A New Method for Calculating the Relative Permeability Curve of Polymer Flooding Based on the Viscosity Variation Law of Polymer Transporting in Porous Media
Abstract
:1. Introduction
2. Experimental Materials and Methods
2.1. Experimental Materials
2.2. Experimental Methods
2.2.1. Viscosity Measurement
2.2.2. Experiment Procedure of Viscosity Variation Experiment
- The target concentration polymer solutions were prepared with the polymer HNT-300 and synthetic water. The apparent viscosity of the polymer solution was measured before being injected into the core.
- The air in the core was extracted by a vacuum pump, and then the synthetic water was pushed into the pore in the core. The pore volume was equal to water volume minus the dead volume.
- The synthetic crude oil was continually injected into the core at a constant injection rate and all outlets of the core holder were closed except the last one, which was farthest from the inlet. The injecting process lasted until that no more water was coming from the exit end. The steady pressure of the core holder inlet during the injecting process was recorded. The oil volume in the core was the same as the volume of the water produced from the core. The inlet and the last outlet were closed after this step to maintain the pressure field in the core.
- The core with initial oil and irreducible water was placed at 63 °C for 12 h before use.
- The polymer solution was injected into the core at a constant injection rate. In this process, the inlet of core holder was opened as soon as the pressure of inlet reached the steady pressure while injecting oil. From the water saturation reaching about 60%, samples were taken from each sampling port for every 0.05% increase in water saturation.
- 6.
- The volumes of oil and water in the sample were measured as soon as the sample was obtained. Then, the water was separated from the sample. Next, the viscosity of the produced water was measured at once.
2.2.3. Experiment Procedure of Polymer Flooding Relative Permeability
2.2.4. Calculation Method of Relative Permeability Curve
3. Results and Discussion
3.1. Results and Discussion of the Viscosity Variation
3.1.1. Experimental Results and Data Analysis
3.1.2. Relationship between Viscosity Retention Rate and Dimensionless Distance
3.1.3. Relationship between Viscosity Retention Rate and Water Saturation
3.2. Results and Discussion of the Polymer-Flooding Relative Permeability
3.2.1. Calculation of the Relative Permeability Curves of Polymer Flooding
3.2.2. Analysis of Polymer Relative Permeability Curves Calculated by Different Viscosity Methods
- The integral viscosity can express the average viscosity of the whole core to the maximum extent. Thus, the polymer relative permeability curves calculated by the integral average viscosity are more accurate than others. From the experimental results, it can be figured out that the polymer solution relative permeability calculated by viscosity of polymer solution from the outlet was lower than that calculated by integral viscosity.
- Comparing the relative permeability curves of polymer flooding with different concentrations, we can find that, with the increase of polymer concentration, the relative permeability of water phase decreases and that of oil phase increases. The reduction of water phase permeability is due to the polymer retention in pore, which is caused by adsorption, mechanical capture and hydrodynamic capture. Furthermore, polymer molecules also have strong hydrogen bond with water molecules, which makes the adsorption of water molecules on the adsorption layer stronger. These two reasons explain the decrease of water phase relative permeability. Additionally, for the increase of oil phase, polymer molecules do not hinder the flow of oil. Furthermore, the adsorption layer formed by polymer molecules on the pore wall of rock will make the wall surface of pore throat smoother, which will reduce the flow resistance of oil.
- From the curves, it can also be figured out that the higher polymer concentration, the lower residual oil saturation. Polymer molecules can improve the mobility of water and increase the micro sweep efficiency. As a result, the increase of polymer concentration can reduce the residual oil saturation in the core.
4. Conclusions
- The viscosity retention rate of the polymer solution transporting in the core is related to the dimensionless distance from the inlet and the water saturation. The relationship can be expressed by the power function formula: VRR(Sw,Ld) = m × en × Sw × Ld−0.248
- In the case of the same water saturation, viscosity of the polymer solution transporting in the porous media decreases with the increase of the distance from the inlet and the viscosity loss happens mainly near the inlet, especially the first third length of the core. Additionally, the two coefficients have power function relationship. Meanwhile, in the case of the same dimensionless distance, the viscosity of the polymer solution transporting in porous media increases with the increase of the water saturation in the core and the two coefficients have power function relationship.
- The viscosity calculated by the integral formula is more representative of the average viscosity of polymer solution in the core, and the relative permeability curves of polymer flooding calculated by this viscosity are more able to describe the actual situation.
- With the increase of polymer concentration, the relative permeability of oil phase increases, and the relative permeability of water phase and the residual oil saturation decrease.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Sample Availability
References
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Ionic Composition | Na+ | K+ | Ca2+ | Mg2+ | Cl− | CO32− | HCO3− | SO42− | Total Salinity |
Concentration (mg/L) | 2819.78 | 270.01 | 111.04 | 4791.47 | 54.01 | 468.17 | 38.08 | 8552.56 |
Experiment Number | Polymer Concentration (mg/L) | Water Saturation (%) | R2 | Sig. | Coefficient a | Coefficient b | Minimum Value of Ld |
---|---|---|---|---|---|---|---|
VV-1 | 500 | 44.41 | 0.99 | 0.000 | 9.819 | −0.265 | 7.95 × 10−5 |
51.36 | 0.98 | 0.001 | 14.451 | −0.232 | 4.59 × 10−4 | ||
56.61 | 0.99 | 0.001 | 20.531 | −0.238 | 1.73 × 10−3 | ||
59.41 | 0.96 | 0.004 | 24.924 | −0.231 | 3.50 × 10−3 | ||
61.69 | 0.98 | 0.002 | 28.671 | −0.238 | 6.23 × 10−3 | ||
VV-2 | 1250 | 51.02 | 0.99 | 0.001 | 5.438 | −0.253 | 9.10 × 10−6 |
55.42 | 0.98 | 0.001 | 9.067 | −0.259 | 8.29 × 10−5 | ||
58.39 | 0.98 | 0.001 | 15.377 | −0.255 | 3.68 × 10−4 | ||
61.78 | 0.98 | 0.001 | 24.291 | −0.25 | 2.02 × 10−3 | ||
65.08 | 0.98 | 0.001 | 28.403 | −0.254 | 1.06 × 10−2 | ||
VV-3 | 1750 | 52.8 | 0.97 | 0.002 | 6.161 | −0.25 | 1.56 × 10−5 |
57.37 | 0.97 | 0.003 | 10.376 | −0.249 | 1.19 × 10−4 | ||
60.93 | 0.97 | 0.003 | 17.16 | −0.247 | 5.83 × 10−4 | ||
64.07 | 0.97 | 0.003 | 24.094 | −0.249 | 2.36 × 10−3 | ||
67.12 | 0.97 | 0.002 | 28.023 | −0.249 | 9.16 × 10−3 | ||
VV-4 | 2000 | 54.24 | 0.95 | 0.004 | 4.792 | −0.243 | 9.98 × 10−6 |
58.47 | 0.97 | 0.002 | 10.604 | −0.245 | 8.74 × 10−5 | ||
61.69 | 0.97 | 0.003 | 19.336 | −0.246 | 4.56 × 10−4 | ||
65.59 | 0.96 | 0.003 | 24.866 | −0.25 | 3.37 × 10−3 | ||
68.14 | 0.97 | 0.002 | 27.979 | −0.247 | 1.25 × 10−2 |
Experiment Number | Polymer Concentration(mg/L) | R2 | Sig. | Coefficient m | Coefficient n |
---|---|---|---|---|---|
VV-1 | 500 | 0.998 | 0.000 | 0.5969 | 0.0626 |
VV-2 | 1250 | 0.976 | 0.002 | 0.0098 | 0.1245 |
VV-3 | 1750 | 0.983 | 0.001 | 0.0189 | 0.1104 |
VV-4 | 2000 | 0.932 | 0.008 | 0.0058 | 0.1272 |
Experiment Number | Polymer Concentration (mg/L) | Water Saturation (%) | Average Viscosity (mPa·s) | Viscosity of Polymer Solution from Outlet (mPa·s) | Apparent Viscosity (mPa·s) |
---|---|---|---|---|---|
RP-1 | 500 | 45.81 | 0.9 | 0.7 | 6.2 |
52.13 | 1.3 | 1.0 | |||
55.89 | 1.6 | 1.2 | |||
58.19 | 1.9 | 1.4 | |||
61.28 | 2.2 | 1.7 | |||
RP-2 | 1250 | 50.28 | 1.5 | 1.1 | 21.6 |
54.61 | 2.5 | 1.9 | |||
57.96 | 3.8 | 2.9 | |||
61.46 | 5.9 | 4.5 | |||
65.53 | 9.4 | 7.4 | |||
RP-3 | 1750 | 53.68 | 3.7 | 2.8 | 39.5 |
58.59 | 6.4 | 4.8 | |||
62.08 | 9.3 | 7.1 | |||
64.59 | 12.2 | 9.3 | |||
67.89 | 17.2 | 13.4 | |||
RP-4 | 2000 | 56.03 | 4.7 | 3.5 | 48.6 |
59.81 | 7.5 | 5.7 | |||
63.02 | 11.3 | 8.5 | |||
66.36 | 17.0 | 13.1 | |||
69.18 | 23.5 | 18.7 |
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Jiang, W.; Hou, Z.; Wu, X.; Song, K.; Yang, E.; Huang, B.; Dong, C.; Lu, S.; Sun, L.; Gai, J.; et al. A New Method for Calculating the Relative Permeability Curve of Polymer Flooding Based on the Viscosity Variation Law of Polymer Transporting in Porous Media. Molecules 2022, 27, 3958. https://doi.org/10.3390/molecules27123958
Jiang W, Hou Z, Wu X, Song K, Yang E, Huang B, Dong C, Lu S, Sun L, Gai J, et al. A New Method for Calculating the Relative Permeability Curve of Polymer Flooding Based on the Viscosity Variation Law of Polymer Transporting in Porous Media. Molecules. 2022; 27(12):3958. https://doi.org/10.3390/molecules27123958
Chicago/Turabian StyleJiang, Wenchao, Zhaowei Hou, Xiaolin Wu, Kaoping Song, Erlong Yang, Bin Huang, Chi Dong, Shouliang Lu, Liyan Sun, Jian Gai, and et al. 2022. "A New Method for Calculating the Relative Permeability Curve of Polymer Flooding Based on the Viscosity Variation Law of Polymer Transporting in Porous Media" Molecules 27, no. 12: 3958. https://doi.org/10.3390/molecules27123958
APA StyleJiang, W., Hou, Z., Wu, X., Song, K., Yang, E., Huang, B., Dong, C., Lu, S., Sun, L., Gai, J., Yao, S., Wang, Y., Nie, C., Yuan, D., & Xu, Q. (2022). A New Method for Calculating the Relative Permeability Curve of Polymer Flooding Based on the Viscosity Variation Law of Polymer Transporting in Porous Media. Molecules, 27(12), 3958. https://doi.org/10.3390/molecules27123958