Surface Modification of Cathode Materials

A special issue of Coatings (ISSN 2079-6412). This special issue belongs to the section "Surface Engineering for Energy Harvesting, Conversion, and Storage".

Deadline for manuscript submissions: closed (30 April 2023) | Viewed by 2352

Special Issue Editors


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Guest Editor
National Research and Development Institute for Cryogenics and Isotopic Technologies—ICIT Rm. Vâlcea, 4th Uzinei Str., P.O. Box 7 Râureni, 240050 Vâlcea, Romania
Interests: switchable mirrors and metal hydrides; water electrolysis and fuel cells; Li-ion batteries and supercapacitors; composite electrodes and membranes; thin films, sensors and actuators; ceramic processing and sintering; sputtering and molecular beam epitaxy; X-ray diffraction and scanning electron microscopy; AFM-Raman imaging and spectroscopy; ellipsometry and impedance spectroscopy; cyclic voltammetry and amperometry

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Guest Editor
Institute of Electrochemistry and Energy Systems, Bulgarian Academy of Sciences, Acad. G. Bonchev Str., Bl.10, 1113 Sofia, Bulgaria
Interests: hydrogen technologies; metal hydride materials; electrocatalysis
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Guest Editor Assistant
National Research and Development, Institute for Cryogenic and Isotopic Technologies, Rm. Valcea, 4 Uzinei, 240050 Ramnicu Valcea, Romania
Interests: oxide based materials, functional ceramics, ceramic processing, perovskites; ceramic membrane, mixed ionic electronic conductors, hydrogen storage, water splitting, materials in sustainable energy applications, in-situ and in-operando studies, X-ray diffraction; thermal analysis, the relationships between structure and propertie

Special Issue Information

Dear Colleagues,

Nowadays, the overall need for green energy harvesting and storage materials, with a proven record for scale-up and low-carbon manufacturing, is a significant fact. With novel, low-cost materials and new performance-enhancing technologies pushing against the existing ones, electrochemical systems will continue to play an important role in the exploitation of renewable energy sources on a worldwide scale. Electrochemical systems rely on porous electrodes with personalized design and chemical potential for specific purposes, such as the anodes and cathodes in fuel cells, batteries and electrolyzers. Upon manufacturing, the electrode materials are often processed in the form of powders with well-defined composition, grain-size, and shape. Further modifications of the electrode surface aim to enhance the overall device performance and durability by also reducing the risks associated with safety upon operation. For that, the physical, chemical, and topological properties of electrodes are manipulated in a way that the processes associated with the charge transfer and ion intercalation at the electrode–electrolyte interface are faster, more favorable and also reversible. In this picture, although significant progress has been achieved so far, the detailed mechanisms of performance enhancement are insufficiently understood to foster the development of more efficient electrode architectures. From this perspective, it is expected that the future work will bridge the gap in knowledge toward novel electrochemical applications with enhanced performance, durability, and safety.

This Special Issue welcomes extensive topics on modified surface cathode materials for efficient energy storage and conversion, including fuel cells, electrolysis, batteries, supercapacitors, and photovoltaics. Theoretical studies, manufacturing methods, experimental investigations, and numerical simulations are equally considered.

This Special Issue aims to cover the following fields:

  • Theoretical aspects related to modified cathodes with enhanced kinetics of charge transfer and ion integration at the cathode–electrolite interface;
  • Novel manufacturing methods of modified cathodes with enhanced specific area and electrochemical activity, with a high potential for up-scale, including but not limited to thin film coating, functionalization and 3D particle decoration for surface catalitic activation and degradation passivation;
  • Non-destructive, in-operando experimental techniques and methods to assess the overall performance and durability of cathods upon prolonged operation, including the irreversible process upon cycling;
  • Numerical calculations and simulations for cathode integration in electrochemical systems in relation to device performance, durability, and safety issues.

We look forward to receiving your contributions.

Dr. Stanica Enache
Prof. Dr. Konstantin Petrov
Guest Editors

Dr. Mirela Dragan
Guest Editor Assistant

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Coatings is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • surface modification methodes and techniques
  • structural properties and morphology
  • electrodeelectrochemical assessment
  • non-destructive / in-operando characterization techniques
  • electrode integration and optimization
  • mathematical modeling and simulations
  • device performance, durability and safety
  • scale-up processing and low-carbon manufacturing

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Published Papers (1 paper)

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Research

10 pages, 7858 KiB  
Communication
Improving the Electrochemical Performance of LiNi1/3Co1/3Mn1/3O2 Cathode Material by LiF Modification
by Sisi Zhou, Xianggong Zhang, Zhihao Zhang, Songting Liu and Rui Wang
Coatings 2023, 13(4), 727; https://doi.org/10.3390/coatings13040727 - 3 Apr 2023
Cited by 4 | Viewed by 1966
Abstract
LiNi1/3Co1/3Mn1/3O2 is a widely used commercial cathode material in the fields of consumer electronics and electric vehicles. However, its energy density still falls short of the standard and needs to be improved. The most effective method [...] Read more.
LiNi1/3Co1/3Mn1/3O2 is a widely used commercial cathode material in the fields of consumer electronics and electric vehicles. However, its energy density still falls short of the standard and needs to be improved. The most effective method is to increase the cut-off voltage, but this will result in a drop in capacity. In this study, a LiF layer is coated on the surface of LiNi1/3Co1/3Mn1/3O2 via an in situ method. It is found that the LiF layer may protect materials from side reactions with electrolytes, improve the interfacial stability, and enhance the cyclic performance. The bare sample shows relatively poor cycling stability, with capacity retention rates of 65.9% (0.2 C) and 12.8% (5 C) after 100 cycles, while 1% LiF-coated NCM has higher cycling stability with capacity retention rates of 83.4% (0.2 C) and 73.3% (5 C) after 100 cycles, respectively. Our findings suggest that a LiF surface layer could be a useful means of boosting the electrochemical performance of NCM cathode materials. Full article
(This article belongs to the Special Issue Surface Modification of Cathode Materials)
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