Even though concrete performs satisfactorily during the envisaged service life and it is considered a durable material, still, it ages and deteriorates. The European Standard EN 206-1 [
38] divides the environmental conditions that cause deterioration in exposure classes, offering descriptions and several informative examples for each class. For environmental conditions causing carbonation, designations from XC1 to XC4 are used, as presented in
Table 1. The process of reinforcement corrosion can be roughly divided into two phases, which are called the initiation phase and the propagation phase [
39].
Fib Bulletin 34 [
7] defines the initiation as a phase that ends with the limit state of reinforcement depassivation being reached. The propagation phase is divided into limit states of crack formation, spalling of concrete cover, and collapse through bond failure or reduction of cross-section. In the following sections, analytical models describing these limit states are included.
3.1. Initiation Phase
The initiation phase of the process of carbonation-induced corrosion is marked by carbonation penetration, and it finishes roughly with the depassivation of reinforcement. Comprehensive descriptions of numerous analytical models of concrete carbonation and their development can be found in [
40]. The analytical model that defines the limit state of carbonation-induced depassivation presented and applied in this article is supported by the
fib [
7,
8,
9]. The model was initially developed in the research projects DuraCrete [
41] and DARTS [
42]. In later development of the model, von Greve-Dierfeld and Gehlen [
43] excluded the inverse carbonation resistance parameter
RNAC−1 and introduced an additional parameter—carbonation rate
kNAC. The limit state equation of carbonation-induced depassivation, where the carbonation depth is compared with concrete cover, is given by Equation (11):
where:
Furthermore, carbonation depth can be expressed as:
where:
kNAC is the carbonation rate for standard test conditions (mm/years0.5),
ke is the function describing the environmental effect of relative humidity,
kc is the function describing the effect of curing/execution,
ka is the function describing the effect of CO2 concentration in the ambient air,
t is time (year), i.e., the age of structure, and
W(t) is the function describing the effect of wetting events.
The carbonation rate
kNAC in Equation (12) represents the resistance of the concrete mixture to carbonation, where the rate of the particular mixture is derived under constant (standard) test conditions. Tested values of carbonation rates of different concrete mixtures under standard test conditions can be found in [
43,
44,
45]. The mean values of such tested carbonation rates are expressed as dependent on cement types, as shown in
Table 2.
The shaded elements in
Table 2 were obtained through linear extrapolation of measured values. Furthermore, von Greve-Dierfeld and Gehlen [
43,
44,
45] consider that carbonation rate is normally distributed with the unique standard deviation
s, which is unrelated to concrete mixture and is equal to 1.1 mm/years
0.5.
The environmental coefficient
ke introduces the effect of relative humidity on carbonation, and is described as:
where:
RHa is the relative humidity of ambient air (%),
RHl is the reference (laboratory) humidity (%),
fe is the exponent (-), and
ge is the exponent (-).
As an input for the relative humidity
RHa, data from the nearest weather station may be used. Since relative humidity varies in a range from 0 to 100%, restricted distributions with an upper limit may be used to describe
RHa, such as beta or Weibull (max) distribution. The reference humidity
RHl has to be chosen in accordance with the test conditions to determine the carbonation resistance of the concrete. Since the carbonation rates presented in
Table 2 were tested under standard test conditions, which imply relative humidity of 65 ± 5%, the reference humidity
RHl should be chosen within the range 60–70%. The parameters
ge and
fe have to be determined by means of a curve-fitting procedure with the actual test data. According to project DARTS [
42], the best results are gained with
fe being equal to 5 and
ge being equal to 2.5.
Curing of newly built structures is performed to prevent the drying of fresh concrete, and as such, it affects the hydration, and subsequently the carbonation, of the concrete. This has a prevailing effect on carbonation, and it can be taken into account through the curing/execution coefficient
kc, expressed in Equation (14):
where:
The curing time
tc is considered a constant, the value of which should be derived from execution documents or valid standards at the time of construction. The value of the variable
bc was quantified in DARTS [
42] as being normally distributed with a mean value
m = −0.567 and standard deviation
s = 0.024.
Coefficient
ka, shown in Equation (15), describes the relation of the ambient air CO
2 content
Ca and the laboratory content
Cl used for standard test purposes:
where:
Ca is the CO2 concentration of ambient air (kg/m3) or (vol. %), and
Cl is the CO2 concentration during concrete testing in laboratory (kg/m3) or (vol. %).
The ambient air CO
2 concentration depends on parameters such as traffic volume, CO
2 emission of local industry, atmospheric stability, wind speed, etc. [
47]. Von Greve-Dierfeld and Gehlen [
44] included assumed maximum and minimum CO
2 concentrations obtained from literature review, and divided these values between rural and urban locations, as shown in
Table 3.
In wetting periods, concrete surface absorbs water and thus inhibits carbonation. To take into account the meso-climatic conditions due to wetting events, the time-dependent function was introduced [
42], called the environmental or wetting function
W(
t):
where:
t0 is the reference time (year),
pdr is the probability of driving rain (-),
ToW is the time of wetness (-), i.e., days with daily rainfall ≥ 2.5 mm, and
bw is the regression exponent (-).
Parameters
ToW and
pdr are introduced in order to take into account the wetness of concrete surfaces that are not horizontal. Time of wetness
ToW represents a percentage of rainy days per year, where a rainy day is considered to be a day with a minimum amount of precipitation water of 2.5 mm. Probability of driving rain
pdr represents an average distribution of the wind direction during rain events, and it depends on the strength and direction of wind, the orientation of the structural element, etc. In addition, the weather function contains two model parameters,
bw and
t0, which were quantified in [
42] based on the analysis of the performed tests. The regression exponent
bw is considered normally distributed with a mean value
m = 0.446 and a standard deviation
s = 0.163. The reference time,
t0, at which the analysis was performed is equal to 28 days, or can be expressed in years as 0.0767 years.
To use the model of carbonation-induced depassivation for determining sojourn times of the semi-Markov process, the model has to express the duration in which the element remains un-depassivated (i.e., the initiation duration
tini). By converting Equation (12), the time of initiation can be expressed as shown in Equation (17):
where:
3.2. Propagation Phase
During the propagation phase, the process of reinforcement corrosion takes place, the rate of which is governed by the availability of water and oxygen on the steel surface [
40]. The consequences of reinforcement corrosion are the cracking of the cover, loss of steel concrete bond, decrease of steel cross-section, and loss of steel ductility [
48]. In
fib Bulletin 34 [
7], these consequences are contained in the limit states of crack formation, spalling of the concrete cover, and collapse. These limit states are divided into serviceability limit states (SLS), which include the events of crack formation and spalling, and the ultimate limit state (ULS), which includes the event of collapse in different modes. To differentiate among collapse modes, different robustness classes (ROC) are described in [
7]. These classes are given in connection with a rough estimate on the percentage of cross-section loss Δ
As that causes particular collapse modes, as presented in
Table 4. In other words, sufficient reliability regarding the ULS could be achieved by adding the needed extra reinforcement (sacrificial cross-section) in the amount presented in
Table 4. However, it should be noted that these values are a rough estimate and need to be confirmed by further research.
Propagation of corrosion can be observed through several performance indicators, including the corrosion depth
Px, rate of corrosion
vcorr, loss of cross-section area Δ
As, loss of bar diameter Δ
φ, concrete crack width
w, and so on. The simplified model for determining the corrosion depth
Px(
t) can be expressed as in Equation (19):
where:
The value of bar diameter
φ(
t) as function of time and corrosion depth can be calculated according to Equation (20):
where:
φ0 is the initial bar diameter (mm), and
α is the factor accounting the type of corrosion (pitting or homogeneous) (-).
Corrosion types can be divided into homogeneous (uniform) corrosion and pitting (localized) corrosion, which result from carbonation-induced depassivation and chloride-induced depassivation, respectively. For homogeneous corrosion, it is assumed that the factor accounting for the type of corrosion α ranges between 0 and 2. On the contrary, for chloride-induced corrosion, it can be as high as 10 [
49]. Furthermore, the loss of bar diameter expressed in percentages Δ
φ(
t) is given by Equation (21):
According to [
41], the concrete crack width
w(
t) can be expressed in connection to corrosion depth
Px(
t), as shown in Equation (22):
where:
w0 is the crack width when it is visible (≈0.05) (mm),
β is the parameter that controls the propagation (-), and
P0 is the loss of reinforcement bar diameter when crack width is visible (mm).
It should be noted that the correlation between concrete quality, corrosion rates and microenvironment has not yet been quantified in detail. This implies that reliable findings are lacking, which would connect critical values of performance indicators (
Px(
t),
w(
t), Δ
As(
t), Δ
φ(
t),…) at which the states of cracking, spalling and collapse are triggered. Hence, it is hard to accurately express the duration of different propagation periods. To overcome this problem, a questionnaire was organized by
fib’s Task Group 5.6, in which experts all over the world gave their opinion on expected penetration depths and propagation periods in carbonation environment. The estimations were given within the exposure class XC4, for a reference temperature of
Tref = 293 K, assuming that depassivation had already occurred. Collected data were statistically elaborated and presented in [
7], where the propagation periods were described by lognormal distribution, as shown in
Table 5.
In cases where the average yearly temperature
Treal of the object being investigated differs from 293 K, the values in
Table 5 need to be adapted using the formula for the temperature dependence of reaction rates (Arrhenius equation) [
50], as presented in Equation (23):
where:
tprop(Treal) is the duration of propagation period based on real temperature Treal (year),
tprop(Tref) is the duration of propagation period based on reference temperature Tref (year),
b is the regression parameter (b = 4900 K),
Tref is the reference temperature (Tref = 293 K), and
Treal is the average yearly ambient temperature of the object considered (K).
Furthermore, in addition to the duration of propagation periods, critical corrosion depths
Pcrit causing the events of cracking and spalling can also be extracted from [
7], as presended in
Table 6.