Microplastic Pollution and Monitoring in Seawater and Harbor Environments: A Meta-Analysis and Review
Abstract
:1. Introduction
2. Research Methodology
3. Data Collection/Bibliometric Analysis for the Meta-Analysis
4. Analysis of Review Papers
5. Bibliometric Analysis of All Articles for Microplastics in Ports and Coasts
6. Results and Discussion
6.1. Sources, Fate, and Route, Transfer
6.2. Methods of Detection/Identification/Characterization
6.3. Status of Microplastics (Size, Shape, Color, Polymer Type)
6.3.1. Polymer Type
6.3.2. Size
6.3.3. Shape
6.3.4. Color
6.4. Ecological Risk
6.5. Monitoring Microplastics
6.6. Legislation
6.7. Gaps
6.8. Practical Solutions/Future Suggestions
7. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Conflicts of Interest
References
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Country | % |
---|---|
China | 41 |
Germany | 27.3 |
UK | 22.7 |
Brazil | 18.8 |
Nigeria, USA | 13.6 |
Country | Publications on Microplastics in Ports and Coasts (%) |
---|---|
China | 17.2 |
Brazil | 15.5 |
Italy | 13.8 |
UK | 12.0 |
Germany | 10.3 |
Japan, India, Norway, Australia | 8.6 |
New Zealand, South Korea | 7.0 |
South Africa, USA, Netherlands | 6.9 |
Indonesia, Spain, France, Iran | 5.2 |
Russia, Kenya, Croatia, Peru, Malaysia, Portugal, Egypt | 3.5 |
Polymer Types | Shape | Size | Color/Texture | Pollution Source | Method of Detection | Location/Area | Ref. |
---|---|---|---|---|---|---|---|
polyesters, PS, PA, PVC, PP, and PE | Fragments and filaments | 5 mm | black or grey color | anthropogenic activities | ATR-FTIR analysis | Kuala Nerus coast and Kuantan port (Malaysia) | [60] |
nylon, PU, PE, and PET | Filaments, fragments, and films | 1–5 mm | range of colors | multiple sources | FTIR | port of Piombino, port of Portoferraio (Italy) | [61] |
Polyester, PE, alkyd resins, and PS | Fibers, hard plastic, and paint particles | (<2 mm) | - | industrial facilities | FTIR | Southeastern coast Sea (Korea) | [28] |
PP, LDPE, PE, PS, PA, PMMA, cellophane, and acrylonitrile | Granular shape and fibrous | 125 μm–1.82 mm | - | anthropogenic activities, oil-rig installations, and shipping operations | ATR-FTIR | Qatar’s Exclusive Economic Zone coast | [62] |
resins | Fragments and foams | 4–5 mm | - | industrial, commercial, and fishing activities | stereomicroscopy | Portuguese coast, fishing ports | [63] |
rayon, PE, PP, PA, PET, PS, PMMA, and PU | Fibers, films, fragments, and pellet | <500 μm | - | river and sewage discharge and maritime activities, shipping | μ-FTIR | Sishili Bay, North Yellow Sea coast, China | [64] |
PE, PP, and PET | Particles, pigments | 200–34,900 μm | - | - | Raman spectroscopy, energy-dispersive X-ray spectroscopy (EDX) | Malaysian coasts | [65] |
PP, PE, PS, and nylon | Filaments and fragments | blue, white, and red | anthropogenic activities | Raman spectroscopy | Kuwait coastal areas | [66] | |
Nylon, acrylic, and ionomer surlyn | Fibers, fragments, and pellets | >251 μm | - | anthropogenic activities, maritime activities | ATR-FTIR | Port Blair Bay, Andaman Islands, India | [67] |
PE | Microcapsules and fragments | 2–3 mm | various colors | fertilizers | FTIR and SEM | Japanese coast | [68] |
PE, PP, alkyd resin polyester, polyolefins, polyester, PS, and PA | Fibers and fragments | 5000 μm | - | - | FTIR | Vietnam coast | [69] |
PE, PP, PS, and PET | Particles | 5 mm | - | maritime activities | ATR-FTIR particle size analysis PSA | Port of Durban, South Africa | [30] |
PE, HDPE, and PP | Microfibers and particles (mostly fragments and films) | - | transparent and blue | swimming, walking, playing with sand, seaside camping, and fishing | binocular microscope | Busher port coastline. Persian Gulf, Iran | [70] |
PP, PE, and polyester | Fibers, fragments, spheres, films, and foams | 0.25–5.0 mm | transparent, blue, yellow, black, and green | port activities and tourism economic activities | Raman | tropical bays (Manzanillo, Santiago, Navidad and Cuastecomates) of the central Mexican Pacific | [71] |
Rayon and PET | Fibers, fragments, and films | 5 mm, 1 mm, 300 μm, and 45 μm. | white, green, black, yellow, and red | human activities, fish and port activities | FTIR-ALPHBROKER-Platinum-ATR spectrometer | Damietta and Port Said, Red and Mediterranean seas, Egypt | [72] |
alkyds, epoxy resins, poly(acrylate-styrene), and PU | Foams, hard plastic fragments, paint fragments, and pellets | 1–5 mm | yellow, gray, and pink | urban and port activities, boat and ship coatings | optical stereomicroscope | Paranagua Estuarine port and coast, South Brazil | [73] |
PE, PP, PET, polyester, nylon, PU, and resins | Filaments, fragments, granules, and spheres | 63–1000 μm | white, black, blue, grey, and brown | fish and port activities | X-ray diffraction (XRD), μ-Raman spectroscopy | Genoa port and a fishpond, Italy | [74] |
HDPE, PS, PP, and PET. | Lines, fragments, pellets, foams, and fibers | <5 mm | - | tourism, anthropogenic, and maritime activities | FTIR | Port Blair, coast of the Andaman and Nicobar Islands, India | [75] |
PET, PP, and PE | Films | <300 μm | white | human activities | Stereomicroscope, FTIR | Vava’u archipelago coast, Tonga | [76] |
Polyether PU, PE, PP, and PS | Foams, pellets, fragments, flakes, fibers, films, and sponges | <1 mm | transparent, white, and yellow | high-intensity human activities, mariculture, tourism, and port construction | ATR-FTIR, SEM | coastline in Shandong province, east China | [77] |
PP, PE, and PET | Fibers and fragments | 25–150 μm | black, red, and blue | port activities | Stereomicroscope, laser infrared imaging spectrometer | fishery port city in southern China | [78] |
PP, PE paint, and epoxies | Fibers and fragments | 100 μm–5 cm | yellow and blue | Marine coating (boat paint and epoxy) | stereo zoom microscope | coast of South Andaman Island, India | [79] |
PET and nylon | Fibers and spherules | 0.1–1 mm | white and black | fishing and fish processing activities along with intensive anthropogenic and industrial activities | FTIR | seaports (Port Jackson, Botany, Kembla, Newcastle, Yamba, and Eden) of New South Wales, Australia | [80] |
PS and cellulose | Fibers, fragments, and films | ~1 mm | black/grey and blue | anthropogenic influence, fisheries, industrial, and port activities | Raman spectroscopy | Ushuaia Bay, Argentina | [81] |
PA, PE, PET, PP, and cellulose | Fibers and fragments | ~1 mm | blue and transparent | industry—tourism, fishing, and shipping ports | FTIR | South Australian coastline | [82] |
Nylon | Fibers | >1000 μm | black | landfill leachate | micro-Raman analysis | Bushehr port, Iran | [83] |
PVC, PP, PE, PS, and PA | Fibers and fragments | 100–500 μm | - | human activities | μ-FTIR | port of Rimini Adriatic Sea, Italy | [84] |
PET, PP, PP-co-PE, alkyd, cellophane, PU, PA, and rayon | Lines and fragments | <1 mm | black and white | harbor, industrial, activity and populated, tourist, residential, and aquaculture area | FTIR | Tanmen Port, China | [85] |
PP, PS, PET, PVC, and PE | Fibers, fragments, films, and beads | 195–4780 μm | red, blue, black/brown, and transparent/white | Packaging, human activities, port and industrial, activity | ATR-FTIR and Micro-Raman spectroscopy | 7 port Cities in China, Japan, South Korea, Sri Lanka, Taiwan, Thailand, and Vietnam | [86] |
Polyester, PP, PE, PET, PS, PVC, nylon, and PU | Fibers, fragments, films, foams, and pellets | 0.3–5 mm | white, transparent, and yellow | Fishing, human activities, construction of ships, insulating materials, fabrics. packaging | FTIR | Goa coast, India | [87] |
PP, PS, PET, and PE | - | 63–500 μm | - | tourism, anthropogenic, and maritime activities | - | New Zealand coasts | [88] |
LDPE | Pellets and fragments | ≤1 mm | white and transparent | Harbor activities | ATR-FTIR | Deep Bay, coast, Tolo Harbour, Tsing Yi coast and Victoria Harbour, Hong Kong, Japan | [89] |
PE and PP | Fragments, fibers, foams, and micro-beads | ~250 μm | transparent, opaque, white, black, blue, green, red, yellow, or multi-colored | Harbor activities | (FTIR) | Kingston Harbour, Jamaica | [90] |
PE, PP, PS, PET, PA, and PVC | Fibers, fragments, spherules, and granules | 0.1–0.5 mm | black, transparent, yellow, red, and blue | Harbor activities | Scanning electron microscopy/energy dispersive spectroscopy | Sanggou Bay, China | [91] |
- | - | 1–5 mm | - | tourism, anthropogenic, and maritime activities | - | Sile Port, Black Sea Coast, Istanbul, Turkey | [92] |
- | Fibers, fragments, and micro-beads | - | brown, grey, semitransparent, and green | anthropogenic pollution | optical microscopy | Fishing port, coast of Peru and Chile | [93] |
- | Pellets | - | white, yellowish, orange, brown, and pigmented | Loading in harbor areas and transport by ships | Visual classification | Port of Santos, Brazil | [94] |
- | Fibers, fragments, and films | - | - | human activities | FTIR | Fishing Ports in Java Island, Indonesia | [95] |
PE, PVC, PET, PS, and PP | - | <200 μm, 200–500 μm, and >500 μm | - | anthropogenic pollution | laser direct infrared (LDIR) technique | Mediterranean marine samples | [96] |
Rayon, PET, PS, PE, and PP | Fibers, fragments, granules, and films | <1 mm | transparent, purple, brown, white, black, blue, and red | human activities | m-ATR-FTIR and SEM-EDS | Qingdao and Dongying, China | [97] |
- | Fragments, foams, fibers, films, pellets, and filaments | 1.6 ± 1.4 mm | - | human activities: packaging materials, and resins | - | Baseco Port Manila Bay, Philippines | [98] |
Polychlorobiphenyls and PU | Fibers, fragments, Styrofoam, and pellets | <5 mm | yellow-brown, black, blue, red, and green | fishing and harbor activities | visual identification under a stereomicroscope | Guanabara Bay, Southeast Brazil | [99] |
PP, PE, PS, PVC, PET, and PMMA | Fibers | ~125 μm | - | Offshore, industries, and ports activities | pyrolysis–gas chromatography–mass spectrometry/thermochemolysis (Py-GC/MS) | German Bight North Sea, Germany | [100] |
Nylon, PET, and PP | Fibers, filaments, and fragments | <5 mm | - | port, industries, and residents activities | light microscope | Dumai Port, Indonesia | [101] |
- | Foam and Styrofoam pieces, rope pieces, and fibers | 2 mm to 40 cm | - | Fishing, shipping, and touristic activities | visual sorting | Port of Cristo and Port of Colonia de Sant Jordi of the Island of Mallorca, Spain | [102] |
- | Fibers, fragments, and films | 500–5000 μm | black, green, red, purple, blue, transparent, and brown | Anthropogenic activities: shipping, plastic production, port activities, and sewage treatment | - | Tudor, Port Reitz, and Mida creeks, Kenya | [103] |
- | Fibers, fragments, and films | - | - | Tourism and industry activities | Stereo Microscope | Kendari Archipelago Harbor, Indonesia | [104] |
PVC and PET | Fibers, fragments, and nurdles | 63–5000 μm | black and grey | Human activity and port activity | Bestscope dissecting microscope | Richard’s Bay Harbour, Durban Harbour, South Africa | [105] |
- | Fibers | <5 mm | red, yellow, black, pink, orange, purple, green, blue, and transparent | Human activities | dissecting microscope | Tudor, Port Reitz, and Mida creeks, Kenya | [106] |
PP, PE, phenoxy resin, PS, polyester, and synthetic rubber | Fragments, spherules, and fibers | <1 mm | white, blue, green, and red | Harbor activities and ship paint resin | FTIR | Jinhae Bay, o southern coast of Korea | [107] |
- | Fragments and pellets | <1 mm | white, blue, brown, and green | Port facilities | stereomicroscope | Northeast coast of Brazil | [108] |
PCBs | Filaments | <5 mm | - | Port activities | stereomicroscope | Grand Harbour Valletta, Malta | [109] |
PVC, rayon, PE, polyester, PS, and cellulose | Fibers, pellets, and plastic fragments | - | black, blue, or white | fishers and maritime ports activities | FTIR | coast of Asturias, Spain | [110] |
alkyds and poly(acrylate-styrene) | Fragments, spherules, and fibers | <1 mm | green, blue, and white | Harbor activities, ship paint resin, and ship coatings | FTIR | southern coast of Korea | [111] |
PS, PE, and PP | Microbeads and pellets | <1 mm; 1–2 mm; or 2–5 mm | white, transparent, red, blue, and green | estuarine and harbor environments | optical/fluorescence imaging and micro-Raman spectroscopy | coastlines in the Canterbury region of New Zealand | [112] |
PE and PP | Fragments and pellets | 1–5 mm | - | human activities | FTIR | Bristol Channel, UK | [113] |
PP-co-PE, PA, PE, PET, PP, and PVC | Fibers, thin films, and fragments | <0.5 mm | blue, black, red, yellow, green, and white | marine fishery and port transportation | FTIR | Tianjin coastal waters, China | [114] |
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Belioka, M.-P.; Achilias, D.S. Microplastic Pollution and Monitoring in Seawater and Harbor Environments: A Meta-Analysis and Review. Sustainability 2023, 15, 9079. https://doi.org/10.3390/su15119079
Belioka M-P, Achilias DS. Microplastic Pollution and Monitoring in Seawater and Harbor Environments: A Meta-Analysis and Review. Sustainability. 2023; 15(11):9079. https://doi.org/10.3390/su15119079
Chicago/Turabian StyleBelioka, Maria-Paraskevi, and Dimitrios S. Achilias. 2023. "Microplastic Pollution and Monitoring in Seawater and Harbor Environments: A Meta-Analysis and Review" Sustainability 15, no. 11: 9079. https://doi.org/10.3390/su15119079
APA StyleBelioka, M. -P., & Achilias, D. S. (2023). Microplastic Pollution and Monitoring in Seawater and Harbor Environments: A Meta-Analysis and Review. Sustainability, 15(11), 9079. https://doi.org/10.3390/su15119079