Advances in Oil Structuring II

A special issue of Gels (ISSN 2310-2861). This special issue belongs to the section "Gel Applications".

Deadline for manuscript submissions: closed (28 February 2023) | Viewed by 5661

Special Issue Editors


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Guest Editor
International Iberian Nanotechnology Laboratory, Av. Mestre José Veiga s/n, 4715-330 Braga, Portugal
Interests: oil gelation; bigels; food science; structural functionality; material characterization
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Guest Editor
International Iberian Nanotechnology Laboratory, 4715-330 Braga, Portugal
Interests: food science; packaging; biopolymers; oleogels; controlled delivery systems
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
State Key Laboratory of Food Science and Technology, School of Food Science and Technology, Jiangnan University, Wuxi 214122, China
Interests: oleogel; oleofoam; emulsion gel; fat crystallization and structure; healthy lipid product development
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

The structural features of gels result from the development of gelator networks and the large amounts of solvent enclosed in these. Gelation techniques have been used for oil structuring purposes, allowing the development of diverse oleogel or organogel systems with a multitude of colloidal architectures (e.g., crystalline networks, self-assembled conformations, or polymeric complexes). Different types of edible oils can be used in the creation of these semi-solid materials, overcoming the natural limitations attributed to their use in liquid forms, thus expanding their applicability. Applications including their use as texture modifiers and fat replacers in foods, or their use in drug delivery functions, are among the most interesting functions. The focal point of oil gelation consists of a physical process of oil entrapment through the formation of a three-dimensional gelator network, which, under certain environmental circumstances, builds viscoelastic, self-standing, thermo-reversible structures. The concept to expanding this principle to the formation of solid-like bigels or structured emulsions has gained interest in the last few years. These colloidal gel-in-gel structures can be developed through the combination of hydrogelation and oleogelation techniques, promoting the individual stabilization of two immiscible liquid phases. The capacity to simultaneously deliver hydrophilic and lipophilic bioactives and increased compatibility with water-based products are important features worthy of further investigation.

Our aim with this Special Issue is to provide researchers with an opportunity to present the latest works and new developments considering the production of oleogels and bigels, converging the most prevalent characterization techniques as well as their applicability, e.g., their use as fat mimetics. A special focus will be given to production practices, materials, and gelation mechanisms, as well as the delivery of bioactives through food, cosmetics, and pharmaceuticals.

Dr. Artur J. Martins
Dr. Miguel A. Cerqueira
Prof. Dr. Zong Meng
Guest Editors

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Keywords

  • delivery of bioactives
  • oil structuring
  • oleogels
  • bigels
  • food
  • cosmetics
  • texture

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Published Papers (2 papers)

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Research

17 pages, 1385 KiB  
Article
Effects of Sorbitan Monostearate and Stearyl Alcohol on the Physicochemical Parameters of Sunflower-Wax-Based Oleogels
by Deepti Bharti, Doman Kim, Indranil Banerjee, Derick Rousseau and Kunal Pal
Gels 2022, 8(8), 520; https://doi.org/10.3390/gels8080520 - 19 Aug 2022
Cited by 13 | Viewed by 2676
Abstract
A rising health concern with saturated fatty acids allowed researchers to look into the science of replacing these fats with unsaturated fatty acids. Oleogelation is a technique to structure edible oil using gelators. The present study looked for the effect of solid emulsifiers; [...] Read more.
A rising health concern with saturated fatty acids allowed researchers to look into the science of replacing these fats with unsaturated fatty acids. Oleogelation is a technique to structure edible oil using gelators. The present study looked for the effect of solid emulsifiers; namely, sorbitan monostearate (SP) and stearyl alcohol (SA), on the physicochemical parameters of oleogels. All the oleogels were formulated using 5% sunflower wax (SW) in sunflower oil (SO). The formulated oleogels displayed irregular-shaped wax crystals on their surface. The bright-field and polarized microscopy showed the fiber/needle network of wax crystals. Formulations consisting of 10 mg (0.05% w/w) of both the emulsifiers (SA10 and SP10) in 20 g of oleogels displayed the appearance of a dense wax crystal network. The SP and SA underwent co-crystallization with wax molecules, which enhanced crystal growth and increased the density and size of the wax crystals. The XRD and FTIR studies suggested the presence of a similar β’ polymorph to that of the triacylglycerols’ arrangement. The incorporation of SA and SP in wax crystal packing might have resulted in a lower crystallization rate in SA10 and SP10. Evaluation of the thermal properties of oleogels through DSC showed better gel recurrence of high melting enthalpy. These formulations also displayed a sustained release of curcumin. Despite the variations in several properties (e.g., microstructures, crystallite size, thermal properties, and nutrient release), the emulsifiers did not affect the mechanical properties of the oleogel. The meager amounts of both the emulsifiers were able to modulate the nutrient release from the oleogels without affecting their mechanical properties in comparison to the control sample. Full article
(This article belongs to the Special Issue Advances in Oil Structuring II)
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15 pages, 2304 KiB  
Article
Impact of Vegetable Oil Type on the Rheological and Tribological Behavior of Montmorillonite-Based Oleogels
by M. A. Martín-Alfonso, José F. Rubio-Valle, Juan P. Hinestroza and José E. Martín-Alfonso
Gels 2022, 8(8), 504; https://doi.org/10.3390/gels8080504 - 13 Aug 2022
Cited by 14 | Viewed by 2513
Abstract
We formulated and characterized oleogels based on montmorillonite clay and vegetable oils that could serve as eco-friendly semi-solid lubricants. In particular, we studied the influence of the physical-chemical properties of olive, castor, soybean, linseed, and sunflower oils on the rheological, chemical, thermal, and [...] Read more.
We formulated and characterized oleogels based on montmorillonite clay and vegetable oils that could serve as eco-friendly semi-solid lubricants. In particular, we studied the influence of the physical-chemical properties of olive, castor, soybean, linseed, and sunflower oils on the rheological, chemical, thermal, and tribological properties of the semi-solid lubricants. We prepared the oleogels via the highly intensive mixing of vegetable oils with clay at a concentration of 30 wt.%. The oleogels exhibited shear-thinning, thixotropy, structural recovery, and gel-like behavior commonly related to that of a three-dimensional network. The results were corroborated via XRD measurements showing the presence of intercalated nanoclay structures well-dispersed in the vegetable oil. Empirical correlations between the content of saturated (SFAs), unsaturated (UFAs), mono-unsaturated (MUFAs) and poly-unsaturated (PUFAs) fatty acids and the plateau modulus of the aerogels were found. From these experimental results, we can conclude that the fatty acid profile of the vegetable oils exerts an important influence on the rheological and tribological properties of resulting clay and vegetable oil oleogels. Full article
(This article belongs to the Special Issue Advances in Oil Structuring II)
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