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Applied Chemistry in Asia

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Applied Chemistry".

Deadline for manuscript submissions: 31 May 2025 | Viewed by 2196

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Guest Editor
Low-Carbon Technology & Chemical Reaction Engineering Laboratory, College of Chemical Engineering, Sichuan University, Chengdu 610065, China
Interests: nano environmental materials; adsorption; CO2 capture; supercapacitor; supwetting surfaces for oil/water separation
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Special Issue Information

Dear Colleagues,

The future of research in the applied chemistry field holds immense potential for exciting advancements and transformative impacts. This Special Issue is devoted to providing an overview of recent advancements in the field of applied chemistry in Asia, and research topics include, but are not limited to, the following:

  • Sustainable and green chemistry;
  • Advanced materials and applications;
  • Energy storage and conversion;
  • Drug discovery and delivery;
  • Solar energy usage and technology;
  • Molecular engineering and nanotechnology;
  • Low carbon and de-carbon technology;
  • Fine chemistry and chemicals;
  • Applied electrochemistry;
  • Membrane science and separation;
  • Data-driven approaches for applied chemistry.

Original research articles, review articles, and state-of-the-art communications are welcome.

Prof. Dr. Shaojun Yuan
Guest Editor

Manuscript Submission Information

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • applied chemistry
  • new molecules and natural materials
  • solar energy and photo-electro-catalysis
  • analytical methods and techniques
  • electrochemistry and energy
  • biodegradable materials and medicines
  • environment and green chemistry

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Published Papers (3 papers)

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Research

14 pages, 4167 KiB  
Article
Impact of Temperature and Substrate Type on the Optical and Structural Properties of AlN Epilayers: A Cross-Sectional Analysis Using Advanced Characterization Techniques
by Wenwang Wei, Yi Peng, Yuefang Hu, Xiuning Xu and Quanwen Xie
Molecules 2024, 29(22), 5249; https://doi.org/10.3390/molecules29225249 - 6 Nov 2024
Viewed by 378
Abstract
AlN, with its ultra-wide bandgap, is highly attractive for modern applications in deep ultraviolet light-emitting diodes and electronic devices. In this study, the surface and cross-sectional properties of AlN films grown on flat and nano-patterned sapphire substrates are characterized by a variety of [...] Read more.
AlN, with its ultra-wide bandgap, is highly attractive for modern applications in deep ultraviolet light-emitting diodes and electronic devices. In this study, the surface and cross-sectional properties of AlN films grown on flat and nano-patterned sapphire substrates are characterized by a variety of techniques, including photoluminescence spectroscopy, high-resolution X-ray diffraction, X-ray photoelectron spectroscopy, ultraviolet photoelectron spectroscopy, and Raman spectroscopy. The results indicate that different sapphire substrates have minimal impact on the photoluminescence spectrum of the epitaxial films. As the temperature increased, the radius of curvature of the AlN films increased, while the warpage decreased. The AlN films grown on nano-patterned substrates exhibited superior quality with less surface oxidation. During the growth of AlN thin films on different types of substrates, slight shifts in the energy bands occurred due to differences in the introduction of carbon-related impurities and intrinsic defects. The Raman shift and full width at half maximum (FWHM) of the E2(low), A1(TO), E2(high), E1(TO), and E1(LO) phonon modes for the cross-sectional AlN films varied with the depth and temperature. The stress state within the film was precisely determined with specific depths and temperatures. The FWHM of the E2(high) phonon mode suggests that the films grown on nano-patterned substrates exhibited better crystalline quality. Full article
(This article belongs to the Special Issue Applied Chemistry in Asia)
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11 pages, 2129 KiB  
Article
Pt Nanoparticles on Multi-Walled Carbon Nanotubes with High CO Tolerance for Methanol Electrooxidation
by Pingping Yang, Shiming Dong, You Shu and Xuejiao Wei
Molecules 2024, 29(21), 5015; https://doi.org/10.3390/molecules29215015 - 23 Oct 2024
Viewed by 532
Abstract
Anode catalysts are important for direct methanol fuel cells (DMFCs) of energy conversion. Herein, we report a novel strategy by ethylene glycol-based deep eutectic solvents (EG-DESs) for the fabrication of a multi-walled carbon nanotubes (MWCNTs)-supported Pt nanoparticles catalyst (referred to as Pt/CNTs-EG-DES). The [...] Read more.
Anode catalysts are important for direct methanol fuel cells (DMFCs) of energy conversion. Herein, we report a novel strategy by ethylene glycol-based deep eutectic solvents (EG-DESs) for the fabrication of a multi-walled carbon nanotubes (MWCNTs)-supported Pt nanoparticles catalyst (referred to as Pt/CNTs-EG-DES). The Pt/CNTs-EG-DES catalyst provides an increased electrochemically active surface area (ECSA) and shows remarkably improved electrocatalytic performance towards methanol oxidation reaction compared to Pt/CNTs-W (fabricated in water) and commercial Pt/C catalysts. The improved performance is attributed to the generation of more Pt–O bonds which change the electronic states of the Pt atoms and the special node structure that obtains more active sites for a high CO resistance. This study suggests an effective synthesis strategy for Pt-based electrocatalysts with high performance for DMFC applications. Full article
(This article belongs to the Special Issue Applied Chemistry in Asia)
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16 pages, 5576 KiB  
Article
Reaction Thermodynamic and Kinetics for Esterification of 1-Methoxy-2-Propanol and Acetic Acid over Ion-Exchange Resin
by Xinyu Liu, Shu Wang, Mingxia Wang, Lifang Chen and Zhiwen Qi
Molecules 2024, 29(19), 4709; https://doi.org/10.3390/molecules29194709 - 4 Oct 2024
Viewed by 1085
Abstract
The esterification of 1-methoxy-2-propanol (PM) and acetic acid (AA) is an important reaction for the production of 1-methoxy-2-propyl acetate (PMA). Herein, we used the macroporous ion-exchange resin Amberlyst-35 as a catalyst to explore the effects of reaction conditions on the reaction rate and [...] Read more.
The esterification of 1-methoxy-2-propanol (PM) and acetic acid (AA) is an important reaction for the production of 1-methoxy-2-propyl acetate (PMA). Herein, we used the macroporous ion-exchange resin Amberlyst-35 as a catalyst to explore the effects of reaction conditions on the reaction rate and equilibrium yield of PMA. Under the optimized conditions of a reaction temperature of 353 K, using the initial reactant PM/AA with a molar ratio of 1:3, and a catalyst loading of 10 wt%, the PMA equilibrium yield reached 78%, which is the highest equilibrium yield so far. The reaction equilibrium constants and activity coefficients were estimated to obtain reaction thermodynamic properties, indicating the exothermicity of the reaction. Furthermore, pseudo-homogeneous (PH), Eley–Rideal (ER), and Langmuir–Hinshelwood–Hougen–Watson (LHHW) kinetic models were fitted based on experimental reaction kinetic data. The results demonstrate that the LHHW model is the most consistent with experimental data, indicating a surface reaction-controlled process and exhibiting an apparent activation energy of 62.0 ± 0.2 kJ/mol. This work represents a valuable example of calculating reaction thermodynamics and kinetics, which are particularly essential for promising industrial reactor designs. Full article
(This article belongs to the Special Issue Applied Chemistry in Asia)
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