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Catalysts
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Palladium-Catalyzed Reactions: Chapter II
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Palladium-Catalyzed Reactions: Chapter II

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalysis in Organic and Polymer Chemistry".

Deadline for manuscript submissions: closed (10 October 2021) | Viewed by 10321

Special Issue Editor

Prof. Dr. Nicola Della Ca’

E-Mail Website
Guest Editor
Department of Chemistry, Life Sciences and Environmental Sustainability (SCVSA), Parco Area delle Scienze 17/A, University of Parma, 43124 Parma, PR, Italy
Interests: catalytic sequential reactions for the synthesis of high value-added compounds from readily available reagents; transition metal-catalyzed C-H activation methodologies; carbonylation reactions; CO2 activation chemistry
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Special Issue Information

Dear Colleagues,

Palladium is probably the most versatile and exploited transition metal in catalysis due to its capability to boost a wide variety of organic reactions (alkylation, arylation, cyclization, hydrogenation, oxidation, isomerization, cross-coupling, cascade, radical reactions, etc.) both on laboratory and industrial scales. Both homogeneous and heterogeneous palladium-catalyzed reactions continue to play an essential role in organic synthesis. Natural alkaloids, bioactive compounds, pharmaceutical agents, agrochemicals, specialty polymers, etc. can be efficiently accessed through the action of palladium catalysts. Particular attention is devoted to the use of palladium catalysts in C-H bond activation, carbonylation and asymmetric reactions often in combination with other metals. High chemo-, regio-, and diastereoselectivities as well as high levels of molecular sophistication can be achieved employing tailored palladium-based catalytic systems under mild reaction conditions.

Original research papers and topical reviews on recent advancements in the field of palladium chemistry are welcome in this Special Issue of Catalysts.

Prof. Dr. Nicola Della Ca
Guest Editor

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Catalysts is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2200 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Pd-catalyzed homogeneous and heterogeneous reactions
  • Pd-catalyzed cascade reactions
  • Pd-catalyzed cross-coupling reactions
  • Pd-catalyzed carbonylation reactions
  • Pd-catalyzed asymmetric reactions

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Related Special Issue

Published Papers (2 papers)

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Review

25 pages, 9998 KiB  
Review
Green Synthesis of Pd Nanoparticles for Sustainable and Environmentally Benign Processes
by Oriana Piermatti
Catalysts 2021, 11(11), 1258; https://doi.org/10.3390/catal11111258 - 20 Oct 2021
Cited by 25 | Viewed by 5046
Abstract
Among transition metal nanoparticles, palladium nanoparticles (PdNPs) are recognized for their high catalytic activity in a wide range of organic transformations that are of academic and industrial importance. The increased interest in environmental issues has led to the development of various green approaches [...] Read more.
Among transition metal nanoparticles, palladium nanoparticles (PdNPs) are recognized for their high catalytic activity in a wide range of organic transformations that are of academic and industrial importance. The increased interest in environmental issues has led to the development of various green approaches for the preparation of efficient, low-cost and environmentally sustainable Pd-nanocatalysts. Environmentally friendly solvents, non-toxic reducing reagents, biodegradable capping and stabilizing agents and energy-efficient synthetic methods are the main aspects that have been taken into account for the production of Pd nanoparticles in a green approach. This review provides an overview of the fundamental approaches used for the green synthesis of PdNPs and their catalytic application in sustainable processes as cross-coupling reactions and reductions with particular attention afforded to the recovery and reuse of the palladium nanocatalyst, from 2015 to the present. Full article
(This article belongs to the Special Issue Palladium-Catalyzed Reactions: Chapter II)
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35 pages, 8821 KiB  
Review
Advances in Visible-Light-Mediated Carbonylative Reactions via Carbon Monoxide (CO) Incorporation
by Vinayak Botla, Aleksandr Voronov, Elena Motti, Carla Carfagna, Raffaella Mancuso, Bartolo Gabriele and Nicola Della Ca’
Catalysts 2021, 11(8), 918; https://doi.org/10.3390/catal11080918 - 29 Jul 2021
Cited by 18 | Viewed by 4093
Abstract
The abundant and inexpensive carbon monoxide (CO) is widely exploited as a C1 source for the synthesis of both fine and bulk chemicals. In this context, photochemical carbonylation reactions have emerged as a powerful tool for the sustainable synthesis of carbonyl-containing compounds (esters, [...] Read more.
The abundant and inexpensive carbon monoxide (CO) is widely exploited as a C1 source for the synthesis of both fine and bulk chemicals. In this context, photochemical carbonylation reactions have emerged as a powerful tool for the sustainable synthesis of carbonyl-containing compounds (esters, amides, ketones, etc.). This review aims at giving a general overview on visible light-promoted carbonylation reactions in the presence of metal (Palladium, Iridium, Cobalt, Ruthenium, Copper) and organocatalysts as well, highlighting the main features of the presented protocols and providing useful insights on the reaction mechanisms. Full article
(This article belongs to the Special Issue Palladium-Catalyzed Reactions: Chapter II)
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