Next Article in Journal
Advancing Plastic Recycling: A Review on the Synthesis and Applications of Hierarchical Zeolites in Waste Plastic Hydrocracking
Previous Article in Journal
The Influence of Au Loading and TiO2 Support on the Catalytic Wet Air Oxidation of Glyphosate over TiO2+Au Catalysts
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Catalysts
Volume 14
Issue 7
10.3390/catal14070449
catalysts-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles thumb_up
...
Endorse textsms
...
Comment
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Novel Starch-Modified NiCrMn-LDH-Based Composite for Photocatalytic Degradation of Reactive Orange 13

by
Muhammad Usman
1,†,
Muhammad Babar Taj
1,*,†,
Afaf Almasoudi
2,
Doaa F. Baamer
2,
Omar Makram Ali
3,
Muhammad Imran Khan
4,*,
Ismat Bibi
1,
Mobeen Ur Rehman
1,
Rabia Rasheed
1,
Ahmad Raheel
5,
Mushtaq Hussain Lashari
6,
Abdallah Shanableh
4,7 and
Javier Fernandez-Garcia
8,9
1
Institute of Chemistry, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan
2
Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 42734, Jeddah 21589, Saudi Arabia
3
Department of Chemistry, Taraba University College, Taraba Branch, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia
4
Research Institute of Sciences and Engineering (RISE), University of Sharjah, Sharjah 27272, United Arab Emirates
5
Department of Chemistry, Quaid-e-Azam University, Islamabad 44000, Pakistan
6
Department of Zoology, The Islamia University of Bahawalpur, Bahawalpur 63100, Pakistan
7
Scientific Research Center, Australian University, Mubarak Al-Abdullah 40250, Kuwait
8
IQS School of Engineering, Universitat Ramon Llull, Via Augusta 390, 08017 Barcelona, Spain
9
Department of Chemical Engineering, University College London, Torrington Place, London WC1E 7JE, UK
*
Authors to whom correspondence should be addressed.
†
These authors contributed equally to this work.
Catalysts 2024, 14(7), 449; https://doi.org/10.3390/catal14070449
Submission received: 5 June 2024 / Revised: 6 July 2024 / Accepted: 8 July 2024 / Published: 12 July 2024
(This article belongs to the Section Photocatalysis)
Browse Figures
Versions Notes

Abstract

:
Water pollution has become a great challenge today. To address this problem regarding wastewater treatment by removing toxic synthetic dyes from wastewater, this research focused on the synthesis of a novel starch-modified NiCrMn-layered double hydroxide composite through the coprecipitation method and applied it as a photocatalyst for the degradation of reactive orange 13 dye. The synthesized photocatalyst was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET), point of zero charges (PZC), dynamic light scattering (DLS), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and Zeta potential techniques. These techniques revealed different characteristics of photocatalysts, like surface and structural properties. According to BET analysis, the final composite had 2.5 × 102 m2/g BET-specific surface area with a 45.56 nm pore radius value, and the overall composite found as mesoporous. Similarly, in DLS analysis, bare NiCrMn-LDH had 404 nm hydrodynamic size, which increased for the final starch composite up to 667 nm. Zeta potential value changed from −14.56 mV to 0.95 mV after the incorporation of starch with NiCrMn-LDH. They confirmed the incorporation of starch with trimetallic NiCrMn-layered double hydroxide (2:1:2). Starch association improved the properties of the photocatalyst like surface area. Different parameters like pH value, initial dye concentration, photocatalyst dose, hydrogen peroxide concentration, effect of sacrificial reagent, and effect of inorganic anions were studied for degradation of RO13. Overall, the photocatalysis process for RO13 followed pseudo-first-order kinetics. Photocatalytic degradation reactions for reactive orange 13 were conducted with an initial dye concentration of 10 mg/L, photocatalyst dosage of 20 mg/50 mL, and pH value at 3 in the presence of sunlight, resulting in an impressive degradation removal rate of 86.68%. This remarkable degradation ability of the photocatalyst for reactive orange 13 proves this composite was highly efficient.

Graphical Abstract

1. Introduction

Water is the utmost vital substance on Earth’s surface. The physical and chemical characteristics of water pose significant considerations regarding water security, water provisioning, and water purification techniques [1]. One of the most pressing environmental issues resulting from industrial development is water contamination, which poses significant risks to both human health and ecosystems [2,3,4].Water treatment has captivated considerable attention over the past few decades because of pollutants that induce detrimental impacts on aquatic environments. Nevertheless, given the swift pace of industrialization and population expansion, the water quality of conventionally processed discharges is steadily deteriorating [5].The expansion of industries has led to the extensive degradation of various aquatic ecosystems worldwide [6]. Among a broad array of water contaminants, dyes have garnered considerable interest owing to their negative impacts on human well-being and the environment [7,8,9,10].
Industries across the globe utilize over 10,000 distinct colorants, and the yearly production of various dyes and pigments exceeds 700,000 tons. Around 10–15% of these colorants are released into water sources during manufacturing or other uses [2,11,12,13]. Dyes exhibit excellent light stability and are not biodegradable; they possess resistance to anaerobic digestion and stand out as one of the most formidable components to eliminate from industrial wastewater [14]. Azo dyes are artificial colorants characterized by intricate structures comprising substituted aromatic rings connected by at least one azo group (–N=N–) [15,16].These dyes find wide applications in various industries such as textile, leather, cosmetics, paper, and food, contributing to approximately 50–60% of the total global dye production [17,18]. The textile sector stands as the largest consumer of azo dyes; regrettably, approximately 10–15% of these dyes are discharged through effluents [19,20]. The untreated release of dyes poses significant environmental and health issues due to their toxicity, alteration of water pH, the elevation of biological and chemical oxygen demand, and the induction of intense coloration, thereby potentially hindering photosynthesis [21,22,23].
Therefore, the application of this treatment is crucial to safeguard human health, plant health, and the environment [24]. Hence, through numerous degrees of achievement, diverse approaches for eliminating dyes have been explored and implemented, encompassing physical, chemical, and biological methodologies [25,26]. These approaches encompass diverse criteria and procedures like precipitation–coagulation, aerobic and anaerobic processes, adsorption, ion exchange, membrane filtration, adsorption membrane filtration, coagulation, adsorption, and reverse osmosis [27,28,29,30,31,32,33]. Photocatalysis stands as one of the most auspicious methodologies extensively utilized in wastewater treatment, representing an oxidation mechanism that surpasses others in terms of advancement [34]. Photocatalysis is distinguished by its considerable oxidizing capability, which enables the decomposition of detrimental dyes [35,36].
Reactive Orange 13, an azo dye, incorporates cyanuric chloride as its reactive moiety. Studies indicate that dyes featuring reactive cyanuric chloride components exhibit greater resilience against anaerobic degradation when compared to those containing the vinyl sulfone group [37].
Presently, the primary goal is to amalgamate environmentally conscious, renewable materials derived from living organisms [38]. Different natural biopolymers can be used for the synthesis of important nanocomposites for wastewater treatment. Among the various biopolymers in nature, starch stands out as the second most abundant. It enjoys widespread usage due to its plentiful availability, lack of toxicity, customizable surface area, pore size, cost-effectiveness, biocompatibility, and structural versatility [39,40,41,42,43].
Currently, the prevailing filler employed to surmount the obstacles of biopolymers when creating composites is double-layered hydroxide (LDH) [39,44]. Double-layered hydroxides represent a category of anionic clays, often referred to as hydrotalcite clays. These clays possess positively charged outer layers with anions present in the interlayers [45,46,47,48]. LDHs can be represented by the overall chemical equation [M1−x2+·MX3+ (OH)2]x+·[Ax/n]n−·mH2O. In this formula, M2+ and M3+ stand for bivalent and trivalent metal cations, correspondingly. The variable x indicates the molar ratio of trivalent cations (0.2 < x < 0.33), m shows the number of water molecules between the layers, whereas An− denotes the interlayer anion with a specific charge [39,49,50,51,52,53]. These materials including layered double hydroxide (LDHs) and their calcined forms (oxides) can be fabricated efficiently and economically to reveal tailored characteristics suitable for specific applications [54,55]. LDHs can be prepared in a variety of shapes and sizes and have been widely studied across various field such as wastewater treatment, energy, and catalysis. A high surface area and the ability to exchange anions make them more effective for adsorbing various organic and inorganic pollutants [56]. Furthermore, double-layered hydroxides hold favorable properties as a catalyst in AOPs because of their low cost fabrication, tunable properties, high surface area, layered structure, and diverse chemical state [57].
Numerous researchers have devoted their efforts to decolorizing various azo dyes using biological methods. However, there has been comparatively less focus on decolorizing cyanuric chloride-based reactive azo dyes. It was noted that reactive dyes incorporating cyanuric chloride as a reactive group exhibited greater resistance to anaerobic reduction when compared to reactive dyes utilizing vinyl sulfone as the reactive group [58]. To the best of our knowledge, starch-based ternary double-layered hydroxide for the decolorization of RO13 is not reported in the open literature.
In this research, an important, starch-based photocatalyst is synthesized by modification of the starch with a novel ternary double-layered hydroxide of nickle, chromium, and manganese, using the coprecipitation method. This novel starch-modified catalyst is used for the photocatalytic degradation of reactive orange 13. Different parameters like pH effect, effect of dye concentration, effect of sacrificial reagents, effect of photocatalyst dose, effect of hydrogen peroxide amount, and effect of inorganic species were used to study the removal of reactive orange 13 in the presence of sunlight.

2. Results and Discussion

2.1. XRD Test

The X-ray diffraction spectrum of starch, NiCrMn-LDH, and its composite starch/NiCrMn-LDH is demonstrated in Figure 1. Different significant peaks are examined in the XRD spectra of NiCrMn-LDH. Peaks present in spectra can be assigned as (003), (006), (012), and (110) according to their diffraction degree 12.95°, 19.89°, 29.18°, 37.27°, and 59.90°. Similarly, all the peaks of NiCrMn-LDH were observed in the XRD spectra of the starch/NiCrMn-LDH composite except one small peak, which was present at 59.90° in the NiCrMn-LDH pattern [39]. The existence of all peaks of simple double-layered hydroxide in the XRD pattern of the composite proves that starch did not destroy the structure of NiCrMn-LDH. Furthermore, the intensity of the peaks already present in NiCrMn-LDH was decreased in the XRD pattern of the composite (starch/NiCrMn-LDH) [50,59]. The decrease in the intensity of the peaks were due to shedding of the NiCrMn-LDH sheet over the surface of the starch [60]. Overall, this confirmed that the double-layered structure of NiCrMn-LDH easily settled in a final composite. In the same way, some extra peaks were also observed in the XRD spectra of the composite, which confirmed the crystallinity of the starch structure [61]. Finally, with the XRD studied, it was concluded that insignificant modification of the crystallinity structure of the composite improved the hydrophilicity of the final composite.

2.2. SEM Analysis

Morphological images of NiCrMn-layered double hydroxide and its starch-based composite is shown in Figure 2. SEM images revealed the porosity and surface roughness before and after attachment of the extra precursor. Figure 2a–c show the irregular surface of NiCrMn-LDH. Figure 2d–f display the porous and coarse microstructure of the nanocomposite, and additional images of high magnification exhibited the cracks and raptures on the surface of the starch/NiCrMn-LDH composite, which shows the even distribution of NiCrMn-LDH particles over the polymeric chain of the starch molecule. It also confirmed the proper association between different functional groups of NiCrMn-LDH and starch during the reaction and caused roughness of the composite surface [39,50]. By comparing SEM images of NiCrMn-LDH and its starch composite, it can be noted that the attachment of starch with LDH causes the increase in surface porosity and also surface area. Furthermore, the fabrication of NiCrMn-LDH with starch is also confirmed with the EDX analysis (Figure 2g,h). The EDX of pure starch is given in Figure S1.

2.3. FTIR Test

The chemical composition and functional groups of the starch/NiCrMn-LDH composite can be confirmed using FTIR spectrometer. The attained results are indicated in Figure 3. The prominent peak at 3401 cm−1 indicates the presence of hydroxyl groups (–OH) and is associated with hydrogen bonding. This hydrogen bonding caused by the presence of water molecules between layers leads to bonding in the interlayer spaces [50]. FTIR peaks below 1000 cm−1 confirm the presence of stretching vibrations in the metal lattice, specifically involving the bonds between metal and oxygen (M–O, M–O–M and O–M–O) [39,62]. Furthermore, the appearance of a distinct and intense peak at 1401 cm−1 indicates the existence of a nitro group (–NO3) [49,63]. The identification of a peak at 1632 cm−1 provides confirmation of the occurrence of bending vibrations of water molecules within the starch/NiCrMn-LDH composite. The presence of a distinct peak at 1157 cm−1 in the FTIR spectrum confirms the stretching vibrations of the C–O of the starch molecule [62,64,65]. The FTIR spectrum confirms the association of starch with NiCrMn-LDH. The FTIR spectrum of pure NiCrMn-LDH and starch is given in Figure 3b,c.

2.4. DLS and ZETA Potential Analysis

The DLS and zeta potential analysis are considered electrokinetic studies. The DLS study of the starch/NiCrMn-LDH composite is related to the hydrodynamic size of particles. According to DLS analysis, the hydrodynamic size for bare NiCrMn-LDH particles is 404 nm, and it increases up to 667 nm when starch (689 nm) is combined with NiCrMn-LDH, as revealed in Figure 4a. The deposition of starch over the bare NiCrMn-LDH surface is the main reason for the shift in the final particle size of the composite. Similarly, the zeta potential is related to the surface charge properties of LDH and its starch composite. According to Figure 4b, the zeta potential value of LDH increases from −14.56 to 0.95 mV with the incorporation of starch (24.41 mV) to form a final composite. The reason for the increase in zeta potential value after the attachment of starch is due to some interaction like hydrogen bonding between hydroxyl groups of starch and water molecules, making surface charge more positive [39].

2.5. PZC

The determination of the point of zero charge (PZC) for the nanoparticles involved a procedure in which 0.01 g of starch/NiCrMn-LDH, NiCrMn-LDH, or starch were dispersed into eight separate 50 mL Erlenmeyer flasks, each containing a 0.1 M NaNO3 solution. The pH of each solution was systematically adjusted within the range of 2 to 9 using either 0.01 mol/L HNO3 or NaOH solutions. After allowing the solutions to equilibrate for 24 h at a constant temperature of 25 °C on an isothermal shaker, the final pH values were measured [66]. The PZC was determined as the point at which the initial pH matched the final pH, and the PZC value for starch/NiCrMn-LDH, NiCrMn-LDH, and starch were 7.2, 6.8, and 5.6, respectively (Figure 5).

2.6. BET Analysis

The structural characteristics of the synthesized particles were assessed through parameters like surface area and pore size, as depicted in the Brunauer–Emmett–Teller (BET) plots presented in Figure 6. The adsorption–desorption plot (Figure 6a) exhibited a type IV curve with an H2b hysteresis loop behavior for the nanoparticles. The BET-specific surface area of the nanoparticles was observed to be 2.5 × 102 m2/g. However, the pore radius of the nanoparticles was found to be 45.56 nm in the BJH analyses, as shown in Figure 6b. The BET surface area of pure starch and NiCrMn-LDH are found to be 656.1 m2/g and 35.5 m2/g, respectively (Figure S2). Results showed that the composite is mesoporous. The notably enhanced surface area/microporous structure of the composite endow it with the capacity to serve as a host for various organic functional groups, biomolecules, and dyes, facilitating applications across diverse fields [67,68].

2.7. TGA and DSC Analysis

Thermogravimetric analysis (TGA) of starch/NiCrMn-LDH, NiCrMn-LDH, and starch is shown in Figure 7a. The TGA curves of starch and starch/NiCrMn-LDH exhibited basically a three-step degradation process in the range of 25 to 700 °C. According to analysis, almost a 12% mass loss was noted in the first step of the starch degradation, mainly due to the evaporation of embedded water molecules. Following this dehydration process, in the second step of degradation, a 95% mass loss was observed at temperatures up to 525 °C, and at the end of the second step, 5% of the total residual mass was obtained. In the third step of the degradation of the starch, curves showed a broader peak, which was due to ash forming. Starch with NiCrMn-LDH showed an almost similar TGA curve with more than 20% residual, which confirms that starch with NiCrMn-LDH has more thermal stability than simple starch. The main reason for this stability is that, after modification of starch, some hydroxyl groups of starch are replaced by carboxymethyl groups [69,70,71]. On the other hand, DSC analysis (Figure 7b) of starch/NiCrMn-LDH, NiCrMn-LDH, and starch collectively confirms the formation of the starch/NiCrMn-LDH composite and also informs about its thermal stability. According to the DSC thermogram, the broad endothermic transition peak noted for simple starch is indicated at 113 °C, which corresponds to the heat required for the melting of the final formed composite. But in the case of starch with NiCrMn-LDH, the thermal transition peak for starch moves up to 163 °C with more than 50 °C extra after attachment of LDH with starch. This behavior is due to the presence of LDH, which causes an obstruction of heat to biopolymer and increases thermal stability [72,73].

2.8. Photocatalytic Degradation of Reactive Orange 13

A synthesized, novel photocatalyst starch/NiCrMn-LDH was used in the presence of light for the degradation of reactive orange 13 dye. The photodegradation results were obtained using a UV-visible spectrophotometer. The lambda max for reactive orange 13 was noted to be at 489 nm. Different parameters were studied in this research, like pH effect, photocatalyst dose, initial dye concentration, hydrogen peroxide concentration, and the effect of inorganic salts on the photocatalytic degradation of RO 13. Photocatalytic degradation of RO13 with respect to time is shown in Figure 8. The broadening of absorption peaks observed is attributed to the formation of intermediates during the reaction. These intermediates overlap with the dye spectrum, causing the observed effect on the absorption band.
Additionally, a slight shift towards lower wavelengths, known as a blue shift, is evident in the absorption peak. This shift can be attributed to a C–N bond cleavage. The departure of the amino group, a typical auxochrome from the benzene ring, may cause a decrease in the peak’s intensity along with a noticeable blue shift [37].

2.8.1. Effect of Photocatalyst Dose

The influence of the photocatalyst dosage on the degradation of RO13 was observed by employing varying quantities of the starch/NiCrMn-LDH photocatalyst, ranging from 5 to 40 mg, in a 50 mL of dye solution (at 10 mg/L) at an optimized pH. Each photoreaction spanned a duration of 60 min. The increase in the catalyst dosage resulted in a heightened generation rate of ˙O2− and ˙OH radicals, attributable to the increased presence of catalytically active sites [74]. However, beyond the 30 mg threshold, there was a decline in the degradation rate, primarily attributed to the surplus catalyst hindering light penetration, with the results shown in Figure 9. As per the results, 30 mg per 50 mL is considered an optimum photocatalyst dose.

2.8.2. Effect of Initial Dye Concentration

Various initial reactive orange 13 dye concentrations ranging from 5 to 40 mg/50 mL were assessed. The findings are depicted in Figure 10. The outcomes indicate that, as the dye concentration increases, more dye fragments are adsorbed onto the catalyst’s surfaces. This increase in fragments obstructs the penetration of light, thereby reducing the generation of active sites during the photoreaction. Consequently, the photocatalyst efficiency substantially diminishes due to the limited availability of active sites [75]. It is evident that a reduced absorption of solar light results in a lower count of active sites on the catalyst, while a higher absorption of light photons on the catalyst surfaces anticipates a greater number of photogenerated charges for dye degradation. Furthermore, the production of photocatalytic ˙OH and ˙O2− on the photocatalyst surface remains consistent since the quantity of the catalyst remains unchanged. Typically, for higher dye concentrations, a greater concentration of ˙OH and ˙O2− reactive species is required to maintain equilibrium when the catalyst quantity is held constant.

2.8.3. Effect of pH

The pH of the reaction mixture can influence the surface charge of the adsorbent, the ionization levels of pollutants, the dissociation of functional groups on the active sites of the adsorbent, and the structure of dye molecules [76]. For the sake of this study, analytical graded reagent hydrochloric acid (HCl) and sodium hydroxide (NaOH) were used to stabilize pH. The pH range was selected for experiments 3–11 for 10 mg/L of reactive orange 13 in 10 mg of photocatalyst in 50 mL for 60 min of every photocatalytic reaction. The dye degradation process undergoes a fast response in acidic conditions because the effectiveness of pollutant removal of photocatalysts is enhanced due to the strong electrostatic interaction resulting from the positive charge layer of the adsorbent and the anionic properties of the pollutant [77]. Experimental results of photoreaction at different pH are illustrated in Figure 11. Results show that, as the pH of the reaction moves toward acidic conditions, the photodegradation of reactive orange 13 increases. At a pH of 3, the maximum degradation efficiency is noted, so the optimum pH for the photoreaction as mentioned earlier is 3.

2.8.4. Effect of Inorganic Salts

The effect of inorganic salts on photocatalysis can vary. However, certain salts may inhibit photocatalysis by competing with reactants, scavenging reactive species, or screening light. The impact depends on the specific salt used for specific photoreaction [74]. For the sake of testing the effect of different inorganic moieties like PO42−, Cl1−, SO42−, and NO31−, photoreaction was performed for 60 min with 10 mg/L of reactive orange 13, and the photocatalyst dose was 10 mg/50 mL at an optimum pH. Experimental analysis, as shown in Figure 12, confirms that inorganic ions have some effect on overall photodegradation of reactive orange 13 with this sequence PO42− > SO42− > NO31− > Cl1−. The maximum decrease in the percentage degradation of dye was noted from 86.68% to 59.42%.

2.8.5. Effect of Hydrogen Peroxide

One of the primary photo-oxidants utilized in water purification is hydrogen peroxide. It is employed in the presence of visible light to monitor the generation of hydroxyl radicals, which play a vital role in breaking down harmful organic contaminants [68]. Photoreaction was performed with various amounts of hydrogen peroxide in the range of 5–20 mL, using 10 mg/L of dye concentration with 10 mg/50 mL of the starch/NiCrMn-LDH photocatalyst for 60 min at an optimized pH. The effect of hydrogen peroxide concentration, as shown in Figure 13 and photodegradation of reactive orange 13 directly relates to the amount of hydrogen peroxide, because H2O2 increases the amount of hydroxyl radicals (˙OH) and the degradation of dye. However, this increasing effect is up to the limit, because excessive amounts of hydrogen peroxide cause a scavenging impact and use extra electrons, inhibiting reactive oxygen species. According to experimental data, 15 mL of hydrogen peroxide is considered to be the optimum quantity for photoreaction.

2.8.6. Effect of Sacrificial Reagents

To understand the phenomenon of active species, i.e., holes (h+), electrons (e−), and hydroxyl groups (−OH), the photodegradation of reactive orange 13 dye before and after the sacrificial reagent was observed. The sacrificial reagents used to trap hole (h+), superoxide radical (˙O2−), and hydroxyl radical (·OH) are ethylene diamine tetra acetate (EDTA), benzoquinone (BQ), and isopropyl alcohol (IPA) respectively [78,79,80,81]. According to experimental data, as shown in Figure 14, degradation decreased up to 70.98% by the addition of IPA (·OH scavenger), which shows that the hydroxyl radical has a minor role in degradation. Similarly, for EDTA (h+ scavenger) and BQ (˙O2− scavenger), degradation decreased up to 45.61% and 58.11%, respectively. The results show that EDTA suppressed degradation maximum, so hole (h+) plays the main role in the photodegradation of RO13.

2.9. Kinetics Study

The linear form of pseudo-first-order kinetics used to study the photocatalysis process of RO13 is expressed in Equation (1):
l n C ο C t = k t .
Here, Co and Ct are the concentration at 0 and time t, respectively. k is the rate constant, and t is time. The value of the regression coefficient (R2) and rate constant for the pseudo-first-order reaction are 0.9979 and 0.034 min−1, respectively. Overall, the photocatalytic degradation process for RO13 follows pseudo-first-order kinetics, as shown in Figure 15.

2.10. Mechanism of Photodegradation

The mechanistic study of photodegradation is presented in Figure 16. Water and hydroxyl groups adhere to the nanoparticle surface, establishing hydrogen bonds with exposed polar groups within the starch. When exposed to visible light, electrons in the valence band (VB) of NiCrMn-LDH become exited and transfer to the conduction band (CB), leaving holes in the VB. These migrated electrons in the CB function as potent reducing agents, capable of oxidizing adsorbed oxygen on the catalyst surface, yielding superoxide anionic radicals (˙O2−). Meanwhile, holes in the valence band interact with surface-bound water or hydroxyl (OH), generating hydroxyl radicals (·OH). Both (˙O2−) and˙OH, known for their strong oxidizing properties, can eventually transform reactive orange 13 into benign inorganic compounds like CO2 and H2O.
Starch sheets play a pivotal role by facilitating a charge transfer for NiCrMn-LDH photocatalysts, amplifying photocatalytic activity due to their high conductivity and electron transport capabilities. Similarly, adsorbed oxygen and water on the starch sheet can interact with photogenerated electrons (e−) and holes (h+) to generate superoxide (·O2−) and hydroxyl (·OH) radicals, which participate in the breakdown of reactive orange 13 molecules.
To deeply understand the degradation mechanism, it is essential to determine the conduction band (CB) and valence band (VB) potentials of the starch/NiCrMn-LDH composite. The ECB and EVB were found using the following equations.
E V B = X − E e + 0.5 E g
E C B = E V B − E g
where χ, Ee, and Eg represent the electronegativity of the composite, the energy of free electrons (4.5 eV vs. NHE), and optical band gap energy (Eg), respectively [58].
The Eg of the starch/NiCrMn-LDH composite was calculated to be 2.4 eV, which is lesser than the pure starch (3.5 eV) and NiCrMn-LDH (2.9 eV) (Figure S3). The ECB and EVB of starch/NiCrMn-LDH were estimated as −0.34 eV and +2.05 eV, respectively, versus the normal hydrogen electrode (NHE). The ECB of the starch/NiCrMn-LDH composite is more negative than that of O2/˙O2− (−0.282 eV versus NHE), indicating that the electrons can reduce EVB O2 to generate superoxide anions ˙O2−. However, the EVB of the starch/NiCrMn-LDH composite (+2.05 eV versus NHE) is not positive enough to fully oxidize OH−/H2O (2.27 V versus NHE) to form active species ˙OH [78]. This suggests that the degradation of MB dye primarily occurs through the active species ˙O2− and the accumulation of holes. The improved photocatalytic degradation efficiency may be attributed to the high concentration of hydroxyl ions in the alkaline medium.

3. Experimental

3.1. Materials and Method

Materials used included beet starch, nickel (II) nitrate hexahydrate, chromium (III) nitrate nonahydrate, manganese (II) chloride tetrahydrate, sodium hydroxide, distilled water, and reactive orange 13 from Sigma Aldrich, Taufkirchen, Germany

3.2. Preparation of Starch Modified NiCrMn-LDH (S/NiCrMn-LDH) Composite

Starch-modified NiCrMn-LDH was fabricated by applying the coprecipitation method (Figure 17). In this method, a known amount of divalent (Ni and Mn) and trivalent (Cr) salt in 2:1:2 ratio was added to 70 mL of distilled water. To dissolve all the salts, the solution underwent stirring for almost 40 min. In a separate beaker containing 100 mL of distilled water, nearly 2.5 g of starch was added, and the solution was sonicated for 20 min. After sonication, the starch solution was added to the salt solution via dropwise. After the complete addition of the starch solution, the mixture was stirred vigorously, and the temperature was raised to 85 °C for 25 min. Subsequently, the pH was maintained about 9–10 by adding 0.1 M solution of sodium hydroxide dropwise to the reaction mixture. After stabilizing the pH, the reaction mixture underwent a continuous stirring for 24 h, and the mixture color changed to brownish black. After that, the mixture was centrifuged at 4000 rpm for 10 min, and the precipitates separated out from the mixture. The precipitates were washed with distilled water and ethanol to remove extra impurities, dried at 70 °C overnight, and then, by using a mortar and pestle, were ground to form a fine powder.

4. Conclusions

In summary, by using an environmentally friendly and cost-effective coprecipitation method, a novel photocatalyst is synthesized by modifying NiCrMn-layered double hydroxide with starch. This photocatalyst was then employed for the efficient degradation of reactive orange 13 dye. Comprehensive characterization of the synthesized photocatalyst was carried out using various techniques, including X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR), Brunauer–Emmett–Teller (BET), point of zero charge (PZC), zeta potential, dynamic light scattering (DLS), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). Hydrodynamic size increased from 404 nm to 667 nm after the attachment of starch with bare NiCrMn-LDH in the DLS analysis. The zeta potential value increased from −14.56 mV to 0.95 mV after deposition of starch over simple NiCrMn-LDH, which confirmed the successful incorporation of starch into the trimetallic double-layered hydroxide, which confirmed the successful incorporation of starch into the trimetallic double-layered hydroxide. This starch association significantly enhanced the photocatalyst properties, particularly its surface area, which caused an increase in the number of active sites over the photocatalyst surface. Overall, the photocatalysis process for RO13 follows pseudo-first-order kinetics. Various parameters were systematically investigated, including pH value, initial dye concentration, photocatalyst dosage, scavenger effect, hydrogen peroxide concentration, and the influence of inorganic anions on RO13 degradation. Remarkably, the highest degradation percentage was achieved at pH value of 3, photocatalyst amount 20 mg/50 mL, and H2O2 concentration 20 mL/L. As a synthesized photocatalyst, it is very effective in wastewater treatment regarding the photocatalysis of dyes.

Supplementary Materials

The following supporting information can be downloaded at: https://www.mdpi.com/article/10.3390/catal14070449/s1, Figure S1: EDX spectrum of pure starch; Figure S2: BET analysis of starch (a) and NiCrMn LDH (b); Figure S3: DRS spectrum of Starch/NiCrMn-LDH (a), starch, and NiCrMn LDH (b).

Author Contributions

Methodology, M.U. and M.B.T.; software, M.U.R., R.R. and I.B.; formal analysis, A.A., A.R. and O.M.A., data curation, D.F.B., M.H.L. and I.B.; writing—original draft, M.U., M.B.T.; writing—review and editing, M.B.T., O.M.A., M.I.K. and J.F.-G.; visualization, A.S. and J.F.-G.; supervision, M.B.T.; project administration, M.B.T., O.M.A., J.F.-G. and M.I.K. All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by Taif University, Saudi Arabia, project number (TU-DSPP-2024-276).

Data Availability Statement

All data are present within the manuscript body.

Acknowledgments

The authors extend their appreciation to the Higher Education Commission Pakistan, IQS-School of Engineering and GESPA group recognized as Consolidated Research Group by the Catalan Government (2021 SGR 00321), and also acknowledge funding from the project HEC-A20.1267.

Conflicts of Interest

Authors declare no conflicts of interest.

References

  1. Hosny, N.M.; Gomaa, I.; Elmahgary, M.G. Adsorption of polluted dyes from water by transition metal oxides: A review. Appl. Surf. Sci. Adv. 2023, 15, 395. [Google Scholar] [CrossRef]
  2. Rehman, M.U.; Taj, M.B.; Carabineiro, S.A. Biogenic adsorbents for removal of drugs and dyes: A comprehensive review on properties, modification and applications. Chemosphere 2023, 338, 139477. [Google Scholar] [CrossRef]
  3. Jaleh, B.; Mousavi, S.S.; Sajjadi, M.; Eslamipanah, M.; Maryaki, M.J.; Orooji, Y.; Varma, R.S. Synthesis of bentonite/Ag nano-composite by laser ablation in air and its application in remediation. Chemosphere 2023, 315, 137668. [Google Scholar] [CrossRef] [PubMed]
  4. Keyikoğlu, R.; Khataee, A.; Orooji, Y.; Kobya, M. Synergistic effect of Fe and Co metals for the enhanced activation of hydrogen peroxide in the heterogeneous electro-Fenton process by Co-doped ZnFe layered double hydroxide. J. Environ. Chem. Eng. 2022, 10, 108875. [Google Scholar] [CrossRef]
  5. Chaudhary, M.; Jain, N.; Barman, L.; Bhowmick, G. Design and principles of adsorbent-based reactors for modular wastewater treatment. In Modular Treatment Approach for Drinking Water and Wastewater; Elsevier: Amsterdam, The Netherlands, 2022; pp. 129–148. [Google Scholar]
  6. Grover, A.; Mohiuddin, I.; Malik, A.K.; Aulakh, J.S.; Vikrant, K.; Kim, K.-H.; Brown, R. Magnesium/aluminum layered double hydroxides intercalated with starch for effective adsorptive removal of anionic dyes. J. Hazard. Mater. 2021, 424, 127454. [Google Scholar] [CrossRef]
  7. Stawiński, W.; Węgrzyn, A.; Freitas, O.; Chmielarz, L.; Mordarski, G.; Figueiredo, S. Simultaneous removal of dyes and metal cations using an acid, acid-base and base modified vermiculite as a sustainable and recyclable adsorbent. Sci. Total. Environ. 2017, 576, 398–408. [Google Scholar] [CrossRef] [PubMed]
  8. Al-Tohamy, R.; Ali, S.S.; Li, F.; Okasha, K.M.; Mahmoud, Y.A.-G.; Elsamahy, T.; Jiao, H.; Fu, Y.; Sun, J. A critical review on the treatment of dye-containing wastewater: Ecotoxicological and health concerns of textile dyes and possible remediation approaches for environmental safety. Ecotoxicol. Environ. Saf. 2022, 231, 113160. [Google Scholar] [CrossRef]
  9. Khan, S.; Naushad, M.; Govarthanan, M.; Iqbal, J.; Alfadul, S.M. Emerging contaminants of high concern for the environment: Current trends and future research. Environ. Res. 2022, 207, 112609. [Google Scholar] [CrossRef] [PubMed]
  10. Usman, M.; Taj, M.B.; Carabineiro, S.A.C. Gum-based nanocomposites for the removal of metals and dyes from waste water. Environ. Sci. Pollut. Res. 2023, 30, 102027–102046. [Google Scholar] [CrossRef]
  11. Samsami, S.; Mohamadizaniani, M.; Sarrafzadeh, M.-H.; Rene, E.R.; Firoozbahr, M. Recent advances in the treatment of dye-containing wastewater from textile industries: Overview and perspectives. Process. Saf. Environ. Prot. 2020, 143, 138–163. [Google Scholar] [CrossRef]
  12. Ismail, M.; Akhtar, K.; Khan, M.I.; Kamal, T.; Khan, M.A.; Asiri, A.M.; Seo, J.; Khan, S.B. Pollution, Toxicity and Carcinogenicity of Organic Dyes and their Catalytic Bio-Remediation. Curr. Pharm. Des. 2019, 25, 3645–3663. [Google Scholar] [CrossRef] [PubMed]
  13. Dhruv Patel, D.; Bhatt, S.J.B.; Reviews, G.E. Environmental pollution, toxicity profile, and physico-chemical and biotechno-logical approaches for treatment of textile wastewater. Biotechnol. Genet. Eng. Rev. 2022, 38, 33–86. [Google Scholar] [CrossRef] [PubMed]
  14. Lellis, B.; Fávaro-Polonio, C.Z.; Pamphile, J.A.; Polonio, J.C. Effects of textile dyes on health and the environment and bioremediation potential of living organisms. Biotechnol. Res. Innov. 2019, 3, 275–290. [Google Scholar] [CrossRef]
  15. Demirkol, O.; Zhang, X.; Ercal, N.J. Oxidative effects of Tartrazine (CAS No. 1934-21-0) and New Coccin (CAS No. 2611-82-7) azo dyes on CHO cells. J. Verbraucherschutz Leb. 2012, 7, 229–236. [Google Scholar] [CrossRef]
  16. Fatima, M.; Farooq, R.; Lindström, R.W.; Saeed, M. A review on biocatalytic decomposition of azo dyes and electrons re-covery. J. Mol. Liq. 2017, 246, 275–281. [Google Scholar] [CrossRef]
  17. Gurav, R.; Bhatia, S.K.; Choi, T.-R.; Choi, Y.-K.; Kim, H.J.; Song, H.-S.; Lee, S.M.; Park, S.L.; Lee, H.S.; Koh, J. Application of macroalgal biomass derived biochar and bioelectrochemical system with Shewanella for the adsorptive removal and bio-degradation of toxic azo dye. Chemosphere 2021, 264, 128539. [Google Scholar] [CrossRef] [PubMed]
  18. El-Rahim, W.M.A.; Moawad, H.; Azeiz, A.Z.A.; Sadowsky, M. Biodegradation of azo dyes by bacterial or fungal consortium and identification of the biodegradation products. Egypt. J. Aquat. Res. 2021, 47, 269–276. [Google Scholar] [CrossRef]
  19. Azin, E.; Moghimi, H. Efficient mycosorption of anionic azo dyes by Mucor circinelloides: Surface functional groups and removal mechanism study. J. Environ. Chem. Eng. 2018, 6, 4114–4123. [Google Scholar] [CrossRef]
  20. Shi, Y.; Yang, Z.; Xing, L.; Zhang, X.; Li, X.; Zhang, D. Recent advances in the biodegradation of azo dyes. World J. Microbiol. Biotechnol. 2021, 37, 1–18. [Google Scholar] [CrossRef]
  21. Tayebi, H.-A.; Ghanei, M.; Aghajani, K.; Zohrevandi, M. Modeling of reactive orange 16 dye removal from aqueous media by mesoporous silica/crosslinked polymer hybrid using RBF, MLP and GMDH neural network models. J. Mol. Struct. 2019, 1178, 514–523. [Google Scholar] [CrossRef]
  22. Javaid, R.; Qazi, U.Y. Catalytic oxidation process for the degradation of synthetic dyes: An overview. Int. J. Environ. Res. Public Health 2019, 16, 2066. [Google Scholar] [CrossRef] [PubMed]
  23. Mishra, S.; Maiti, A. Applicability of enzymes produced from different biotic species for biodegradation of textile dyes. Clean Technol. Environ. Policy 2019, 21, 763–781. [Google Scholar] [CrossRef]
  24. Donkadokula, N.Y.; Kola, A.K.; Naz, I.; Saroj, D. A review on advanced physico-chemical and biological textile dye wastewater treatment techniques. Rev. Environ. Sci. Bio/Technol. 2020, 19, 543–560. [Google Scholar] [CrossRef]
  25. Eteba, A.; Bassyouni, M.; Saleh, M. Utilization of chemically modified coal fly ash as cost-effective adsorbent for removal of hazardous organic wastes. Int. J. Environ. Sci. Technol. 2022, 20, 7589–7602. [Google Scholar] [CrossRef]
  26. Zarrini, K.; Rahimi, A.A.; Alihosseini, F.; Fashandi, H. Highly efficient dye adsorbent based on polyaniline-coated nylon-6 nanofibers. J. Clean. Prod. 2017, 142, 3645–3654. [Google Scholar] [CrossRef]
  27. Ponraj, M.; Gokila, K.; Zambare, V. Bacterial decolorization of textile dye-Orange 3R. Int. J. Adv. Biotechnol. Res. 2011, 2, 168–177. [Google Scholar]
  28. Ihsanullah, I.; Jamal, A.; Ilyas, M.; Zubair, M.; Khan, G.; Atieh, M.A. Bioremediation of dyes: Current status and prospects. J. Water Process. Eng. 2020, 38, 101680. [Google Scholar] [CrossRef]
  29. Kekes, T.; Tzia, C.; Kolliopoulos, G. Drinking and Natural Mineral Water: Treatment and Quality–Safety Assurance. Water 2023, 15, 2325. [Google Scholar] [CrossRef]
  30. Aziz, K.H.H.; Mustafa, F.S.; Omer, K.M.; Hama, S.; Hamarawf, R.F.; Rahman, K.O. Heavy metal pollution in the aquatic environment: Efficient and low-cost removal approaches to eliminate their toxicity: A review. RSC Adv. 2023, 13, 17595–17610. [Google Scholar] [CrossRef]
  31. Intisar, A.; Ramzan, A.; Hafeez, S.; Hussain, N.; Irfan, M.; Shakeel, N.; Gill, K.A.; Iqbal, A.; Janczarek, M.; Jesionowski, T. Adsorptive and photocatalytic degradation potential of porous polymeric materials for removal of pesticides, pharmaceuticals, and dyes-based emerging contaminants from water. Chemosphere 2023, 336, 139203. [Google Scholar] [CrossRef]
  32. Tahir, M.S.; Sagir, M.; Tahir, M.B. Wastewater Treatment Methods. In Advances in Water and Wastewater Treatment Technology; Springer: Berlin/Heidelberg, Germany, 2023; pp. 35–52. [Google Scholar]
  33. Hussain, Z.; Chang, N.; Sun, J.; Xiang, S.; Ayaz, T.; Zhang, H.; Wang, H. Modification of coal fly ash and its use as low-cost adsorbent for the removal of directive, acid and reactive dyes. J. Hazard. Mater. 2022, 422, 126778. [Google Scholar] [CrossRef] [PubMed]
  34. Saleh, T.A.; Mustaqeem, M.; Khaled, M. Water treatment technologies in removing heavy metal ions from wastewater: A review. Environ. Nanotechnol. Monit. Manag. 2021, 17, 100617. [Google Scholar] [CrossRef]
  35. Li, P.; Li, Y.-X.; Wu, Y.-Z.; Xu, Z.-L.; Zhang, H.-Z.; Gao, P.; Xu, S.-J. Thin-film nanocomposite NF membrane with GO on macroporous hollow fiber ceramic substrate for efficient heavy metals removal. Environ. Res. 2021, 197, 111040. [Google Scholar] [CrossRef] [PubMed]
  36. Alansi, A.M.; Qahtan, T.F.; Saleh, T.A. Solar-Driven Fixation of Bismuth Oxyhalides on Reduced Graphene Oxide for Efficient Sunlight-Responsive Immobilized Photocatalytic Systems. Adv. Mater. Interfaces 2020, 8. [Google Scholar] [CrossRef]
  37. Shah, P.D.; Dave, S.R.; Rao, M. Enzymatic degradation of textile dye Reactive Orange 13 by newly isolated bacterial strain Alcaligenes faecalis PMS-1. Int. Biodeterior. Biodegrad. 2012, 69, 41–50. [Google Scholar] [CrossRef]
  38. Swain, S.K.; Barik, S.; Pradhan, G.C.; Behera, L. Delamination of Mg-Al Layered Double Hydroxide on Starch: Change in Structural and Thermal Properties. Polym. Technol. Eng. 2018, 57, 1585–1591. [Google Scholar] [CrossRef]
  39. Bansal, M.; Pal, B. Starch modified NiFe layered double hydroxide composites for better adsorption and photocatalytic removal of reactive dye and piroxicam-20 drug. Environ. Sci. Pollut. Res. 2023, 30, 73825–73848. [Google Scholar] [CrossRef] [PubMed]
  40. Falua, K.J.; Pokharel, A.; Babaei-Ghazvini, A.; Ai, Y.; Acharya, B. Valorization of Starch to Biobased Materials: A Review. Polymers 2022, 14, 2215. [Google Scholar] [CrossRef]
  41. Pradhan, S.; Brooks, A.; Yadavalli, V. Nature-derived materials for the fabrication of functional biodevices. Mater. Today Bio 2020, 7, 100065. [Google Scholar] [CrossRef]
  42. Tabasum, S.; Younas, M.; Zaeem, M.A.; Majeed, I.; Majeed, M.; Noreen, A.; Iqbal, M.N.; Zia, K.M. A review on blending of corn starch with natural and synthetic polymers, and inorganic nanoparticles with mathematical modeling. Int. J. Biol. Macromol. 2018, 122, 969–996. [Google Scholar] [CrossRef]
  43. Teixeira, M.A.; Antunes, J.C.; Seabra, C.L.; Fertuzinhos, A.; Tohidi, S.D.; Reis, S.; Amorim, M.T.P.; Ferreira, D.P. Antibacterial and hemostatic capacities of cellulose nanocrystalline-reinforced poly (vinyl alcohol) electrospun mats doped with Tiger 17 and pexiganan peptides for prospective wound healing applications. Biomater. Adv. 2022, 137, 212830. [Google Scholar] [CrossRef]
  44. Barik, S.; Badamali, S.K. Layer double hydroxide reinforced polymer bionanocomposites for packaging applications. In Bionanocomposites for Packaging Applications; Springer: Cham, Switzerland, 2018; pp. 269–290. [Google Scholar]
  45. Abdallah, I.A.; Hammad, S.F.; Bedair, A.; Abdelhameed, R.M.; Locatelli, M.; Mansour, F.R. Applications of layered double hydroxides in sample preparation: A review. Microchem. J. 2023, 192. [Google Scholar] [CrossRef]
  46. Kameliya, J.; Verma, A.; Dutta, P.; Arora, C.; Vyas, S.; Varma, R.S. Layered Double Hydroxide Materials: A Review on Their Preparation, Characterization, and Applications. Inorganics 2023, 11, 121. [Google Scholar] [CrossRef]
  47. Sharma, A.; Kumari, S.; Sharma, S.; Singh, T.; Kumar, S.; Thakur, A.; Bhatia, S.K.; Sharma, A.K. Layered Double Hydroxides: An insight into the role of Hydrotalcite-type Anionic Clays in Energy and Environmental applications with Current Progress and Recent Prospects. Mater. Today Sustain. 2023, 22, 100399. [Google Scholar] [CrossRef]
  48. Huang, Y.; Liu, C.; Rad, S.; He, H.; Qin, L. A Comprehensive Review of Layered Double Hydroxide-Based Carbon Composites as an Environmental Multifunctional Material for Wastewater Treatment. Processes 2022, 10, 617. [Google Scholar] [CrossRef]
  49. Lu, Y.; Jiang, B.; Fang, L.; Ling, F.; Gao, J.; Wu, F.; Zhang, X. High performance NiFe layered double hydroxide for methyl orange dye and Cr(VI) adsorption. Chemosphere 2016, 152, 415–422. [Google Scholar] [CrossRef]
  50. Zubair, M.; Jarrah, N.; Khalid, A.; Manzar, M.S.; Kazeem, T.S.; Al-Harthi, M.A. Starch-NiFe-layered double hydroxide composites: Efficient removal of methyl orange from aqueous phase. J. Mol. Liq. 2018, 249, 254–264. [Google Scholar] [CrossRef]
  51. Lei, C.; Pi, M.; Kuang, P.; Guo, Y.; Zhang, F. Organic dye removal from aqueous solutions by hierarchical calcined Ni-Fe layered double hydroxide: Isotherm, kinetic and mechanism studies. J. Colloid Interface Sci. 2017, 496, 158–166. [Google Scholar] [CrossRef]
  52. Liu, M.; Chen, Q.; Lu, K.; Huang, W.; Lü, Z.; Zhou, C.; Yu, S.; Gao, C. High efficient removal of dyes from aqueous solution through nanofiltration using diethanolamine-modified polyamide thin-film composite membrane. Sep. Purif. Technol. 2017, 173, 135–143. [Google Scholar] [CrossRef]
  53. Shan, R.-R.; Yan, L.-G.; Yang, Y.-M.; Yang, K.; Yu, S.-J.; Yu, H.-Q.; Zhu, B.-C.; Du, B. Highly efficient removal of three red dyes by adsorption onto Mg–Al-layered double hydroxide. J. Ind. Eng. Chem. 2015, 21, 561–568. [Google Scholar] [CrossRef]
  54. Yang, Z.; Wang, F.; Zhang, C.; Zeng, G.; Tan, X.; Yu, Z.; Zhong, Y.; Wang, H.; Cui, F. Utilization of LDH-based materials as potential adsorbents and photocatalysts for the decontamination of dyes wastewater: A review. RSC Adv. 2016, 6, 79415–79436. [Google Scholar] [CrossRef]
  55. Liu, C.; Mao, S.; Shi, M.; Wang, F.; Xia, M.; Chen, Q.; Ju, X. Peroxymonosulfate activation through 2D/2D Z-scheme CoAl-LDH/BiOBr photocatalyst under visible light for ciprofloxacin degradation. J. Hazard. Mater. 2021, 420, 126613. [Google Scholar] [CrossRef]
  56. Liu, G.; Zhang, X.; Liu, H.; He, Z.; Show, P.L.; Vasseghian, Y.; Wang, C. Biochar/layered double hydroxides composites as catalysts for treatment of organic wastewater by advanced oxidation processes: A review. Environ. Res. 2023, 234, 116534. [Google Scholar] [CrossRef]
  57. Khan, M.A.; Fattah-Alhosseini, A.; Kaseem, M. Recent advances in the design and surface modification of titanium-based LDH for photocatalytic applications. Inorg. Chem. Commun. 2023, 153, 110739. [Google Scholar] [CrossRef]
  58. Ebrahimpour, Z.; Pliekhova, O.; Cabrera, H.; Abdelhamid, M.; Korte, D.; Gadedjisso-Tossou, K.S.; Niemela, J.; Stangar, U.L.; Franko, M. Photodegradation mechanisms of reactive blue 19 dye under UV and simulated solar light irradiation. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 2021, 252, 119481. [Google Scholar] [CrossRef]
  59. Zubair, M.; Jarrah, N.; Manzar, M.S.; Al-Harthi, M.; Daud, M.; Mu’azu, N.D.; Haladu, S.A. Adsorption of eriochrome black T from aqueous phase on MgAl-, CoAl- and NiFe- calcined layered double hydroxides: Kinetic, equilibrium and thermodynamic studies. J. Mol. Liq. 2017, 230, 344–352. [Google Scholar] [CrossRef]
  60. Chang, P.R.; Zheng, P.; Liu, B.; Anderson, D.P.; Yu, J.; Ma, X. Characterization of magnetic soluble starch-functionalized carbon nanotubes and its application for the adsorption of the dyes. J. Hazard. Mater. 2011, 186, 2144–2150. [Google Scholar] [CrossRef]
  61. Mujtaba, G.; Ullah, A.; Khattak, D.; Shah, M.U.H.; Daud, M.; Ahmad, S.; Hai, A.; Ahmed, F.; Alshahrani, T.; Banat, F. Simultaneous adsorption of methylene blue and amoxicillin by starch-impregnated MgAl layered double hydroxide: Parametric optimization, isothermal studies and thermo-kinetic analysis. Environ. Res. 2023, 235, 116610. [Google Scholar] [CrossRef]
  62. Mu’azu, N.D.; Haladu, S.A.; Jarrah, N.; Zubair, M.; Essa, M.H.; Ali, S.A. Polyaspartate extraction of cadmium ions from contaminated soil: Evaluation and optimization using central composite design. J. Hazard. Mater. 2018, 342, 58–68. [Google Scholar] [CrossRef]
  63. Popa, M.I.; Alexandrica, M.C.; Silion, M.; Hritcu, D. Layered double hydroxides as adsorbents for anionic dye removal from aqueous solutions. Environ. Eng. Manag. J. 2015, 14, 381–388. [Google Scholar] [CrossRef]
  64. Samuei, S.; Fakkar, J.; Rezvani, Z.; Shomali, A.; Habibi, B. Synthesis and characterization of graphene quantum dots/CoNiAl-layered double-hydroxide nanocomposite: Application as a glucose sensor. Anal. Biochem. 2017, 521, 31–39. [Google Scholar] [CrossRef] [PubMed]
  65. Silion, M.; Hritcu, D.; Popa, M. Preparation and characterization of ketoprofen-layered double hydroxide compounds. J. Optoelectron. Adv. Mater. Interfaces 2010, 12, 2150–2156. [Google Scholar]
  66. Taj, M.B.; Alkahtani, M.D.F.; Raheel, A.; Shabbir, S.; Fatima, R.; Aroob, S.; Yahya, R.; Alelwani, W.; Alahmadi, N.; Abualnaja, M.; et al. Bioconjugate synthesis, phytochemical analysis, and optical activity of NiFe2O4 nanoparticles for the removal of ciprofloxacin and Congo red from water. Sci. Rep. 2021, 11, 5439. [Google Scholar] [CrossRef] [PubMed]
  67. Biswas, S.; Siddiqi, H.; Meikap, B.C.; Sen, T.K.; Khiadani, M. Preparation and Characterization of Raw and Inorganic Acid-Activated Pine Cone Biochar and Its Application in the Removal of Aqueous-Phase Pb2+ Metal Ions by Adsorption. Water Air Soil Pollut. 2019, 231, 3. [Google Scholar] [CrossRef]
  68. Kotp, Y.H. Fabrication of cerium titanate cellulose fiber nanocomposite materials for the removal of methyl orange and methylene blue from polluted water by photocatalytic degradation. Environ. Sci. Pollut. Res. 2022, 29, 81583–81608. [Google Scholar] [CrossRef] [PubMed]
  69. Fang, K.; Li, K.; Yang, T.; Li, J.; He, W. Starch-based magnetic nanocomposite as an efficient absorbent for anticancer drug removal from aqueous solution. Int. J. Biol. Macromol. 2021, 184, 509–521. [Google Scholar] [CrossRef] [PubMed]
  70. Das, D.; Jha, S.; Kumar, K.J. Effect of carboxymethylation on physicochemical and release characteristics of Indian Palo starch. Int. J. Biol. Macromol. 2015, 77, 181–187. [Google Scholar] [CrossRef] [PubMed]
  71. Fernandes, S.C.; Freire, C.S.; Silvestre, A.J.; Neto, C.P.; Gandini, A.; Berglund, L.A.; Salmén, L. Transparent chitosan films reinforced with a high content of nanofibrillated cellulose. Carbohydr. Polym. 2010, 81, 394–401. [Google Scholar] [CrossRef]
  72. Valera-Zaragoza, M.; Huerta-Heredia, A.A.; Peña-Rico, M.A.; Juarez-Arellano, E.A.; Navarro-Mtz, A.K.; Ramírez-Vargas, E.; Sánchez-Valdes, S. Morphological, structural and cytotoxic behavior of starch/silver nanocomposites with synthesized silver nanoparticles using Stevia rebaudiana extracts. Polym. Bull. 2020, 78, 1683–1701. [Google Scholar] [CrossRef]
  73. Bibi, A.; Sadiq-Ur-Rehman, S.-U.; Akhtar, T.; Shahzad, M.I. Effective removal of carcinogenic dye from aqueous solution by using alginate-based nanocomposites. Desalination Water Treat. 2020, 208, 386–398. [Google Scholar] [CrossRef]
  74. Liu, X.; Zhang, T.; Xu, D.; Zhang, L. Microwave-Assisted Catalytic Degradation of Crystal Violet with Barium Ferrite Nanomaterial. Ind. Eng. Chem. Res. 2016, 55, 11869–11877. [Google Scholar] [CrossRef]
  75. Battin, E.E.; Brumaghim, J.L. Antioxidant activity of sulfur and selenium: A review of reactive oxygen species scavenging, glutathione peroxidase, and metal-binding antioxidant mechanisms. Cell Biochem. Biophys. 2009, 55, 1–23. [Google Scholar] [CrossRef]
  76. Rojas-Carbonell, S.; Artyushkova, K.; Serov, A.; Santoro, C.; Matanovic, I.; Atanassov, P. Effect of pH on the Activity of Platinum Group Metal-Free Catalysts in Oxygen Reduction Reaction. ACS Catal. 2018, 8, 3041–3053. [Google Scholar] [CrossRef]
  77. Faria, P.; Órfão, J.; Pereira, M. Adsorption of anionic and cationic dyes on activated carbons with different surface chemistries. Water Res. 2004, 38, 2043–2052. [Google Scholar] [CrossRef]
  78. Ilyas, A.; Rafiq, K.; Abid, M.Z.; Rauf, A.; Hussain, E. Growth of villi-microstructured bismuth vanadate (Vm-BiVO4) for photocatalytic degradation of crystal violet dye. RSC Adv. 2023, 13, 2379–2391. [Google Scholar]
  79. Wang, M.; Shen, S.; Li, L.; Tang, Z.; Yang, J. Effects of sacrificial reagents on photocatalytic hydrogen evolution over different photocatalysts. J. Mater. Sci. 2017, 52, 5155–5164. [Google Scholar] [CrossRef]
  80. Abunowara, M.; Bustam, M.A.; Sufian, S.; Babar, M.; Eldemerdash, U.; Mukhtar, A.; Ullah, S.; Assiri, M.A.; Al-Sehemi, A.G.; Lam, S.S. High pressure CO2 adsorption onto Malaysian Mukah-Balingian coals: Adsorption isotherms, thermodynamic and kinetic investigations. Environ. Res. 2023, 218, 114905. [Google Scholar] [CrossRef] [PubMed]
  81. Hao, L.; Luan, J. The Fabrication and Property Characterization of a Ho2YSbO7/Bi2MoO6 Heterojunction Photocatalyst and the Application of the Photodegradation of Diuron under Visible Light Irradiation. Int. J. Mol. Sci. 2024, 25, 4418. [Google Scholar] [CrossRef] [PubMed]
Catalysts 14 00449 g001
Figure 1. X-ray diffraction spectra of starch, NiCrMn-LDH and its composite.
Figure 1. X-ray diffraction spectra of starch, NiCrMn-LDH and its composite.
Catalysts 14 00449 g001
Catalysts 14 00449 g002aCatalysts 14 00449 g002bCatalysts 14 00449 g002c
Figure 2. SEM images of NiCrMn-LDH (a–c) and starch/NiCrMn-LDH composite (d–f), EDX images of NiCrMn-LDH (g), and starch/NiCrMn-LDH composite (h).
Figure 2. SEM images of NiCrMn-LDH (a–c) and starch/NiCrMn-LDH composite (d–f), EDX images of NiCrMn-LDH (g), and starch/NiCrMn-LDH composite (h).
Catalysts 14 00449 g002aCatalysts 14 00449 g002bCatalysts 14 00449 g002c
Catalysts 14 00449 g003
Figure 3. FTIR spectrum of starch/NiCrMn-LDH composite (a), NiCrMn-LDH (b), and starch (c).
Figure 3. FTIR spectrum of starch/NiCrMn-LDH composite (a), NiCrMn-LDH (b), and starch (c).
Catalysts 14 00449 g003
Catalysts 14 00449 g004
Figure 4. DLS analysis (a) and ZETA potential study (b) of starch/NiCrMn-LDH composite, NiCrMn-LDH, and starch.
Figure 4. DLS analysis (a) and ZETA potential study (b) of starch/NiCrMn-LDH composite, NiCrMn-LDH, and starch.
Catalysts 14 00449 g004
Catalysts 14 00449 g005
Figure 5. Determination of PZC value for starch/NiCrMn-LDH composite, NiCrMn-LDH, and starch (black line represent the pH initial).
Figure 5. Determination of PZC value for starch/NiCrMn-LDH composite, NiCrMn-LDH, and starch (black line represent the pH initial).
Catalysts 14 00449 g005
Catalysts 14 00449 g006
Figure 6. N2 adsorption-desorption isotherm (a) BJH analysis for pore radius (b) for starch/NiCrMn-LDH composite.
Figure 6. N2 adsorption-desorption isotherm (a) BJH analysis for pore radius (b) for starch/NiCrMn-LDH composite.
Catalysts 14 00449 g006
Catalysts 14 00449 g007
Figure 7. TGA analysis (a) and DSC analysis (b) of starch/NiCrMn-LDH, NiCrMn-LDH, and starch.
Figure 7. TGA analysis (a) and DSC analysis (b) of starch/NiCrMn-LDH, NiCrMn-LDH, and starch.
Catalysts 14 00449 g007
Catalysts 14 00449 g008
Figure 8. The gradual decrease in absorbance peak of RO13 during photocatalytic degradation.
Figure 8. The gradual decrease in absorbance peak of RO13 during photocatalytic degradation.
Catalysts 14 00449 g008
Catalysts 14 00449 g009
Figure 9. Effect of photocatalyst dose in photocatalytic degradation of RO13.
Figure 9. Effect of photocatalyst dose in photocatalytic degradation of RO13.
Catalysts 14 00449 g009
Catalysts 14 00449 g010
Figure 10. Effect of initial dye concentration in photocatalytic degradation of RO13.
Figure 10. Effect of initial dye concentration in photocatalytic degradation of RO13.
Catalysts 14 00449 g010
Catalysts 14 00449 g011
Figure 11. Effect of pH in photocatalytic degradation of RO13.
Figure 11. Effect of pH in photocatalytic degradation of RO13.
Catalysts 14 00449 g011
Catalysts 14 00449 g012
Figure 12. Effect of inorganic salts in photocatalytic degradation of RO13.
Figure 12. Effect of inorganic salts in photocatalytic degradation of RO13.
Catalysts 14 00449 g012
Catalysts 14 00449 g013
Figure 13. Effect of hydrogen peroxide (H2O2) concentration in photocatalytic degradation of RO13.
Figure 13. Effect of hydrogen peroxide (H2O2) concentration in photocatalytic degradation of RO13.
Catalysts 14 00449 g013
Catalysts 14 00449 g014
Figure 14. Effect of sacrificial reagent in photocatalytic degradation of RO13.
Figure 14. Effect of sacrificial reagent in photocatalytic degradation of RO13.
Catalysts 14 00449 g014
Catalysts 14 00449 g015
Figure 15. Pseudo-first-order kinetics model for photocatalytic degradation of RO13.
Figure 15. Pseudo-first-order kinetics model for photocatalytic degradation of RO13.
Catalysts 14 00449 g015
Catalysts 14 00449 g016
Figure 16. Mechanism of photocatalytic degradation of RO13.
Figure 16. Mechanism of photocatalytic degradation of RO13.
Catalysts 14 00449 g016
Catalysts 14 00449 g017
Figure 17. Schematic diagram for preparation of starch/NiCrMn-ldh composite.
Figure 17. Schematic diagram for preparation of starch/NiCrMn-ldh composite.
Catalysts 14 00449 g017
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.

Share and Cite

MDPI and ACS Style

Usman, M.; Taj, M.B.; Almasoudi, A.; Baamer, D.F.; Ali, O.M.; Khan, M.I.; Bibi, I.; Rehman, M.U.; Rasheed, R.; Raheel, A.; et al. Novel Starch-Modified NiCrMn-LDH-Based Composite for Photocatalytic Degradation of Reactive Orange 13. Catalysts 2024, 14, 449. https://doi.org/10.3390/catal14070449

AMA Style

Usman M, Taj MB, Almasoudi A, Baamer DF, Ali OM, Khan MI, Bibi I, Rehman MU, Rasheed R, Raheel A, et al. Novel Starch-Modified NiCrMn-LDH-Based Composite for Photocatalytic Degradation of Reactive Orange 13. Catalysts. 2024; 14(7):449. https://doi.org/10.3390/catal14070449

Chicago/Turabian Style

Usman, Muhammad, Muhammad Babar Taj, Afaf Almasoudi, Doaa F. Baamer, Omar Makram Ali, Muhammad Imran Khan, Ismat Bibi, Mobeen Ur Rehman, Rabia Rasheed, Ahmad Raheel, and et al. 2024. "Novel Starch-Modified NiCrMn-LDH-Based Composite for Photocatalytic Degradation of Reactive Orange 13" Catalysts 14, no. 7: 449. https://doi.org/10.3390/catal14070449

APA Style

Usman, M., Taj, M. B., Almasoudi, A., Baamer, D. F., Ali, O. M., Khan, M. I., Bibi, I., Rehman, M. U., Rasheed, R., Raheel, A., Lashari, M. H., Shanableh, A., & Fernandez-Garcia, J. (2024). Novel Starch-Modified NiCrMn-LDH-Based Composite for Photocatalytic Degradation of Reactive Orange 13. Catalysts, 14(7), 449. https://doi.org/10.3390/catal14070449

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop