Advance in Oleogels

A special issue of Gels (ISSN 2310-2861).

Deadline for manuscript submissions: closed (15 August 2022) | Viewed by 3481

Special Issue Editor


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Guest Editor
Agricultural Research Organization, Volcani Center, Rishon LeZion, Israel
Interests: gels; self-assembly; structured oils; emulsions; colloids and interfaces; nanomaterials

Special Issue Information

Dear Colleagues,

Growing consumer concerns on low-calorie diets, animal proteins and sustainable ingredients require the development of structured foods without compromising the flavor and mouthfeel. Oleogels play a prominent role in the field of alternative edible oil structuring, where vegetable oils are structured/entrapped by a network of solid oleogelators. Over the past decade, oleogels research has taken new strides in reformulating fat-containing food products. Legislative limitations across the globe on saturated and trans fats have propelled the advancement of oleogels for commercial low-fat foods in the form of confectionaries, bakeries, spreads, dairy, and meat products. The design and implementation of oleogels in such diverse foods has been made possible with the discovery of a variety of structuring agents ranging from fatty acids, fatty alcohols, proteins, resins, waxes, cellulose derivatives, and sugar–fatty acyl derivatives. Precise control over the supramolecular architectures of gelators is necessary to design such novel foods. This has also facilitated the purview of oleogels toward pharmaceutical and cosmetic fields as controlled delivery carriers of drugs, nutraceuticals, and pre- and probiotics.

The main aim of this Special Issue is to highlight advances in oleogels research by focusing on the relationship between the supramolecular architecture of oleogelators and corresponding functional properties (morphological, rheological, textural, and sensory properties) in the designed foods. To achieve this goal, we invite high-quality submissions addressing supramolecular and biopolymer chemistry and food science. We also welcome researchers who envisage oleogels as controlled carriers in the fields of biomedicine, pharmaceutics, and cosmetics. Topics of interest for this Special Issue include, but are not restricted to:

  • Supramolecular self-assembly and polymeric gelation mechanisms of oleogels;
  • Role of oleogelators in modifying the textural and sensory properties of foods;
  • Oleogels as fat mimetics or replacers in meat products;
  • Design of oleogel-based bigels and structured emulsions for controlled delivery applications.

Dr. Sai Sateesh Sagiri
Guest Editor

Manuscript Submission Information

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Keywords

  • edible oleogels
  • fat mimetics
  • low-fat foods
  • supramolecular self-assembly
  • controlled delivery carriers

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Published Papers (1 paper)

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Research

15 pages, 1679 KiB  
Article
Walnut Oil Oleogels as Milk Fat Replacing System for Commercially Available Chocolate Butter
by Andreea Pușcaș, Anda Elena Tanislav, Andruţa Elena Mureșan, Anca Corina Fărcaș and Vlad Mureșan
Gels 2022, 8(10), 613; https://doi.org/10.3390/gels8100613 - 26 Sep 2022
Cited by 18 | Viewed by 3056
Abstract
A breakfast spread named chocolate butter exists on the market. For economic and technological reasons, cream in the original recipe is replaced with vegetable oils such as palm oil or by partially hydrogenated sunflower oil. The study aims to reformulate chocolate flavor butter, [...] Read more.
A breakfast spread named chocolate butter exists on the market. For economic and technological reasons, cream in the original recipe is replaced with vegetable oils such as palm oil or by partially hydrogenated sunflower oil. The study aims to reformulate chocolate flavor butter, using cold pressed walnut oil (WO) oleogels (OGs) structured with 10% waxes and monoglyceride (MG), as a milk fat replacing system. The rheological, textural and microscopic characteristics of the oleogels and the spreads were compared. Oil binding capacity (OBC) and colorimetry were also assessed. Fourier transform infrared studies were used to monitor the composition of the samples. Oleogels and oleogel based chocolate butter behaved like strong gels (G’ > G”). The use of candelilla wax (CW) led to the formation of a much firmer spread (S-CW), with a hardness of 3521 g and G’LVR of 139,920 Pa, while the monoglyceride-based spread (S-MG) registered a hardness of 1136 g and G’LVR 89,952 Pa. In the spreadability test, S-CW registered a hardness of 3376 g and hardness work of 113 mJ, comparable to the commercially available chocolate butter. The formulated spreads exhibited shear thinning effects, and increased viscosity with decreasing temperature. A large round peak at 3340 cm−1 was present in the spectra of the candelilla wax-based oleogel (OG-CW) and the reference spreads due to hydrogen bonding, but was absent in S-CW or S-MG. The FTIR spectra of the alternative spreads exhibited the same peaks as the WO and the oleogels, but with differences in the intensities. S-CW exhibited a dense crystal network, with spherulitic crystals of 0.66–1.73 µm, which were statistically similar to those of the reference made from cream (S-cream). S-MG exhibited the lowest stability upon centrifugation, with an OBC of 99.76%. Overall, both oleogel-based chocolate spreads can mimic the properties of the commercially existing chocolate butter references. Full article
(This article belongs to the Special Issue Advance in Oleogels)
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