2.1. Terminology in Sustainability Analyses
The environmental impact of a product is commonly identified through a life cycle analysis (LCA). An LCA is a structured and comprehensive method of quantifying material and energy flows and the associated emissions during the life cycle of a product [
13]. It is often referred to as a “cradle to grave” analysis, which includes materials and processes from raw material extraction through to the production, transportation, use and end-of-life of the product [
13]. Furthermore, it encompasses the impact on people involved in all product life stages and on the environment [
14].
LCA has specific terminology including embodied energy (EE), embodied carbon (EC) and several impact categories. EE is the energy required for processing and supplying the material. EC is directly associated with the EE of the material and also includes GHG emissions during the life cycle of the product, which can be represented as a CO2 equivalent. A measure of the environmental performance of the product is its energy payback time (EPBT), which is the time required by the system to generate the amount of energy required during its production. Analogically, the definition for the greenhouse gas payback time (GPBT) is the amount of time a system requires to compensate for the GHG emissions that were released during its production.
The impact on the environment and human health is assessed and categorised in terms of global warming potential (GWP), acidification potential (AP), eutrophication potential (EP), human toxicity potential (HTP), photochemical ozone creation potential (POCP) and ozone layer depletion potential (ODP) [
15]. According to the IPCC, the GWP refers to the release of gases that contribute to global warming [
16]. AP denotes the amount of air pollutants, such as sulphur dioxide and nitrogen oxide, released during electricity production and fuel combustion, which can lead to the acidification of soils and water when transformed into acids [
15,
17]. Čuček et al. [
18] define EP as the contribution to the increase in nitrogen and phosphorus in the rivers or lakes leading to the rapid growth of water plants. Overstimulation of the growth of water plants on the surface causes a reduction of sunlight in the deeper waters, reducing photosynthesis and leading to the suffocation of fish due to the lack of oxygen [
17]. Singh et al. [
19] indicated that HTP relates to the emissions of substances, which due to their chemical or physical properties can cause damage to a person’s health over a period of time. It includes the point source of the emissions, its behaviour and the potential to spread in the environment [
17]. ODP refers to the emissions of chlorofluorocarbons and nitrogen oxides, which lead to the depletion of the ozone layer and thus to an increased amount of short-wave UV radiation, which harms animal and vegetational health [
17,
20]. Ozone at the ground level and in the troposphere, however, can harm the ecosystems and be toxic to humans. It is created in a reaction between nitrogen oxides and hydrocarbons under solar radiation. The main contributor to the POCP is attributed to electricity production and fuel combustion. Thus, the production process of PV cells contributes the most to the POCP.
2.2. Low Concentration Photovoltaic (LCPV) Sustainability Analyses in Literature
To date, only a limited number of LCA studies on concentrated photovoltaic (CPV) systems can be found. Lamnatou and Chemisana [
11] have conducted a comparative analysis of all CPV LCA studies up to 2016 and concluded that the majority of CPV LCA studies were on high-concentration PV systems. For low-concentration PV (LCPV), only a few LCA studies have been published, which are referred to in the following paragraphs.
Lamnatou et al. [
21,
22] carried out two LCA studies for the truncated dielectric asymmetric compound parabolic concentrator (Di-ACPC) module, which was proposed by Sarmah [
23] for building integration. The Di-ACPC was made of polyurethane, had a geometric concentration ratio of 2.8× and was assumed to be used with monocrystalline (mono-c-Si) cells. The first study [
21] examined the influence of the user’s location on the EPBT and showed an overall reduction in EBPT by 1.2 years compared to a flat PV module. From this analysis, PV cells were found to have the highest contribution to the embodied energy and the embodied carbon followed by the dielectric concentrators.
Lamnatou et al. [
22] then completed a more advanced study of the Di-ACPC module using different life cycle impact assessment methods and environmental indicators. From the second study, PV cells were found to have the highest contribution to climate change and the highest impact on ecosystems, human health and toxicity. The concentrator, on the other hand, had the highest impact on resource depletion. The amount of resources used for the concentrator production depends on the gain-to-volume relation of the concentrator. The Di-ACPC-55 is a less compact design than the GOCRSH_A, with an optical concentration ratio of around 2.3×, while the optical concentration ratio of the Di-ACPC-55 at normal incidence is 19% smaller compared to the optical concentration ratio of the GOCRSH_A and its volume for a 100 mm
2 solar cell is smaller by 4% (Di-ACPC-55 volume for a 100 mm
2 solar cell is estimated as 2633 mm
3). Furthermore, the GOCRSH_A has a larger field of view and thus enables electricity generation for more hours. Larger sustainability benefits can therefore be assumed from the GOCRSH design compared to the Di-ACPC design.
Lamnatou et al. [
24] conducted a further LCA for the 3D crossed compound parabolic concentrator (CCPC) proposed by Sellami [
25]. The 3D CCPC was made from polyurethane, assumed to be used with mono-c-Si cells, had a geometric concentration ratio of 3.6× and was analysed for building integration in seven different cities. Using several LCA methodologies, similar results as the Di-ACPC LCA were obtained, with the PV cells showing the strongest impact on human health and ecosystems whilst the 3D CCPC module contributed the most to resource depletion. Since the gain-to-volume relation of the GOCRSH_A is higher than of the 3D CCPC within the angles of incidence of ±40°, the GOCRSH is expected to further reduce the impact on human health and ecosystems and to use fewer resources. The optical concentration ratio of the GOCRSH_A within the angles of incidence of ±40° is higher by 9.3% while its volume is smaller by 32% compared to the 3D CCPC.
A further study was undertaken by De Feo et al. [
26] for a reflective V-trough concentration system installed in Italy. With a geometric concentration ratio of 2.0× and integration with poly-ci-Si cells, the analysis concluded that an environmental impact reduction in CO
2 equivalent of around 17% can be achieved.
Zawadzki et al. [
27] carried out an LCA on a rotationally asymmetrical compound parabolic concentrator (RACPC) that has a geometrical concentration ratio of 2.67× and integrated with mono-c-Si cells. They found that 67% of the total embodied energy is put towards the manufacture of PV material for a conventional PV module whereas for the RACPC-PV module, 50% of all total embodied energy is used in the manufacture of all concentrators made from Poly(methyl methacrylate) (PMMA). They concluded that the RACPC-PV module has a reduction of 11.76% of the embodied energy material manufactured when compared to a conventional solar photovoltaic (PV) module.
An LCA for the asymmetric compound parabolic concentrator (a-CPC) system made of PMMA, with a power ratio of 1.74× and integration with mono-c-Si cells was carried out by Li et al. [
17]. The authors identified that PV cells had the main contribution to the AP, GWP, EP and HTP followed by the production of the a-CPC device. The production of the mono-c-Si solar cells and the transformation from MMA to PMMA were identified as the most energy-intensive process steps. Therefore, a reduction in PV and PMMA materials is crucial to minimise the environmental impact of the CPV system.
Overall, the AP, EP and HTP in CPV systems are associated with the electricity generation required for the production of the module components. The AP impact increases with the amount of coal-based electricity in the electricity mix since the combustion of coal leads to the release of nitrogen oxide. The EP influence is mainly due to the release of phosphate and nitrite acid during electricity and steam production. From the module assembly process, the polyethylene terephthalate (PET), polyvinyl fluoride (PVF), ethylene-vinyl acetate (EVA) foils and the glue, as well as the aluminium, were identified as the main contributors [
17]. Furthermore, the HTP effect is mainly due to heavy metals and emissions released to the air and clean water during the production of electricity, steam and materials [
17]. In contrast to the indicators discussed above, the main contributors to the ODP are primarily attributed to the fabrication of primary aluminium for the module frame [
17]. From the LCPV LCA analyses carried out in the literature, it can be concluded that the substitution of the PV material with dielectric concentrators reduces the impact of the modules on the environment mainly by reducing the energy embodied in the module materials [
17]. In the following
Section 3, a comparison is drawn between the energy embodied in the materials of the GOCRSH_A module and a flat PV module.
2.5. GOCRSH_A and Flat PV Module Components
The basic components of the GOCRSH_A module and the flat PV module are listed in
Table 7. Although the front sheet of the d.light S300, which is taken for reference, has a polymer front sheet, glass is taken as the front sheet for the flat module and as the front and backsheet for the concentrated module, since the type of polymer used in the d.light S300 is not known.
In conventional PV modules, the backsheet is typically a composite material of a 0.25 mm PET film between two Tedlar films of 40 µm thickness (TPT) [
35]. Therefore, the back sheet does not provide a support structure but is used for weather resistance, UV resistance and acts as a moisture barrier.
The GOCRSH_A module, however, needs a backsheet that can carry the weight of the GOCRSH_A concentrators, which is a total of 175 g here. A glass–glass module structure is therefore assumed for the concentrated module with 2-mm-thick tempered glass.