1. Introduction
The challenge of understanding how brick properties change in the presence of moisture necessitates the use of advanced quantitative interpretation techniques, which should be integrated with geophysical and petrophysical methods. In this paper, we introduce an innovative interdisciplinary approach to identify high-permeability bricks, demonstrating that moisture percentage can be inferred from the combined utilization of brick images obtained with smartphones, color theory, color formats, unsupervised learning, and the fluid distribution above the free water level [
1]. Our findings reveal that bricks with anomalously high permeability show significant variations in the bulk volume of water (BVW) when compared to conventional bricks. We emphasize the importance of linking moisture content, or bulk volume of water (BVW) values, with water saturation (
). The key to understanding permeability lies in the pore structure, wherein capillary-bound water, represented by BVW, is typically found in the pores. BVW quantifies the pore geometry, which is influenced by the size, shape, and arrangement of grains, thereby relating it to both permeability and porosity [
1]. As mentioned before, highly permeable bricks are characterized by a notably lower moisture content or BVW.
Brick is one of the oldest and most influential building materials in history, originating over 6000 years ago in ancient Mesopotamia [
2]. Initially made from sun-dried mud, bricks evolved with the introduction of kiln firing by civilizations such as the Sumerians, Babylonians, and Egyptians, which enhanced their durability [
2]. The Romans further advanced brickmaking, using fired clay bricks to construct some structures [
2]. In Mesoamerica, the Mayans used red bricks in the construction of pyramids, such as those in Comalcalco, a key trading port with significant architectural developments [
3]. Throughout the Middle Ages, brick was integral to the construction of cathedrals, castles, and urban infrastructure in Europe, contributing to the distinct Gothic architectural style. In the Modern Age, bricks were used extensively in Northern European architecture and Georgian England [
2]. Today, brick remains a versatile and durable material in contemporary architecture, valued for its strength and aesthetic appeal [
4,
5].
Fired red brick is a cornerstone of construction globally, prized for its durability and versatility. However, its performance can be significantly compromised by moisture within its structure. Moisture can degrade mechanical strength, promote mold formation, and reduce thermal insulation, ultimately affecting the integrity of buildings [
6]. Fired clay ceramics exhibit long-term moisture-induced expansion due to a slow chemical reaction with atmospheric water [
7]. This expansion, though it decreases over time, is significant and often underestimated. Early recognition of moisture expansion as a cause of cracking in brickwork was delayed, likely because older masonry used soft lime mortars [
8]. This expansion is driven by the slow diffusion of water within the solid phases of the ceramic matrix [
7]. This moisture expansion is directly linked to mass gain. While accelerated by high-temperature steaming, the expansion progresses slowly under normal atmospheric conditions, underscoring the persistent risk of cracking in brick structures over time [
7]. Various studies have shown that temperature and moisture content are critical factors influencing the thermal conductivity of insulating materials [
9]. Specifically, moisture transfer in building envelopes significantly impacts heat transfer processes, especially in hot and humid areas [
9]. These studies highlight the issue that the thermal conductivity of commonly used insulation materials increases with rising temperature and humidity, underscoring moisture as a critical issue in bioclimatic structures [
9].
Eco-friendly bricks, particularly those containing bagasse fibers, may face challenges in the future regarding biological degradation. This study introduces a methodology that can assist in performing quality control for bricks that incorporate organic fibers. The inclusion of organic materials in construction materials aims to enhance their sustainability and mechanical properties [
10]. However, these fibers can introduce vulnerability to microbial attack, particularly in humid environments. Different investigations have been conducted to evaluate the growth of microorganisms on construction materials containing various percentages of organic fibers [
10]. Although the firing process reduces organic matter, residual fibers can still pose a risk of biological degradation. Due to the amount of organic matter, this firing process could also increase the number and size of voids in the bricks. Long-term exposure to moisture may compromise the durability and structural integrity of eco-friendly building materials. Further research is needed to understand the influence of moisture on eco-friendly bricks, particularly those containing organic fibers [
11]. Considering that moisture can lead to biological degradation in eco-friendly bricks, it is crucial to assess whether their heightened porosity and water absorption could accelerate this process, potentially compromising their structural integrity over time [
11]. The short-term improvements in compressive strength and bending resistance [
10] might not translate into long-term durability, especially if the bricks are more susceptible to moisture-related issues due to increased porosity. Bricks that contain organic fibers have demonstrated low performance in capillarity tests [
11]. This is crucial for eco-friendly bricks, where maintaining structural integrity over time is a key concern, especially in the context of climate change and increased seismic activity. As climate change intensifies weather patterns and moisture exposure, and as earthquakes become more frequent or severe, the durability of these bricks must be rigorously assessed to ensure their long-term performance in increasingly unpredictable environments. In the specialized literature, there is also a lack of information about the scalability of eco-friendly bricks and the potential challenges in maintaining consistent quality when applied to larger construction projects, such as the associated infrastructure required for the development of the Interoceanic Corridor. This is a major infrastructure project in México aimed at creating a trade and logistics route between the Atlantic and Pacific Oceans.
The non-destructive evaluation of moisture content in fired red bricks is crucial for ensuring the safety of structures. Traditional moisture measurement techniques, like drilling, are intrusive and costly, limiting their application in construction and conservation. Approaches that rely on a single non-destructive method often result in limited accuracy [
12]. However, recent advancements have demonstrated that a more accurate quantitative assessment of moisture content in saline brick walls can be achieved using a combination of machine learning and two complementary non-destructive methods [
12]. The cost of inadequate moisture management can be substantial, leading to millions of dollars in damages, structural repairs, downtime, and long-term operational costs. According to the United States Environmental Protection Agency [
6], proper moisture management is essential to avoid significant costs, emphasizing the need for effective moisture control measures from the outset of construction projects.
Digital image processing presents a promising solution for non-invasively estimating the moisture content in fired red bricks. By capturing high-resolution images and analyzing them with advanced algorithms, it could be possible to detect and quantify moisture economically and effectively. Despite its potential, there is a scarcity of studies on this approach, and no established methodology exists for using digital image processing to estimate the moisture percentage or identify patterns associated with fractures and moisture levels in bricks. In the current digital era, process automation is vital for efficiency and competitiveness across various sectors. Unsupervised learning, a branch of artificial intelligence, allows machines to learn from data without human supervision, making it a powerful tool for automating imaging processes in the construction industry [
13,
14]. Identifying the hidden patterns in images of construction materials can help architects and engineers develop more effective bioclimatic strategies and create waterproof materials tailored to specific needs [
6].
Photographing large areas for purposes such as structural inspection poses technical and logistical challenges. Achieving complete coverage, coordinating multiple cameras, and managing large volumes of data are significant obstacles. While unmanned aerial vehicles (UAVs) equipped with infrared cameras are used in various fields, their integration into the construction sector remains limited [
15]. Ensuring image quality under varying lighting and weather conditions further complicates this task [
16].
Building upon these longstanding challenges, our study seeks to integrate modern digital and AI-driven methodologies to address the impact of moisture on fired red brick, particularly in traditional settings. This study hypothesizes that applying digital image processing techniques, combined with artificial intelligence algorithms, can develop a reliable methodology to estimate moisture percentage and detect fractures in fired red bricks non-destructively. This approach aims to provide the construction industry with an effective tool for material evaluation and quality control, thereby enhancing efficiency and sustainability in building projects.
In this context, our research offers a methodology that combines digital image analysis with AI techniques to deliver non-destructive moisture estimates. The primary objective of this study is to address critical knowledge gaps by adapting methodologies from industries like the energy sector, where digital image processing is extensively utilized to estimate moisture content in soils and crops [
17] and to detect fractures [
18]. By leveraging these techniques, this research identifies the visual characteristics and specific patterns related to moisture levels and fracturing in captured images. The findings could have practical applications in construction and building conservation, offering innovative, non-invasive tools for assessing material integrity. This interdisciplinary approach could not only enhance current practices but also contribute to the sustainability and resilience of construction materials.
4. Artificial Intelligence: Unsupervised Learning
While color theory provides foundational insights into moisture-related color variations, artificial intelligence enhances our ability to quantify and interpret these changes across image datasets. AI algorithms can analyze historical data, climate patterns, budget constraints, and other factors to create optimal architectural designs. Notable examples include the work of the architect Michael Hansmeyer, who employs generative algorithms to create complex and visually stunning architectural structures. Recently, advanced programs for architectural design, such as MidJourney, have been developed [
23]. The visual representations generated by these tools exhibit a high degree of aesthetic quality. AI demonstrates its precise processing capabilities by automatically incorporating the characteristics of an object into a digital image, even without explicit input in the form of keywords. Additionally, it is important to highlight the undeniable advantage of the speed at which these tools create outputs [
24,
25].
Unsupervised learning is a branch of artificial intelligence that focuses on processing data without labels or prior supervision. This technique is applied in four steps: in the first step, the attributes are extracted; in the second, dimensionality is reduced; in the third, data groups with similar characteristics are identified; and, in the fourth step, the segmented information is mapped back to the original image [
18].
(a) Attribute selection: attribute selection in unsupervised learning involves choosing which features of the data are most important for the computer to correctly process the information. For example, if the goal is to identify the most illuminated regions of a painting, such as the one illustrated in
Figure 3 [
26], which depicts a perspective view of a tourist walkway in Oaxaca, attributes must first be extracted from a digital photograph of the painting. The computer must process the input information corresponding to these attributes to distinguish the regions of interest. Attributes can correspond to the various combinations of
RGB or
YUV values (see
Figure 4,
Figure 5 and
Figure 6) present in each pixel. In
Figure 5, the attribute representing the contours of the buildings is visible. This attribute was obtained through a genuine combination of
RGB values, wherein the edges were emphasized [
27]. Identifying the most relevant attributes in an image may require several iterations to clearly determine which features are most significant [
13,
14]. Artistic paintings can display a diverse spectrum of tones, ranging from dark areas to bright and luminous regions. Similarly, images of construction materials, such as bricks, also reveal a distinct array of visual characteristics. In the
RGB (red, green, and blue) color model, darker (“wet”) areas of a brick might be represented by lower values across each color channel, whereas brighter (“dry”) regions would be indicated by higher values. In contrast, when analyzing the same brick image within the
YUV color space, the differentiation between dry and wet areas may be attributed to the luminance (
Y) and chrominance (
U and
V) components. Here, luminance reflects the intensity of brightness, while chrominance captures subtle variations in moisture and texture. This comparison highlights how the choice of color representation can significantly influence the perception of visual characteristics, whether in artistic paintings or in construction materials. Once the key attributes are identified, the next step is to simplify data complexity through dimensionality reduction, ensuring that the essential visual characteristics are preserved for effective analysis.
(b) Dimensionality reduction (PCA): dimensionality reduction is an essential mathematical technique that simplifies multidimensional data, enabling more effective management of design projects.
Figure 7 illustrates information related to three attributes derived from the painting presented in
Figure 3. With these three attributes, the data can be visualized in three dimensions. Data can be projected onto a plane to facilitate simpler visualization. One of the most fundamental and powerful methods in this context is principal component analysis (PCA) [
13,
14]. PCA aims to transform a high-dimensional dataset into a reduced set of variables, known as principal components.
Figure 8 displays the results obtained after applying principal component analysis (PCA) to reduce the dimensionality of a problem associated with the study of attributes derived from the image of the painting shown in
Figure 3. The objective is to automatically identify and isolate the most illuminated region of the painting. As mentioned before, in
Figure 8, the dataset has been projected into a two-dimensional space, allowing for a clearer visualization of the different clusters associated with the various characteristics of the painting.
(c) Clustering: in the expansive realm of machine learning, clustering emerges as a powerful and versatile technique within the realm of unsupervised learning. Unsupervised learning is distinguished by its ability to extract knowledge from data without the use of prior labels, with clustering serving as a fundamental pillar in this domain [
13,
14]. Clustering, or group segmentation, is a process that involves dividing a dataset into groups or clusters, where the elements within each group are more similar to each other than to those elements outside the group.
Figure 9 shows the result obtained after applying the K-means technique to detect three clusters of points.
The clustering process is crucial for the organization, understanding, and simplification of complex data. Clustering has applications across a wide range of fields, making it an essential tool in data analysis [
13,
14].
For the painting previously described, the data clusters may be associated with combinations of various attributes derived from the RGB or YUV values. The number of attributes corresponds to the number of dimensions in the dataset.
The K-means algorithm is used to identify and group similar data points into clusters. K-means groups the data points into clusters by repeatedly assigning them to the nearest centroid and updating the centroids until they stabilize.
The key advantage of the K-means algorithm is its simplicity and efficiency, making it fast and scalable for large datasets. It is easy to implement and understand, providing clear and well-defined clusters.
As mentioned before,
Figure 9 illustrates the results obtained after applying the K-means technique to identify three clusters of points with similar characteristics.
The algorithm differentiates these clusters using distinct colors.
Figure 10,
Figure 11 and
Figure 12 present the various characteristics of the painting associated with the three groups identified through the application of PCA and the K-means algorithm.
Figure 12 shows a group of pixels corresponding to the most illuminated area of the painting, which was automatically identified by PCA and the K-means algorithm.
When applying principal component analysis (PCA) to paintings in RGB format, we analyze how the primary colors—red, green, and blue—combine to form the image. PCA identifies the color combinations that exhibit the greatest variability within the painting.
For instance, the analysis may reveal distinct combinations of blue and yellow in the depiction of a sky with clouds, while darker shades of blue and brown might be associated with areas representing buildings. In contrast, when PCA is applied to the YUV format, the analysis focuses on separating luminance (Y) from the chrominance (U and V) information.
Luminance corresponds to the brightness of the image, while chrominance conveys color and saturation details. PCA, when applied to the YUV format, may demonstrate that luminance is more critical for representing detail and intensity, whereas chrominance emphasizes color nuances and subtle variations. Similarly, when applying the K-means clustering to paintings in RGB format, we classify pixels based on their red, green, and blue values.
This method enables the identification of those regions within the painting that share similar colors. For example, the K-means algorithm might group the yellow pixels of the sky into one cluster and the blue pixels of the clouds into another. In the
YUV format, the K-means algorithm would cluster pixels based on luminance and chrominance values, facilitating the segmentation of the image into regions with similar brightness levels and color variations. In
Figure 13, three groups are identified, which may correspond to the areas with buildings and the illuminated zone presented in
Figure 3.
PCA and K-means methods have their disadvantages. The primary limitations of PCA include its assumption of linear relationships and its extreme sensitivity to the scaling of attributes. Conversely, K-means clustering depends on the initial placement of centroids, is sensitive to outliers, and does not guarantee convergence [
13,
14]. PCA enables the visualization of data along the direction of maximum variance.
For instance, when taking a photograph of a group of people, the goal is to position them in such a way that everyone appears in the photo. If the people are arranged in a line, the direction of maximum variance aligns with the direction of the line [
28].
Therefore, the camera should be positioned perpendicular to the line of people to capture everyone in the frame. PCA identifies new dimensions, known as principal components, which summarize the essential information of the dataset [
13,
14,
28].
(d) Image segmentation: the illuminated region in
Figure 12 was delineated through the application of K-means and PCA techniques. In this particular example, the clusters identified by the K-means algorithm exhibit some dispersion (see
Figure 9).
This dispersion can be mitigated by combining and considering additional attributes.
Figure 13 presents the clusters shown in
Figure 7 in light of the modification of one of the attributes. Attributes are instrumental in data representation and in enhancing the algorithm’s ability to uncover patterns and hidden structures. Certain attributes may be more informative for a specific problem. Informative attributes significantly influence clustering and dimensionality reduction as they contain critical information about the underlying data structure.
Some unsupervised learning algorithms are capable of capturing nonlinear relationships or interactions between attributes, while others may be less sensitive to these factors. As described above, in
Figure 13, three distinct groups are observed, which may correspond to those areas with buildings and the illuminated zone of the painting (
Figure 3).
It is essential to emphasize that PCA identifies the directions of maximum variance in the data, often revealing underlying trends and relationships between the variables. This helps to reduce data complexity while preserving essential information.
In contrast, the K-means algorithm clusters data based on similarities, facilitating the identification of natural groupings within the data. By combining PCA and K-means methods, it is possible to detect complex patterns that might not be immediately apparent, aiding in informed decision-making and the extraction of valuable insights from complex datasets.
Figure 14 shows the result of applying PCA to the data presented in
Figure 13.
In contrast,
Figure 15 presents the outcome of applying K-means clustering to the data shown in
Figure 14. In PCA, appropriate attribute selection enhances the capture of principal variations, while irrelevant attributes will negatively impact simplification.
In K-means analysis, the choice of attributes affects the quality of the clusters, potentially leading to erroneous groupings [
13,
14].
Figure 16 and
Figure 17 present the images associated with those regions that correspond to the sky and buildings of the painting shown in
Figure 3. Similar to its application in painting restoration, PCA could be employed to highlight the most relevant features that influence the estimation of moisture levels in bricks.
Applying PCA to artworks, such as paintings, helps identify significant details like colors or patterns; its application to brick images can reveal textural patterns, color variations, and visual features related to moisture.
6. Methodology
Images of the four types of bricks showing varying moisture levels were obtained. Images corresponding to the fired red bricks, categorized as first-class, second-class, apparent, and spongy, were obtained. These bricks are predominantly used in residential construction in the state of Oaxaca. For all images, the smartphone was positioned at the same distance from the brick under consistent illumination conditions. One face of the brick, associated with its largest dimension, was in contact with the free water surface to ensure the capillary rise of the water. First-class bricks are characterized by their red color, which is derived from the clay used and the high temperatures applied during the firing process. Their rough texture and rustic appearance also contribute to their aesthetic appeal. In construction, first-class fired red bricks are highly regarded, not only for their traditional look but also for their structural load-bearing capacity, making them a versatile and reliable material.
The second-class fired red brick, depicted in
Figure 18a, differs from the first-class brick in that it often exhibits imperfections or aesthetic defects, such as color variations, deformations, or irregular dimensions. These characteristics make it less suitable for applications that require a uniform and attractive appearance. However, the second-class brick is a more economical alternative to the first-class brick, making it appropriate for projects where aesthetics are not the primary concern and budget constraints are significant. It is essential to ensure that this brick meets the standards set by relevant building codes, particularly in regions like Oaxaca, which is located in a highly active seismic zone.
The apparent fired red brick is a prominent construction material renowned for its traditional aesthetics and durability. Characterized by its red hue, which is derived from the clay and high-temperature firing process, this brick features a rough, textured surface that adds rustic charm. The surface of the apparent brick is rich in minerals, including quartz. Due to its versatility, the apparent fired red brick is employed in various applications, including exterior cladding, walls, and fireplaces, offering both aesthetic appeal and functional benefits in architectural projects.
Figure 18b shows the presence of variable moisture due to capillary water rising in the fired red brick type known as spongy. The permeability of this brick can vary in different areas due to reasons related to its manufacturing and composition, which are described below.
Variability in firing: the temperature and firing time may not be uniform. This can result in certain areas of the brick being more fully fired. Extremely well-fired areas may become less permeable.
Variations in composition: the exact composition of the clay or the material used to make bricks can vary in different parts of the raw material.
Density and compaction: during the manufacturing of bricks, the material is compacted into molds before firing. The way in which the material is compacted can vary, affecting the density and porosity of the brick in different areas. Less well-compacted areas may be more permeable than more well-compacted areas.
Table 1 presents the moisture percentage values for the different types of bricks.
Figure 19 and
Figure 20 present images of the spongy, apparent, first-class, and second-class bricks using different color formats such as
RGB,
YUV, and
HSV.
The images, in RGB, YUV, and HSV formats, obtained from fired red bricks can provide indirect information regarding moisture, as follows:
RGB (red, green, and blue). Changes in color intensity, especially in darker tones, can indicate areas of the brick surface affected by moisture. Wet areas tend to show darker colors or color variations, which may be an indication of moisture problems.
YUV. The luminance (Y) in the YUV color space can be useful for detecting differences in surface reflectance. Wet areas tend to reflect less light, which could manifest as lower luminance in the image.
HSV (hue, saturation, and value). Saturation and value in the HSV color space can help identify areas with different water contents. Wet areas may show different saturation levels and values compared to dry areas.
This is important when building inspection and quality control applications to detect moisture problems that can affect the structural integrity and energy efficiency of a building [
6]. In-depth moisture analysis typically requires specific sensors and measurement techniques. However, images in the aforementioned formats can provide an initial visual indication of moisture problems.
Analyzing images in various formats enables the assessment of texture and coloration differences in bricks, which may correlate with their permeability and overall quality. This approach can assist in material inspection and construction quality control. Additionally, image analysis facilitates the inference of mineral presence and distribution within fired bricks, contributing to their mineralogical characterization. However, precise mineral identification often requires advanced techniques such as microscopy and X-ray diffraction. While color images provide an initial overview of mineral composition, they cannot replace these detailed analytical methods. However, the surface texture characterization of bricks can be enhanced through image analysis. The
HSI (hue, saturation, and intensity) format, employed in video technology and adapted by previous researchers to study fluid content [
33], is illustrated in
Figure 21, demonstrating its application.
Attributes, derived from photographs, encompass specific measures such as
RGB or
YUV amplitudes. Analogous to the
RGB color model in image representation, which decomposes an image into three color components, seismic attributes in geophysics disaggregate the seismic data into features like amplitude, frequency, and wave velocity. This process provides a detailed view of subsurface conditions, similar to the way in which the
RGB model enables a broad range of color representation in images. Seismic attributes thus facilitate a comprehensive characterization of geological and structural properties, enhancing geophysical exploration and assessment [
18].
Digital image processing, augmented by artificial intelligence, enables the analysis of fired red brick images to estimate moisture content effectively. Through unsupervised learning, AI can detect key characteristics related to moisture—such as texture, color, and the distribution of moisture spots—directly from photographs. This advanced methodology streamlines the evaluation process and improves accuracy in moisture percentage estimation, offering significant benefits for research and practical applications in the construction industry and building conservation.
Figure 22 illustrates the application of principal component analysis (PCA) to specific attribute combinations, as shown in
Figure 20, for the second-class brick.
With color intensity variations providing initial moisture indicators, further insights are obtained through clustering techniques that categorize the image data into distinct moisture-related patterns. As mentioned before, the K-means algorithm is a robust clustering technique that is widely used in data mining and machine learning. It partitions a dataset into clusters in which the points within each cluster exhibit high similarity. The algorithm iteratively assigns data points to these clusters and updates the cluster centroids. Its simplicity and efficiency are valuable for pattern recognition in unlabeled data, though its performance can be influenced by the initial centroid selection and the number of clusters. K-means clustering identifies the moisture levels in images, distinguishing between the dry and wet areas of a brick wall. Analyzing these clusters reveals the moisture distribution patterns, offering insights into how moisture varies and its correlation with material characteristics. Comparison of segmented images (
Figure 22a,b) with the reference photograph (
Figure 18a) indicates that the unsupervised learning approach used in digital image processing is robust and reliable. These clusters not only reveal moisture distribution but also set the stage for estimating moisture levels by calculating relative amplitudes from the segmented images. For more detailed moisture analysis, additional clusters are recommended.
6.1. Estimation of Moisture Percentage and Hydraulic Diffusivity
First, the volume of water added to the brick via capillarity is calculated using the following formula:
considering the different heights (3, 4, 5, 6, 7, 8, 9, and 10 cm) of the invasion front in the brick.
corresponds to the weight of the wet brick (considering that the height of the invasion front is
) and
corresponds to the weight of the dry brick. For each value of
, a corresponding table is generated, where multiple specimens are analyzed. Subsequently, the light intensities for both the wet and dry regions, denoted as
and
respectively, are calculated for each height.
The light intensity is calculated as
, where
,
, and
correspond to the values of the red, green, and blue channels of the
format.
Figure 23 shows a typical image of the
G-channel and its respective amplitudes, which correspond to the second-class brick. To achieve more accurate estimates of light intensities and reduce errors, the average
values were obtained from the central areas of both the dry and wet regions (see
Figure 24). Using the values
and
for each height, the luminosity percentages were calculated using the following expression:
Using this approach, luminosity percentages were calculated for varying heights of the invasion front. The moisture percentage in a brick sample can then be correlated with the relative difference between the average light intensity values in the dry and wet regions of the image, as follows:
where
is an expression that correlates the moisture percentage with the luminosity percentage, as defined by Equations (1) and (2). Moisture percentages in the brick sample and luminosity values in the image were estimated to subsequently adjust the coefficients in Equation (3). The selection of these coefficients is contingent upon the specific experimental conditions and on the relationship between luminosity percentage and water content in the samples. The relative difference in luminosity values, which represent the average of the color layer values between the dry and wet areas in an image, can mitigate the influence of lighting variations. This relative difference serves as a form of internal normalization, accounting for lighting variations that affect both areas equally. However, several additional considerations must be addressed:
Uniformity of lighting: significant lighting disparities within the image may limit the effectiveness of this procedure.
Additional corrections: in cases where lighting is a critical factor, additional corrections to the images may be necessary to ensure reliable estimates.
It is worth emphasizing that using the relative difference in luminosity between dry and wet areas can be an effective strategy to mitigate the impact of lighting on measurements. However, the effectiveness of this technique is contingent upon the uniformity and variability of lighting conditions. Therefore, careful analysis and additional corrections are always advisable. The relationship between moisture content and the relative difference in average luminosity values can provide significant insights and facilitate the detection of water content in porous materials. Potential interpretations of this relationship include:
Water content indicator: the relative difference in luminosity values between dry and wet areas may serve as an indicator of the presence of water in the brick sample.
Sensitivity to capillarity: this analysis technique may be sensitive to capillarity effects, as changes in water content can impact luminosity values.
Non-destructive monitoring: this relationship can be useful for the non-destructive monitoring of water content in bricks or similar materials.
Process control: in industrial applications, this relationship could be used as a process control tool to monitor and ensure appropriate moisture levels during brick production or other porous material manufacturing.
The construction of the expression that relates moisture and luminosity percentages is described below. Figures illustrating this information display the results from various examples. As previously mentioned,
Figure 24 shows the areas used to estimate luminosity intensities in the dry and wet zones. The luminosity intensities represent the averages of the
R,
G, and
B values in each of the studied regions, which are then used to calculate luminosity (as shown in Equation (2)).
The luminosity percentage, as defined by Equation (2), was estimated for various invasion front heights. It is important to note that variations in pixel size can influence these percentages due to the fractal nature of the experiment, as observed in previous studies on rock porosity [
34]. Fractals, characterized by repeating patterns at different scales, have a mathematical connection to nature [
35].
Figure 25 and
Figure 26 illustrate the variations in the moisture percentage of the bricks, relative to the square root of the invasion time, and the height of the invasion front (
), respectively.
Figure 27 displays a graph of the luminosity and moisture percentages for different bricks, with a consistent pixel size being used in all cases.
Figure 28 shows the hue and moisture percentages for different bricks, with a consistent pixel size being used in all cases.
The
HSI format is used to define the color vector with set components: hue, saturation, and intensity. It has a certain relationship to the Munsell color system, which is used for soil classification and allows a precise and standardized description of the colors present in the terrain. Developed by Albert H. Munsell [
36] in the early 20th century, this scale provides a numerical and alphabetical notation combining hue, value, and chroma to uniquely define each color. In geology, color formats are used to characterize materials, identify horizons, and evaluate soil quality [
37,
38,
39]. The scale’s internationally recognized character ensures consistent and comprehensible communication, making it a fundamental pillar in soil study research. Hue refers to the attribute that characterizes pure color. Saturation relates to the mixture of color with white. Intensity corresponds to the level of gray in a black-and-white image. The advantage of using the
HSI format lies in its approximation to human color perception and interpretation. Since the eye detects some color differences based on varying levels of water content, it is expected that the water content in a brick sample is more closely related to hue than to intensity, saturation, or other attributes of the different color formats [
33].
Figure 28 illustrates how the moisture percentage varies with respect to hue in the
HSI format, considering different types of bricks. As with
Figure 27, the same size of pixel was used in all the cases studied, and the experimental setup remained consistent.
Regarding the estimation of hydraulic diffusivity, this can be determined using the following equation [
40,
41,
42]:
where
,
,
, and
represent the water saturation, the height of the invasion front (in the examples presented here, the rise of the invasion front is nearly uniform, except in the case of the so-called spongy brick), hydraulic diffusivity, and time, respectively. It should be noted that Equation (4) represents an approximation, which may be insufficient in certain cases [
43], in particular, in the presence of coupled processes [
43]. The influence of gravity is not accounted for in the derivation of Equation (4). The function
corresponds to the complementary error function, which is commonly used in the fields of probability and statistics. Hydraulic diffusivity (
), sometimes also referred to as the coefficient of hydraulic diffusion, is a parameter that describes the rate at which water moves through a porous medium. It is a fundamental property in hydrogeology and geotechnics, as it influences the soil’s ability to transport and retain water, as well as the recharge and discharge of aquifers. Hydraulic diffusivity is expressed in units of area per time (typically recorded in square meters per second,
), and its value depends on the porosity, permeability, and tortuosity of the medium. Water saturation (
) in bricks refers to the amount of water that a brick can absorb or retain in its structure.
Assuming
(the percentage of the brick’s volume occupied by water), moisture can be related to
using the following equation [
34]:
where
is the porosity of the sample. To illustrate the procedure used to obtain hydraulic diffusivity, consider the case of the second-class brick, where the height of the invasion front is
cm and
. In ceramic bricks, the porosity (
) ranges from 10% to 50% [
7]. The time that elapsed from the start of the experiment until the invasion front reached a height of 6 cm was 20 min.
Assuming a porosity of 15% for the brick, and using the previously mentioned parameters, the water saturation is determined from Equation (5) as . From tables corresponding to the , where , it follows that . Consequently, it can be deduced that . Solving for hydraulic diffusivity, . Thus, the hydraulic diffusivity obtained from Equation (4) is .
Hydraulic diffusivity can vary within the same sample, especially if the brick has structural heterogeneities or variations in porosity. The effective hydraulic diffusivity values for first-class, second-class, apparent, and spongy bricks, assuming and cm, are the following: , , , and .
For the estimation of hydraulic diffusivity in the spongy brick type, those bricks with the most uniform invasion fronts were selected.
Different digital photography formats, such as
HSV, can provide indirect information about the type of fluid invading a particular brick. The distinction between the
HSV values of images obtained using UV light, showing a brick containing chlorides and one that does not, will be noticeable in a visual representation (
Figure 29 and
Figure 30).
The color range exhibited by a brick with chlorides differs from one without this substance, due to the interaction of chlorides with light, leading to reflection and absorption effects that alter the material’s appearance. This discrepancy in
HSV values can be useful for visually detecting areas that are potentially influenced by chlorides. The tracking of chloride ions in a brick can be indirectly visualized through a simple experiment that involves inducing the capillary rise of water combined with aniline (
) and sodium chloride in the brick (
Figure 31). This results in the appearance of layers marked by different colors—a type of chromatography that is associated with ion movement, wherein lighter ions advance further distances [
44].
Figure 31 illustrates three distinct stages of efflorescence evolution: (a) early stage, (b) intermediate stage, and (c) advanced stage. In the early stage, the invasion front is clearly visible, along with the stratification of ions indicated by the different colors.
Figure 31 also demonstrates that ions travel faster in some regions of the brick.
6.2. Specific Surface and Porosity
In well-sorted granular systems, the specific surface area decreases with increasing porosity, as demonstrated by both digital experiments and theoretical models [
45]. However, this relationship can be reversed in systems with binary or more complex grain size distributions [
45]. In sandstone and carbonate samples with low to medium porosity, the specific surface increases as the porosity rises. In contrast, granular samples exhibit the opposite behavior [
45]. This behavior can be modeled using hollow ellipsoids immersed within the mineral matrix. The grains can also be modeled as solid ellipsoids situated in the otherwise vacant pore space. Considering that a particular material is composed of identical grains denoted by ellipsoids, the specific surface area (
), which is defined as the ratio of the surface area of all grains to the volume of the pack, can be expressed as follows [
45]:
where
,
, and
correspond to the semi-axes of the ellipsoid that defines each grain. If these semi-axes are equal, the expression defined above is simplified to:
Figure 32 presents a plot with the vertical axis representing the specific surface area and the horizontal axis representing porosity. In this figure, two scenarios are presented that correspond to: (a) a material containing spherical grains with the radius
, and (b) a material that contains grains with an ellipsoidal form and semi-axes of
,
, and
. Scenario (a) could represent the first- and second-class bricks, while scenario (b) may correspond to the apparent and spongy bricks, respectively. These scenarios are shown in the colors blue and black, respectively. When small particles fill the pores within a large-particle framework, the specific surface area (
S) increases as the porosity (
φ) decreases. Conversely, when large particles are dispersed within a continuum of smaller particles, fewer large particles result in higher porosity (
φ) and a greater specific surface (
S). As previously mentioned, in uniform particle packs,
S decreases with increasing
φ [
45].
6.3. Microscopic Images
The following equipment was used to study the samples: (a) a binocular stereoscopic microscope with a focal objective ranging from 0.7 to 11.5×; (b) a scanning electron microscope (SEM) with an energy-dispersive spectroscopy (EDS) detector; and (c) a reflected-light petrographic microscope. The microscope images are shown in
Figure 33,
Figure 34 and
Figure 35.
7. Discussions
The variability in the permeability of masonry units, as discussed above, is a critical issue in the construction industry that warrants significant attention and may lead to substantial debate [
7]. Permeability can vary across the different areas of a masonry unit due to several factors, including firing variability, material composition, compaction, and manufacturing defects. Firing variability can cause the inconsistent curing of bricks, resulting in differential porosity and permeability [
7]. The material composition, particularly the type and proportion of clay, additives, and other raw materials, is fundamental in determining the permeability characteristics of the units [
7]. Compaction during the manufacturing process also affects the density and uniformity of bricks; inadequate compaction can lead to higher permeability [
7]. Additionally, manufacturing defects, such as cracks or incomplete formations, can exacerbate these issues. Variations in these factors can significantly impact the quality standards of masonry units. Highly permeable units can allow moisture ingress, leading to a cascade of problems including structural deterioration, efflorescence, and mold growth [
6]. These issues not only compromise structural integrity but also affect the aesthetic and functional aspects of buildings. Furthermore, the presence of mold in buildings poses serious health risks, contributing to respiratory problems and other health issues for the occupants [
6]. These concerns underscore the importance of adopting best construction practices and striving to create healthy and comfortable indoor environments [
6]. They also highlight the need for stringent regulations and standards governing the manufacture of masonry units to ensure consistency and quality [
6]. Effective quality control measures, such as regular permeability testing and adherence to standardized manufacturing processes, are essential for mitigating these issues [
6].
Table 2 presents the total water absorption values for various masonry units. These values demonstrate that the units comply with the NMX-C-404-ONNCCE-2012 standard [
32], which sets a maximum allowable water absorption criterion of 23%. This compliance indicates that the masonry units meet the necessary quality standards for water absorption, ensuring their suitability for construction purposes. Irregular water saturation typically refers to conditions in which the water content within a specific medium, such as a masonry unit or a porous rock, is not uniformly distributed. Instead, the water is concentrated in localized or discontinuous regions within the material. This phenomenon can arise due to several factors, including inconsistencies in material composition, varying degrees of porosity, and differences in compaction during manufacturing. Irregular water saturation can significantly impact the performance and durability of masonry units, leading to potential issues such as uneven structural stress, localized deterioration, and the compromised integrity of the construction [
7]. Understanding the patterns and causes of irregular water saturation is crucial for improving the manufacturing processes and quality control measures of masonry units. By addressing these factors, manufacturers can enhance the uniformity and overall performance of the units, thereby contributing to the longevity and stability of masonry structures [
7]. Moreover, further research and advanced testing methods are essential to accurately assess and mitigate the effects of irregular water saturation in masonry materials.
Changes in color intensity in the image formats can serve as indicators of moisture-affected areas in the masonry units. This visual information is highly relevant for building inspection and quality control applications, aiding in the detection and assessment of moisture problems. In RGB images, color variations may be associated with differences in surface texture and composition, which can influence the permeability of the material. These variations can provide preliminary insights into potential areas of concern.
Furthermore, utilizing alternative color spaces such as YUV, HSV, and HSI can enhance the analysis. These color spaces offer distinct advantages by providing information on luminance, hue, saturation, and value, which data can be instrumental in identifying permeable areas within the masonry units. For instance, the YUV color space separates luminance (brightness) from chrominance (color information), making it easier to detect subtle changes in moisture levels. Similarly, the HSV and HSI color spaces, which emphasize hue, saturation, and intensity, can help in distinguishing between moist and dry regions more effectively. However, it is crucial to validate the moisture percentage estimates derived from photographic analysis with measurements obtained using other established techniques, namely, electrical resistance and neutron scattering. Cross-validation with these methods ensures the accuracy and reliability of the moisture detection process, thereby enhancing the credibility of the visual inspection results.
The use of digital image processing driven by artificial intelligence presents a promising approach for estimating moisture percentages in fired red bricks, thereby aiding in moisture management and quality control.
The methodology described in this study is intended to complement, rather than replace, traditional moisture measurement techniques. By leveraging AI algorithms, this image processing method has demonstrated its reliability, as evidenced by the close agreement between the segmented images and reference photographs. A key aspect of this methodology is the identification of moisture clusters through the combined application of principal component analysis (PCA) and K-means clustering. PCA helps in reducing the dimensionality of the image data, highlighting the most significant features, while K-means clustering can effectively group similar data points, thereby identifying those regions with varying moisture content.
The results of this study indicate that this AI-driven image processing technique can significantly impact the evaluation of moisture in structures. The ability to accurately and efficiently detect moisture clusters can lead to better-informed decisions in the construction and maintenance of buildings.
Using relative brightness differences as a form of “internal normalization” is important for minimizing the effects of lighting variations across an image. This technique relies on the assumption that changes in lighting impact all areas of the image uniformly.
By focusing on relative brightness differences rather than absolute values, the influence of variable lighting conditions can be mitigated. In the context of images with different pixel sizes, brightness percentages can vary, due to the inherently fractal nature of image processing using different pixel sizes.
Fractals are characterized by self-similarity across different scales, meaning that an object displaying fractal properties will exhibit similar patterns at various levels of magnification. This self-similarity is relevant when analyzing digital images, especially when pixel sizes and image resolutions are adjusted.
For instance, natural elements such as coastlines demonstrate fractal characteristics, showing complex, irregular shapes that persist at multiple scales. When measuring geometric properties like the length or area of such fractal objects, the results can differ based on the scale at which measurements are taken.
This scale-dependent variation is a consequence of the fractal dimension, which quantifies the complexity of an object [
34]. The choice of pixel size and image resolution plays a significant role in how these physical properties are represented and measured. Internal normalization through relative brightness differences helps account for variations in lighting, which could facilitate a more consistent analysis of fractal-like structures in digital images.
In the realm of construction material evaluation and architectural heritage preservation, accurately identifying the substances within masonry units is paramount. The presence of chlorides, for instance, can greatly influence the integrity and longevity of these structures [
6]. Traditional methods of detection often grapple with uncertainties that can compromise the accuracy of the results.
Advancements in digital photography and image processing offer promising solutions. Digital photography formats such as RGB (red, green, and blue), HSV (hue, saturation, and value), and HSI (hue, saturation, and intensity) can help to reduce any uncertainties in the identification of moisture percentages within masonry units. Each of these formats offers unique advantages in capturing and analyzing the interactions between light and materials.
The RGB color model is fundamental in digital imaging, representing images in terms of the primary colors of light. By analyzing the intensity of red, green, and blue components, we can infer the presence of chlorides, which typically alter the color balance of the material.
The HSV color model separates the chromatic content (hue) from the intensity and purity (saturation and value). This separation allows for a more intuitive identification of color changes caused by chlorides. Similar to HSV, the HSI color model provides a representation that aligns closely with human perceptions of colors. By focusing on hue, saturation, and intensity, this model facilitates the detection of subtle changes in appearance due to chlorides.
Similar to HSV, the HSI color model provides a representation that aligns closely with human perceptions of colors. By focusing on hue, saturation, and intensity, this model facilitates the detection of subtle changes in appearance due to chlorides. Chlorides can cause noticeable changes in the appearance of masonry materials, such as discoloration or efflorescence. By utilizing different digital photography formats, these changes can be quantified and analyzed, providing a more accurate assessment of the presence of chloride. Beyond chloride detection, these digital photography formats are instrumental in estimating the moisture percentage within masonry units. Moisture can affect the material’s appearance, and by leveraging RGB, HSV, and HSI values, we can derive the correlations between visual changes and moisture levels. This capability is essential for evaluating the condition of construction materials and preserving architectural heritage.
Beyond their theoretical implications, these findings have practical value, particularly for quality control in traditional and eco-friendly brick construction. The percentage of luminosity was observed to be highly sensitive to slight inclinations in first-grade bricks. In contrast, hue values demonstrated a better fit to a single regression line and were less affected by environmental variations, with the exception of some strong outliers. In experiments considering soil-oil-water systems, the hue (
HSI system) of the transmitted light has been found to correlate directly with the water content in porous media [
33]. This parameter offers a high-resolution measurement of both the water and oil contents in transient flow fields [
33]. The
HSI format is similar to the Munsell color chart used for soil classification. As mentioned before, this specifies a color using hue, saturation, and intensity [
33]. Hue describes the pure color, saturation indicates the degree of dilution with white, and intensity corresponds to the gray level [
33]. The
HSI format aligns with human color perception, making it useful for interpreting color differences. Since these differences are noticeable to the human eye in varying water and oil contents, water content is expected to correlate more directly with hue than with other color formats [
33]. However, certain strong outliers were noted, likely associated with drastic light absorption and fluorescence. These hue anomalies could be attributed to several factors, including: (a) the presence of heterogeneities like rock fragments that can contain grains of quartz; and (b) the presence of genuine clays that, in combination with water, could be capable of absorbing light. Chemical reactions may occur during the capillary rise of water in the brick. The clays in question could exhibit honeycomb-like molecular structures, further influencing their absorption characteristics.
Materials and minerals interact with electromagnetic radiation by reflecting and absorbing it in a manner that varies with the radiation’s wavelength. These interactions are depicted in the reflectance spectra, which highlight the differences in reflection and absorption across various wavelengths [
46]. The mechanisms responsible for the absorption of electromagnetic radiation operate at the molecular and atomic levels and can be categorized into two primary types: electronic and vibrational processes [
46]. Electronic processes involve the absorption of photons by individual atoms or ions within minerals at specific wavelengths, leading to distinctive absorption features in the reflectance spectra [
46]. For example, the absorption of certain wavelengths by iron atoms in oxides and hydroxides results in these minerals exhibiting a red color [
46]. Vibrational processes, on the other hand, involve the absorption of photons by molecular bonds, which induces vibrations within the molecules. This type of absorption is characteristic of the bonds in materials such as clay minerals, where the molecular structure absorbs specific wavelengths, contributing to the material’s overall spectral properties [
46]. Both electronic and vibrational processes are critical for understanding the optical behavior and colors of minerals and materials (including gas and liquids, which could be situated around the grains of the materials).
Efflorescence, a common issue in masonry units, results from the deposition of soluble salts on the surface of bricks [
6]. Detecting and analyzing efflorescence is crucial for maintaining the structural integrity and aesthetic value of masonry constructions [
6]. This study presents a methodology leveraging UV light, digital imaging, and AI to address the identification of areas affected by efflorescence. Efflorescence can be efficiently detected in fired red bricks through the application of UV light, capitalizing on the fluorescence properties of many soluble salts. According to Pirson [
47], salts such as calcium carbonate and sodium chloride exhibit fluorescence under UV light, emitting a visible light that facilitates their detection.
The proposed process comprises the following steps: (a) a UV light source is employed to illuminate the surface of the masonry unit. UV light’s ability to excite the soluble salts present in the material’s pores makes it an effective tool for highlighting efflorescence. Ensuring an optimal environment with minimal ambient light enhances the visibility of the fluorescence. (b) Under UV illumination, incipient efflorescence becomes visible, due to the fluorescence of the soluble salts. This fluorescence aids in the early detection of efflorescence, which might not be easily discernible under normal lighting conditions. (c) Photographic documentation of the illuminated surface is crucial for detailed analysis. High-resolution images captured under UV light can be digitally processed to enhance the visibility and contrast of the efflorescence. (d) Once photographic images of efflorescence are obtained, unsupervised learning can be applied to analyze the data. AI algorithms can identify the presence, size, and distribution of efflorescence within the masonry unit. This automated analysis provides a comprehensive understanding of the extent and severity of the efflorescence, enabling more informed decisions for remediation and preservation. The integration of UV light detection, digital photography, and AI analysis can represent a significant advancement in the study of efflorescence in fired red bricks. This methodology enhances the accuracy of the analysis, which is critical for effective maintenance and preservation strategies. Future research should focus on refining the AI algorithms employed and exploring the fluorescence properties of different salts to broaden the applicability of this technique.
Ion stratification within masonry units results from the differential movement of ions as water ascends through the material, carrying dissolved substances with it. This process bears a resemblance to chromatography, where substances are separated based on their movement through a medium. Understanding ion stratification is crucial for comprehending the diffusion processes and material behavior in masonry. Kovats [
44] draws a parallel between ion stratification in sand saturated with brine and chromatographic separation. In chromatography, substances are separated based on their interaction with a stationary phase and their relative mobility. Similarly, in masonry units, ions stratify according to their size and charge, with the lighter ions traveling further and faster than heavier ones.
This analogy provides a framework for analyzing ion movement and diffusion within the material. The experimental setup, depicted in
Figure 31, involved the use of a 15%
solution to study ion stratification. The steps followed in this experiment are as follows: (a) a masonry unit was saturated with a 15%
solution, mixed with aniline, to indirectly observe the movement of ions; (b) the solution was allowed to ascend through the masonry unit, simulating natural water movement and ion transport; (c) as the solution ascended, the stratification of ions occurred, with lighter ions traveling longer distances than heavier ones. This stratification was visualized using aniline, which highlighted the different layers formed due to varying ion migration rates. (d) The resulting stratified layers were analyzed using AI and image processing. This experiment demonstrated how ion stratification can reveal insights into the diffusion processes and the behavior of ions within the masonry unit. The experiment illustrated that the lighter ions in the 15%
solution traveled longer distances within the masonry unit compared to heavier ions. This stratification mirrors chromatographic separation, confirming the analogy and providing a valuable tool for studying diffusion processes in masonry [
44].
The observed layers offer insights into how ions interact with the masonry material, and how they influence the overall diffusion behavior and the adsorption process. Adsorption is the process by which ions, atoms, or molecules adhere to the surface of a solid. In the case of clay, chloride ion adsorption can occur due to the specific surface properties of the clay [
47]. Chloride ions, which are negatively charged anions, can be attracted to positively charged sites on the clay surface due to electrostatic interaction.
This adsorption process is significant in the chemistry of material that contains clays [
47]. The ions that adsorb onto the clay surface can be important in ion exchange processes [
47]. The negatively charged ions, corresponding to chlorine, adhere to the surface of the clay [
47], grouping together and forming specific structures [
47]. These structures can capture atomic particles and lead to chemical reactions, which, in turn, can induce crystallization [
47].
The adsorption of chloride ions on clay surfaces is somehow linked to the concept of the exclusion zone (EZ) layer [
48], a key phenomenon in water science. The EZ layer refers to a structured, quasi-crystalline phase of water that forms near hydrophilic surfaces, distinct from bulk water, and excludes particles and solutes. This process underscores the critical role of surface chemistry in governing the behavior of water and ions at material interfaces, such as those found in clay. The interplay between a specific surface, porosity, permeability, the EZ layer, ion adsorption, and light absorption reveals a complex interaction between material properties and water behavior near surfaces. The specific surface (
) is pivotal in EZ layer formation, as a larger specific surface facilitates greater interaction with water molecules, leading to a more extensive EZ layer. This is particularly relevant with porous materials, where the specific surface significantly contributes to EZ development.
Porosity and permeability further modulate this relationship: higher porosity allows more water to occupy the material, while permeability influences the water movement within it. The EZ layer can, in turn, alter both porosity and permeability by restructuring water near the surfaces, potentially reducing flow in highly permeable materials. UV light absorption plays a crucial role in enhancing EZ layer formation by providing the energy needed for structuring water molecules [
48]. Consequently, materials with a high specific surface and optimized porosity and permeability can exhibit significant changes in their interaction with water and light, with the EZ layer serving as a mediator influencing these properties.
It should be mentioned that the color of a red brick has a notable impact on the absorption of visible light by those pores saturated with water. Red bricks typically contain pigments or iron oxides that reflect red wavelengths while absorbing other colors within the visible spectrum, such as blue and green. When the brick’s pores are saturated with water, the interaction between light and the brick’s color becomes more complex. Water absorbs light across the visible spectrum, with a higher absorption in the blue region due to its intrinsic properties. The red coloration of the brick, however, affects the light penetrating into these pores by reflecting the blue and green wavelengths away. As a result, the overall light absorption characteristics of the water in the pores are influenced by both the water’s absorption properties and the brick’s color (which depends on the ingredients), thereby altering the light spectrum. Percentages derived from images of bricks containing water are presented in
Figure 36. In this figure, the subscripts 1, 2, P, and A denote the following: first brick, apparent brick, hue (
HSI format) of the first brick, and hue (
HSI format) of the apparent brick, respectively.
During the capillary rise of water in a red brick, chemical reactions between the water and the brick can generate various gases. Key gases that may be produced include carbon dioxide from carbonate reactions and, potentially, hydrogen from redox reactions involving metal components in the brick. If the brick contains metals such as iron or aluminum, hydrogen gas could be generated through these redox reactions. Notably, hydrogen absorbs light, primarily in the ultraviolet (UV) and far-infrared (IR) regions of the spectrum, rather than in the visible light range. Conversely, chloride-containing compounds in the brick could facilitate the generation of chlorine gas, which has the ability to absorb visible light.
Salts cause damage to construction materials and can lead to efflorescence on walls and slabs. This has increased research interest in understanding chloride transfer phenomena in porous materials, such as bricks. It is worth noting that there is still a scarcity of information on this topic in the specialized literature, particularly regarding the diffusion coefficients of salts in different types of brick. The diffusivity coefficient for sodium chloride in fired red bricks can be estimated using Fick’s law through regression techniques [
49].
The diffusion equation describes how energy (in the form of heat) or mass (in the form of moisture) is transferred from regions of high concentration to regions of low concentration [
50]. The direction of transfer is driven by the temperature gradient (for heat) or the moisture concentration gradient. The diffusion coefficients (
for moisture and
for heat) are critical parameters. These determine the rate at which the studied quantity (heat or moisture) diffuses through the medium. High values of these coefficients indicate a greater rate of diffusion [
40]. For an estimation of the hydraulic diffusivities of bricks, the sharp front model concept was utilized [
7]. The capillary diffusivity of most porous materials exhibits substantial variation with liquid content, leading to very steep capillary absorption profiles. Consequently, it is often practical and beneficial to depict the wetted region as a rectangular or sharp-fronted profile, which is referred to as the sharp front approximation [
7]. Utilizing this model allows for relatively simple mathematical descriptions of the numerous wetting processes [
7]. We also assume that the water content in the bricks is proportional to the products of porosity and water saturation [
34]. The estimated effective hydraulic diffusivity values, calculated with an invasion front height of 6 cm, align with those documented in the specialized literature. The observed variability in hydraulic diffusivity can be attributed to several factors, including porosity, the presence of microfractures, material imperfections, and contaminants. These elements influence the movement and distribution of fluids within the material, thereby affecting its hydraulic properties.
Moisture is often associated with the presence of fractures, making it a critical factor in the characterization of walls and slabs that may be compromised by differential settlement. Advanced methods for inspecting these fractures, such as digital photography, have been well-documented [
51,
52,
53]; in these methods, transfer and unsupervised learning are utilized, which have demonstrated the potential of unsupervised learning for differentiating cracks from noise in images of concrete [
52]. However, the use of drone-acquired digital photographs to study moisture in slabs and walls represents a novel approach that can significantly enhance the monitoring and management of architectural challenges [
54,
55]. The methodology presented in our study can combine the multi-spectral imaging capabilities of drones with unsupervised learning. This approach can be further improved by the incorporation of InSAR (interferometric synthetic aperture radar) imaging [
46]. InSAR works by using the radar signals emitted from satellites or aircraft to capture images of the Earth’s surface. By comparing two or more radar images taken from slightly different positions or at different times, InSAR can detect small changes in the Earth’s surface, such as those caused by infrastructure deformation [
46]. InSAR imaging provides valuable data on surface deformation over time, which can reveal subtle ground movements that are indicative of deeper structural issues [
56]. Cracks observed in buildings due to subsidence may facilitate the propagation of moisture, which, in turn, could compromise the structural and bioclimatic integrity of walls and roofs. Thermal imaging is particularly useful in detecting temperature variations that correlate with moisture levels and underlying structural anomalies. UV imaging offers the ability to identify surface irregularities and microfractures that may be invisible in standard or thermal images. By combining these imaging techniques, we propose a comprehensive and detailed method for assessing structural integrity. This approach can not only improve the accuracy and reliability of moisture and fracture detection but also offer a tool for the ongoing management of architectural structures. However, the methodology’s applicability is influenced by certain limitations, particularly in environments with highly variable lighting, which can impact image-based moisture estimates.