Thermal and Structural Properties of Shape Memory Alloys

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Metallic Functional Materials".

Deadline for manuscript submissions: closed (29 February 2024) | Viewed by 1555

Special Issue Editors


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Guest Editor
School of Metallurgy and Materials Engineering, University of Tehran, Tehran 11155-4563, Iran
Interests: shape memory alloys; shape memory effect; pseudoelastic; thermoelastic; martensitic transformation

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Guest Editor
Department of Materials Engineering, Tarbiat Modares University, Tehran 14115-111, Iran
Interests: phase transformation; shape memory alloys; ultrafine-grained and nanostructured materials; microstructure engineering

Special Issue Information

Dear Colleagues,

Shape memory alloys (SMAs) are one of the most important classes of active materials that can memorize a predefined shape or show superelastic strain. In fact, a temperature increment can lead to shape recovery, therefore resulting in high actuation energy densities. In addition, applied mechanical loading subjects SMAs to a reversible hysteretic shape change, enabling them to absorb and damp mechanical energy. These unique features of SMAs have made them popular for many functional applications: impact absorption or sensing and actuation in a wide range of sectors such as biomedical, aerospace, energy, automobile industries and civil engineering.

Different alloys may exhibit the shape memory effect (SME), among which NiTi, Cu, Ti and Fe-based alloys are the most popular. Thermoelastic martensitic transformation is the core mechanism of the SME, which distinguishes these alloys from other alloys representing conventional martensitic phase transformation. Therefore, the chemical composition, microstructure, and thermal and structural properties of alloys are the important characteristic variables which determine the shape memory behavior.

The aim of this Special Issue is to present the work conducted on different SMAs by considering important variables such as chemical composition, microstructure and thermal properties. Experts are invited to submit papers related to experimental research, applications, simulation and modelling of the various aspects of SMAs. In addition, studies on the effect of new processes such as additive manufacturing on the microstructure and SME are also welcome.

Prof. Dr. Mahmoud Nili Ahmadabadi
Dr. Hamed Shahmir
Guest Editors

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Keywords

  • shape memory alloys
  • martensitic transformation
  • thermo-mechanical behavior
  • shape memory effect
  • superelasticity
  • elastocaloric effect
  • hysteresis behavior
  • actuation system
  • vibration control
  • functional properties

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Published Papers (1 paper)

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Research

15 pages, 7774 KiB  
Article
Study of Structure and Phase Transformations in Rejuvenated Rapidly Quenched TiNiCu Alloys
by Alexander Shelyakov, Nikolay Sitnikov, Irina Zaletova, Kirill Borodako and Natalia Tabachkova
Metals 2023, 13(7), 1175; https://doi.org/10.3390/met13071175 - 24 Jun 2023
Cited by 1 | Viewed by 1270
Abstract
Alloys of the quasibinary TiNi-TiCu system manufactured by melt quenching in the form of thin 20–50 μm ribbons have proven to show good potential as materials for the fabrication of micromechanical devices. At high cooling rates (about 106 K/s), this method allows [...] Read more.
Alloys of the quasibinary TiNi-TiCu system manufactured by melt quenching in the form of thin 20–50 μm ribbons have proven to show good potential as materials for the fabrication of micromechanical devices. At high cooling rates (about 106 K/s), this method allows producing high-copper (more than 20 at.%) amorphous alloys which exhibit an excellent shape-memory effect after crystallization. Their properties are known to largely depend on the crystallization conditions and the structure of the initial amorphous material acting as a precursor for the formation of crystal phases. It has been shown recently that the rejuvenation procedure (cryogenic thermocycling) of metallic glasses is one of the most promising methods of improving their properties. In this study, we investigated for the first time the effect of cryogenic thermocycling of rapidly quenched amorphous TiNiCu on the initial state, as well as on structure formation and the phase transformation patterns of subsequent crystallization conducted using various methods. The effect was analyzed utilizing the methods of scanning and transmission electron microscopy, X-ray diffraction analysis, and differential scanning calorimetry. The results show that rejuvenation treatment slightly reduces the glass transition and crystallization onset temperatures and moderately changes the sizes of structural features (grains, martensite plates), the quantity of the martensite phase, and the characteristic temperatures and enthalpy of the martensitic transformation. Full article
(This article belongs to the Special Issue Thermal and Structural Properties of Shape Memory Alloys)
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