Oceanic Ferromanganese Deposits

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Mineral Deposits".

Deadline for manuscript submissions: closed (24 September 2021) | Viewed by 7366

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Instituto Oceanográfico, Universidade de São Paulo, Praça do Oceanográfico, 191, São Paulo 05508-120, SP, Brazil
Interests: magnetic methods; geophysical surveys; seismic methods; mineral exploration; rock physics
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Guest Editor
British Geological Survey, Keyworth, Nottingham NG12 5GG, UK
Interests: mineralogy; geochemistry; mineral resources; isotopes; paleoceanography; age models

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Guest Editor
Geological Oceanography Division, CSIR-National Institute of Oceanography, Dona Paula Goa 403004, India
Interests: marine mineral deposits; environmental aspects of offshore mining; marine geochemistry; benthic biogeochemistry; marine sediments; paleochemistry

Special Issue Information

Dear Colleagues,

Ferromanganese oxides are a ubiquitous mineral occurrence in the oceanic realm resulting from the precipitation of Fe and Mn oxides from three-endmember fluids—hydrothermal, seawater (hydrogenetic), and/or pore fluid (diagenetic). The metal enrichment may involve microbial involvement. As such, Fe-Mn oxide deposits are found in a large range of environments, with characteristic morphologies, mineralogies, and compositions reflecting their origin(s).

Owing to the unique physio-chemical properties of Fe-Mn oxides and their slow rate of formation, nodules and hydrogenetic crusts constitute effective scavengers of dissolved species in seawater and pore fluids. As a result, Fe-Mn nodules and crusts are widely regarded as a major repository for many elements of growing economic interest (Co, Ni, Cu, Pt, Te, REY) whilst hydrothermal deposits, usually of low-economic potential, can sometimes present unusual metal content but potentially scavenge the elements from hydrothermal plumes which are now known to disperse over large oceanic areas. Additionally, the growth layers of hydrogenetic deposits record the chemical evolution of seawater through time as they precipitate layer by layer. From this perspective, crusts and nodules form condensed paleoceanographic archives of major geological and climatic events, on tectonic timescales, affecting the chemical budget of our oceans through the differential weathering of continental landmass, evolution of basin morphology and water masses, and the opening and closing of oceanic gateways. These records can extend as far back as the Late Cretaceous on the oldest seamounts found in the world oceans.

The formation of ferromanganese deposits may also involve benthic biogeochemical processes, and thus the study of ferromanganese deposits cuts across many scientific disciplines to unlock their full economic and paleoceanographic potential. However, the attractiveness and development of many of these deposits is hindered by the lack of constraints on their spatial variability, continuity over areas sufficient to sustain potential mining activity, and our poor understanding of the disturbance of marine environments associated with human activities.

For this Special Issue, we welcome any contributions related to oceanic ferromanganese deposits, their mineralogy, elemental and isotope geochemistry, substrate/nucleus characteristics and origin, benthic biogeochemical aspects of depositional areas, their evolution through time, their full economic potential, technological development for exploration and mining, modern ore processing techniques, exploitation management, and environmental impact studies of marine mining activities.

Prof. Dr. Luigi Jovane
Dr. Pierre Josso
Prof. Dr. B. Nagender Nath
Guest Editors

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Keywords

  • ferromanganese deposits 
  • elemental and isotope geochemistry 
  • mineralogy
  • internal structures and growth features 
  • metal speciation and geochemical phases 
  • dating methods 
  • biological processes
  • benthic associations 
  • geophysical methods 
  • economic assessment 
  • political and Legal issues 
  • habitat analysis and ecosystem studies 
  • paleoceanography, tectonics–climate linkages
  • sustainability and environmental aspects 
  • exploration, metal extraction and exploitation techniques

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Published Papers (2 papers)

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Research

30 pages, 105655 KiB  
Article
Geochemistry and Mineralogy of Ferromanganese Crusts from the Western Cocos-Nazca Spreading Centre, Pacific
by Dominik Zawadzki, Łukasz Maciąg, Iker Blasco, Francisco Javier González, Benjamin Wernette, Egidio Marino, Gabriela A. Kozub-Budzyń, Adam Piestrzyński, Rafał J. Wróbel and Kevin McCartney
Minerals 2022, 12(5), 538; https://doi.org/10.3390/min12050538 - 26 Apr 2022
Cited by 8 | Viewed by 3273
Abstract
Late Pleistocene–Holocene rocks from the western part of Cocos-Nazca Spreading Centre (C-NSC) include ferromanganese crusts that elucidate the geochemistry and mineralogy of a deep-sea geological setting. Six representative Fe-Mn crust samples were studied using petrological methods, such as optical transmitted light microscopy, energy [...] Read more.
Late Pleistocene–Holocene rocks from the western part of Cocos-Nazca Spreading Centre (C-NSC) include ferromanganese crusts that elucidate the geochemistry and mineralogy of a deep-sea geological setting. Six representative Fe-Mn crust samples were studied using petrological methods, such as optical transmitted light microscopy, energy dispersive X-ray fluorescence spectrometry, inductively coupled plasma mass spectrometry, bulk X-ray diffraction, scanning electron microscopy and electron probe microanalysis. Geochemical, mineralogical and petrological signatures indicate complex formation influenced by mild hydrothermal processes. These crusts consist mostly of mixed birnessite, todorokite-buserite, and Mn-(Fe) vernadite with traces of diagenetic manganates (asbolane), Fe-oxides and oxyhydroxides or hydrothermally associated and relatively pure Mn-oxyhydroxides (manganite). The average Mn/Fe ratio is 2.7, which suggests predominant mixed hydrogenous-early diagenetic crusts with hydrothermal influences. The mean concentrations of three prospective metals (Ni, Cu and Co) are low: 0.17, 0.08 and 0.025 wt %, respectively. The total content of ΣREY is also low, and ranges from 81 to 741 mg/kg (mean 339 mg/kg). We interpret the complex geochemical and mineralogical data to reflect mixed origin of the crusts, initially related with formation of hydrothermal plume over the region. This process occurred during further interactions with seawater from which additional diagenetic and hydrogenetic elemental signatures were acquired. Full article
(This article belongs to the Special Issue Oceanic Ferromanganese Deposits)
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27 pages, 5607 KiB  
Article
Origin and Composition of Ferromanganese Deposits of New Caledonia Exclusive Economic Zone
by Paul Staszak, Julien Collot, Pierre Josso, Ewan Pelleter, Samuel Etienne, Martin Patriat, Sandrine Cheron, Audrey Boissier and Yaël Guyomard
Minerals 2022, 12(2), 255; https://doi.org/10.3390/min12020255 - 16 Feb 2022
Cited by 5 | Viewed by 3181
Abstract
Located in the South-West Pacific, at the northern extremity of the mostly submerged Zealandia continent, the New Caledonian Exclusive Economic Zone (EEZ) covers 1,470,000 km² and includes basins, ridges and seamounts where abundant ferromanganese crusts have been observed. Several investigations have been conducted [...] Read more.
Located in the South-West Pacific, at the northern extremity of the mostly submerged Zealandia continent, the New Caledonian Exclusive Economic Zone (EEZ) covers 1,470,000 km² and includes basins, ridges and seamounts where abundant ferromanganese crusts have been observed. Several investigations have been conducted since the 1970s on the nature and composition of ferromanganese crusts from New Caledonia’s seamounts and ridges, but none have covered the entire EEZ. We present data from 104 ferromanganese crusts collected in New Caledonia’s EEZ during twelve oceanographic cruises between 1974 and 2019. Samples were analysed for mineralogy, geochemical compositions, growth rates, and through a statistical approach using correlation coefficients and factor analysis. Crust thicknesses range from 1 mm to 115 mm, with growth rates between 0.45 mm/Ma and 102 mm/Ma. Based on textures, structures, discrimination plots, and growth rates, we distinguish a group of hydrogenetic crusts containing the highest mean contents of Co (0.42 wt%), Ni (0.31 wt%), and high contents of Mo, V, W, Pb, Zn, Nb, from a group of hydrothermal and/or diagenetic deposits showing high mean contents of Mn (38.17 wt%), Ba (0.56 wt%) and low contents of other trace metals. Several samples from this later group have exceptionally high content of Ni (0.7 wt%). The data shows that crusts from the southern part of the EEZ, notably seamounts of the Loyalty Ridge and the Lord Howe Rise, present high mineral potential for prospectivity owing to high contents of valuable metals, and constitute a great target for further investigation. Full article
(This article belongs to the Special Issue Oceanic Ferromanganese Deposits)
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