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Crystals
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Advances in Liquid Crystals
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Advances in Liquid Crystals

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Liquid Crystals".

Deadline for manuscript submissions: closed (30 June 2013) | Viewed by 91149

Special Issue Editor

Prof. Dr. Wolfgang Haase

E-Mail Website
Guest Editor
Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Petersenstrasse 20, D-64287 Darmstadt, Germany
Interests: liquid crystals; molecular magnetism; bioinorganic chemistry; nonlinear optics of functonal polymers
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Liquid Crystals are one of the prominent Soft Materials, attractive for a broad and growing community of Scientists and Engineers.

Scientists based on their fundamental knowledge of Liquid Crystals trying to understand the working functions of Liquid Crystals in the biological environment, in Colloids, Polymers, LB-films etc. The applicability of Liquid Crystals in Optics, for Lasing, for functional Devices in a broad frequency range, is one of the key topics for applied scientists. Last but not least the technological verification of LCs in Displays is part of our daily life. Displays are an important media for transforming information, for entertainment etc. The current volume ‘Advances in Liquid Crystals’ provide a unique forum allowing the dissemination of results in the entire field of Liquid Crystals. Scientist and Engineers working in a broader sense on Liquid Crystals are invited to use this unique opportunity for presenting their work.

The topics summarized under the keywords should be considered only as examples, as guidelines. The volume is open for any advanced topics in the field of Liquid Crystals.

Prof. Dr. Wolfgang Haase
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Crystals is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2100 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • molecular design of liquid crystals
  • liquid crystals in biological systems
  • liquid crystalline nanocolloids
  • liquid crystals for photonics
  • liquid crystals for lasing
  • optical properties of liquid crystals
  • liquid crystals in the microwave and terahertz regime

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Published Papers (7 papers)

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Research

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582 KiB  
Article
Influence of Mesogenic Properties of Cruciform-Shaped Liquid Crystals by Incorporating Side-Arms with a Laterally-Substituted-Fluorine
by Yi-Hui Lin, Yamuna Ezhumalai, Yu-Ling Yang, Ching-Ting Liao, Hsiu-Fu Hsu and Chunhung Wu
Crystals 2013, 3(2), 339-349; https://doi.org/10.3390/cryst3020339 - 30 May 2013
Cited by 4 | Viewed by 8106
Abstract
Fluoro substitution in thermotropic liquid crystals provides a general way of modifying the properties of a parent system. Transition temperatures, mesophase types and other physical properties can be affected by fluoro substitution, so that frequently the behaviors of the parent compound can be [...] Read more.
Fluoro substitution in thermotropic liquid crystals provides a general way of modifying the properties of a parent system. Transition temperatures, mesophase types and other physical properties can be affected by fluoro substitution, so that frequently the behaviors of the parent compound can be manipulated and improved in a predictable manner. This paper discusses the effects of a fluoro substitution in each side-arm of 1,2,4,5-tetrakis((4-(alkoxy)phenyl)ethynyl)benzenes on the resulting mesomorphic properties characterized by optical polarizing microscopy and differential scanning calorimetry. Without any fluoro-substituted side-arms, longer chain-length leads to a wider nematic temperature range on cooling. Incorporation of a fluoro substitution in each side-arm induces the formation of a lamellar suprastructure, lowers transition temperatures and results in a wider mesophase temperature range on cooling. Full article
(This article belongs to the Special Issue Advances in Liquid Crystals)
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1131 KiB  
Article
Generation of Light Scattering States in Cholesteric Liquid Crystals by Optically Controlled Boundary Conditions
by Jonathan P. Vernon, Svetlana V. Serak, Rafael S. Hakobyan, Vincent P. Tondiglia, Timothy J. White, Nelson V. Tabiryan and Timothy J. Bunning
Crystals 2013, 3(1), 234-247; https://doi.org/10.3390/cryst3010234 - 18 Mar 2013
Cited by 7 | Viewed by 9785
Abstract
Circularly polarized light was previously employed to stimulate the reversible and reconfigurable writing of scattering states in cholesteric liquid crystal (CLC) cells constructed with a photosensitive layer. Such dynamic photodriven responses have utility in remotely triggering changes in optical constructs responsive to optical [...] Read more.
Circularly polarized light was previously employed to stimulate the reversible and reconfigurable writing of scattering states in cholesteric liquid crystal (CLC) cells constructed with a photosensitive layer. Such dynamic photodriven responses have utility in remotely triggering changes in optical constructs responsive to optical stimulus and applications where complex spatial patterning is required. Writing of scattering regions required the handedness of incoming radiation to match the handedness of the CLC and the reflection bandwidth of the CLC to envelop the wavelength of the incoming radiation. In this paper, the mechanism of transforming the CLC into a light scattering state via the influence of light on the photosensitive alignment layer is detailed. Specifically, the effects of: (i) the polarization state of light on the photosensitive alignment layer; (ii) the exposure time; and (iii) the incidence angle of radiation on domain formation are reported. The photogenerated light-scattering domains are shown to be similar in appearance between crossed polarizers to a defect structure that occurs at a CLC/air interface (i.e., a free CLC surface). This observation provides strong indication that exposure of the photosensitive alignment layer to the circularly polarized light of appropriate wavelength and handedness generates an out-of-plane orientation leading to a periodic distortion of the original planar structure. Full article
(This article belongs to the Special Issue Advances in Liquid Crystals)
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Review

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1241 KiB  
Review
High Performance Negative Dielectric Anisotropy Liquid Crystals for Display Applications
by Yuan Chen, Fenglin Peng, Takashi Yamaguchi, Xiaolong Song and Shin-Tson Wu
Crystals 2013, 3(3), 483-503; https://doi.org/10.3390/cryst3030483 - 3 Sep 2013
Cited by 54 | Viewed by 13674
Abstract
We review recent progress in the development of high birefringence (Δn ≥ 0.12) negative dielectric anisotropy (Δε < 0) liquid crystals (LCs) for direct-view and projection displays. For mobile displays, our UCF-N2 (low viscosity, negative Δε, high Δn [...] Read more.
We review recent progress in the development of high birefringence (Δn ≥ 0.12) negative dielectric anisotropy (Δε < 0) liquid crystals (LCs) for direct-view and projection displays. For mobile displays, our UCF-N2 (low viscosity, negative Δε, high Δn) based homogeneous alignment fringe-field switching (called n-FFS) mode exhibits superior performance to p-FFS in transmittance, single gamma curve, cell gap insensitivity, and negligible flexoelectric effect. For projection displays using a vertical alignment liquid-crystal-on-silicon (VA LCOS), our high birefringence UCF-N3 mixture enables a submillisecond gray-to-gray response time, which is essential for color sequential displays without noticeable color breakup. Our low viscosity UCF-N2 also enables multi-domain VA displays to use a thinner cell gap for achieving faster response time. Full article
(This article belongs to the Special Issue Advances in Liquid Crystals)
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1757 KiB  
Review
High Birefringence Liquid Crystals
by Roman Dąbrowski, Przemysław Kula and Jakub Herman
Crystals 2013, 3(3), 443-482; https://doi.org/10.3390/cryst3030443 - 3 Sep 2013
Cited by 236 | Viewed by 24379
Abstract
Liquid crystals, compounds and mixtures with positive dielectric anisotropies are reviewed. The mesogenic properties and physical chemical properties (viscosity, birefringence, refractive indices, dielectric anisotropy and elastic constants) of compounds being cyano, fluoro, isothiocyanato derivatives of biphenyl, terphenyl, quaterphenyl, tolane, phenyl tolane, phenyl ethynyl [...] Read more.
Liquid crystals, compounds and mixtures with positive dielectric anisotropies are reviewed. The mesogenic properties and physical chemical properties (viscosity, birefringence, refractive indices, dielectric anisotropy and elastic constants) of compounds being cyano, fluoro, isothiocyanato derivatives of biphenyl, terphenyl, quaterphenyl, tolane, phenyl tolane, phenyl ethynyl tolane, and biphenyl tolane are compared. The question of how to obtain liquid crystal with a broad range of nematic phases is discussed in detail. Influence of lateral substituent of different kinds of mesogenic and physicochemical properties is presented (demonstrated). Examples of mixtures with birefringence ∆n in the range of 0.2–0.5 are given. Full article
(This article belongs to the Special Issue Advances in Liquid Crystals)
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4424 KiB  
Review
Soft Elasticity in Main Chain Liquid Crystal Elastomers
by Sonal Dey, Dena M. Agra-Kooijman, Wanting Ren, Philip J. McMullan, Anselm C. Griffin and Satyendra Kumar
Crystals 2013, 3(2), 363-390; https://doi.org/10.3390/cryst3020363 - 7 Jun 2013
Cited by 57 | Viewed by 17781
Abstract
Main chain liquid crystal elastomers exhibit several interesting phenomena, such as three different regimes of elastic response, unconventional stress-strain relationship in one of these regimes, and the shape memory effect. Investigations are beginning to reveal relationships between their macroscopic behavior and the nature [...] Read more.
Main chain liquid crystal elastomers exhibit several interesting phenomena, such as three different regimes of elastic response, unconventional stress-strain relationship in one of these regimes, and the shape memory effect. Investigations are beginning to reveal relationships between their macroscopic behavior and the nature of domain structure, microscopic smectic phase structure, relaxation mechanism, and sample history. These aspects of liquid crystal elastomers are briefly reviewed followed by a summary of the results of recent elastic and high-resolution X-ray diffraction studies of the shape memory effect and the dynamics of the formation of the smectic-C chevron-like layer structure. A possible route to realizing auxetic effect at molecular level is also discussed. Full article
(This article belongs to the Special Issue Advances in Liquid Crystals)
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29778 KiB  
Review
One-, Two-, and Three-Dimensional Hopping Dynamics
by Keiko M. Aoki, Susumu Fujiwara, Kiyoshi Sogo, Shuhei Ohnishi and Takenori Yamamoto
Crystals 2013, 3(2), 315-332; https://doi.org/10.3390/cryst3020315 - 29 Apr 2013
Cited by 11 | Viewed by 6664
Abstract
Hopping dynamics in glass has been known for quite a long time. In contrast, hopping dynamics in smectic-A (SmA) and hexatic smectic-B (HexB) liquid crystals (LC) has been observed only recently. The hopping in SmA phase occurs among the smectic layers (one-dimensionally), while [...] Read more.
Hopping dynamics in glass has been known for quite a long time. In contrast, hopping dynamics in smectic-A (SmA) and hexatic smectic-B (HexB) liquid crystals (LC) has been observed only recently. The hopping in SmA phase occurs among the smectic layers (one-dimensionally), while hopping in HexB phase occurs inside the layers (two-dimensionally). The hopping dynamics in SmA and HexB liquid crystal phases is investigated by parallel soft-core spherocylinders, while three-dimensional hopping dynamics in inherent glassy states is investigated by systems of Weeks–Chandler–Andersen (WCA) spheres. The temperature dependence of diffusion coefficients of hopping in SmA phase can be described by the Arrhenius equation characteristic of activation process. In HexB LC phase, the diffusion coefficients saturate at higher temperatures. In a system of WCA spheres, the values and temperature dependence of diffusion coefficients depend on the observed states. Full article
(This article belongs to the Special Issue Advances in Liquid Crystals)
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1226 KiB  
Review
Photoaligning and Photopatterning — A New Challenge in Liquid Crystal Photonics
by Vladimir G. Chigrinov
Crystals 2013, 3(1), 149-162; https://doi.org/10.3390/cryst3010149 - 1 Mar 2013
Cited by 58 | Viewed by 9340
Abstract
Photoalignment possesses obvious advantages in comparison with the usually “rubbing” treatment of the substrates of liquid crystal display (LCD) cells. The application of the photoalignment and photopatterning nanotechnology for the new generation of photonic and display devices will be reviewed. Full article
(This article belongs to the Special Issue Advances in Liquid Crystals)
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