Physical Metallurgy of Refractory Alloys (2nd Edition)

A special issue of Metals (ISSN 2075-4701).

Deadline for manuscript submissions: closed (30 April 2024) | Viewed by 1185

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Department of Materials Engineering, Ben-Gurion University, P.O. Box 653, Beer-Sheva 84105, Israel
Interests: mechanical properties; micromechanics; martensitic transformations; physical metallurgy of tungsten alloys
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Special Issue Information

Dear Colleagues,

The high melting temperature, high strength at elevated temperatures, low thermal expansion, and high heat conduction of refractory metal alloys make them a favored candidate material for terrestrial energy production
facilities. Niobium, molybdenum, tantalum, tungsten, and their alloys are fabricated as powders through the reduction of their oxides, consolidation by sintering, activated sintering, or liquid phase sintering. Heavy tungsten alloys bound by nickel, iron, or copper are used as radiation shields, balancing weights, and penetrators. At higher temperatures, refractory alloys are used for tools and molds for metal and glass forming and in load-bearing parts of jet engines. At higher temperatures under a protective atmosphere, tungsten is used for heating filaments and elements, and electrodes are used for welding. The strong chemical bonds of refractory metals make their microstructure stable and generate potential for developing high-strength alloys for elevated temperature service. However, applications are limited by the brittle–ductile transition at relatively high temperatures and their high reactivity with oxygen, as well as the volatility of their oxides. These limitations are encountered by alloying with other refractory metals. The high bond strength and high atomic mass make them stable against radiation damage, and therefore leading candidates for the first wall material in fusion reactors.

A Special Issue of Metals will be devoted to the physical metallurgy of
refractory alloys. It intends to give an account of the scientific and technological state of the art of recent and potential developments of refractory alloys and environmental protection (see the Keywords/Topics below). Your contribution to this work will be highly valued and appreciated

Prof. Dr. Roni Z. Shneck
Guest Editor

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Keywords

  • refractory metal alloys and coatings
  • sintering and forming of refractory alloys
  • tungsten heavy metal
  • tungsten penetrators
  • high-strength alloys
  • elevated temperature and oxidation-resistant refractory alloys
  • tools and molds
  • refractory radiation shields
  • first wall reactor material
  • radiation damage

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Published Papers (1 paper)

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Research

11 pages, 4461 KiB  
Article
High-Pressure Torsion: A Path to Refractory High-Entropy Alloys from Elemental Powders
by Andrey Mazilkin, Mahmoud R. G. Ferdowsi, Evgeniy Boltynjuk, Roman Kulagin and Rimma Lapovok
Metals 2024, 14(6), 672; https://doi.org/10.3390/met14060672 - 6 Jun 2024
Cited by 1 | Viewed by 806
Abstract
For the first time, the refractory high-entropy alloys with equiatomic compositions, HfNbTaTiZr and HfNbTiZr, were synthesized directly from a blend of elemental powders through ten revolutions of high-pressure torsion (HPT) at room temperature. This method has demonstrated its effectiveness and simplicity not only [...] Read more.
For the first time, the refractory high-entropy alloys with equiatomic compositions, HfNbTaTiZr and HfNbTiZr, were synthesized directly from a blend of elemental powders through ten revolutions of high-pressure torsion (HPT) at room temperature. This method has demonstrated its effectiveness and simplicity not only in producing solid bulk materials but also in manufacturing refractory high-entropy alloys (RHEAs). Unlike the melting route, which typically results in predominantly single BCC phase alloys, both systems formed new three-phase alloys. These phases were defined as the Zr-based hcp1 phase, the α-Ti-based hcp2 phase, and the Nb-based bcc phase. The volume fraction of the phases was dependent on the accumulated plastic strain. The thermal stability of the phases was studied by annealing samples at 500 °C for one hour, which resulted in the formation of a mixed structure consisting of the new two hexagonal and cubic phases. Full article
(This article belongs to the Special Issue Physical Metallurgy of Refractory Alloys (2nd Edition))
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