(4D)3F4622,060
168.4360.000593,698254 IX8273G326,9684p54d5(4G)3F2620,664
168.741−0.003592,625205093F2228,0514p54d5(4G)3F2620,664
168.932−0.002591,953109 IX20311G4243,1054p54d5(4G)3G3635,050
169.010−0.003591,683245915D23,2124p54d5(6S)5P2594,881
169.2350.002590,894374323D336,8784p54d5(4P)3D3627,779
169.6130.003589,57872 IX8315D352924p54d5(6S)5P2594,881
169.6760.001589,357495973G432,6984p54d5(4D)3F4622,060
170.070 587,9944810803F3162,5524p54d5(4F)3D2650,545
170.271 587,298395131G4243,1054p54d5(2D3)1F3630,389
170.359d0.002586,994312 IX14903F4160,9814p54d5(4F)3F3647,982
170.359d−0.003586,994312 IX6643G535,0784p54d5(4D)3F4622,060
170.5950.002586,184576283G535,0784p54d5(2I)1I6621,268
170.812−0.003585,439238813F3162,5524p54d5(4F)3F3647,982
171.0750.001584,539356433F2161,6454p54d5(4D)3P2646,185
171.339−0.001583,638464923F3162,5524p54d5(4D)3P2646,185
171.512−0.001583,050343371F352,0044p54d5(4G)3G3635,050
171.539 582,957383 IX22073F4160,9814p54d5(2H)1G4643,939
171.5870.003582,795272111F352,0044p54d5(4G)3G4634,810
171.7480.004582,247205743D238,4034p54d5(4G)3F2620,664
171.960−0.002581,53026764201I639,7444p54d5(2I)1I6621,268
172.171−0.001580,818666065D113404p54d5(6S)5P1582,154
172.2150.000580,67178725581G4169,5854p54d5(4F)3F4650,256
172.372−0.006580,1406115121D2188,5874p54d5(2G1)1F3668,708
172.460 579,8467114983F2161,6454p54d5(4F)3F2641,516
172.7300.001578,937925495D232124p54d5(6S)5P1582,154
172.968−0.002578,1432011383H526,2494p54d5(2G1)3G4604,385
173.3270.000576,94329557753H628,1854p54d5(2I)3H6605,128
173.5250.000576,287283233D336,8784p54d5(4G)3F4613,166
173.6820.003575,7664511871F352,0044p54d5(4P)3D3627,779
174.487−0.004573,110104 IX23843H526,2494p54d5(4F)3G5599,345
174.558−0.002572,875166053H423,3044p54d5(2I)3H4596,171
174.618−0.003572,67870 IX3433F4229,5554p54d5(4F)3F4602,225
174.742−0.004572,271404863F3162,5524p54d5(4G)3G4634,810
174.993 571,4506322903G535,0784p54d5(4G)3G5606,529
175.054d−0.004571,253484643G326,9684p54d5(4F)3G4598,206
175.054d0.004571,2533916511G4243,1054p54d5(2G1)1H5614,370
175.0860.004571,1493111043H628,1854p54d5(4F)3G5599,345
175.419d−0.001570,0633028991G4243,1054p54d5(4G)3F4613,166
175.419d−0.004570,063379463G535,0784p54d5(2I)3H6605,128
175.580−0.004569,541417223G432,6984p54d5(4F)3F4602,225
175.652−0.001569,306294705D474424d34f(4F)3H5576,746
175.8550.000568,6514615213F4229,5554p54d5(4F)3G4598,206
176.130−0.006567,761203505D352924d34f(4F)3H4573,036
176.4890.002566,6094012053F4229,5554p54d5(2I)3H4596,171
176.526−0.002566,490181623H423,3044p54d5(2H)3G4589,786
176.699d−0.021565,93316014403H526,2494p54d5(2H)1H5592,118
176.699d−0.002565,93316027883H423,3044p54d5(2I)3H4589,229
176.8330.001565,5045211713G432,6984p54d5(4F)3G4598,206
176.8720.001565,381336521I639,7444p54d5(2I)3H6605,128
177.1560.000564,474339063G326,9684p54d5(4F)3G3591,442
177.4840.002563,431476883P1226,5254p54d5(2D1)3P2589,963
177.625−0.001562,983244353H526,2494p54d5(2I)3H4589,229
177.674−0.003562,827151513G326,9684p54d5(2H)3G4589,786
178.240w0.013561,041616853F4160,9814p54d5(4D)3F4622,060
178.2800.004560,9166010993P2232,1374p54d5(2F1)3D3593,064
178.292−0.001560,87811318595D474424d34f(4F)3I5568,319
178.695d 559,61429927565D232124p54d5(4G)5F3562,825
178.695d−0.001559,61429934085D352924p54d5(4F)5D4564,902
178.7280.002559,50829419565D113404p54d5(4G)5F2560,857
178.7650.008559,394508703G432,6984p54d5(2H)1H5592,118
178.864d0.003559,083505875D352924p54d5(4F)5D4564,383
178.864d0.00559,08350145D232124p54d5(4F)5D3562,295
178.916−0.003558,922503625D113404d34f(4F)5D2560,251
179.2170.000557,98338333905D474424p54d5(4G)5F5565,427
179.296−0.002557,7386810585D004d34f(4F)5D1557,732
179.323−0.003557,653227525D232124p54d5(4G)5F2560,857
179.383−0.003557,468172685D474424p54d5(4F)5D4564,902
179.431−0.001557,3191359035D113404p54d5(4G)5F1558,654
179.531d0.010557,0072609585D232124d34f(4F)5D2560,251
179.531d−0.001557,00726027395D352924p54d5(4F)5D3562,295
179.550−0.002556,94937538575D474424p54d5(4F)5D4564,383
179.574−0.005556,87211124623F3232,9254p54d5(2H)3G4589,786
179.642−0.009556,663355253G326,9684p54d5(2G1)3F3583,603
179.795−0.002556,190184793D336,8784p54d5(2F1)3D3593,064
180.0380.001555,437605275D232124p54d5(4G)5F1558,654
180.1940.001554,9596011115D352924d34f(4F)5D2560,251
180.2290.001554,849457705D474424p54d5(4F)5D3562,295
180.288−0.002554,667205153D238,4034p54d5(2F1)3D3593,064
180.3380.002554,513224085D232124d34f(4F)5D1557,732
180.455 554,1562812763P1226,5254p54d5(2F2)3D2580,680
180.685−0.002553,449261343H423,3044d34f(4F)3H5576,746
180.8190.000553,038317483D238,4034p54d5(4F)3G3591,442
180.8690.006552,888285253D336,8784p54d5(2H)3G4589,786
180.9190.001552,735559363H628,1854d34f(4F)3H6580,923
181.004−0.002552,475508723F4229,5554d34f(4P)3G5582,024
181.0470.003552,343338263D336,8784p54d5(2I)3H4589,229
181.236−0.005551,768336113F4229,5554p54d5(2G2)3G4581,306
181.302−0.002551,565143643D238,4034p54d5(2D1)3P2589,963
181.3410.007551,4484610073P2232,1374p54d5(2G1)3F3583,603
181.5630.002550,772608673H628,1854d34f(2H)1K7578,963
181.6540.000550,496372163H526,2494d34f(4F)3H5576,746
181.7520.007550,20015921251F352,0044p54d5(4F)3F4602,225
181.7810.001550,114172563G326,9684p54d5(2H)3G3577,085
182.0430.002549,32119227993G432,6984d34f(4P)3G5582,024
182.137d−0.008549,03815713931G4243,1054p54d5(2H)1H5592,118
182.137d−0.002549,03815726093F2228,0514p54d5(2H)3G3577,085
182.354−0.001548,3846511753F3232,9254p54d5(2G2)3G4581,306
182.749−0.003547,19914525203F4229,5554d34f(4F)3H5576,746
183.1310.004546,05823431983G326,9684d34f(4F)3H4573,036
183.2020.000545,84535549913G535,0784d34f(4F)3H6580,923
183.4210.002545,194274543D238,4034p54d5(2G1)3F3583,603
183.4820.001545,01426028893H423,3044d34f(4F)3I5568,319
183.5030.000544,949621153P2232,1374p54d5(2H)3G3577,085
183.556−0.003544,792307211G4169,5854p54d5(2G1)1H5614,370
183.6850.006544,411418013D336,8784p54d5(2G2)3G4581,306
183.8080.001544,0477614183G432,6984d34f(4F)3H5576,746
184.0010.002543,474242883F4229,5554d34f(4F)3H4573,036
184.113−0.003543,14459462243H526,2494d34f(4F)3I6569,385
184.456−0.003542,13310220953H423,3044p54d5(4G)5F5565,427
184.4810.003542,061294033H526,2494d34f(4F)3I5568,319
184.5600.002541,8304416233F3162,5524p54d5(2G1)3G4604,385
184.6200.005541,655325453G535,0784d34f(4F)3H5576,746
184.6410.003541,59229743H423,3044p54d5(4F)5D4564,902
184.780d0.006541,184342643H628,1854d34f(4F)3I6569,385
184.780d−0.002541,184342551I639,7444d34f(4F)3H6580,923
185.452−0.001539,22352064291I639,7444d34f(2H)1K7578,963
185.553 538,93074167793H628,1854d34f(2H)1K7567,115
185.607−0.003538,773625363F4229,5554d34f(4F)3I5568,319
185.8970.001537,931313063G326,9684p54d5(4F)5D4564,902
185.9590.010537,753276131F352,0044p54d5(2H)3G4589,786
186.6150.003535,862241213F4229,5554p54d5(4G)5F5565,427
187.168 534,28024323861G4169,5854d34f(2D1)1H5603,864
188.2790.004531,1276811003F4160,9814p54d5(2H)1H5592,118
a Observed wavelengths: d—doubly identified, w—wide; b Difference between the observed wavelength and the wavelength derived from the final level energies (Ritz wavelength). A blank value indicates that the upper level is derived only from that line; c Relative intensity; IX—line is also identified as Ag IX; e Numbers following the term values display Nielson and Koster sequential indices [20]; f Designation and configuration attribution is arbitrary in a few cases (see text), for the level composition, see Table A9. Numbers following the term values of the 4d5 configuration display Nielson and Koster sequential indices [20].
Table
Table A4. Identified lines of the 4d3–(4d25p + 4d24f + 4p54d4) transitions in the spectrum of Ag8+.
Table A4. Identified lines of the 4d3–(4d25p + 4d24f + 4p54d4) transitions in the spectrum of Ag8+.
λ, Å ao-c, (Å) bν (cm−1)I cgA, (109 s−1)4d34d25p + 4d24f + 4p54d4
Term eConfig. fTerm fE (cm−1)
160.8370.005621,749100 X10924F7/24p54d4(5D)4D5/2628,302
161.466−0.005619,3275031414F9/24p54d4(5D)4D7/2629,173
162.302 616,135250 X10912D5/224p54d4(3P1)2P3/2649,186
162.411−0.002615,72319013272F7/24p54d4(1G1)2F7/2659,798
162.500 615,3831306454F3/24p54d4(5D)4D1/2615,385
162.6440.002614,83954025162H9/24p54d4(3H)2G7/2647,197
163.010−0.003613,45837046842H11/24p54d4(3H)2G9/2644,980
163.1320.003613,0019018632F5/24p54d4(3G)2F5/2657,606
163.228−0.003612,641804642H9/24p54d4(3H)2G9/2644,980
163.2670.001612,494705772G7/24p54d4(3F2)2F7/2634,657
163.4160.003611,9371803562D5/214p54d4(3F1)2D3/2680,196
163.532−0.004611,50322022722D3/214p54d4(3F1)2D3/2680,196
163.5890.004611,287110 X12372G9/24p54d4(3F2)2F7/2634,657
163.839 610,35614012542D3/224p54d4(5D)4P1/2637,178
163.949−0.003609,94740017024P5/24p54d4(5D)4P5/2632,322
164.099 609,3871106684F5/24p54d4(5D)4D3/2612,491
164.397 608,28431028662D5/214p54d4(3F1)2D5/2676,533
164.493 607,930805784P5/24p54d4(5D)4P3/2630,316
164.542d0.013607,749740 VIII16772F7/24p54d4(3P2)2D5/2651,880
164.542d−0.005607,74974077772H11/24p54d4(3H)2H11/2639,262
164.7720.004606,9001705762H9/24p54d4(3H)2H11/2639,262
164.8080.005606,766370 X17814P5/24p54d4(5D)4D7/2629,173
164.952−0.000606,239707254F7/24p54d4(5D)4D5/2612,769
165.036−0.003605,9271708314P5/24p54d4(5D)4D5/2628,302
165.4180.001604,53110012452G7/24p54d4(1D1)2F5/2626,693
165.945−0.002602,6109016792F5/24p54d4(3H)2G7/2647,197
165.9990.003602,412510 X14032P3/24p54d4(3P2)2P3/2638,784
166.023−0.005602,32520013482H9/24p54d4(3F2)2F7/2634,657
166.4230.005600,8809016502F7/24p54d4(3H)2G9/2644,980
166.518−0.000600,537605092H11/24p54d4(3H)2H9/2632,069
166.7440.000599,721490 VIII52982H9/24p54d4(3H)2H9/2632,069
166.8720.002599,262508622D5/224p54d4(5D)4P5/2632,322
167.307 597,70462050282G9/24p54d4(1G2)2G9/2621,061
167.460−0.002597,158270 VIII29122F7/24p54d4(1G2)2F7/2641,234
167.492−0.001597,0421008834F7/24p54d4(5D)4F9/2603,570
167.814 595,89612012782G7/24p54d4(3D)2F5/2618,058
167.898−0.000595,601170 X12484P3/24p54d4(5D)4D5/2612,769
168.022−0.004595,16216015202D5/214p54d4(3P1)2P3/2663,396
168.130 594,778409644P1/24p54d4(5D)4D3/2612,491
168.1590.004594,677303222D3/214p54d4(3P1)2P3/2663,396
168.294−0.002594,197904692F5/24p54d4(3P2)2P3/2638,784
168.414−0.001593,775907074F5/24p54d4(5D)4F7/2596,876
168.436d0.007593,698430 VIII19552G7/24p54d4(1G2)2G7/2615,884
168.436d0.001593,698430 VIII38274F9/24p54d4(5D)4F9/2603,570
168.479−0.002593,5451109092F5/24p54d4(3F2)2F5/2638,134
168.6050.005593,1015011532G9/24p54d4(3F2)2G9/2616,475
168.766−0.003592,5378015852G9/24p54d4(1G2)2G7/2615,884
168.8080.002592,389110 X7594F7/24p54d4(3F1)4D7/2598,929
168.932d−0.003591,953150 VIII9672P3/24p54d4(5D)4D5/2628,302
168.932d−0.000591,953150 VIII12672G9/24p54d4(3H)2H11/2615,308
169.0490.002591,54314031392D5/214p54d4(1G1)2F7/2659,798
169.392d−0.004590,34627011572P3/24p54d4(1D1)2F5/2626,693
169.392d−0.001590,34627027014F7/24p54d4(5D)4F7/2596,876
169.4750.001590,05850 X5482F5/24p54d4(3F2)2F7/2634,657
169.5950.001589,642504284F3/24p54d4(5D)4F5/2589,644
169.6130.000589,578100 VIII7654F9/24p54d4(1I)2H9/2599,446
169.7620.000589,062507874F9/24p54d4(3F1)4D7/2598,929
169.806−0.002588,9072014622D3/214p54d4(3G)2F5/2657,606
170.1920.002587,57230804F7/24p54d4(1D1)2F5/2594,111
170.306−0.001587,180606204F5/24d24f(3P)4D3/2590,280
170.359t0.007586,994440 VIII18824F9/24d24f(3F)2I11/2596,885
170.359t0.004586,994440 VIII7694F9/24p54d4(5D)4F7/2596,876
170.359t−0.001586,994440 VIII15012G7/24p54d4(3G)2G7/2609,152
170.490−0.001586,54528024144F5/24p54d4(5D)4F5/2589,644
170.933 585,02612025982D5/224d24f(3P)2F7/2618,075
171.286 583,81826020184F3/24d24f(3F)4F3/2583,819
171.339−0.002583,638608482D5/214p54d4(3P2)2D5/2651,880
171.493−0.000583,114404094F7/24p54d4(5D)4F5/2589,644
171.5390.001582,957530 VIII50002H9/24p54d4(3H)2H11/2615,308
171.9960.001581,408404822G7/24p54d4(5D)4F9/2603,570
172.215d−0.001580,671110049484F7/24p54d4(3H)4G9/21587,200
172.215d−0.001580,671110039514F5/24d24f(3F)4G7/21583,771
172.372 580,1409011202D3/224d24f(1D)2D3/2606,963
172.556−0.005579,52139031494F3/24d24f(3F)4G5/2579,505
173.077−0.001577,77889050634F9/24p54d4(3H)4G11/2587,642
173.224d0.014577,2886707654F9/24p54d4(3H)4G9/2587,200
173.224d−0.000577,28867049442G7/24p54d4(1I)2H9/2599,446
173.236−0.002577,2463809324F7/24d24f(3F)4G7/2583,771
173.445−0.003576,55115018694P5/24p54d4(3F1)4D7/2598,929
173.4950.005576,386605284F5/24d24f(3F)4G5/2579,505
173.578−0.003576,11011013092D5/224p54d4(3G)2G7/2609,152
174.2480.003573,89530204F9/24d24f(3F)4G7/2583,771
174.357−0.002573,535360 VIII35682G9/24d24f(3F)2I11/2596,885
174.4870.000573,11014013024P3/24d24f(3P)4D3/2590,280
174.5260.002572,979406902D5/214p54d4(1G2)2F7/2641,234
174.618 572,678100 VIII10884P5/24p54d4(3P1)4S3/2595,066
174.701−0.004572,40734025512F7/24p54d4(3F2)2G9/2616,475
174.908−0.002571,73060944P5/24p54d4(1D1)2F5/2594,111
175.6170.001569,4223013172D3/214p54d4(3F2)2F5/2638,134
175.738 569,02994079912H11/4d24f(3F)2I13/2600,561
176.977−0.001565,044403282G7/24p54d4(3H)4G9/2587,200
177.136d0.006564,53910011142F5/24p54d4(3G)2G7/2609,152
177.216d0.000564,28336020772G9/24p54d4(3H)4G11/2587,642
221.880−0.001450,69480224F9/24d25p(3P)4D7/2460,559
223.0610.001448,30740122G9/24d25p(1G)2H11/2471,667
226.0300.003442,420120174F9/24d25p(1G)2G9/2452,292
226.2260.000442,03660152G9/24d25p(3P)4D7/2465,394
227.202−0.001440,1377001442H11/24d25p(1G)2H11/2471,667
227.723−0.004439,130400814F9/24d25p(3F)2F7/2448,989
228.487 437,662320674F3/24d25p(3F)4D1/2437,662
228.9630.004436,751140454P5/24d25p(3P)4P3/2459,146
229.415 435,8915201724F7/24d25p(3F)4D5/2442,423
229.557 435,621400914F5/24d25p(3F)4D3/2438,725
229.7830.001435,193340364F5/24d25p(3F)4F5/2438,297
229.820 435,124200322F5/24d25p(1G)2F5/2479,718
229.877 435,015100202F5/24d25p(1G)2F5/2479,610
230.1760.004434,450230612H11/24d25p(1G)2H9/2465,990
230.241 434,3286301574F9/24d25p(3F)4F9/2444,195
230.601−0.005433,6503501132H9/24d25p(1G)2H9/2465,990
230.922−0.001433,047500892H9/24d25p(3P)4D7/2465,394
231.1790.002432,565150164F3/24d25p(3F)4F5/2432,569
231.545 431,8826201062H9/24d25p(1D)2F7/2464,230
231.602d−0.005431,774580194F7/24d25p(3F)4F5/2438,297
231.602d−0.002431,7745801494F9/24d25p(3F)4D7/2441,637
231.819 431,370300322F7/24p54d4(3G)4G7/2475,453
231.946−0.003431,1354501544F7/24d25p(3F)4F7/2437,662
232.127 430,799130132D3/224d25p(3P)4D5/2457,621
232.259−0.005430,5544102512G9/24d25p(1G)2G7/2453,902
232.337 430,4103301592G7/24d25p(1D)2F5/2452,569
232.845−0.002429,4705501024F5/24d25p(3F)4F5/2432,569
233.133−0.003428,940450892G9/24d25p(1G)2G9/2452,292
233.206−0.005428,80650164P5/24d25p(3P)4S3/2451,183
233.5310.000428,209750 m1032H9/24d25p(3P)4D7/2460,559
233.691 427,915310914F3/24d25p(3F)4F3/2427,916
233.7590.003427,790300174F9/24d25p(3F)4F7/2437,662
233.877 427,576170644F9/24d25p(3F)4G9/2437,442
234.539 426,36810004242H11/24d25p(3F)2G9/2457,900
234.686−0.003426,101150222D5/224d25p(3P)4P3/2459,146
234.9450.001425,631350362G9/24d25p(3F)2F7/2448,989
235.240−0.002425,098360882G7/24d25p(3F)2G7/2447,255
235.532d 424,570200194F3/24d25p(3F)4G5/2424,571
235.532d 424,570200172D5/224d25p(3P)4D5/2457,621
235.581 424,482190512G7/24d25p(3F)2F5/2446,642
235.649 424,360200712D3/224d25p(3P)4S3/2451,183
235.726 424,2222301012F5/24d25p(3P)2D3/2468,817
235.9070.002423,895100212G9/24d25p(3F)2G7/2447,255
236.756 422,376110322F7/24d25p(1D)2D5/2466,458
237.2220.004421,54670332H9/24d25p(1G)2G7/2453,902
237.4580.001421,12780154P3/24d25p(3F)4F5/2438,297
239.0770.003418,275160342G9/24d25p(3F)4D7/2441,637
239.1610.002418,12960192D5/224d25p(3P)4S3/2451,183
240.4230.002415,934160322D5/224d25p(3F)2F7/2448,989
243.734−0.001410,284160302P3/24d25p(3F)2F5/2446,642
a Observed wavelengths: d—doubly identified, t—trebly identified; b Difference between the observed wavelength and the wavelength derived from the final level energies (Ritz wavelength). A blank value indicates that the upper level is derived only from that line; c Relative intensity: X, VIII—line is also identified as respectively Ag X or Ag VIII; m masked by O IV; e Numbers following the term values display Nielson and Koster sequential indices [20]; f Designation and configuration attribution is arbitrary in a few cases (see text), for the level composition, see Table A11. Numbers following the term values of the 4d4 configuration display Nielson and Koster sequential indices [20].
Table
Table A5. Energies (in cm−1) of the 4d5 configuration of Ag VII.
Table A5. Energies (in cm−1) of the 4d5 configuration of Ag VII.
E ao-c bEigenvector Composition c
J = 1/2
94,730 * 98% 32P2% 52S
63,467 * 96% 52S2% 34P2% 32P
38,685667% 54D32% 34P1% 52S
34,605−2066% 34P33% 54D1% 52S
J = 3/2
104,821−2774% 12D18% 52D6% 32P
93,529 * 94% 32P4% 12D1% 52D
71,517−297% 32D2% 12D1% 54D
53,796055% 34F37% 52D6% 12D
48,086242% 52D43% 34F13% 12D
39,788−152% 54D44% 34P1% 34F
32,994−453% 34P44% 54D1% 34F
J = 5/2
103,9963480% 12D19% 52D1% 32D
72,934−2691% 32D6% 52F2% 54D
59,954−530% 32F29% 52F19% 52D
57,413253% 52F18% 32F17% 52D
51,0491174% 34F12% 32F8% 52F
47,119231% 52D32% 32F13% 34P
39,2991054% 54D32% 34P7% 52D
32,005−1944% 34P35% 54D13% 54G
29,3902779% 54G8% 32F4% 34P
0498% 56S2% 34P
J = 7/2
79,705496% 32G2% 52F1% 52G
59,7921175% 52F15% 34F6% 32F
55,773874% 52G17% 32F8% 52F
53,353247% 32F34% 34F8% 52G
48,7121045% 34F26% 32F15% 52G
36,485992% 54D4% 34F3% 54G
30,378093% 54G3% 32F2% 34F
J = 9/2
79,131−1399% 32G1% 52G
59,223247% 52G42% 32H10% 34F
53,797−1152% 32H30% 34F18% 52G
49,104−1159% 34F34% 52G6% 32H
30,907−297% 54G1% 34F1% 32H
J = 11/2
57,962286% 32H11% 52I2% 54G
44,011188% 52I10% 32H1% 54G
30,662−1496% 54G3% 32H
J = 13/2
45,5463100% 52I
a The star * indicates a calculated value for the level; b The difference between the observed and the calculated energies; c For the eigenvector composition, up to three components with the largest percentages in the LS-coupling scheme are listed. The number preceding the terms is the seniority number.
Table
Table A6. Energies (in cm−1) of the 4d45p configuration of Ag VII.
Table A6. Energies (in cm−1) of the 4d45p configuration of Ag VII.
E ao-c bEigenvector Composition c
J = 1/2
448,199 * 68% (01S)2P15% (1S)2P14% (21D)2P
419,718 * 64% (21D)2P12% (01S)2P11% (1D)2P
409,158 * 47% (3P)2S27% (3P)2S12% (23P)2P
406,6733739% (23F)4D20% (3F)4D13% (23P)2P
405,606 * 28% (23P)2P13% (23F)4D10% (3P)2P
394,516 * 41% (23P)4P11% (3P)4P9% (23P)4D
392,424−5736% (23P)4D21% (23P)4D11% (23P)4P
389,336 * 59% (1D)2P9% (3P)4P7% (21D)2P
380,449 * 48% (3D)2P23% (1S)2P9% (3D)4D
375,4891764% (3D)4P10% (23P)4P6% (3D)4D
374,810−2435% (3P)2P16% (1S)2P9% (3P)4P
370,586 * 22% (1S)2P19% (3P)2S15% (3P)2S
368,200 * 32% (3F)4D30% (3D)4D11% (3D)2P
366,416 * 32% (3D)4D31% (23F)4D13% (23F)4D
364,278 * 19% (3P)4P19% (3P)2P11% (23P)2S
355,790−1932% (3P)4P16% (3P)4P13% (23P)2S
352,2702677% (5D)4D9% (3P)4D4% (3D)4D
347,791 * 32% (3P)4D23% (23P)4D10% (3P)2P
341,227−165% (5D)6D30% (5D)4P1% (23P)2S
328,555 * 54% (5D)4P33% (25D)6D5% (3P)4P
325,860 * 89% (5D)6F3% (3P)4D3% (5D)4D
J = 3/2
455,917 * 74% (01S)2P16% (1S)2P7% (21D)2P
429,981 * 65% (21D)2D24% (1D)2D6% (21D)2P
416,277 * 29% (23F)2D18% (3P)2D14% (3P)2D
415,087 * 56% (21D)2P6% (3P)2D6% (1D)2P
406,960 * 38% (23F)4D17% (23F)4D11% (23P)4D
404,310 * 23% (23P)2P14% (23P)4S13% (23P)4S
403,643 * 31% (23P)2P22% (3P)4S19% (3P)4S
399,850241% (1F)2D13% (3F)2D8% (23P)2D
395,638 * 39% (1F)2D18% (23F)4F12% (23P)2D
393,610−222% (1D)2P15% (23P)4P8% (23F)4D
391,553719% (23P)4D14% (23P)4D14% (23F)2D
389,2932645% (23F)4F7% (23P)4D7% (3D)2D
387,806 * 21% (23P)4P10% (3P)4P10% (1D)2P
386,582−3831% (1S)2P10% (21D)2D8% (3D)2P
383,280446% (3D)2D19% (3F)2D9% (1D)2D
377,9103419% (1S)2P18% (1D)2D17% (1D)2P
375,7062130% (3D)4D13% (3D)2P11% (3D)4F
374,938022% (3D)2P11% (3P)2P11% (3D)4F
374,2363124% (3D)4P18% (3G)4F9% (3D)4F
371,218 * 25% (3P)2D14% (23P)2P13% (23P)2D
369,448−427% (3D)4P18% (3D)4D15% (3P)2P
368,569022% (3F)4D10% (3D)4D8% (3D)4F
366,573325% (3F)4F14% (3F)4D9% (3F)2D
366,078−417% (3F)4F16% (3P)4S14% (23P)4S
363,454−2331% (3D)4F29% (3G)4F12% (3P)4P
361,846 * 20% (3P)2P9% (3P)4S9% (5D)4D
360,092−5134% (3P)4P14% (3P)4P11% (3D)4D
356,993−220% (3F)2D18% (3F)4F10% (3P)4D
353,5492244% (5D)4D22% (23P)4D8% (23P)4D
351,904 * 34% (5D)4D16% (3P)4D14% (23P)4D
342,965 * 48% (5D)4F25% (5D)6D16% (5D)4P
341,983431% (5D)4F27% (5D)4P26% (5D)6D
336,333−2472% (5D)6P16% (5D)6D6% (5D)4P
331,200−441% (5D)4P31% (5D)6D22% (5D)6P
327,322 * 91% (5D)6F3% (5D)4D2% (23P)4D
J = 5/2
432,566 * 64% (21D)2D23% (1D)2D8% (21D)2F
422,985−1043% (21D)2F17% (1G)2F13% (1G)2F
414,230846% (23F)2D17% (3F)2D14% (23P)2D
409,1865051% (21G)2F21% (21D)2F8% (23F)2F
405,964 * 45% (23F)4D16% (3F)4D12% (23P)4D
400,6371628% (1F)2D10% (23P)4D10% (23F)2F
398,662−1632% (23F)2F22% (3F)4G8% (3F)4G
395,990 * 44% (23P)4P15% (23P)4P10% (23P)2D
394,049728% (23F)4F20% (21F)2D12% (23P)4D
391,3962829% (23F)4G11% (3F)2F11% (3F)4G
390,060−6638% (23F)4F11% (3P)4D6% (23F)4D
387,358 * 20% (23P)2D12% (23F)2D11% (1F)2D
386,268−625% (1D)2D17% (21D)2F9% (23F)2F
385,9621021% (3D)2F13% (23D)2D12% (1G)2F
383,1092225% (3D)2F8% (1F)2F7% (3P)2D
380,891−1828% (1G)2F18% (3D)2D8% (3F)2F
379,478−2525% (3G)2F21% (1D)2F12% (3P)2D
379,077−729% (1F)2F13% (3P)2D12% (23P)2D
376,5431723% (3D)4F17% (3D)4D9% (3G)4F
374,426−013% (3G)4F11% (1G)2F11% (3P)2D
372,051−624% (3H)4G20% (3G)4G16% (3F)2F
370,940 * 16% (3D)4D15% (3F)4D12% (3F)4F
369,5781221% (3F)2F15% (3D)4P11% (3H)4G
367,9191324% (3D)4P23% (3P)4P9% (3G)4G
366,693−1514% (3D)4D13% (3F)4F13% (3F)4D
364,877−317% (3P)4P13% (3P)4P8% (3P)2D
364,025−2815% (3D)2D14% (3D)4P10% (3H)4G
362,975325% (3P)4D17% (23F)4F13% (3G)4F
362,3815620% (3H)4G11% (3D)2F10% (3D)4F
361,296−1422% (3F)4F13% (3G)4F11% (3F)2D
358,3922921% (3F)4G12% (3G)2F8% (3P)4D
356,233114% (3F)4D13% (3F)4G12% (3P)4D
354,2351678% (5D)4D4% (3D)4D2% (3F)4F
352,6854526% (3G)4G22% (3F)4G14% (23F)4G
344,695632% (5D)4F30% (5D)4P27% (5D)6D
343,336−1742% (5D)4F33% (5D)4P5% (5D)6P
339,172150% (5D)6D30% (5D)6P8% (5D)4P
333,3271861% (5D)6P18% (5D)4P17% (5D)6D
329,356 * 89% (5D)6F4% (5D)4F2% (5D)4D
J = 7/2
428,522−670% (21D)2F15% (1D)2F7% (1G)2F
409,889539% (21G)2F14% (1G)2G10% (23F)2G
406,495−446% (23F)2G17% (3F)2G12% (21G)2G
404,117−827% (23F)2F19% (23F)4D9% (21G)2G
403,133−525% (23F)4D17% (1G)2G10% (23P)4D
397,8581226% (23F)4G22% (23F)4F9% (3F)4G
396,241−2232% (23P)4D21% (23F)2F15% (3P)4D
393,295−1020% (23F)4G15% (23F)4D13% (23F)2F
391,3383243% (23F)4F12% (23F)4G12% (1D)2F
388,163−323% (1F)2G14% (23D)2F13% (1D)2F
386,6151526% (1F)2G21% (21F)2F7% (23F)4F
384,7722524% (1D)2F16% (1G)2G11% (3F)2F
380,468−620% (1F)2F19% (3G)2G10% (3D)2F
379,061−321% (1G)2G18% (1F)2F15% (3D)2F
377,163−327% (3D)4F17% (3D)4D17% (3G)4F
375,365337% (3G)2G9% (3D)2F8% (3D)4D
374,839−514% (3H)4G13% (1G)2F11% (3G)4F
373,577−3013% (3F)4D10% (3D)4D10% (3G)2F
371,673025% (3G)4G24% (1G)2F7% (21G)2F
370,993−5033% (3F)2F25% (3G)2F10% (3D)4D
369,879−2328% (3P)4D13% (3D)4F11% (23P)4D
368,968315% (3P)4D10% (3H)4G10% (23P)4D
366,8062129% (3F)4F11% (3G)4F8% (3H)4G
365,842316% (3F)2G15% (3F)4F14% (3D)2F
362,942−425% (3G)4H25% (3H)4H10% (3H)2G
361,593−1825% (3G)4F18% (3D)4F9% (5D)4F
361,173−039% (3F)4G12% (3H)4G11% (3G)4H
359,687−1016% (3G)4G12% (3F)4D12% (3H)4G
356,493−017% (3F)4D11% (3G)4G10% (3H)4H
354,869−968% (5D)4D6% (3D)4D5% (3F)4F
353,454−2219% (3G)4H18% (3H)2G9% (3F)4G
349,0471047% (3H)4H23% (3G)4H9% (3H)2G
346,061−155% (5D)4F28% (5D)6D3% (5D)6F
341,458159% (5D)6D18% (5D)4F12% (5D)6F
334,9062585% (5D)6P6% (5D)6D4% (5D)4D
331,831 * 82% (5D)6F8% (5D)4F4% (5D)6D
J = 9/2
409,779334% (21G)2G17% (1G)2G16% (21G)2H
403,942−3249% (23F)2G12% (3F)2G11% (23F)4G
401,561−2633% (21G)2H14% (1G)2H14% (21G)2G
398,4311637% (23F)4F25% (3F)4G7% (21G)2H
392,4861229% (23F)4G21% (1F)2G17% (23F)4F
390,7591945% (1F)2G31% (23F)4F5% (23F)2G
382,720431% (1G)2G22% (1G)2G18% (3G)2G
382,377−2757% (1I)2H13% (23G)2H10% (21G)2H
379,2261220% (3G)2G12% (23G)4F11% (1G)2H
377,3932422% (3F)2G13% (3H)2G11% (3D)4F
375,593853% (3D)4F14% (3G)2G9% (3H)2G
373,120422% (3G)4G14% (3H)2H11% (3H)4G
371,061−622% (3H)2H21% (3G)2H13% (3H)4G
370,501113% (3G)2H11% (3G)2G10% (3H)2H
368,429−825% (3G)4H17% (3F)4G14% (3F)4F
365,569−3343% (3F)4F10% (3G)2H8% (3G)4H
364,772−1417% (3F)4G17% (3G)4F13% (3H)2G
362,447−230% (3G)4F22% (3H)4H6% (3G)4H
361,650034% (3H)4G22% (3G)4G13% (3F)2G
360,482015% (3F)4G13% (3G)4F12% (1G)2H
356,416−933% (3H)4I11% (3G)4H11% (3G)4G
354,122−629% (3H)4H14% (3H)4I13% (3H)2G
349,721−1327% (3H)4I27% (3H)4H18% (3G)4H
348,377−1443% (5D)6D29% (5D)4F5% (3H)4I
342,289−1241% (5D)6D27% (5D)6F24% (5D)4F
334,849 * 69% (5D)6F15% (5D)4F9% (5D)6D
J = 11/2
409,441864% (21G)2H26% (1G)2H5% (1I)2H
399,022−178% (23F)4G14% (3F)4G4% (21G)2H
383,539−1424% (1I)2H20% (1G)2H17% (21G)2H
377,7171438% (1G)2H24% (1I)2H14% (3G)2H
376,414−132% (3G)4G23% (3G)2H18% (3H)4G
372,676645% (3H)2H14% (1I)2H14% (3G)4G
370,488−120% (3G)4H18% (3G)2H15% (3G)4G
369,661633% (1I)2I21% (3H)2I15% (3H)2H
367,483−241% (3F)4G21% (3H)2I9% (1I)2I
365,017−228% (3H)4H23% (3G)4H17% (3G)2H
362,535−135% (3H)2I14% (3F)4G13% (3G)2H
360,481152% (3H)4I14% (3G)4G14% (3H)4H
357,689245% (3H)4G12% (3H)2H12% (3G)4G
352,082−739% (3H)4H30% (3H)4I17% (3G)4H
340,947 * 96% (5D)6F3% (3F)4G1% (23F)4G
J = 13/2
376,4191455% (1I)2I38% (1I)2K4% (3H)4H
372,822−252% (3G)4H29% (3H)2I8% (3H)4H
369,654739% (1I)2K23% (1I)2I19% (3H)2I
364,5181234% (3H)2I22% (3G)4H20% (3H)4I
363,614−2649% (3H)4I37% (3H)4H6% (1I)2K
354,719348% (3H)4H24% (3H)4I13% (3H)2I
J = 15/2
378,355994% (1I)2K6% (3H)4I
365,186 * 94% (3H)4I6% (1I)2K
a The star * indicates a calculated value for the level; b The difference between the observed and the calculated energies; c For the eigenvector composition, up to three components with the largest percentages in the LS-coupling scheme are listed. The number preceding the terms is the seniority number.
Table
Table A7. Energies (in cm−1) of the 4d4 configuration of Ag VIII.
Table A7. Energies (in cm−1) of the 4d4 configuration of Ag VIII.
E ao-c bEigenvector Composition c
J = 0
114,851 * 82% 01S117% 41S21% 23P1
65,762 * 62% 23P135% 43P23% 41S2
45,338 * 72% 41S216% 01S111% 43P2
21,309−3750% 43P232% 23P18% 45D
0−2692% 45D4% 23P14% 43P2
J = 1
63,371−5063% 23P137% 43P20% 43D
39,191−795% 43D3% 23P11% 43P2
26,5261960% 43P232% 23P14% 43D
1,340−1096% 45D2% 23P12% 43P2
J = 2
88,5863480% 21D119% 41D20% 43D
61,644668% 23F124% 43F25% 41D2
58,958 * 64% 23P128% 43P23% 41D2
48,505 * 61% 41D213% 21D110% 43D
38,4021763% 43D12% 23P18% 43P2
32,134−1955% 43P222% 43D21% 23P1
28,051470% 43F221% 23F15% 41D2
3,212−798% 45D1% 23P11% 43D
J = 3
62,552−1072% 23F117% 43F210% 41F
52,0043185% 41F7% 23F15% 43D
36,879−3992% 43D3% 41F1% 23F1
32,9262350% 43F242% 43G7% 23F1
26,9671155% 43G31% 43F212% 23F1
5,292198% 45D1% 43F21% 43D
J = 4
69,584−6066% 21G128% 41G24% 23F1
60,9804283% 23F110% 43F26% 21G1
43,104−452% 41G218% 21G116% 43F2
32,698−1156% 43G20% 43F216% 41G2
29,5551742% 43F225% 43H21% 43G
23,302−468% 43H15% 43G6% 43F2
7,443−595% 45D3% 43F21% 23F1
J = 5
35,0771184% 43G16% 43H
26,2501284% 43H16% 43G
J = 6
39,744−491% 41I9% 43H
28,185−591% 43H9% 41I
a The star * indicates a calculated value for the level; b The difference between the observed and the calculated energies; c For the eigenvector composition, up to three components with the largest percentages in the LS-coupling scheme are listed. The number preceding the terms is the seniority number. The number following the terms displays Nielson and Koster sequential indices [20].
Table
Table A8. Energies (in cm−1) of the 4d35p configuration of Ag VIII.
Table A8. Energies (in cm−1) of the 4d35p configuration of Ag VIII.
E ao-c bEigenvector Composition c
J = 0
460,564 * 72% (12D)3P26% (32D)3P1% (32P)3P
422,372 * 44% (32D)3P30% (32P)3P12% (32P)1S
410,445 * 48% (34P)3P27% (32P)1S8% (32D)3P
400,473 * 53% (32P)3P15% (34P)3P14% (32D)3P
398,971 * 39% (32P)1S39% (34P)5D10% (34F)5D
391,021 * 34% (34P)5D27% (34P)3P17% (32P)1S
382,525−7873% (34F)5D20% (34P)5D2% (32D)3P
J = 1
466,227−1673% (12D)1P18% (32D)1P4% (12D)3P
459,403 * 64% (12D)3P22% (32D)3P6% (12D)3D
444,840 * 53% (12D)3D19% (32F)3D15% (32D)3D
433,769 * 60% (32F)3D26% (12D)3D8% (32D)1P
430,256 * 45% (32P)1P13% (34P)3S10% (32D)1P
426,4683369% (34P)3S10% (32D)3P5% (34P)3P
419,422 * 33% (32D)3P22% (32D)1P11% (34P)3S
415,902 * 47% (34P)3D27% (32P)3S9% (32P)3P
413,3444733% (32P)3P25% (34P)3D22% (32P)3S
412,118−955% (32D)3D11% (32P)3S7% (12D)3D
411,728 * 35% (32P)1P13% (32D)1P10% (32P)3S
404,530954% (32P)3D13% (34P)3P9% (32P)3S
403,127 * 44% (34P)3P30% (34P)5D8% (32P)3D
399,8693216% (32P)3P15% (32D)3P14% (34P)5P
393,703 * 37% (34P)5D23% (34P)3P19% (34F)5D
391,2838172% (34P)5P7% (32P)3S6% (32P)3P
386,317−253% (34F)5F26% (34F)3D7% (34P)3D
383,568−4864% (34F)5D21% (34P)5D6% (34F)5F
374,8911347% (34F)3D36% (34F)5F7% (34F)5D
J = 2
457,523 * 59% (12D)3P14% (32D)3P12% (12D)3D
453,343−7536% (12D)1D23% (12D)3F12% (32F)1D
447,730−2031% (12D)3F21% (32F)1D10% (32D)3F
444,532−3644% (12D)3D12% (12D)3F12% (12D)3P
432,431−9054% (32F)3D16% (12D)3D11% (12D)1D
431,074 * 30% (12D)1D26% (32F)1D12% (32F)3D
424,635−1933% (32D)1D26% (32P)1D17% (32F)3F
421,941 * 26% (32F)3F22% (32P)1D12% (32P)3P
420,0315825% (32P)3P22% (34P)3D14% (32D)3P
417,7583126% (32D)3D16% (32F)3F16% (32P)3P
412,8943028% (34P)3D21% (34P)5S16% (32D)3P
412,412−4450% (32P)3D18% (32G)3F11% (32D)3F
411,461−2948% (34P)5S20% (34P)3P11% (32D)3P
409,522−1419% (32D)3F15% (32F)1D14% (32D)1D
408,409−1652% (32G)3F12% (32P)3D9% (32P)1D
406,270−1225% (32D)3D23% (32P)3P22% (32D)3P
402,086 * 25% (34P)3P23% (34P)5D16% (34P)5P
400,9043123% (34P)5D21% (34F)3F16% (32D)3F
396,0415936% (34P)5P18% (34P)5D15% (34F)5D
394,552 * 52% (34F)3F8% (32D)3F7% (34F)5G
393,630−434% (34P)5P27% (34P)3P13% (34F)3D
386,800−955% (34F)5F12% (34F)3D5% (34P)3D
385,302−6955% (34F)5D22% (34P)5D5% (34F)5F
377,661438% (34F)3D33% (34F)5F17% (34F)5D
371,899 * 86% (34F)5G7% (34F)3F3% (32D)3F
J = 3
460,10410062% (12D)1F15% (32D)1F11% (12D)3F
452,80817241% (12D)3D35% (12D)3F9% (32D)3F
446,318−1333% (12D)3D26% (12D)3F13% (12D)1F
436,451−2574% (32F)1F11% (32F)3D5% (32F)3G
430,642226% (32F)3D19% (32F)3F19% (32F)3G
427,542 * 21% (32H)3G19% (32F)3D18% (32F)3G
424,006−2524% (32P)3D23% (32D)1F11% (32G)1F
422,8957725% (32F)3F22% (32D)3D17% (32H)3G
420,1233624% (32F)3F17% (34P)3D11% (32P)3D
417,7244324% (32H)3G23% (32F)3G16% (34P)3D
415,16511424% (34P)3D14% (32G)1F10% (32H)3G
411,469−6724% (32D)3D18% (32P)3D15% (32F)3D
409,750−925% (32G)1F13% (32D)1F11% (32D)3F
409,432−1431% (32D)3F20% (32G)3F15% (32D)3D
407,5063923% (32G)3F22% (32G)3G11% (34F)3F
402,520 * 62% (34P)5D11% (34F)5D8% (32P)3D
399,3994672% (34P)5P9% (34F)3D5% (32P)3D
398,7042035% (32G)3G21% (32G)1F16% (34F)3G
397,779159% (34F)3F7% (32D)3F6% (34P)5P
390,887−1029% (34F)5F21% (34F)3D18% (34F)3G
389,944−831% (34F)3G15% (34F)3D14% (34F)5D
387,329−234% (34F)5F25% (34F)5D19% (34F)3G
381,580−540% (34F)5D29% (34F)5F21% (34F)3D
375,456 * 87% (34F)5G5% (34F)3F2% (34F)3G
J = 4
455,2612977% (12D)3F15% (32D)3F3% (32F)1G
437,32211261% (32F)1G28% (32H)1G6% (32F)3G
431,659 * 48% (32F)3G25% (32F)3F18% (32H)3G
424,999147% (32F)3F13% (32H)3G11% (32F)3G
420,8223735% (32H)3G16% (32F)3G14% (32G)3F
417,492−6267% (32D)3F10% (12D)3F7% (34F)3F
412,977622% (32F)1G17% (32G)1G13% (32F)3G
412,041−4733% (32H)1G28% (32G)1G13% (32H)3G
408,2363730% (34P)5D14% (32H)3H13% (32G)3H
407,173−5057% (34P)5D14% (32G)3F9% (32H)3H
405,162−2152% (32G)3G16% (32G)3F13% (32H)3H
400,219−1058% (34F)3F18% (32G)3F3% (32H)3G
399,2651434% (32G)1G18% (32G)3H13% (32H)3H
396,4811843% (34F)3G19% (32H)3H18% (32G)3H
393,193−234% (34F)5F32% (32G)3H11% (32H)3H
388,964433% (34F)5F23% (34F)3G16% (34F)5G
385,218−1167% (34F)5D15% (34F)5F6% (34F)3F
379,386 * 80% (34F)5G7% (34F)3G6% (34F)5F
J = 5
432,1543285% (32F)3G13% (32H)3G1% (32G)1H
421,021445% (32H)3G16% (32G)1H13% (32H)1H
415,995−1552% (32H)1H24% (32G)3G17% (32H)3I
413,3295761% (32G)1H20% (32H)3G10% (32H)3I
408,910154% (32G)3H31% (32H)3H9% (32G)3G
407,246−1938% (32H)3I36% (32G)3G8% (32H)3G
405,1442626% (32H)3H23% (32H)1H11% (32H)3I
399,831−147% (34F)3G23% (34F)5F16% (32H)3H
395,955−232% (34F)5F22% (32G)3H16% (32H)3I
390,458−640% (34F)5G28% (34F)5F18% (34F)3G
383,426−4858% (34F)5G15% (34F)3G13% (34F)5F
J = 6
421,1895267% (32H)1I19% (32G)3H7% (32H)3I
413,999−766% (32H)3I24% (32H)3H5% (32H)1I
410,8512057% (32G)3H25% (32H)1I14% (32H)3H
403,359−1355% (32H)3H25% (32H)3I14% (32G)3H
391,512 * 94% (34F)5G6% (32G)3H
J = 7
417,658−35100% (32H)3I
a The star * indicates a calculated value for the level; b The difference between the observed and the calculated energies; c For the eigenvector composition, up to three components with the largest percentages in the LS-coupling scheme are listed. The number preceding the terms is the seniority number.
Table
Table A9. Energies (in cm−1) of the 4d34f + 4p54d5 configurations of Ag VIII.
Table A9. Energies (in cm−1) of the 4d34f + 4p54d5 configurations of Ag VIII.
E ao-c bJEigenvector Composition c
557,732258124% 4d34f (4F)5D20% 4p54d5 (4F)5D10% 4p54d5 (4D)5D
557,962 * 440% 4p54d5 (2G1)3H10% 4p54d5 (2D1)3F6% 4p54d5 (2F2)3G
558,654182122% 4p54d5 (4G)5F18% 4d34f (4F)5F17% 4d34f (4P)5F
560,251257231% 4d34f (4F)5D27% 4p54d5 (4F)5D13% 4p54d5 (4D)5D
560,857186227% 4p54d5 (4G)5F21% 4d34f (4F)5F20% 4d34f (4P)5F
560,877 * 424% 4p54d5 (2D1)3F13% 4p54d5 (2D3)3F11% 4p54d5 (2G1)3F
562,295122321% 4d34f (4F)5D21% 4p54d5 (4F)5D13% 4p54d5 (4G)5F
562,82592314% 4p54d5 (4G)5F10% 4d34f (4P)5F10% 4d34f (4F)5F
564,383−53420% 4p54d5 (4F)5D17% 4d34f (4F)5D16% 4p54d5 (4G)5F
565,233 * 314% 4p54d5 (2D1)3F11% 4p54d5 (2D1)1F9% 4d34f (2D1)1F
564,902−365414% 4p54d5 (4G)5F13% 4p54d5 (4F)5D10% 4d34f (4F)5F
565,427−49517% 4p54d5 (4G)5F10% 4d34f (4F)5F9% 4d34f (4P)5F
567,115119721% 4d34f (2H)1K18% 4d34f (4F)3I15% 4d34f (2H)3I
568,31912515% 4d34f (4F)3I13% 4p54d5 (2I)3I13% 4p54d5 (4G)5F
568,352 * 226% 4p54d5 (2P)3D14% 4p54d5 (2D1)3D10% 4p54d5 (2D1)3F
569,385138622% 4d34f (4F)3I18% 4p54d5 (2I)3I18% 4d34f (2H)3I
571,903 * 138% 4p54d5 (2P)3P20% 4p54d5 (2D1)3P18% 4p54d5 (2D3)3P
573,036−36417% 4d34f (4F)3H11% 4p54d5 (2H)3H8% 4d34f (2G)3H
576,375 * 120% 4p54d5 (2F2)3D10% 4d34f (2P)3D10% 4d34f (2D2)3D
576,746−170517% 4d34f (4F)3H10% 4p54d5 (2H)3H8% 4d34f (2G)3H
577,085−795314% 4p54d5 (2H)3G12% 4d34f (2G)3G11% 4p54d5 (2G2)3G
578,963209729% 4d34f (2H)1K18% 4d34f (2G)1K14% 4p54d5 (2I)1K
578,767 * 221% 4p54d5 (2P)3P15% 4p54d5 (2D1)3P12% 4p54d5 (2D2)3P
579,661 * 136% 4p54d5 (2P)3D11% 4p54d5 (2D1)3D7% 4d34f (2D1)3D
580,373 * 315% 4p54d5 (2D2)1F15% 4p54d5 (2D1)3F8% 4d34f (2D2)1F
580,680 * 213% 4p54d5 (2F2)3D9% 4d34f (2P)3D6% 4p54d5 (2F1)3D
580,568 * 039% 4p54d5 (2P)3P20% 4p54d5 (2D3)3P12% 4p54d5 (2P)1S
581,094 * 132% 4d34f (2D1)1P19% 4d34f (2D2)1P12% 4p54d5 (2P)1P
580,923−221622% 4d34f (4F)3H14% 4p54d5 (4G)3H14% 4p54d5 (2H)3H
581,30622411% 4p54d5 (2G2)3G11% 4d34f (4P)3G7% 4d34f (2G)3G
582,024−42513% 4d34f (4P)3G11% 4p54d5 (2G2)3G7% 4d34f (2G)3G
582,154−19130% 4p54d5 (6S)5P10% 4d34f (4F)5P10% 4p54d5 (4P)3S
583,60346315% 4p54d5 (2G1)3F10% 4d34f (2D2)3F10% 4p54d5 (4F)3F
585,291 * 310% 4p54d5 (2D2)3D9% 4p54d5 (2F2)3D6% 4d34f (2G)3D
587,262 * 210% 4p54d5 (2P)3D9% 4p54d5 (2D1)3F7% 4p54d5 (2G1)3F
589,229−70412% 4p54d5 (2I)3H8% 4d34f (2H)3H5% 4p54d5 (4F)3G
589,963238212% 4p54d5 (2D1)3F10% 4p54d5 (2D1)3P8% 4p54d5 (2D2)3D
589,786−10749% 4p54d5 (2H)3G4% 4p54d5 (2I)3H4% 4d34f (2D2)1G
590,761 * 19% 4p54d5 (2D2)3D8% 4p54d5 (2F1)3D8% 4p54d5 (2D2)1P
591,056 * 213% 4p54d5 (2D1)3F11% 4p54d5 (2G2)3F8% 4p54d5 (2G1)3F
591,442124317% 4p54d5 (4F)3G6% 4d34f (4F)3G6% 4p54d5 (4G)3G
591,781 * 111% 4p54d5 (6S)5P11% 4p54d5 (2D1)3P7% 4p54d5 (4D)3P
592,118−4959% 4p54d5 (2H)1H9% 4d34f (2G)1H8% 4d34f (2D1)3G
593,449 * 219% 4p54d5 (6S)5P6% 4p54d5 (2D2)3F6% 4p54d5 (2D1)3P
593,578 * 017% 4p54d5 (4P)3P16% 4p54d5 (2D1)3P15% 4p54d5 (4D)3P
593,064−698315% 4p54d5 (2F1)3D11% 4p54d5 (4D)3D11% 4d34f (2P)3D
594,881−367227% 4p54d5 (6S)5P8% 4p54d5 (4D)5P8% 4p54d5 (4P)5P
596,171−1549% 4p54d5 (2I)3H9% 4p54d5 (2G2)1G8% 4d34f (2H)3H
598,210207416% 4p54d5 (4F)3G7% 4p54d5 (2G2)3G6% 4p54d5 (2F1)1G
598,784 * 317% 4p54d5 (2G1)3G15% 4d34f (2D1)3G5% 4p54d5 (2F2)3D
599,01815111% 4p54d5 (2P)3S10% 4d34f (2F)3P9% 4p54d5 (2S)3P
599,345109515% 4p54d5 (4F)3G10% 4p54d5 (2I)3H8% 4p54d5 (2G2)3G
602,22572348% 4p54d5 (4F)3F7% 4p54d5 (2G2)1G7% 4d34f (2F)1G
601,789 * 211% 4p54d5 (2D3)3P8% 4d34f (2F)3P7% 4p54d5 (4P)3P
602,116 * 39% 4p54d5 (4F)3G8% 4d34f (2G)3F8% 4p54d5 (2G2)3F
603,864132520% 4d34f (2D1)1H11% 4p54d5 (2I)3H9% 4p54d5 (2G1)1H
604,385−19424% 4p54d5 (2G1)3G13% 4d34f (2D1)3G7% 4d34f (2H)3G
604,6003343% 4p54d5 (6S)5P12% 4p54d5 (4D)5P9% 4p54d5 (4P)5P
605,132−102625% 4p54d5 (2I)3H14% 4p54d5 (2I)1I13% 4p54d5 (4G)3H
606,52991517% 4p54d5 (4G)3G16% 4p54d5 (4F)3G8% 4d34f (4F)3G
607,167 * 116% 4p54d5 (2P)3S14% 4p54d5 (4P)3S6% 4p54d5 (2D3)1P
607,348 * 216% 4p54d5 (4D)3P9% 4p54d5 (2D1)3P7% 4p54d5 (4P)3P
607,709 * 027% 4p54d5 (2P)3P20% 4p54d5 (2S)3P19% 4d34f (2F)3P
608,132 * 112% 4p54d5 (2D2)1P10% 4p54d5 (2D2)3D6% 4d34f (2G)3D
607,628−663310% 4p54d5 (2F2)3D10% 4p54d5 (2F1)1F8% 4d34f (2F)1F
613,166−109412% 4p54d5 (4G )3F9% 4p54d5 (2F2)1G7% 4d34f (2G)1G
614,37076519% 4p54d5 (2G1)1H13% 4p54d5 (2G1)3G6% 4p54d5 (2I)1H
615,653 * 311% 4p54d5 (2D1)3D8% 4p54d5 (4D)3D7% 4p54d5 (2F1)3D
615,971 * 119% 4p54d5 (4D)3D16% 4p54d5 (2D3)3D11% 4p54d5 (4P)3D
616,249 * 211% 4p54d5 (4D)3D11% 4p54d5 (2D2)1D11% 4p54d5 (2D3)3D
617,860 * 134% 4p54d5 (2D1)3D7% 4d34f (2D1)3D6% 4d34f (2D2)1P
619,061 * 226% 4p54d5 (2D1)3D11% 4p54d5 (4P)3D9% 4d34f (2D1)3D
620,379 * 315% 4p54d5 (4G)3F13% 4p54d5 (4D)3F5% 4p54d5 (4G)3G
620,664128213% 4p54d5 (4G)3F10% 4p54d5 (2F1)1D9% 4p54d5 (2D3)1D
621,268−115641% 4p54d5 (2I)1I16% 4p54d5 (2I)3H11% 4d34f (2H)1I
622,060−146420% 4p54d5 (4D)3F12% 4p54d5 (4G)3G8% 4p54d5 (2G1)3F
622,489 * 315% 4p54d5 (4D)3D9% 4p54d5 (4P)3D7% 4p54d5 (4G)3G
624,693 * 215% 4p54d5 (2D2)1D10% 4p54d5 (2P)1D8% 4p54d5 (4P)3D
627,779−430312% 4p54d5 (4P)3D11% 4p54d5 (2G2)1F8% 4p54d5 (2F2)1F
630,389405314% 4p54d5 (2D3)1F11% 4p54d5 (4G)3G11% 4p54d5 (2F1)1F
630,848 * 214% 4p54d5 (2P)1D10% 4p54d5 (2F2)1D7% 4p54d5 (4G)3F
634,810230433% 4p54d5 (4G)3G8% 4p54d5 (4F)3G8% 4p54d5 (4G)3F
635,050−166322% 4p54d5 (4G)3G11% 4p54d5 (2F2)1F7% 4p54d5 (2F1)1F
635,935510541% 4p54d5 (4G)3G18% 4p54d5 (2H)3G13% 4p54d5 (4F)3G
635,583 * 129% 4p54d5 (2D3)1P15% 4p54d5 (2S)1P6% 4p54d5 (2D3)3D
636,245 * 139% 4p54d5 (4P)3S21% 4p54d5 (2P)3S8% 4d34f (2F)3S
641,51656216% 4p54d5 (4F)3F7% 4p54d5 (4F)3D5% 4p54d5 (4D)3P
643,491 * 318% 4p54d5 (4F)3D11% 4p54d5 (2D1)3D9% 4p54d5 (2D1)1F
644,043065528% 4p54d5 (2H)1H26% 4p54d5 (2I)1H21% 4p54d5 (2G2)1H
643,939−245418% 4p54d5 (2H)1G15% 4p54d5 (4F)3F13% 4p54d5 (2G1)1G
644,760 * 125% 4p54d5 (4D)3P10% 4p54d5 (2D2)3P9% 4p54d5 (4F)3D
645,906221215% 4p54d5 (2D2)1D11% 4p54d5 (2D1)1D7% 4d34f (2D1)1D
646,185348211% 4p54d5 (4D)3P9% 4p54d5 (4F)3F7% 4p54d5 (2D2)3P
647,898 * 040% 4p54d5 (4D)3P14% 4p54d5 (2D2)3P10% 4p54d5 (4P)3P
647,98230322% 4p54d5 (4F)3F12% 4p54d5 (4F)3D5% 4p54d5 (2G1)3F
650,256171419% 4p54d5 (4F)3F13% 4p54d5 (2G1)1G11% 4p54d5 (2G1)3F
650,545−375223% 4p54d5 (4F)3D7% 4p54d5 (2P)3D5% 4p54d5 (4F)3F
651,358 * 318% 4p54d5 (2F1)1F15% 4p54d5 (2G2)1F14% 4p54d5 (2D1)1F
664,590 * 140% 4p54d5 (2P)1P15% 4p54d5 (2D1)1P9% 4d34f (2D1)1P
668,708−344332% 4p54d5 (2G1)1F15% 4p54d5 (2D2)1F13% 4p54d5 (2F2)1F
a The star * indicates a calculated value for the level; b The difference between the observed and the calculated energies; c For the eigenvector composition, up to three components with the largest percentages in the LS-coupling scheme are listed. The number following the terms displays Nielson and Koster sequential indices [20].
Table
Table A10. Energies (in cm−1) of the 4d3 configuration of Ag IX.
Table A10. Energies (in cm−1) of the 4d3 configuration of Ag IX.
E ao-c bEigenvector Composition c
J = 1/2
28,502 * 87% 2P13% 4P
17,851 * 87% 4P13% 2P
J = 3/2
68,7074876% 2D124% 2D2
36,360−657% 2P27% 2D210% 2D1
26,8232441% 2D225% 4P20% 2P
17,1695669% 4P23% 2P5% 2D2
01295% 4F3% 2D21% 2D1
J = 5/2
68,249−2283% 2D112% 2D23% 2F
44,595−4196% 2F2% 2D12% 2D2
33,0511084% 2D212% 2D12% 4P
22,387−1097% 4P2% 2D11% 2D2
3103098% 4F1% 2D20% 2D1
J = 7/2
44,082−398% 2F1% 2G0% 4F
22,160−2496% 2G2% 4F1% 2F
6532497% 4F2% 2G0% 2F
J = 9/2
32,3491957% 2H41% 2G2% 4F
23,357−2250% 2G43% 2H7% 4F
9867−1391% 4F8% 2G1% 2H
J = 11/2
31,53215100% 2H
a The star * indicates a calculated value for the level; b The difference between the observed and the calculated by orthogonal parameter technique energies; c For the eigenvector composition, up to three components with the largest percentages in the LS-coupling scheme are listed. The number following the terms displays Nielson and Koster sequential indices [20].
Table
Table A11. Energies (in cm−1) of the 4d25p + 4d24f + 4p54d4 configurations of Ag IX.
Table A11. Energies (in cm−1) of the 4d25p + 4d24f + 4p54d4 configurations of Ag IX.
E ao-c bJConfig. cEigenvector Composition d
424,571905/24d25p71% 4d25p (3F)4G17% 4d25p (3F)2F7% 4d25p (1D)2F
427,386 * 7/24p54d481% 4p54d4 (5D)6D11% 4p54d4 (5D)6F6% 4p54d4 (5D)6P
427,916−1123/24d25p61% 4d25p (3F)4F25% 4d25p (3F)2D7% 4d25p (3F)4D
428,156 * 5/24p54d478% 4p54d4 (5D)6D9% 4p54d4 (5D)6P8% 4p54d4 (5D)6F
428,306 * 9/24p54d485% 4p54d4 (5D)6D12% 4p54d4 (5D)6F1% 4p54d4 (5D)4F
430,308 * 3/24p54d476% 4p54d4 (5D)6D9% 4p54d4 (5D)6P5% 4p54d4 (5D)6F
431,109 * 7/24d25p77% 4d25p (3F)4G9% 4d25p (3F)4F9% 4d25p (3F)2F
432,5691575/24d25p56% 4d25p (3F)4F16% 4d25p (3F)2D16% 4d25p (3F)4D
433,690 * 1/24p54d484% 4p54d4 (5D)6D6% 4p54d4 (5D)4P4% 4p54d4 (3D)4P
437,442349/24d25p58% 4d25p (3F)4G25% 4d25p (3F)4F11% 4d25p (3F)2G
437,662681/24d25p49% 4d25p (3F)4D35% 4d25p (3P)4D6% 4d25p (3P)2S
437,662−4787/24d25p53% 4d25p (3F)4F27% 4d25p (3F)4D10% 4d25p (3F)2F
438,297−1075/24d25p29% 4d25p (3F)4F22% 4d25p (3F)4G22% 4d25p (3F)2F
438,725−1033/24d25p36% 4d25p (3F)4D28% 4d25p (3F)4F14% 4d25p (3F)2D
440,957 * 3/24d25p25% 4d25p (3P)4D25% 4d25p (3F)2D18% 4d25p (3P)2D
441,473 * 1/24d25p73% 4d25p (3P)2S15% 4d25p (3P)4P6% 4d25p (3F)4D
441,637−1227/24d25p26% 4d25p (3F)4D23% 4d25p (3F)2F20% 4d25p (3F)4F
442,4231205/24d25p46% 4d25p (3F)4D25% 4d25p (3P)4D13% 4d25p (1D)2F
444,1952209/24d25p43% 4d25p (3F)4F41% 4d25p (3F)4G10% 4d25p (3F)2G
444,319 * 11/24p54d492% 4p54d4 (5D)6F5% 4p54d4 (3F2)4G1% 4p54d4 (3F1)4G
444,355 * 3/24d25p50% 4d25p (3P)4S15% 4d25p (1D)2P6% 4d25p (3F)4D
445,529 * 5/24p54d441% 4p54d4 (3H)4G32% 4d24f (3F)4G10% 4p54d4 (3G)4G
446,642−45/24d25p41% 4d25p (3F)2F20% 4d25p (3F)2D18% 4d25p (3P)2D
447,243 * 7/24d25p43% 4d25p (3F)2G18% 4d25p (1G)2G10% 4d25p (3F)4F
447,255−2797/24p54d433% 4p54d4 (3H)4G30% 4d24f (3F)4G11% 4p54d4 (3G)4G
447,694 * 11/24d25p97% 4d25p (3F)4G1% 4d25p (1G)2H1% 4d24f (3F)4G
448,369 * 7/24d24f32% 4d24f (3F)2G10% 4p54d4 (3H)2G8% 4d25p (3F)2G
448,623 * 3/24p54d428% 4p54d4 (3P2)4S11% 4d25p (1D)2P8% 4p54d4 (3P2)4P
448,9892327/24d25p31% 4d25p (3F)2F22% 4d25p (3F)4D12% 4d25p (3P)4D
448,995 * 1/24d25p54% 4d25p (3P)4D36% 4d25p (3F)4D3% 4d25p (3P)2P
449,006 * 9/24p54d416% 4p54d4 (5D)6F16% 4d24f (3F)4G14% 4p54d4 (3H)4G
450,334 * 3/24p54d416% 4p54d4 (3G)4F12% 4d24f (3F)4F10% 4p54d4 (3F2)4D
451,183−533/24d25p31% 4d25p (3P)4S23% 4d25p (1D)2P13% 4d25p (1D)2D
451,424 * 9/24p54d428% 4p54d4 (5D)6F14% 4p54d4 (3H)4G13% 4d24f (3F)4G
451,430 * 5/24p54d417% 4p54d4 (5D)6F16% 4p54d4 (3F2)4D12% 4p54d4 (5D)6P
451,946 * 1/24p54d441% 4p54d4 (3F2)4D12% 4p54d4 (5D)4D12% 4p54d4 (3D)4D
452,041 * 7/24p54d428% 4p54d4 (5D)6F11% 4p54d4 (3F2)4D9% 4p54d4 (5D)6P
452,2921989/24d25p22% 4d25p (1G)2G21% 4d25p (3F)4F18% 4d25p (3F)2G
452,5692495/24d25p59% 4d25p (1D)2F12% 4d25p (3F)2F11% 4d25p (3F)2D
452,857 * 3/24d25p28% 4d25p (3P)4D15% 4d25p (3F)4D11% 4p54d4 (5D)6P
452,951 * 9/24p54d421% 4p54d4 (5D)6F20% 4d24f (3F)2G8% 4p54d4 (3H)2G
453,404 * 3/24d25p24% 4d25p (3P)4D13% 4p54d4 (3G)4F11% 4d25p (3F)4D
453,632 * 11/24p54d426% 4d24f (3F)4G22% 4p54d4 (3H)4G17% 4p54d4 (3F2)4G
453,902−2097/24d25p52% 4d25p (1G)2G14% 4d25p (1D)2F11% 4d25p (3F)2G
454,133 * 5/24p54d427% 4p54d4 (3G)4F12% 4d24f (3F)4F10% 4p54d4 (3F2)4D
455,093 * 7/24p54d413% 4p54d4 (3F2)4D13% 4p54d4 (5D)6F13% 4p54d4 (3G)4F
455,362 * 3/24p54d431% 4p54d4 (5D)6P18% 4p54d4 (3D)4P15% 4p54d4 (3F2)4D
455,506 * 5/24p54d420% 4p54d4 (3P1)4P15% 4d24f (3F)4P10% 4p54d4 (3P2)4D
457,009 * 1/24d25p50% 4d25p (1D)2P39% 4d25p (3P)4P5% 4d25p (3F)4D
457,621415/24d25p49% 4d25p (3P)4D19% 4d25p (3F)4D12% 4d25p (3F)2D
457,734 * 7/24d24f80% 4d24f (3F)4H3% 4p54d4 (3G)4H3% 4p54d4 (3H)4G
457,9001119/24d25p52% 4d25p (3F)2G33% 4d25p (1G)2G10% 4d25p (1G)2H
457,882 * 9/24p54d422% 4d24f (3F)4H9% 4d24f (3F)4I9% 4p54d4 (3H)4H
458,434 * 1/24d24f26% 4d24f (3F)2S18% 4p54d4 (3D)4P16% 4d24f (3F)4P
458,503 * 9/24d24f34% 4d24f (3F)4H33% 4d24f (3F)4I7% 4d24f (1D)2H
458,762 * 11/24p54d439% 4d24f (3F)4H23% 4p54d4 (3H)4H15% 4p54d4 (3G)4H
459,044 * 7/24p54d419% 4d24f (3F)4F16% 4p54d4 (5D)6F15% 4p54d4 (3P2)4D
459,146−453/24d25p59% 4d25p (3P)4P11% 4d25p (1D)2P9% 4d25p (1D)2D
460,347 * 13/24p54d431% 4d24f (3F)4H23% 4p54d4 (3H)4H22% 4p54d4 (3G)4H
460,559−657/24d25p37% 4d25p (3P)4D15% 4d25p (1D)2F12% 4d25p (3F)4D
460,753 * 5/24p54d411% 4p54d4 (3F2)4F11% 4d24f (3F)2F11% 4d24f (3F)4F
460,784 * 9/24d24f25% 4p54d4 (3D)4F20% 4d24f (3F)4I13% 4d24f (3F)4H
460,974 * 11/24d24f57% 4d24f (3F)4I13% 4d24f (3F)4H7% 4p54d4 (3H)4I
461,009 * 1/24d25p29% 4d25p (3P)4P22% 4d25p (1D)2P10% 4d24f (3F)2S
461,370 * 5/24p54d415% 4p54d4 (5D)6P12% 4d25p (3P)4P12% 4d25p (1D)2D
461,715 * 3/24p54d415% 4d25p (1D)2D11% 4p54d4 (5D)6F9% 4d25p (3P)4P
461,846 * 5/24d25p30% 4d25p (1D)2D22% 4d25p (3P)4P10% 4d25p (3P)4D
461,926 * 3/24d25p21% 4d25p (1D)2D18% 4d25p (3P)4P8% 4d25p (1D)2P
462,202 * 9/24d24f29% 4p54d4 (1I)2H18% 4d24f (3F)4I16% 4d24f (1G)2H
462,353 * 1/24d25p17% 4d24f (3F)2S14% 4d25p (3P)4P11% 4d24f (3F)4P
462,396 * 5/24p54d416% 4p54d4 (5D)6P15% 4p54d4 (3D)4P10% 4p54d4 (5D)4P
462,523 * 7/24p54d420% 4p54d4 (3F2)4F12% 4p54d4 (3F1)4F7% 4p54d4 (3D)4F
462,635 * 3/24p54d418% 4p54d4 (5D)6F7% 4p54d4 (3P2)4S7% 4d24f (3F)4F
463,146 * 9/24p54d431% 4d24f (3F)4F20% 4p54d4 (3F2)4F13% 4p54d4 (3F1)4F
463,748 * 13/24d24f53% 4d24f (3F)4I26% 4d24f (3F)4H16% 4p54d4 (3H)4I
464,491 * 15/24p54d458% 4p54d4 (3H)4I40% 4d24f (3F)4I1% 4p54d4 (1I)2K
464,230−2947/24d25p21% 4d25p (1D)2F16% 4d24f (3F)4D8% 4p54d4 (3P2)4D
464,852 * 11/24p54d421% 4p54d4 (1I)2H18% 4d24f (1D)2H16% 4d24f (1G)2H
465,027 * 1/24d24f41% 4d24f (3F)4D13% 4p54d4 (5D)6F10% 4d24f (3F)2S
465,143 * 3/24p54d419% 4d24f (3F)4D9% 4p54d4 (1F)2D7% 4d24f (1D)2D
465,394−3357/24d25p28% 4d25p (3P)4D17% 4d25p (1D)2F11% 4p54d4 (3P2)4D
465,872 * 5/24d25p24% 4d25p (3P)4P17% 4d25p (1D)2D8% 4d25p (3P)2D
465,990629/24d25p68% 4d25p (1G)2H28% 4d25p (1G)2G1% 4d25p (3F)4F
466,458265/24d25p19% 4d25p (1D)2D16% 4d25p (3P)4P7% 4p54d4 (3F2)4F
467,537 * 7/24p54d411% 4d24f (3F)2G10% 4p54d4 (3H)4H9% 4p54d4 (3G)4G
467,914 * 3/24p54d415% 4d24f (3F)4D10% 4d25p (3P)2D6% 4d24f (3F)4P
467,929 * 1/24p54d426% 4p54d4 (5D)6F17% 4p54d4 (3F2)4D14% 4d24f (3F)4D
468,8171383/24d25p46% 4d25p (3P)2D15% 4d25p (3P)2P11% 4d25p (3F)2D
468,895 * 11/24p54d434% 4p54d4 (3G)4G24% 4p54d4 (3F2)4G13% 4d24f (3F)4H
469,199 * 5/24d24f45% 4d24f (3F)4D6% 4p54d4 (3P1)4P6% 4p54d4 (5D)6F
469,249 * 11/24d24f23% 4d24f (3F)4H21% 4d24f (3F)4I10% 4p54d4 (3H)4H
469,387 * 3/24p54d413% 4d24f (3P)4D10% 4p54d4 (3F2)4F6% 4d24f (3F)4D
469,401 * 7/24p54d419% 4d24f (3P)4D14% 4p54d4 (5D)6P13% 4p54d4 (3P2)4D
470,136 * 9/24p54d421% 4p54d4 (3H)4H18% 4p54d4 (3G)4G15% 4d24f (3F)4H
470,867 * 7/24d24f14% 4d24f (3P)4D14% 4d24f (3F)2F13% 4p54d4 (3H)4H
471,042 * 5/24p54d420% 4d24f (3P)4D11% 4d24f (1D)2D9% 4p54d4 (3D)4D
471,491 * 1/24d25p46% 4d25p (3P)2P17% 4d24f (3F)2P8% 4d24f (1D)2P
471,6673111/24d25p92% 4d25p (1G)2H2% 4p54d4 (3F2)4G1% 4d25p (3F)4G
471,960 * 5/24d25p25% 4d25p (3P)2D13% 4d25p (3F)2D11% 4d25p (3P)4P
472,224 * 3/24d24f23% 4d24f (3F)2P21% 4d24f (1D)2P6% 4d24f (3F)4D
472,431 * 5/24p54d419% 4d25p (3P)2D12% 4d24f (1D)2D8% 4p54d4 (1F)2D
472,982 * 9/24p54d415% 4p54d4 (3F2)4G12% 4p54d4 (3G)4G12% 4d24f (3F)2G
473,124 * 3/24p54d416% 4p54d4 (1S2)2P14% 4d24f (1D)2P11% 4p54d4 (1F)2D
473,235 * 13/24d24f33% 4d24f (3F)4H28% 4d24f (3F)4I26% 4p54d4 (3H)4H
474,478 * 11/24d24f36% 4d24f (1G)2I28% 4d24f (3F)2I6% 4p54d4 (3F2)4G
474,797 * 7/24d25p61% 4d25p (1G)2F7% 4d25p (1G)2G6% 4d25p (1D)2F
474,983 * 1/24d24f31% 4d24f (1D)2P27% 4d25p (3P)2P10% 4p54d4 (1D2)2P
475,4531507/24p54d419% 4p54d4 (3G)4G13% 4d25p (1G)2F7% 4p54d4 (3D)4F
475,428 * 9/24p54d432% 4d24f (3P)4G18% 4p54d4 (3F2)4G12% 4p54d4 (1G2)2G
475,874 * 3/24d25p23% 4d25p (3P)2P10% 4d24f (3P)4D8% 4d25p (3P)2D
476,126 * 5/24d24f17% 4d24f (3P)4G12% 4d24f (3P)2D9% 4d24f (3F)4G
476,268 * 1/24p54d414% 4d25p (3P)2P12% 4p54d4 (1D2)2P11% 4d24f (3F)2P
476,658 * 13/24d24f39% 4d24f (1G)2I19% 4d24f (3F)2I12% 4p54d4 (1I)2I
476,896 * 15/24d24f55% 4d24f (3F)4I33% 4p54d4 (3H)4I11% 4p54d4 (1I)2K
477,099 * 7/24p54d413% 4d24f (3P)4G11% 4p54d4 (1D2)2F11% 4p54d4 (3F2)4G
477,494 * 1/24p54d428% 4p54d4 (5D)6F24% 4d24f (3P)4D14% 4p54d4 (3F1)4D
477,525 * 5/24p54d419% 4p54d4 (3G)4G17% 4d24f (1D)2F8% 4p54d4 (3H)4G
477,730 * 3/24d25p35% 4d25p (3P)2P8% 4d24f (3P)4D6% 4d24f (1D)2D
478,297 * 7/24d24f31% 4d24f (3P)4G10% 4p54d4 (1D2)2F9% 4d24f (1D)2F
478,563 * 11/24p54d423% 4p54d4 (3H)4I16% 4d24f (3P)4G10% 4p54d4 (3F1)4G
478,577 * 5/24d24f28% 4d25p (1G)2F14% 4d24f (3P)2D6% 4d24f (3F)2D
479,341 * 9/24d24f21% 4d24f (3F)2H21% 4d24f (1D)2H10% 4p54d4 (3G)2H
479,610455/24p54d422% 4d25p (1G)2F19% 4d24f (3P)4G6% 4p54d4 (1G1)2F
479,719 * 3/24p54d423% 4p54d4 (3P2)2D9% 4p54d4 (3P1)2D7% 4d24f (3F)2D
479,718−2335/24d25p35% 4d25p (1G )2F14% 4d24f (3P)4G5% 4p54d4 (3F2)4G
480,710 * 13/24p54d439% 4p54d4 (3H )4I18% 4p54d4 (3H)2I13% 4p54d4 (3G)4H
570,288 * 9/24p54d424% 4p54d4 (1G2)2H22% 4p54d4 (1G1)2H16% 4p54d4 (3F1)2G
570,992 * 7/24p54d447% 4p54d4 (1D1)2F17% 4p54d4 (1G2)2F12% 4p54d4 (1D2)2F
579,5054725/24d24f32% 4d24f (3F)4G28% 4p54d4 (3H)4G15% 4d24f (3P)4G
583,7712787/24p54d432% 4d24f (3F)4G31% 4p54d4 (3H)4G14% 4d24f (3P)4G
583,819213/24p54d422% 4d24f (3F)4F20% 4p54d4 (5D)4F18% 4p54d4 (3F1)4F
587,2001009/24p54d429% 4p54d4 (3H)4G27% 4d24f (3F)4G12% 4d24f (3P)4G
587,64214111/24d24f17% 4p54d4 (3H)4G15% 4d24f (3F)4G12% 4d24f (3F)2H
589,6441375/24p54d424% 4p54d4 (5D)4F23% 4d24f (3F)4F18% 4p54d4 (3G)4F
590,2804723/24p54d414% 4d24f (3P)4D10% 4p54d4 (3F1)4D10% 4p54d4 (3F2)4D
590,209 * 1/24p54d421% 4d24f (3P)4D16% 4p54d4 (3F1)4D15% 4d24f (3F)4D
594,1115575/24p54d438% 4p54d4 (1D1)2F16% 4p54d4 (1G2)2F14% 4p54d4 (1D2)2F
594533 * 5/24p54d417% 4p54d4 (3F1)4D14% 4d24f (3P)4D11% 4d24f (3F)4D
595,066−2923/24p54d427% 4p54d4 (3P1)4S21% 4d24f (3F)4S15% 4p54d4 (3P2)4S
596,8761717/24p54d425% 4p54d4 (5D)4F21% 4d24f (3F)4F19% 4p54d4 (3G)4F
596,885−1611/24d24f22% 4d24f (3F)2I20% 4d24f (1G)2I15% 4p54d4 (3H)4G
598,929−857/24p54d420% 4p54d4 (3F1)4D11% 4d24f (3P)4D10% 4d24f (3F)4D
599,4461909/24p54d418% 4p54d4 (1I)2H15% 4d24f (3F)2H13% 4d24f (1D)2H
600,561−1513/24d24f36% 4d24f (3F)2I29% 4d24f (1G)2I21% 4p54d4 (1I)2I
601,905 * 3/24p54d430% 4p54d4 (1S1)2P26% 4p54d4 (1D1)2P15% 4p54d4 (1S2)2P
603,5702059/24p54d422% 4p54d4 (5D)4F17% 4p54d4 (3G)4F15% 4d24f (3F)4F
605,674 * 5/24p54d411% 4d24f (1D)2F10% 4p54d4 (1G1)2F8% 4p54d4 (3F2)2D
606,963−393/24p54d422% 4d24f (1D)2D22% 4p54d4 (1F)2D6% 4p54d4 (3F2)2D
609,1521537/24p54d414% 4p54d4 (3G)2G13% 4p54d4 (3F2)2G11% 4d24f (3F)2G
612,491−4633/24p54d421% 4p54d4 (5D)4D8% 4p54d4 (3F2)4D7% 4p54d4 (5D)4P
612,769−6505/24p54d417% 4p54d4 (5D)4D14% 4p54d4 (5D)4P7% 4p54d4 (3F2)4D
613,700 * 1/24p54d421% 4p54d4 (3P2)2P19% 4p54d4 (1D2)2P8% 4d24f (3F)2P
615,308−17211/24p54d421% 4p54d4 (3H)2H14% 4d24f (3F)2H12% 4p54d4 (1I)2H
615,385−2971/24p54d440% 4p54d4 (5D)4D10% 4p54d4 (3F2)4D9% 4p54d4 (3P2)2S
615,884−6397/24p54d419% 4p54d4 (1G2)2G18% 4p54d4 (3F1)2G13% 4d24f (1G)2G
616,475−6149/24p54d415% 4p54d4 (3F2)2G14% 4p54d4 (3G)2G13% 4p54d4 (1G1)2G
618,0751527/24p54d414% 4d24f (3P)2F12% 4d24f (1D)2F11% 4p54d4 (1G1)2F
618,058−1255/24p54d413% 4p54d4 (3D)2F12% 4p54d4 (1D1)2F11% 4p54d4 (1F)2D
618,894 * 1/24p54d420% 4p54d4 (1S1)2P15% 4p54d4 (1D1)2P12% 4p54d4 (3P2)2S
620,387 * 3/24p54d420% 4p54d4 (5D)4D11% 4p54d4 (3D)2P6% 4d24f (3F)2P
621,0611079/24p54d417% 4p54d4 (1G2)2G17% 4p54d4 (3H)2H11% 4p54d4 (3H)2G
622,698 * 1/24p54d415% 4p54d4 (1S1)2P14% 4p54d4 (1D1)2P10% 4p54d4 (3D)2P
625,187 * 3/24p54d412% 4p54d4 (3D)2P10% 4p54d4 (5D)4P8% 4p54d4 (5D)4D
626,6935435/24p54d410% 4p54d4 (1D1)2F10% 4p54d4 (3D)2F9% 4p54d4 (3F2)2F
628,3022155/24p54d427% 4p54d4 (5D)4D10% 4p54d4 (3F2)4D8% 4p54d4 (3F2)2D
629,1733637/24p54d456% 4p54d4 (5D)4D15% 4p54d4 (3F2)4D6% 4d24f (3P)4D
630,316−2773/24p54d426% 4p54d4 (5D)4P11% 4p54d4 (3D)4P7% 4d24f (3F)4P
632,069−3119/24p54d429% 4p54d4 (3H)2H12% 4p54d4 (3F1)2G10% 4p54d4 (3G)2G
632,322−1175/24p54d427% 4p54d4 (5D)4P14% 4p54d4 (3D)4P8% 4d24f (3F)4P
634,65747/24p54d424% 4p54d4 (3F2)2F19% 4p54d4 (3D)2F12% 4p54d4 (1G2)2F
635,225 * 1/24p54d424% 4p54d4 (3P1)2P17% 4p54d4 (3P2)2S14% 4p54d4 (1S2)2P
637,1782861/24p54d420% 4p54d4 (5D)4P17% 4p54d4 (3P2)2S9% 4p54d4 (3P1)2P
638,134− 705/24p54d420% 4p54d4 (3F2)2F14% 4p54d4 (3F1)2F13% 4d24f (3P)2F
638,784813/24p54d418% 4p54d4 (3P2)2P12% 4p54d4 (1D2)2P11% 4p54d4 (3F2)2D
639,26230811/24p54d436% 4p54d4 (3H)2H32% 4p54d4 (1I)2H12% 4d24f (1G)2H
641,234− 787/24p54d416% 4p54d4 (3F1)2F16% 4p54d4 (1G2)2F13% 4p54d4 (3G)2F
644,980−2489/24p54d433% 4p54d4 (3H)2G17% 4p54d4 (3G)2G14% 4p54d4 (3F2)2G
647,197−457/24p54d435% 4p54d4 (3H)2G15% 4p54d4 (3G)2G11% 4p54d4 (3F2)2G
649,1861443/24p54d420% 4p54d4 (3P1)2P14% 4p54d4 (1D2)2P12% 4p54d4 (3P2)2P
651,8802595/24p54d419% 4p54d4 (3P2)2D12% 4p54d4 (3F1)2D11% 4p54d4 (1D1)2D
657,6061225/24p54d438% 4p54d4 (3G)2F11% 4p54d4 (3F1)2F10% 4p54d4 (1G1)2F
659,798−6197/24p54d424% 4p54d4 (1G1)2F20% 4p54d4 (3G)2F17% 4p54d4 (3F1)2F
664,136 * 1/24p54d437% 4p54d4 (1S1)2P16% 4p54d4 (3P1)2P13% 4p54d4 (1S2)2P
663,396−9393/24p54d430% 4p54d4 (3P1)2P22% 4p54d4 (1D1)2P8% 4d24f (1G)2P
676,5337355/24p54d436% 4p54d4 (3F1)2D13% 4p54d4 (3D)2D8% 4p54d4 (1F)2D
680,1963603/24p54d442% 4p54d4 (3F1)2D13% 4p54d4 (3D)2D11% 4p54d4 (1D1)2D
a The star * indicates a calculated value for the level; b The difference between the observed and the calculated energies; c Configuration attribution is arbitrary in a few cases (see text); d For the eigenvector composition, up to three components with the largest percentages in the LS-coupling scheme are listed. The number following the terms of the 4d4 configuration displays Nielson and Koster sequential indices [20].
Table
Table A12. Energy parameters (in cm−1) of the ground configuration in Ag VII, Ag VIII and Ag IX calculated by orthogonal parameter technique in comparison with the Dirac-Fock (DF) parameters.
Table A12. Energy parameters (in cm−1) of the ground configuration in Ag VII, Ag VIII and Ag IX calculated by orthogonal parameter technique in comparison with the Dirac-Fock (DF) parameters.
NameAgVII (4d5)AgVIII (4d4)AgIX (4d3)
FITError aDFFIT/DFFITError aDFFIT/DFFITError aDFFIT/DF
Eav51914360,8630.85337,710642,7760.88227,795831,4400.884
O28652210,1750.8508978610,5150.8549295810,8340.858
O2’5512369230.7965701771280.8005892873230.805
Ea’2132 2233 2516
Eb’382 456 50f
ζ2493224281.0272655526031.0202830727821.017
T1−4.620.08 −4.620.19 −4.850.36
T20.40f 0.50f
Ac7.801.513.210.67.46f12.430.67.08f11.810.6
A31.93r3.270.61.90f3.180.61.87f3.130.6
A43.28r5.560.63.31f5.520.63.32f5.530.6
A53.16r5.360.63.31f5.510.63.42f5.710.6
A60.96r1.630.60.47f0.780.60.00f−0.001.0
A1−0.10r−0.160.6−0.05f−0.080.60f00.6
A2−0.32r−0.550.6−0.43f−0.720.6−0.53f−0.880.6
A0−0.49r0.290.6−0.28f−0.460.6−0.25f−0.420.6
σ14 26 27
a r—parameters are fixed at DF ratio to Ac, f- fixed parameter.
Table
Table A13. Energy parameters (in cm−1) of the 4d45p configuration in Ag VII and 4d35p configuration in Ag VIII calculated by orthogonal parameter technique in comparison with the DF parameters.
Table A13. Energy parameters (in cm−1) of the 4d45p configuration in Ag VII and 4d35p configuration in Ag VIII calculated by orthogonal parameter technique in comparison with the DF parameters.
NameAg VIIAg VIII
FITError aDFFIT/DFFITError bDFFIT/DF
Eav37,38622384,1680.97341,10525417,7020.984
O2dd8849210,4180.8499147810,7380.852
O2’dd5581470700.78957471272650.791
Ea’2161 2216
Eb’363 316
T1−4.860.09 −5.080
T20.480.09 0.50f
ζ(4d)2631425721.0232809827471.022
Ac8.011.812.680.6311.76f11.761.0
A31.97r13.120.633.44f3.441.0
A43.25r15.150.635.40f5.401.0
A53.46r15.480.635.68f5.681.0
A60.64r11.020.620.18f0.181.0
A1−0.17r1−0.280.63−0.23f−0.231.0
A2−0.63r1−1.000.63−0.35f−0.351.0
A0−0.69r1−1.100.63−0.18f−0.191.0
C1dp3702442700.86740121146210.868
C2dp2605329980.86927551031760.867
C3dp1258414110.89113211014710.898
S1dp673 638
S2dp−1183 −1298
ζ(5p)6317559751.05772681469331.048
Sd.Lp−27.491.5−34.810.79−27.2f−34.040.8
Sp.Ld−2.77r2−3.520.79−2.7f−3.460.8
Zp2ppa−19.98r2−25.290.79−20.0f−25.010.8
Zp2dda13.74r217.420.7913.5f16.930.8
Zp1ppa41.56r252.620.7941.2f51.560.8
Zp1dda−2.94r2−3.710.79−2.3f−2.990.8
Zp3ppa10.85r213.740.7911.0f13.810.8
Zp3dda−2.22r2−2.820.79−2.3f−2.950.8
SS(dp)02−1.53r2−1.950.79−1.8f−2.320.8
SS(dp)20−0.52r2−0.660.79−0.3f−0.400.8
t16’−23.82.8 −23.8f
t17’8.02.8 8.0f
t18’−10.42.9 −10.4f
t19’−8.92.1 −8.9f
t20’−42.23.6 −42.2f
t21’−3.42.3 −3.4f
t22’−14.44.6 −14.4f
t23’−4.23.9 −4.2f
t24’−7.52.9 −7.5f
t25’3.62.5 3.6f
t26’−33.53.0 −33.5f
t27’18.52.4 18.5f
t28’35.63.5 35.6f
t29’−12.12.5 −12.1f
t30’−45.52.7 −45.5f
t31’−4.43.0 −4.4f
t32’−0.32.2 −0.3f
t33’11.92.8 11.9f
t34’−30.23.2 −30.2f
t35’−32.33.4 −32.3f
σ19 47
a r1—parameters are fixed at DF ratio to Ac, r1 parameters are fixed at DF ratio to Sd.Lp; b f—parameter is fixed on predetermined value.
Table
Table A14. Fitted (FIT) with their uncertainties (Unc.) and Hartree - Fock (HF) energy parameters in cm−1 of the odd 4d35p, 4d34f, and 4p54d4 configurations in Ag VIII and 4d25p, 4d24f and 4p54d3 configurations in Ag IX calculated with the Cowan code.
Table A14. Fitted (FIT) with their uncertainties (Unc.) and Hartree - Fock (HF) energy parameters in cm−1 of the odd 4d35p, 4d34f, and 4p54d4 configurations in Ag VIII and 4d25p, 4d24f and 4p54d3 configurations in Ag IX calculated with the Cowan code.
Name aAg VIIIAg IX
HFFITUnc. bFIT/HF cHFFITUnc. bFIT/HF c
Eav(5p)417,702412,72826−4974459,300455,71688−3584
F2(4d,4d)95,97880,9722370.84498,60383,04611590.842
F4(4d,4d)64,36656,7504840.88266,31454,36432270.820
α 495 7126
β −627−99 −600f
T1 −4−1
ζ(4d)27022812361.04128702919651.017
ζ (5p)65107299661.121742683381651.123
F1(4d,5p) −2072−265 −2000f
F2(4d,5p)39,20532,0052750.81641,77735,9508980.861
G1(4d,5p)12,35910,5051370.850 d12,92611,6493420.901 d
G3(4d,5p)12,11010,2931340.850 d12,83611,5683400.901 d
Eav(4f)508,665496,302569−12,363522,389507,990380−14,399
F2(4d,4d)95,12680,381f0.84597,64080,359f0.823
F4(4d,4d)63,72855,443f0.8765,59454,443f0.83
α 48f 62f
β −600f
T1 −4f
ζ(4d)26522732f1.0328082910f1.036
ζ(4f)9595f1.0124124f1.0
F2(4d,4f)70,56964,43314520.913 d78,43371,374f0.91
F4(4d,4f)44,63640,7559190.913 d50,34445,814f0.91
G1(4d,4f)83,51672,6485720.8793,84085,394f0.91
G3(4d,4f)51,47747,8763770.930 d58,48153,218f0.91
G5(4d,4f)36,16933,6402650.930 d4127637,562f0.91
Eav(pd)538,566526,473194−12,093529,36152,3487344−5874
F2(4d,4d)94,30579,0143930.83897,01885,7024960.883
F4(4d,4d)63,11951,3185980.81365,13350,60710800.777
α 48f 60f
β −600f −600f
T1 −4f −4f
ζ(4p)29,35529,355f130,23930,5764151.011
ζ(4d)26022849f1.095276727821161.005
F2(4p,4d)100,31483,91610650.837102,72379,5189730.774
G1(4p,4d)127,225101,1621920.795 d130,315101,0563420.775 d
G3(4p,4d)79,353630971200.795 d81,52363,2192140.775 d
σ 213 327
a Eav(5p), Eav(4f) and Eav(pd) stand for Eav(4dk−15p), Eav(4dk−14f) and Eav(4p54dk+1) for Ag VIII and Ag IX where k = 4 and 3, respectively; b f- parameter is fixed on predetermined value; c For Eav the FIT-HF difference is listed; d Adjacent pairs of parameters are linked at their HF ratios.

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Figure 1. Spectrum of silver in the region 150–350 Å excited in a vacuum spark. Lines of different ion spectra are marked by different colours: Ag VI—royal blue, Ag VII—wine, Ag VIII—magenta, Ag IX—green, Ag X—blue, Ag XI—red, Ag XII—black and unidentified lines—gray.
Figure 1. Spectrum of silver in the region 150–350 Å excited in a vacuum spark. Lines of different ion spectra are marked by different colours: Ag VI—royal blue, Ag VII—wine, Ag VIII—magenta, Ag IX—green, Ag X—blue, Ag XI—red, Ag XII—black and unidentified lines—gray.
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Figure 2. Energy levels of Ag VII. The arrows show electric dipole transitions. The levels found in this work and studied transitions are marked by red color. Black color indicates unknown levels and transitions.
Figure 2. Energy levels of Ag VII. The arrows show electric dipole transitions. The levels found in this work and studied transitions are marked by red color. Black color indicates unknown levels and transitions.
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Figure 3. Energy levels of Ag VIII. The arrows show electric dipole transitions studied in this article. The levels found in this work are marked by red color. Black color indicates unknown levels.
Figure 3. Energy levels of Ag VIII. The arrows show electric dipole transitions studied in this article. The levels found in this work are marked by red color. Black color indicates unknown levels.
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Figure 4. Energy levels of Ag IX. The arrows show electric dipole transitions studied in this article. The levels found in this work are marked by red color. Black color indicates calculated positions of unknown levels.
Figure 4. Energy levels of Ag IX. The arrows show electric dipole transitions studied in this article. The levels found in this work are marked by red color. Black color indicates calculated positions of unknown levels.
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Ryabtsev, A.; Kononov, E. Resonance Transitions in the Spectra of the Ag6+–Ag8+ Ions. Atoms 2017, 5, 11. https://doi.org/10.3390/atoms5010011

AMA Style

Ryabtsev A, Kononov E. Resonance Transitions in the Spectra of the Ag6+–Ag8+ Ions. Atoms. 2017; 5(1):11. https://doi.org/10.3390/atoms5010011

Chicago/Turabian Style

Ryabtsev, Alexander, and Edward Kononov. 2017. "Resonance Transitions in the Spectra of the Ag6+–Ag8+ Ions" Atoms 5, no. 1: 11. https://doi.org/10.3390/atoms5010011

APA Style

Ryabtsev, A., & Kononov, E. (2017). Resonance Transitions in the Spectra of the Ag6+–Ag8+ Ions. Atoms, 5(1), 11. https://doi.org/10.3390/atoms5010011

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