Modern Luminescence Spectroscopy of Minerals

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Crystallography and Physical Chemistry of Minerals & Nanominerals".

Deadline for manuscript submissions: closed (31 October 2019) | Viewed by 10981

Special Issue Editor


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Guest Editor
Department of Physics, Ariel University, Ariel, West Bank, Israel
Interests: spectroscopy

Special Issue Information

Dear Colleagues,

Laser based spectroscopy has become an integral part of the routine analytical tools applied in mineralogy. Increased, and currently still even further increasing, use of different kinds of spectroscopy is favored by a number of aspects, including the availability of reliable spectrometer systems in many institutions worldwide. A shortcoming, however, still exists, namely, the limited availability of comprehensive and dependable spectrum databases comprising modern spectroscopy spectra. Researchers often are obliged to do troublesome literature searches, in order to find reliable references backing up their own analytical findings and interpretations. The task of this special issue to survey the modern possibilities and aims in mineral investigations, including the main characteristics of all the methods and the most important problems. Each manuscript presents a complete, albeit condensed, form problems, methods, theories, and directions of investigations, and estimates their importance and strategic position in mineralogy. The following fields will be covered: laser induced time resolved luminescence, optically stimulated luminescence, Laser Induced Breakdown Spectroscopy (LIBS), Infrared spectroscopy, Raman Spectroscopy. Special manuscripts will be devoted to combination of laser-based spectroscopy with other techniques, such as optical spectroscopy, laser ablation techniques and electron paramagnetic resonance (EPR).

Prof. Dr. Michael Gaft
Guest Editor

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Keywords

  • laser
  • spectroscopy
  • mineralogy
  • physics
  • chemistry

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Published Papers (3 papers)

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Research

10 pages, 3183 KiB  
Article
Ultrafast Elemental Mapping of Platinum Group Elements and Mineral Identification in Platinum-Palladium Ore Using Laser Induced Breakdown Spectroscopy
by Kheireddine Rifai, Lütfü-Çelebi Özcan, François R. Doucet, Kyle Rhoderick and François Vidal
Minerals 2020, 10(3), 207; https://doi.org/10.3390/min10030207 - 25 Feb 2020
Cited by 13 | Viewed by 3950
Abstract
This paper demonstrates the capability of performing an ultrafast chemical mapping of drill cores collected from a platinum/palladium mine using laser-induced breakdown spectroscopy (LIBS). A scan of 40 mm × 30 mm was performed, using a commercial LIBS analyzer, onto the flat surface [...] Read more.
This paper demonstrates the capability of performing an ultrafast chemical mapping of drill cores collected from a platinum/palladium mine using laser-induced breakdown spectroscopy (LIBS). A scan of 40 mm × 30 mm was performed, using a commercial LIBS analyzer, onto the flat surface of a drill core with a scanning speed of 1000 Hz, and a spatial resolution of 50 µm, in about 8 min. Maps of the scanned areas for seven chemical elements (platinum, palladium, nickel, copper, iron, silicon, and magnesium), as well as a single map including the seven elements altogether, were then generated using the proprietary software integrated into the LIBS analyzer. Based on the latter image, seven minerals were identified using the principal component analysis (PCA) and correlations with the elemental maps. Full article
(This article belongs to the Special Issue Modern Luminescence Spectroscopy of Minerals)
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31 pages, 5302 KiB  
Article
The In-Situ Quantification of Structural Radiation Damage in Zircon Using Laser-Induced Confocal Photoluminescence Spectroscopy
by Christoph Lenz, Elena Belousova and Gregory R. Lumpkin
Minerals 2020, 10(1), 83; https://doi.org/10.3390/min10010083 - 20 Jan 2020
Cited by 5 | Viewed by 3809
Abstract
We present a new methodology for laser-induced steady-state photoluminescence (PL) spectroscopy of Dy3+ that aims at a direct quantification of the amorphous fraction fa present in zircon (ZrSiO4), which undergoes a transition from a crystalline to a metamict state [...] Read more.
We present a new methodology for laser-induced steady-state photoluminescence (PL) spectroscopy of Dy3+ that aims at a direct quantification of the amorphous fraction fa present in zircon (ZrSiO4), which undergoes a transition from a crystalline to a metamict state due to cumulative self-irradiation damage caused by the radioactive decay of substituted U and Th. Using state-of-the-art confocal spectrometers attached to optical microscopes, measurements may be performed non-destructively on the micrometre length-scale with the option to visualize radiation-damage patterns as revealed by hyperspectral PL maps. Zircon from the Ratnapura district (Sri Lanka, ~520 Ma), was used as reference material to substantiate the applicability of the proposed method. The accumulation of radiation damage in this material was investigated in detail and obtained fa values correlate with calculated α-doses in accordance to the direct impact model reported variously in the literature. The impact of chemically-induced, heterogeneous broadening of Raman and Dy3+ emission spectral bands is discussed on two examples from Mt. Malosa district, Malawi. A mean weighted U-Pb isotope age of 111 ± 1 Ma (pegmatitic-type) and a discordia age of 112 ± 1.6 Ma (hydrothermal-type) as obtained by LA-ICP-MS confirm their close genetic and temporal relationship. Studied zircon examples demonstrate that the amount of radiation damage present may have a substantial effect on the precision of LA-ICP-MS ages, but cannot be considered an exclusive cause for bias of obtained isotope ages. Full article
(This article belongs to the Special Issue Modern Luminescence Spectroscopy of Minerals)
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13 pages, 5499 KiB  
Article
Luminescence of Agrellite Specimen from the Kipawa River Locality
by Maria Czaja and Radosław Lisiecki
Minerals 2019, 9(12), 752; https://doi.org/10.3390/min9120752 - 3 Dec 2019
Cited by 3 | Viewed by 2559
Abstract
Using steady-state luminescence measurements, the luminescence spectra of Ce3+, Pr3+, Nd3+, Sm3+, Eu3+, Dy3+, Er3+ and Yb3+ for the agrellite sample from the Kipawa River region have been measured. [...] Read more.
Using steady-state luminescence measurements, the luminescence spectra of Ce3+, Pr3+, Nd3+, Sm3+, Eu3+, Dy3+, Er3+ and Yb3+ for the agrellite sample from the Kipawa River region have been measured. The emission spectra of Eu3+ and Dy3+ next to those of Sm3+ and Pr3+ have been measured for characteristic excitation conditions. The most efficient luminescence activator in the studied sample was Ce3+. This ion was also a sensitizer of Pr3+, Sm3+, Eu3+, and Dy3+ luminescence. Full article
(This article belongs to the Special Issue Modern Luminescence Spectroscopy of Minerals)
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