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Proceeding Paper

Aqueous Micellar Systems Formed by Surfactant Ionic Liquids. Application in Diels-Alder Reactions †

by
Jesica B. Soffietti
,
Claudia G. Adam
* and
Claudia D. Della Rosa
*
IQAL (UNL-CONICET), Laboratorio Fisicoquímica Orgánica, Facultad de Ingeniería Química, University Nacional del Litoral, Santiago del Estero 2829, Santa Fe 3000, Argentina
*
Authors to whom correspondence should be addressed.
†
Presented at the 23rd International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2019; Available online: https://ecsoc-23.sciforum.net/.
Proceedings 2019, 41(1), 72; https://doi.org/10.3390/ecsoc-23-06464
Published: 14 November 2019
(This article belongs to the Proceedings of The 23rd International Electronic Conference on Synthetic Organic Chemistry)
Versions Notes

Abstract

In the present work, our objective is to take advantage of the property presented by Ionic Liquids (ILs) based on 1-alkyl-3-methylimidazolium cations by having amphiphilic character when the alkyl group is a long hydrocarbon chain. These ILs can act as surfactants forming micelles in aqueous solution. In this sense, the micellar effect on a Diels-Alder reaction (DA) was analyzed taken as a reference. The reactive system studied consists of maleic anhydride and isoprene, variables such as diene:dienophile ratio and reaction temperatura among the most important were optimized. N,N-dodecylmethylimidazolium bromide was used at the critical micellar concentration (CMC) of 1 × 10−2 M. These “new systems” microheterogeneous would allow, in addition to better solubilization of non-polar substrates, to adopt milder reaction conditions.
Keywords: ionic liquids; surfactants; micelles; Diels-Alder ionic liquids; surfactants; micelles; Diels-Alder

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MDPI and ACS Style

Soffietti, J.B.; Adam, C.G.; Rosa, C.D.D. Aqueous Micellar Systems Formed by Surfactant Ionic Liquids. Application in Diels-Alder Reactions. Proceedings 2019, 41, 72. https://doi.org/10.3390/ecsoc-23-06464

AMA Style

Soffietti JB, Adam CG, Rosa CDD. Aqueous Micellar Systems Formed by Surfactant Ionic Liquids. Application in Diels-Alder Reactions. Proceedings. 2019; 41(1):72. https://doi.org/10.3390/ecsoc-23-06464

Chicago/Turabian Style

Soffietti, Jesica B., Claudia G. Adam, and Claudia D. Della Rosa. 2019. "Aqueous Micellar Systems Formed by Surfactant Ionic Liquids. Application in Diels-Alder Reactions" Proceedings 41, no. 1: 72. https://doi.org/10.3390/ecsoc-23-06464

APA Style

Soffietti, J. B., Adam, C. G., & Rosa, C. D. D. (2019). Aqueous Micellar Systems Formed by Surfactant Ionic Liquids. Application in Diels-Alder Reactions. Proceedings, 41(1), 72. https://doi.org/10.3390/ecsoc-23-06464

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