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Proceeding Paper

C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics †

by
Josué Jiménez
1,
Juan Sánchez-Camacho
1,
Florencio Moreno
1,
Antonia R. Agarrabeitia
1,
Teresa Arbeloa
2,
Trevor A. Cabreros
3,
Gilles Muller
3,
Jorge Bañuelos
2,
Beatriz L. Maroto
1,* and
Santiago de la Moya
1,*
1
Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, 28040 Madrid, Spain
2
Departamento de Química Física, Facultad de Ciencias y Tecnología, Universidad del País Vasco-EHU, 48080 Bilbao, Spain
3
Department of Chemistry, San José State University, San José, CA 95192-0101, USA
*
Authors to whom correspondence should be addressed.
†
Presented at the 23rd International Electronic Conference on Synthetic Organic Chemistry, 15 November – 15 December 2019; Available online: https://ecsoc-23.sciforum.net/.
Proceedings 2019, 41(1), 53; https://doi.org/10.3390/ecsoc-23-06610
Published: 20 January 2020
(This article belongs to the Proceedings of The 23rd International Electronic Conference on Synthetic Organic Chemistry)
Versions Notes

Abstract

C*-BODIPYs, that is, boron dipyrromethenes (BODIPYs) which have chiral carbons attached directly to the boron center, are introduced for the first time. These novel chiral BODIPYs mean a new strategy for the chiral perturbation of the inherently achiral BODIPY chromophore that is directed to enable chiroptical properties. Their preparation is very simple and only implies the complexation of a dipyrrin with an enantiopure dialkylborane having boron bonded to chiral carbons.
Keywords: BODIPYs; circular dichroism; circularly polarized luminescence; CPL-SOMs BODIPYs; circular dichroism; circularly polarized luminescence; CPL-SOMs

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MDPI and ACS Style

Jiménez, J.; Sánchez-Camacho, J.; Moreno, F.; Agarrabeitia, A.R.; Arbeloa, T.; Cabreros, T.A.; Muller, G.; Bañuelos, J.; Maroto, B.L.; Moya, S.d.l. C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics. Proceedings 2019, 41, 53. https://doi.org/10.3390/ecsoc-23-06610

AMA Style

Jiménez J, Sánchez-Camacho J, Moreno F, Agarrabeitia AR, Arbeloa T, Cabreros TA, Muller G, Bañuelos J, Maroto BL, Moya Sdl. C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics. Proceedings. 2019; 41(1):53. https://doi.org/10.3390/ecsoc-23-06610

Chicago/Turabian Style

Jiménez, Josué, Juan Sánchez-Camacho, Florencio Moreno, Antonia R. Agarrabeitia, Teresa Arbeloa, Trevor A. Cabreros, Gilles Muller, Jorge Bañuelos, Beatriz L. Maroto, and Santiago de la Moya. 2019. "C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics" Proceedings 41, no. 1: 53. https://doi.org/10.3390/ecsoc-23-06610

APA Style

Jiménez, J., Sánchez-Camacho, J., Moreno, F., Agarrabeitia, A. R., Arbeloa, T., Cabreros, T. A., Muller, G., Bañuelos, J., Maroto, B. L., & Moya, S. d. l. (2019). C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics. Proceedings, 41(1), 53. https://doi.org/10.3390/ecsoc-23-06610

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