In this study, an improved CO
2 separation and purification system is proposed based on in-depth analyses of cryogenic separation and distillation theory as well as the phase transition characteristics of gas mixtures containing CO
2. Multi-stage compression, refrigeration, and separation are
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In this study, an improved CO
2 separation and purification system is proposed based on in-depth analyses of cryogenic separation and distillation theory as well as the phase transition characteristics of gas mixtures containing CO
2. Multi-stage compression, refrigeration, and separation are adopted to separate the majority of the CO
2 from the gas mixture with relatively low energy penalty and high purity. Subsequently, the separated crude liquid CO
2 is distilled under high pressure and near ambient temperature conditions so that low energy penalty purification is achieved. Simulation results indicate that the specific energy consumption for CO
2 capture is only 0.425 MJ/kgCO
2 with 99.9% CO
2 purity for the product. Techno-economic analysis shows that the total plant investment is relatively low. Given its technical maturity and great potential in large-scale production, compared to conventional MEA and Selexol
TM absorption methods, the cost of CO
2 capture of the proposed system is reduced by 57.2% and 45.9%, respectively. The result of this study can serve as a novel approach to recovering CO
2 from high CO
2 concentration gas mixtures.
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