Advances in Thermochromic Liquid Crystals and Functional Colour-Changing Materials

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Liquid Crystals".

Deadline for manuscript submissions: 15 December 2024 | Viewed by 1261

Special Issue Editors


E-Mail Website
Guest Editor
Faculty of Graphic Arts, University of Zagreb, Getaldićeva 2, 10000 Zagreb, Croatia
Interests: thermochromic liquid crystals; thermochromic printing inks; printing technology; material characterization; surface coating; graphic materials; smart packaging; security; printability testing; optical properties

E-Mail Website
Guest Editor
Department of Chemistry, The University of York, York YO10 5DD, UK
Interests: liquid crystals; ferroelectric; antiferroelectric; dichroic dye; smectic; nematic
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Thermochromic liquid crystals (TLCs) stand out due to their unique ability to change colour in response to temperature fluctuations, a property that arises from their liquid–crystalline phases. This remarkable combination of thermal sensitivity and optical responsiveness has led to their application in various fields, from temperature mapping and medical diagnostics to smart packaging and security. However, there are many other dynamic, colour-changing materials with the potential to be employed in various technologies. This Special Issue focuses on the utilization of TLCs and other functional colour-changing systems, such as leuco dyes, photochromic, piezochromic, and electrochromic materials. These systems, while differing in their stimulus (e.g., heat, light, pressure, or electric fields), all use molecular or crystalline structures that enable reversible colour changes. By investigating the functional behaviours of these diverse materials, this Special Issue aims to address the application of thermally responsive TLCs and broader classes of colorimetric materials.

The scope of the Special Issue includes, but is not limited to, the following topics:

  • Thermochromic liquid crystals—the development of new TLC formulations, including hybrid systems that enhance temperature sensitivity and durability across different substrates, such as fibre-based and bio-based materials.
  • Leuco dyes—exploring their reversible and/or irreversible colour-changing behaviour, with potential applications in security printing and temperature indicators.
  • Photochromic and electrochromic systems—investigating their use in dynamic displays, smart packaging, and light-sensitive technologies.
  • Piezochromic materials—studying pressure-induced colour changes for use in sensors and wearable devices.

The research of these materials and their interactions could provide the basis for flexible, lightweight, and customizable applications in smart packaging, temperature-sensitive labels, medical diagnostics, and intelligent textiles. The ability to create dynamic visual feedback based on environmental stimuli makes these materials particularly valuable for sustainable design and energy-efficient systems.

We therefore also welcome submissions that address the following topics:

  • The formulation, rheological behaviour, and printability of TLCs and related functional inks.
  • The application of TLCs in smart packaging, temperature sensors, and security features.
  • Advances in leuco dyes, photochromic, piezochromic, and electrochromic materials.
  • The role of crystalline and molecular structures in enabling colour-changing effects.
  • Industrial challenges in scaling these materials for practical applications.

Dr. Maja Strižić Jakovljević
Dr. Stephen J. Cowling
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Crystals is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2100 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • thermochromic liquid crystals (TLCS)
  • leuco dyes
  • functional colour-changing materials
  • photochromic systems
  • electrochromic systems
  • piezochromic materials
  • smart packaging
  • temperature sensors
  • sensing technologies
  • responsive materials
  • optical properties

Benefits of Publishing in a Special Issue

  • Ease of navigation: Grouping papers by topic helps scholars navigate broad scope journals more efficiently.
  • Greater discoverability: Special Issues support the reach and impact of scientific research. Articles in Special Issues are more discoverable and cited more frequently.
  • Expansion of research network: Special Issues facilitate connections among authors, fostering scientific collaborations.
  • External promotion: Articles in Special Issues are often promoted through the journal's social media, increasing their visibility.
  • e-Book format: Special Issues with more than 10 articles can be published as dedicated e-books, ensuring wide and rapid dissemination.

Further information on MDPI's Special Issue polices can be found here.

Published Papers (1 paper)

Order results
Result details
Select all
Export citation of selected articles as:

Research

13 pages, 2973 KiB  
Article
Liquid Crystal Ordering in Densely Packed Colloidal Suspensions of Highly Anisotropic Monolayer Nanosheets
by Yue Shi, Min Shuai, Yongqiang Shen, Dong Chen, Joseph E. Maclennan, Zhengdong Cheng and Noel A. Clark
Crystals 2024, 14(11), 963; https://doi.org/10.3390/cryst14110963 - 6 Nov 2024
Viewed by 417
Abstract
Monolayer nanosheets of zirconium phosphate in aqueous suspension exhibit short-range repulsion and long-range attraction, producing, at overall volume fractions larger than about half a percent, phase separation into higher-concentration liquid crystal and lower-concentration isotropic regions. At high concentrations, this phase separation takes the [...] Read more.
Monolayer nanosheets of zirconium phosphate in aqueous suspension exhibit short-range repulsion and long-range attraction, producing, at overall volume fractions larger than about half a percent, phase separation into higher-concentration liquid crystal and lower-concentration isotropic regions. At high concentrations, this phase separation takes the form of an emulsion of condensed, liquid-crystalline droplets, which anneal to form lens-shaped tactoids. These tactoids provide an opportunity to study the liquid crystal ordering of inorganic nanosheets in the limit of large shape anisotropy (diameter/thickness~400) and high packing fraction (volume fraction 70%). The internal liquid crystal structure of the tactoids remains nematic even under conditions that would usually favor ordering into lamellar smectics. Local lamellar ordering is suggested by short-range, smectic-like layer correlations, but a full transition into a smectic phase appears to be inhibited by the nanosheet edges, which act as a perturbative population of dislocation loops in the system of layers. Under conditions of thermal equilibrium, the nanoplates organize positionally to enable bend deformation of the director, a hallmark of the nematic phase and its principal distinction from the smectic, where bend must be expelled. Full article
Show Figures

Figure 1

Back to TopTop