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Catalysts
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Catalytic Carbonylation Reactions
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Catalytic Carbonylation Reactions

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalysis in Organic and Polymer Chemistry".

Deadline for manuscript submissions: closed (10 October 2021) | Viewed by 35193

Special Issue Editor

Prof. Dr. Raffaella Mancuso

E-Mail Website
Guest Editor
Laboratory of Industrial and Synthetic Organic Chemistry (LISOC), Department of Chemistry and Chemical Technologies, University of Calabria, Via Pietro Bucci 12/C, 87036 Arcavacata di Rende, CS, Italy
Interests: innovative syntheses of high-value molecules through catalytic process; new syntheses of heterocyclic compounds of pharmaceutical interest; carbonylation catalyzed chemistry; application of unconventional solvents in advanced organic synthesis; synthesis of novel materials for advanced applications
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Catalytic carbonylation reactions are the most important processes for the direct introduction of the carbonyl group into an organic substrate, and are of primary importance in both industry and academia. Thanks to the development of novel and more efficient and selective catalytic systems during the last decades, carbonylation reactions have allowed researchers to synthesize a plethora of functionalized molecules (heterocycles, in particular) under mild reaction conditions and with high chemo-, regio-, and stereoselectivity.

This Special Issue scope is devoted to the latest advancements in this exciting area of synthetic Chemistry. Both original research papers and reviews are welcomed. The scope is broad and may include the elaboration of novel and more performing catalysts, including heterogenous catalysts, as well as the development of new carbonylation processes in conventional and/or nonconventional solvents for the synthesis of products of industrial interest and of fine chemicals, including bioactive compounds.

Dr. Raffaella Mancuso
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Catalysts is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2200 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Carbonylation
  • Catalyzed Organic Synthesis
  • Heterogeneous Catalysis
  • Heterocycles
  • Homogeneous Catalysis
  • Carbonylated Compounds

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Related Special Issue

Published Papers (6 papers)

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Editorial

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2 pages, 165 KiB  
Editorial
Catalytic Carbonylation Reactions
by Raffaella Mancuso
Catalysts 2021, 11(4), 470; https://doi.org/10.3390/catal11040470 - 5 Apr 2021
Cited by 2 | Viewed by 2502
Abstract
In the last few years, the development of catalytic carbonylation reactions has increased greatly [...] Full article
(This article belongs to the Special Issue Catalytic Carbonylation Reactions)

Research

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11 pages, 1346 KiB  
Article
Asymmetric Michael Addition of Malononitrile with Chalcones via Rosin-Derived Bifunctional Squaramide
by Ning Lin, Qiu-Xiang Wei, Li-Hua Jiang, Yan-Qiu Deng, Zhen-Wei Zhang and Qing Chen
Catalysts 2020, 10(1), 14; https://doi.org/10.3390/catal10010014 - 20 Dec 2019
Cited by 8 | Viewed by 3645
Abstract
A rosin-derived bifunctional squaramide catalyzed asymmetric Michael addition of malononitrile with chalcones was discovered. This protocol provides a methodology for the facile synthesis of chiral γ-cyano carbonyl compounds in high yields and enantioselectivities (up to 99% yield and 90% ee) with a [...] Read more.
A rosin-derived bifunctional squaramide catalyzed asymmetric Michael addition of malononitrile with chalcones was discovered. This protocol provides a methodology for the facile synthesis of chiral γ-cyano carbonyl compounds in high yields and enantioselectivities (up to 99% yield and 90% ee) with a lower catalyst loading (0.3 mol%). The predominant R-configured adducts were obtained by this organocatalystic reaction, according to the experimental findings. Full article
(This article belongs to the Special Issue Catalytic Carbonylation Reactions)
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17 pages, 1972 KiB  
Article
Membrane Technology in Catalytic Carbonylation Reactions
by Francesco Galiano, Roberto Castro-Muñoz, Raffaella Mancuso, Bartolo Gabriele and Alberto Figoli
Catalysts 2019, 9(7), 614; https://doi.org/10.3390/catal9070614 - 19 Jul 2019
Cited by 14 | Viewed by 6673
Abstract
In this review, the recent achievements on the use of membrane technologies in catalytic carbonylation reactions are described. The review starts with a general introduction on the use and function of membranes in assisting catalytic chemical reactions with a particular emphasis on the [...] Read more.
In this review, the recent achievements on the use of membrane technologies in catalytic carbonylation reactions are described. The review starts with a general introduction on the use and function of membranes in assisting catalytic chemical reactions with a particular emphasis on the most widespread applications including esterification, oxidation and hydrogenation reactions. An independent paragraph will be then devoted to the state of the art of membranes in carbonylation reactions for the synthesis of dimethyl carbonate (DMC). Finally, the application of a specific membrane process, such as pervaporation, for the separation/purification of products deriving from carbonylation reactions will be presented. Full article
(This article belongs to the Special Issue Catalytic Carbonylation Reactions)
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14 pages, 5935 KiB  
Article
Alkali and Alkaline Earth Cation-Decorated TiO2 Nanotube-Supported Rh Catalysts for Vinyl Acetate Hydroformylation
by Hongyuan Chuai, Penghe Su, Hongchi Liu, Baolin Zhu, Shoumin Zhang and Weiping Huang
Catalysts 2019, 9(2), 194; https://doi.org/10.3390/catal9020194 - 20 Feb 2019
Cited by 12 | Viewed by 3876
Abstract
Alkali and alkaline earth cation-decorated TiO2 nanotube (TNT)-supported rhodium catalysts were synthesized and characterized by inductively-coupled plasma optical emission spectrometer, surface characterization analyzer, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and Fourier transforming infrared spectrum, respectively. Their catalytic performances were evaluated [...] Read more.
Alkali and alkaline earth cation-decorated TiO2 nanotube (TNT)-supported rhodium catalysts were synthesized and characterized by inductively-coupled plasma optical emission spectrometer, surface characterization analyzer, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and Fourier transforming infrared spectrum, respectively. Their catalytic performances were evaluated by the hydroformylation of vinyl acetate. Results showed that both the conversion rate of vinyl acetate and selectivity for aldehyde were improved after Rh/TNTs were modified by alkali or alkali-earth cations. Such improved selectivity for aldehyde might be attributed to the presence of alkali or alkaline earth cations which enhanced CO adsorption, while the high conversion rate of vinyl acetate was likely due to the proper interaction of Lewis acid–base between cations modified TNTs and vinyl acetate. Full article
(This article belongs to the Special Issue Catalytic Carbonylation Reactions)
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Review

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32 pages, 18256 KiB  
Review
PdI2-Based Catalysis for Carbonylation Reactions: A Personal Account
by Raffaella Mancuso, Nicola Della Ca’, Lucia Veltri, Ida Ziccarelli and Bartolo Gabriele
Catalysts 2019, 9(7), 610; https://doi.org/10.3390/catal9070610 - 18 Jul 2019
Cited by 72 | Viewed by 7447
Abstract
In this account, we review our efforts in the field of carbonylation reactions promoted by palladium iodide-based catalysts, which have proven to be particularly efficient in diverse kinds of carbonylation processes (oxidative carbonylations as well as additive and substitutive carbonylations). Particularly in the [...] Read more.
In this account, we review our efforts in the field of carbonylation reactions promoted by palladium iodide-based catalysts, which have proven to be particularly efficient in diverse kinds of carbonylation processes (oxidative carbonylations as well as additive and substitutive carbonylations). Particularly in the case of oxidative carbonylations, more emphasis has been given to the most recent results and applications. Full article
(This article belongs to the Special Issue Catalytic Carbonylation Reactions)
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59 pages, 22511 KiB  
Review
Recent Advances in the Chemical Fixation of Carbon Dioxide: A Green Route to Carbonylated Heterocycle Synthesis
by Renato Dalpozzo, Nicola Della Ca’, Bartolo Gabriele and Raffaella Mancuso
Catalysts 2019, 9(6), 511; https://doi.org/10.3390/catal9060511 - 6 Jun 2019
Cited by 60 | Viewed by 9457
Abstract
Carbon dioxide produced by human activities is one of the main contributions responsible for the greenhouse effect, which is modifying the Earth’s climate. Therefore, post-combustion CO2 capture and its conversion into high value-added chemicals are integral parts of today’s green industry. On [...] Read more.
Carbon dioxide produced by human activities is one of the main contributions responsible for the greenhouse effect, which is modifying the Earth’s climate. Therefore, post-combustion CO2 capture and its conversion into high value-added chemicals are integral parts of today’s green industry. On the other hand, carbon dioxide is a ubiquitous, cheap, abundant, non-toxic, non-flammable and renewable C1 source. Among CO2 usages, this review aims to summarize and discuss the advances in the reaction of CO2, in the synthesis of cyclic carbonates, carbamates, and ureas appeared in the literature since 2017. Full article
(This article belongs to the Special Issue Catalytic Carbonylation Reactions)
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