3.1. Technical Proposal for NOx Measurement Method
As explained in
Appendix A, NOx emissions from diesel vehicles strongly correlate with engine power demand [
24], and the “% engine load” is an ECU parameter related to the engine power demand.
This proposal is based on the analysis of the variation of the NOx concentration at the vehicle exhaust gas pipe, caused by the modification of the “% engine load” at idle. The engine idle state is chosen to simplify the test and ensure repeatability for the reasons explained in
Section 2.2.
At this idling condition, the engine can be easily subjected to two different engine load states defined by the measurement of the “% engine load”. The NOx concentration variation and other engine working parameters are read through the OBD system.
Experience tells us that the better way to increase the “% engine load” value, if the vehicle is in static conditions, is not with a free acceleration from idling, but increasing the power demand from the equipment in the vehicle. Simply switching on the engine and working at a natural engine idle speed, some of the torque available is consumed by the necessary accessories of the engine (water pump, alternator, etc.). This consumption translates directly into a “% engine load” value, which gives us the percentage of torque used compared with the available peak torque at natural engine idle speed. We name the situation of the engine with minimum power demand as “Unloaded state”.
Increasing the power demand when the vehicle is idling increases the “% engine load” significantly. One of the easiest ways to increase the power demand is connecting some vehicle equipment, such as the Air Conditioning (A/C) system, the lighting and signaling system, and the rear window heater system.
The power demand from the Air Conditioning system and the vehicle’s electric equipment are not considered in the type approval NEDC test. However, it is estimated that it may vary the CO
2 emissions. Instead, the USA SC03 Air Conditioning test is used to control the pollutant’s emissions of the vehicles because the Air Conditioner compressor is the highest power-consuming accessory, and it increases NOx emissions [
60]. Several previous measurements demonstrate that A/C system use increases the engine load and NOx emissions [
61]. Furthermore, the battery’s state of charge at the start of the NEDC test can vary by as much as 3% of the CO
2 emissions, so, for the tests to be consistent between measurements, full battery charge must be ensured [
16]. This gives an idea of the influence that Air Conditioning and electrical consumption can have on vehicle pollutant’s emissions while idling. We name the situation of the engine with the vehicle’s equipment connected as “Loaded state”.
Through this procedure, it is possible to double the “% engine load” from the initial Unloaded state to the Loaded state and even reach a higher “% engine load” than in a simulation bench. Depending on the vehicle, a “% engine load” of more than 50% can be reached with the vehicle at the natural engine idle speed. The average increase in “% engine load” from the Unloaded state to the Loaded state is about 100%.
Instead, free acceleration from natural engine idle speed without a gear engaged increases the “% engine load” for a short time, decreasing immediately to a lower natural engine idle speed level. If the engine speed is increased, the available peak torque is increased too, but the torque consumed from the engine remains constant if there is no new consumption. As a consequence, the “% engine load” decreases. The initial increase in “% engine load” comes from the inertial forces of the engine that are necessary to overcome. When the new engine speed is reached, the “% engine load” decreases. This behavior can be observed in
Figure 1.
The gas analyzer uses an OBDII reader to measure and register the “% engine load” value. This connector plugs into the OBDII port of the vehicle and transmits the required parameters to the measurement equipment [
43,
62,
63,
64].
The “% engine load” is not the only parameter registered from the ECU of the vehicle. Other relevant parameters that could be registered through the vehicle’s OBD port are available: the engine speed, the % EGR opening, and the engine temperature, among others.
Summarizing, through the OBDII port, several working parameters are read from the vehicle’s ECU, the “% engine load” being the most important. Simultaneously, a gas analyzer measures NOx concentration from the vehicle’s exhaust pipe. The details of the gas analyzer used are shown in
Appendix B.
Combining the OBD data and the NOx concentration measures from the gas analyzer, it is possible to analyze the relationship between the exhaust gases NOx concentration from the vehicle and the operational engine parameters, precisely the “% engine load”.
3.2. Protocol
A protocol must be followed to ensure that every test is performed in the same way. This protocol consists of three steps: (a) verification of vehicle conditions for the performance of the test, (b) preconditioning of the vehicle, and (c) execution of the defined cycle for the test.
The first and second steps are shared with the current opacity measurement procedure [
43]. The only difference is the measurement equipment used: an opacimeter is used for the current measure of opacity in diesel vehicles. However, for the NOx measurement, equipment able to measure NOx concentration (such as the equipment described in the Appendices, but not exclusively) are used.
For the first step, the conditions of the vehicle must be verified to ensure that the vehicle is suitable and is prepared to be subjected to the test. The following aspects must be checked: the state of the exhaust system is correct and does not show any apparent damage or modifications (visual checking), any extra loads and equipment of the vehicle are disconnected, the vehicle shows an adequate mechanical and electrical condition, and the vehicle does not indicate faults using the MIL indicator (or OBD).
In the second step (preconditioning), it must be checked if the engine is in normal working condition, using the engine oil temperature. At this point, vehicle manufacturer information must be used. If it is not available, the engine oil temperature or, alternatively, the engine crankcase temperature should reach at least 80 °C, according to preconditioning for opacity test [
43].
The third step consists of the implementation of the cycle defined in
Table 2. The blowpipe of the measurement equipment is introduced into the exhaust pipe and the OBD connector is plugged into the OBD port of the vehicle. Once the measurement equipment is ready, the five stages indicated in
Table 2, must be followed while NOx concentration is measured.
As OBD data reading is necessary, only vehicles with OBDII port and supported communication protocol available are suitable for the test. That includes most Euro 4 vehicles, as well as Euro 5 and Euro 6. Some Euro 3 vehicles are suitable for this type of measurement, but OBD reading is not always ensured.
The procedure and results obtained for a vehicle (vehicle No. 20, from the vehicle set listed in
Section 3.4) are presented below to illustrate the testing process. The results of the test are compiled following the instructions from
Table 3. With these data, the graph shown in
Figure 1 is built. The measurement time is along the x-axis, NOx concentration and mass flow are on the left y-axis, and engine speed, “% engine load”, and % EGR aperture are on the right y-axis.
Reading time for each stage can be defined at convenience, but 20 s for each stage can be enough. With the engine working at a steady state, it is unnecessary to wait for a long time to get enough representative values. If engine working is irregular, a longer time might be required to get enough measurements to reach a representative average. The simplicity of the method allows using as much time as necessary to make a correct measurement easily.
For each stage, the average value of the recorded parameters is calculated. The combination of the average concentration of NOx and the average of the corresponding “% engine load” provides the numeric results for the test. To calculate the average values of NOx concentration, only data of steady emissions and “% engine load” are selected, avoiding sections of data where emissions are increasing or decreasing (limits between stages). In this way, the average calculated represents, more accurately, the NOx emissions for the corresponding engine load state.
Figure 1 presents the five stages described before. In the first place, the first Unloaded stage can be seen, where the average value of “% engine load” is 13%, and the average NOx concentration read is about 150 ppm. In the second stage (Loaded state), the “% engine load” increases to an average value of 36%, while an increase in average NOx concentration to 465 ppm is observed.
In these two stages, the EGR system was inactive, so the control emissions system does not affect the value of NOx concentration read. That means the correlation between NOx concentration in the exhaust pipe and “% engine load”, if it exists, is not modified by the influence of another parameter. The tests carried out show that the indicators of the correlation (R
2 and
p-value, see
Appendix D) between data of both variables are generally higher in these two stages than in other parts of the cycle, where other parameters may affect the concentration of NOx. To summarize, at these stages, the correlation between both variables is so strong (evidenced by the R
2 and
p-value from NOx concentration and “% engine load” data) because of the absence of other factors.
In stage 3, the engine is accelerated to an average speed of 2163 rpm, which provokes some changes in the engine’s behavior.
A free acceleration reduces the “% engine load”. When engine speed is increased, the available torque and power from the engine also increase. Still, the power demand in stage 3 remains the same as in stage 2 (after an initial peak of power, the engine needs to overcome the inertial forces from the engine acceleration). Consequently, if available torque and power are higher, but the power demand remains the same, the “% engine load” value decreases. This situation can be observed in
Figure 1: as soon as the engine speed increases, the “% engine load” decreases. The same situation was observed in every test carried out.
A second change is when the engine speed increases and NOx concentration decreases. This reduction results from the “% engine load” reduction, which is another validation of the relationship between NOx concentration and “% engine load”. Although power demand is steady in stages 2 and 3, the NOx concentration in stage 3 decreases. This reduction is related to the “% engine load” reduction. The same behavior was observed in every test carried out.
Besides this, the engine acceleration causes the opening of the EGR valve and an additional reduction in NOx concentration. As shown in
Table 3, in the Loaded & Accelerated section, the EGR valve is 56% opened on average. As a consequence, the average NOx concentration in this 3rd stage is similar to the 1st stage but with the following difference: in the 1st stage, the NOx concentration was steady and continuous, while in the 3rd stage, the NOx concentration is strongly decreasing from a maximum value of 478 ppm to a value near to 100 ppm. Meanwhile, the engine load was reduced and maintained at 11% throughout this stage (slightly lower than at unloaded conditions).
In the 4th stage, the engine speed goes back to 750 rpm, the same speed as the 1st and 2nd stages, and engine load returns to 35 ”% engine load”, the same level as the 2nd loaded stage. However, the NOx concentration in the 4th stage is lower than in the 2nd stage. This is because the EGR valve remains open at 30%, reducing the NOx emissions of the vehicle. As a result, the average NOx concentration in the 4th stage is slightly higher than in the 1st stage and significantly lower than in the 2nd stage.
Finally, in the 5th stage, the EGR valve remains open (even more than in the 4th stage), while “% engine load” is reduced to the same level as the 1st stage. As a consequence, NOx concentration in the 5th stage is lower than in the 1st stage.
This behavior supports the hypothesis that NOx concentration is related to “% engine load” at idling, and % EGR reduces the NOx concentration in the vehicle’s exhaust gas.
As a result of the static NOx test,
Table 3 is obtained. Data from stage 1 and stage 5 are joined in the “Unloaded idle state”, and data from stage 2 and stage 4 are joined in the “Loaded idle state”, while data from stage 3 are placed in the “Loaded & Accelerated state” to build the table. The average values of NOx concentration, “% engine load” and the other emissions and parameters are summarized and calculated for each of the states.
The accelerated section is necessary to make sure that the EGR system or other EATS (Exhaust After-Treatment Systems) are working if they were not previously activated (usually they are not), although these NOx values are not used to define the NOx emissions level. In this way, EGR and EATS work along stages 4 and 5 (according to ECU programming), and the influence over the NOx concentration from this system is accounted for by the average values in the final result. This stage is not useful for checking emission rates during acceleration because it is a free acceleration without additional load (the load only appears when engine acceleration increases vehicle speed). The result of this type of free acceleration is a decrease in the “% engine load”.
This behavior reproduces what happens in actual urban driving conditions, where once the vehicle stops and remains idling (e.g., at a red light), the EGR and EATS also stop working until the vehicle is back in motion, and the operating conditions programmed in the ECU are reached.
These results make it possible to use the average NOx concentration at both states (Unloaded idle state and Loaded idle state) as a simple indicator of NOx concentration level. Moreover, Unloaded state concentration or Loaded state concentration could be used to make a comparison between vehicles (
Table 3).
Although NOx concentration could be used to compare the level of NOx emissions between vehicles (most of the NOx test methods explained in the
Section 2.1.1 and
Section 2.1.2 provide NOx concentration as a result), it is more appropriate to make this comparison in absolute terms. For the same NOx concentrations, higher engine size and/or higher engine idle speed arguably emit a greater mass of NOx than smaller vehicles.
In approval type procedures, emission factors (g/km) are used to compare pollutant emissions, yet this value cannot be obtained from a static test. Instead, the NOx mass emissions flow in mg/s can be used to compare emissions. This value is not directly obtained from the measurement equipment and should be calculated. The procedure to do so is explained in
Appendix C.
In this way, it is possible to determine NOx emission mass flow (see
Figure 1) in mg/s throughout the test. With these data, the average value of NOx emission mass flow in each of the five stages of the test can be obtained and used in the same way as with the NOx concentration. These values are included in
Table 4 for a complete overview of NOx concentration and mass emissions at both states. The results summary in
Table 4 includes the maximum value of NOx concentration read in the test (in the Unloaded or Loaded state) because it is further used to estimate the maximum value of NOx concentration by extrapolation with the unloaded and loaded values.
Uncertainties associated with measured and estimated data are calculated according to the Guide JCGM 100:2008 [
65] and presented in
Table 5. Uncertainties depend on the measuring equipment used.
Once the set of values is completed for both states, including the maximum instantaneous value, it is possible to define a linear regression function relating NOx concentration and NOx mass emissions with “% engine load”, as is shown in
Figure 2.
As a part of the data, the value of 0 ppm NOx concentration is related to the value 0 “% engine load”, and the value of 0 mg/s NOx emission is also related to the value 0 “% engine load”. According to the definition of “% engine load”, its value is 0% at engine off and ignition on [
60]. With this (0,0) point, and the three points defined in
Table 4 (pair NOx (mg/s)- “% engine load”, pair NOx (ppm)-”% engine load”), a linear regression function is defined to extrapolate the value of NOx emissions mass flow at 100 ”% engine load” (
Figure 2, left plot). Another linear regression function is defined to extrapolate the value of NOx concentration at 100 ”% engine load” (
Figure 2, right plot).
Finally, once both linear regression functions are available,
Table 4 can be completed. The TMV (Theoretical Maximum Value) is the estimation of the vehicle’s NOx emissions if it were at 100% of “% engine load” at idling state. This estimated data is the final result of the test. It defines the NOx emissions level of the vehicle, which can then be used to compare NOx emissions between different vehicles. The calculation of TMV can be easily incorporated into measurement software as the final result of the test.
As an indicator, the TMV could be helpful to detect the NOx high emitters and to classify the fleet, according to NOx emissions levels.
Moreover, idle Unloaded and idle Loaded average NOx emissions mass flow provide a close estimation of the actual value of NOx emissions from a vehicle when, during urban circulation, it is stopped at a red light or remains stopped in a traffic jam. A significant amount of the vehicle NOx emissions throughout a trip are emitted while the vehicle is stationary and idling, i.e., in the conditions under which the test is performed.
The determination of this information from a significant amount of the vehicle fleet can allow us to characterize the expected NOx emissions from actual vehicle information. This information, in turn, can be beneficial in generating appropriate environmental protection policies. For example, it can be used to optimize traffic light frequencies from a NOx emissions point of view in sensitive areas.
In summary, the average values obtained from the test are a close estimation of NOx actual emissions when the vehicle is stopped during actual circulation. In addition to this, the TMV of NOx emission mass flow (mg/s) could be a good indicator of the NOx emissions level, obtained from a test performed under the same operating conditions on all vehicles, so it may be a suitable way to compare emissions between vehicles. In this way, emissions from vehicles with different technical characteristics can be compared because the relative tested condition for all of them is the same: at the lowest possible engine load (unloaded idling) and the theoretical maximum load while idling. These two conditions are the minimum and the maximum possible load demand for idling, and although the absolute values of load demand involved can be very different, the relative situation is the same for every vehicle tested and can be used for comparison purposes between them.
3.4. Results
The explained method has been applied to the diesel vehicles indicated in
Table 8. The vehicles come from 14 different manufacturers representative of the European market. They have emission levels from Euro 3 to Euro 6, with engine sizes from 1248 cm
3 to 2993 cm
3, and engine power from 66 kW to 210 kW. For each vehicle, several tests have been carried out to compare the dispersion of the results in a similar way as was explained before. One petrol vehicle (vehicle No. 18) has also been tested in the same way to compare the NOx emissions of diesel engine vehicles with petrol engine vehicles.
The average results of this complete set of measurements are shown in
Table 9. The average NOx concentration at loaded idle was
152% higher than average NOx concentration at unloaded idle, and the average “% engine load” at loaded idle was
106% higher than average “% engine load” at unloaded idle. The increase in “% engine load” between both load states is large enough for the explained linear extrapolation. Furthermore, these results confirm the assumption, used as a basis for the proposal, that the concentration of NOx in the exhaust pipe is related to the “% engine load”.
The same situation is observed for the NOx mass flow emissions, where the average value of loaded state emissions is 146% higher than average unloaded idle emissions. Again, the increase in NOx mass flow emissions between both load states allows the building of a linear function.
Comparing the average results for each diesel vehicle (see
Figure 4), it can be observed that increases in NOx concentration and NOx mass flow from the unloaded to the loaded state is heterogeneous but always significant, with the lower increase being 102% (vehicle No. 12), and the largest increase being 431% (vehicle No. 4). The same behavior can be observed for the TMV values, with the lower increase from loaded state to TMV of 172% (Vehicle No. 7) and the largest increase being 394% (Vehicle No. 8). Heterogeneity in the results (that means the different NOx emission behavior), even between vehicles from the same emission level, comes from different ECU’s vehicle management of EGR and EATS.
It can also be observed how some vehicles with more demanding emission levels present equal or higher emissions than less demanding vehicles. This is one of the problems indicated in the introduction [
6,
14], and it is detected with the process of measuring. From RSD tests [
66,
67,
68], Euro 6 emissions are lower than Euro 4 and Euro 5 (which are very similar between them). Still, comparing vehicle to vehicle, we can find Euro 6 vehicles with similar emissions to Euro 4 or Euro 5. The NOx emissions behavior of the sample vehicles is similar to that observed with other types of measurements such as with RSD.
The average engine load reached at loaded idle is 41.7% (in some cases, it went up to 60%), while the average engine load at unloaded idle is 20.3%. This shows how this static NOx measurement method, without any additional equipment or simulation bench, makes it possible to double the “% engine load” between unloaded and loaded idle, allowing to analyze and compare NOx emissions for two different load demand situations.
For the petrol engine vehicle, NOx concentration in unloaded idle state and loaded idle state is at least 20 times lower than the average NOx concentration for diesel engines. This difference is even higher for the NOx mass flow emissions. However, the “% engine load” reached is similar to diesel engine vehicles. The value for both states, 22% for unloaded idle and 38 % for loaded idle, is near the mean of the complete set of vehicles previously mentioned. These results verify the fact that diesel vehicles are the main NOx emitters [
11,
12,
13].
Summarizing, the results show that for the set of vehicles analyzed:
- (a)
There is an average increase of 106% of “% engine load” from Unloaded idle to the Loaded idle for the complete set of vehicles tested
- (b)
There is a significant increase in NOx concentration from the Unloaded idle to the Loaded idle in all vehicles, with an average increase of 152%.
- (c)
There is a significant increase in NOx flow mass emission from the Unloaded idle to the Loaded idle in all vehicles, with an average increase of 146%.
- (d)
The petrol engine vehicle shows the same levels of “% engine load”, but NOx concentration values are 20 times smaller than average diesel vehicles NOx concentration, and the difference is even higher for the NOx mass flow emission.
- (e)
The relationship between NOx concentration and “% engine load” is better for the initial section, due to the inactivity of the EGR and after-treatment systems in this section. As a result, there is less dispersion of results.
- (f)
Standard Deviation for NOx concentration and NOx mass flow emissions is lower for unloaded idle than loaded idle.
- (g)
Standard Deviation for “% engine load” is lower for unloaded idle, but in both states, it is very low (1.4% unloaded idle, 2.6% loaded idle). This means that the “% engine load” shows low dispersion when the test is carried out several times over the same vehicle.
- (h)
The average Coefficient of Variation is similar for the NOx concentration and NOx mass flow emission for unloaded idle and loaded idle (17–18%). This means the dispersion of data is the same for both states and types of measurements.
- (i)
The Coefficient of Variation for “% engine load” is 7% for both idle states. It confirms that “% engine load” data dispersion is low, and the tests are always deployed under the same conditions of “% engine load”.